DE69004575D1 - Verbesserung bei der herstellung von chiralen katalysatoren auf basis von ruthenium- und phosphorkomplexen. - Google Patents

Verbesserung bei der herstellung von chiralen katalysatoren auf basis von ruthenium- und phosphorkomplexen.

Info

Publication number
DE69004575D1
DE69004575D1 DE90912758T DE69004575T DE69004575D1 DE 69004575 D1 DE69004575 D1 DE 69004575D1 DE 90912758 T DE90912758 T DE 90912758T DE 69004575 T DE69004575 T DE 69004575T DE 69004575 D1 DE69004575 D1 DE 69004575D1
Authority
DE
Germany
Prior art keywords
ruthenium
improvement
production
catalysts based
chiral catalysts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE90912758T
Other languages
English (en)
Other versions
DE69004575T2 (de
Inventor
Sylvain Juge
Jean-Pierre Genet
Sergio Mallari
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Societe National Elf Aquitaine
Original Assignee
Societe National Elf Aquitaine
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Societe National Elf Aquitaine filed Critical Societe National Elf Aquitaine
Publication of DE69004575D1 publication Critical patent/DE69004575D1/de
Application granted granted Critical
Publication of DE69004575T2 publication Critical patent/DE69004575T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/1875—Phosphinites (R2P(OR), their isomeric phosphine oxides (R3P=O) and RO-substitution derivatives thereof)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C227/00—Preparation of compounds containing amino and carboxyl groups bound to the same carbon skeleton
    • C07C227/30—Preparation of optical isomers
    • C07C227/32—Preparation of optical isomers by stereospecific synthesis
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C231/00—Preparation of carboxylic acid amides
    • C07C231/16—Preparation of optical isomers
    • C07C231/18—Preparation of optical isomers by stereospecific synthesis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
    • B01J2231/643—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of R2C=O or R2C=NR (R= C, H)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
DE69004575T 1989-08-23 1990-08-10 Verbesserung bei der herstellung von chiralen katalysatoren auf basis von ruthenium- und phosphorkomplexen. Expired - Fee Related DE69004575T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR8911159A FR2651152B1 (fr) 1989-08-23 1989-08-23 Perfectionnement a la preparation de catalyseurs chiraux a base de complexes du ruthenium et du phosphore.
PCT/FR1990/000607 WO1991002588A1 (fr) 1989-08-23 1990-08-10 Perfectionnement a la preparation de catalyseurs chiraux a base de complexes du ruthenium et du phosphore

Publications (2)

Publication Number Publication Date
DE69004575D1 true DE69004575D1 (de) 1993-12-16
DE69004575T2 DE69004575T2 (de) 1994-05-19

Family

ID=9384870

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69004575T Expired - Fee Related DE69004575T2 (de) 1989-08-23 1990-08-10 Verbesserung bei der herstellung von chiralen katalysatoren auf basis von ruthenium- und phosphorkomplexen.

Country Status (8)

Country Link
US (1) US5324850A (de)
EP (1) EP0489071B1 (de)
JP (1) JPH05500023A (de)
CA (1) CA2064870A1 (de)
DE (1) DE69004575T2 (de)
ES (1) ES2060195T3 (de)
FR (1) FR2651152B1 (de)
WO (1) WO1991002588A1 (de)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5559262A (en) * 1995-01-31 1996-09-24 E. I. Du Pont De Nemours And Company Process for the preparation of ruthenium complexes and their in situ use as hydrogenation catalysts
ES2136437T3 (es) * 1995-11-22 1999-11-16 Firmenich & Cie Catalizadores de rutenio y su utilizacion en la hidrogenacion asimetrica de ciclopentenonas.
US6156692A (en) * 1996-04-30 2000-12-05 Bp Amoco Corporation Ruthenium-containing catalyst composition for olefin metathesis
US6159890A (en) * 1996-04-30 2000-12-12 Bp Amoco Corporation Ruthenium-containing catalyst system for olefin metathesis
DE69820205T2 (de) * 1997-05-20 2004-09-30 Firmenich S.A. Ruthenium-katalysatoren und ihre verwendung zur asymmetrischen hydrierung von substraten mit schwacher koordination
US6214763B1 (en) 1997-05-20 2001-04-10 Firmenich Sa Ruthenium catalysts and their use in the asymmetric hydrogenation of weakly coordinating substrates
IT1308629B1 (it) * 1999-02-23 2002-01-09 Recordati Chem Pharm Processo per la produzione di paroxetina.
US8975414B2 (en) 2011-10-13 2015-03-10 Elevance Renewable Sciences, Inc. Methods for preparing ruthenium carbene complex precursors and ruthenium carbene complexes
US8779152B2 (en) 2011-10-13 2014-07-15 Elevance Renewable Sciences, Inc. Methods for preparing ruthenium carbene complex precursors and ruthenium carbene complexes

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2396735A1 (fr) * 1977-07-04 1979-02-02 Rhone Poulenc Ind Procede de preparation de citronellal optiquement actif
US4331818A (en) * 1980-03-19 1982-05-25 The Procter & Gamble Company Chiral phospine ligand
EP0218970B1 (de) * 1985-10-18 1992-06-17 F. Hoffmann-La Roche Ag Chirale Rhodium-diphosphinkomplexe für asymmetrische Hydrierungen
JPS63145291A (ja) * 1986-12-09 1988-06-17 Takasago Corp ルテニウム−ホスフイン錯体
DE3773882D1 (de) * 1987-01-21 1991-11-21 Sumitomo Chemical Co Verfahren zur herstellung von optisch aktiven arylessigsaeurederivaten.
JPH0667947B2 (ja) * 1987-09-08 1994-08-31 高砂香料工業株式会社 ルテニウム−ホスフイン錯体
JPH0692427B2 (ja) * 1989-07-11 1994-11-16 高砂香料工業株式会社 ２，２’―ビス（ジシクロヘキシルホスフィノ）―６，６’―ジメチル―１，１’―ビフェニルを配位子とする錯体，およびその錯体を用いた有機カルボン酸とそのエステルの製造方法
US5118825A (en) * 1990-12-10 1992-06-02 Ethyl Corporation Ruthenium phosphine complex

Also Published As

Publication number Publication date
WO1991002588A1 (fr) 1991-03-07
US5324850A (en) 1994-06-28
EP0489071B1 (de) 1993-11-10
FR2651152B1 (fr) 1991-11-29
JPH05500023A (ja) 1993-01-14
FR2651152A1 (fr) 1991-03-01
EP0489071A1 (de) 1992-06-10
ES2060195T3 (es) 1994-11-16
DE69004575T2 (de) 1994-05-19
CA2064870A1 (en) 1991-02-24

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Legal Events

Date Code Title Description
8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee