DE694130C - Wetting, emulsifying and plasticizing agents - Google Patents
Wetting, emulsifying and plasticizing agentsInfo
- Publication number
- DE694130C DE694130C DE1935I0052281 DEI0052281A DE694130C DE 694130 C DE694130 C DE 694130C DE 1935I0052281 DE1935I0052281 DE 1935I0052281 DE I0052281 A DEI0052281 A DE I0052281A DE 694130 C DE694130 C DE 694130C
- Authority
- DE
- Germany
- Prior art keywords
- emulsifying
- wetting
- plasticizing agents
- aliphatic hydrocarbon
- biguanides
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 230000001804 emulsifying effect Effects 0.000 title claims description 4
- 238000009736 wetting Methods 0.000 title claims description 4
- 229940123208 Biguanide Drugs 0.000 claims description 6
- 150000004283 biguanides Chemical class 0.000 claims description 3
- 239000004902 Softening Agent Substances 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- 239000003995 emulsifying agent Substances 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- 239000000080 wetting agent Substances 0.000 claims description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 1
- -1 alkyl biguanides Chemical class 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- 229920002955 Art silk Polymers 0.000 description 1
- XNCOSPRUTUOJCJ-UHFFFAOYSA-N Biguanide Chemical compound NC(N)=NC(N)=N XNCOSPRUTUOJCJ-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 241000219422 Urtica Species 0.000 description 1
- 235000009108 Urtica dioica Nutrition 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000009990 desizing Methods 0.000 description 1
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 239000008240 homogeneous mixture Substances 0.000 description 1
- 230000001050 lubricating effect Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 150000003139 primary aliphatic amines Chemical class 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 150000005619 secondary aliphatic amines Chemical class 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
- D06M13/432—Urea, thiourea or derivatives thereof, e.g. biurets; Urea-inclusion compounds; Dicyanamides; Carbodiimides; Guanidines, e.g. dicyandiamides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C279/00—Derivatives of guanidine, i.e. compounds containing the group, the singly-bound nitrogen atoms not being part of nitro or nitroso groups
- C07C279/20—Derivatives of guanidine, i.e. compounds containing the group, the singly-bound nitrogen atoms not being part of nitro or nitroso groups containing any of the groups, X being a hetero atom, Y being any atom, e.g. acylguanidines
- C07C279/24—Y being a hetero atom
- C07C279/26—X and Y being nitrogen atoms, i.e. biguanides
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S516/00—Colloid systems and wetting agents; subcombinations thereof; processes of
- Y10S516/01—Wetting, emulsifying, dispersing, or stabilizing agents
- Y10S516/07—Organic amine, amide, or n-base containing
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/2352—Coating or impregnation functions to soften the feel of or improve the "hand" of the fabric
Description
Netz-, Emulgier- und Weichmachungsmittel Es wurde gefunden, daß Verbindungen der allgemeinen Formel sog. Biguanide, in der Reinen geraden oder verzweigten aliphatischen Kohlenwasserstoffrest mit mehr als 6 Kohlenstoffätomen und R2 Wassferstoff oder einen beliebigen aliphatischen Kohlenwasserstoffrest bedeuten, als Netz-, Emulgier- und Weichmachungsmittel verwendet werden können.Wetting, emulsifying and softening agents It has been found that compounds of the general formula so-called biguanides, in which pure straight or branched aliphatic hydrocarbon radicals with more than 6 carbon atoms and R2 represent hydrogen or any aliphatic hydrocarbon radical, can be used as wetting, emulsifying and plasticizing agents.
Die Herstellung der Verbindungen erfolgt nach an sich bekannten Verfahren, beispielsweise durch Einwirkung von Dicyandiamid auf die Salze von primären oder sekundären aliphatischen Aminen in der Wärme; vgl. hierzu die Abhandlung in Journal für praktische Chemie, Neue Folge, Bd. 84, S. 394 ff, »Zur Kenntnis der Biguanide«. In vielen. Fällen ist es nicht erforderlich, die Verbingen zu isolieren, sondern die Umsetzungsprodukte können direkt im Rohzustand Verwendung finden.The compounds are produced according to processes known per se, for example by the action of dicyandiamide on the salts of primary or secondary aliphatic amines in heat; see the treatise in Journal for practical chemistry, new series, vol. 84, p. 394 ff, "On the knowledge of biguanides". In many. In some cases it is not necessary to isolate the connections, but rather the reaction products can be used directly in their raw state.
Es ist bereits bekannt, Alkylguanidine bzw. Alkylisoharnstoffe als Textilhilfsmittel zu verwenden. Gegenüber diesen Verbindungsklassen besitzen die Alkylbiguanide jedoch den Vorteil der stärkeren Wirksamkeit, so daß der gleiche oder sogar bessere Effekt bereits mit wesentlich geringeren Mengen erzielt wird.It is already known to use alkylguanidines or alkylisoureas as To use textile auxiliaries. Compared to these compound classes, the However, alkyl biguanides have the advantage of greater effectiveness, so the same or even a better effect is already achieved with much smaller amounts.
Beispiele I. Kunstseide im Strang wird mit einer warmen Lösung, die 5 g Octodecylbiguanid im Liter enthält, aviviert. Der Griff der Seide ist dadurch weich und fließend und die Verarbeitung verbessert worden.Examples I. Artificial silk in a strand is made with a warm solution that Contains 5 g octodecyl biguanide per liter. The handle of the silk is thereby soft and flowing and the workmanship has been improved.
z. z Teile Rizinusöl und I Teil Laurylbiguanid werden in einem Rühr- ader Schlagwerk bis zur homogenen Mischung verrührt. Durch Verdünnen mit Wasser erhält man eine beständige, hochdisperse Emulsion, die zum Schmieren, Weichmacher uAgl. Verwendung finden kann.z. z parts of castor oil and I part of lauryl biguanide are The hammer mechanism is stirred until a homogeneous mixture is obtained. By diluting with water you get a stable, highly dispersed emulsion, which is used for lubricating, plasticizer etc. Can be used.
3. Roher, unentschlichteter Baumwollnessel, der von heißem Wasser überhaupt nicht benetzt wird, wird auf Zusatz von 2 g Isöpropyldödecylbiguanid je Liter Wasser sofort vollständig durchgenetzt, wodurch die nachfolgenden Arbeitsgänge, wie Entschlichten, mit wesentlich besserem Erfolg und erhöhter Sicherheit durchgeführt werden können.3. Raw, undiluted cotton nettle, that of hot water at all is not wetted, is on the addition of 2 g of Isöpropyldödecylbiguanid immediately fully wetted per liter of water, which means that the following operations, such as desizing, carried out with significantly better success and increased security can be.
4. Ungeseifte Viscosekunstfaser wird im Strang mit o,25g Stearylbiguanidhydrochlorid im Liter bei 4o°, wie üblich, behandelt und anschließend .getrocknet. Man erhält eine Seide, die in Anbetracht der geringen Menge des Wechmachungsmittels überraschend weichen Griff besitzt und sich ohne weiteres auf den üblichen Textilverarbeitungsmaschinen verarbeiten läßt. Außerdem erhält die Faser durch die beschriebene Behandlung eine Affinität gegenüber Wollfarbstoffen.4. Unsoaped synthetic viscose fiber is stranded with 0.25 g of stearyl biguanide hydrochloride per liter at 40 °, treated as usual, and then dried. You get a silk which is surprising considering the small amount of the make-up agent has a soft grip and is easy to use on the usual textile processing machines can be processed. In addition, the treatment described gives the fiber a Affinity for wool dyes.
Claims (1)
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE1935I0052281 DE694130C (en) | 1935-05-09 | 1935-05-09 | Wetting, emulsifying and plasticizing agents |
| FR805768D FR805768A (en) | 1935-05-09 | 1936-05-01 | Manufacturing process of wetting, emulsifying, softening and auxiliary agents for the textile industry |
| US7819536 US2149709A (en) | 1935-05-09 | 1936-05-06 | Textile assistants |
| GB13052/36A GB475039A (en) | 1935-05-09 | 1936-05-08 | Process for treating textiles |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE1935I0052281 DE694130C (en) | 1935-05-09 | 1935-05-09 | Wetting, emulsifying and plasticizing agents |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE694130C true DE694130C (en) | 1940-07-26 |
Family
ID=89834536
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE1935I0052281 Expired DE694130C (en) | 1935-05-09 | 1935-05-09 | Wetting, emulsifying and plasticizing agents |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US2149709A (en) |
| DE (1) | DE694130C (en) |
| FR (1) | FR805768A (en) |
| GB (1) | GB475039A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE914490C (en) * | 1950-01-13 | 1954-07-05 | Bayer Ag | Process to increase the utility value of textiles |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE740539C (en) * | 1938-05-13 | 1943-10-29 | Ig Farbenindustrie Ag | Treatment of fibers |
| DE741891C (en) * | 1938-09-10 | 1943-11-18 | Zschimmer & Schwarz Chem Fab D | Process for the preparation of water-soluble nitrogen-containing condensation products |
| DE872788C (en) * | 1939-12-21 | 1953-04-09 | Geigy Ag J R | Process for the preparation of water-soluble, higher molecular acyl biguanides |
| US2467371A (en) * | 1944-05-10 | 1949-04-19 | Ici Ltd | Biguanide derivatives |
| US2482710A (en) * | 1945-03-24 | 1949-09-20 | American Cyanamid Co | Process of reacting dicyandiamide and aniline |
| US2455897A (en) * | 1945-10-12 | 1948-12-07 | American Cyanamid Co | 1, 5-diarylbiguanides from aromatic amines and dicyanimide |
| US2455896A (en) * | 1945-10-12 | 1948-12-07 | American Cyanamid Co | 1-aryl, 5-alkyl, biguanides |
| US2622075A (en) * | 1946-12-03 | 1952-12-16 | Sandoz Ltd | Polyamine-cyanamide resins |
| US2577593A (en) * | 1946-12-21 | 1951-12-04 | Du Pont | Stabilizing cellulose yarns |
| US2961377A (en) * | 1957-08-05 | 1960-11-22 | Us Vitamin Pharm Corp | Oral anti-diabetic compositions and methods |
| US3080423A (en) * | 1958-08-20 | 1963-03-05 | Proske Gerhard | Process for the manufacture of the acid-addition salts of n-butylbiguanide |
| US3059029A (en) * | 1959-10-29 | 1962-10-16 | U S Vitamin And Pharmaceutical | Process for alkyl and aralkyl biguanides |
-
1935
- 1935-05-09 DE DE1935I0052281 patent/DE694130C/en not_active Expired
-
1936
- 1936-05-01 FR FR805768D patent/FR805768A/en not_active Expired
- 1936-05-06 US US7819536 patent/US2149709A/en not_active Expired - Lifetime
- 1936-05-08 GB GB13052/36A patent/GB475039A/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE914490C (en) * | 1950-01-13 | 1954-07-05 | Bayer Ag | Process to increase the utility value of textiles |
Also Published As
| Publication number | Publication date |
|---|---|
| FR805768A (en) | 1936-11-28 |
| US2149709A (en) | 1939-03-07 |
| GB475039A (en) | 1937-11-08 |
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