DE69003570D1 - Hydrierung aromatischer amine unter benuetzung von rhodium auf titandioxyd- oder zirkoniumdioxydtraeger. - Google Patents

Hydrierung aromatischer amine unter benuetzung von rhodium auf titandioxyd- oder zirkoniumdioxydtraeger.

Info

Publication number
DE69003570D1
DE69003570D1 DE90106800T DE69003570T DE69003570D1 DE 69003570 D1 DE69003570 D1 DE 69003570D1 DE 90106800 T DE90106800 T DE 90106800T DE 69003570 T DE69003570 T DE 69003570T DE 69003570 D1 DE69003570 D1 DE 69003570D1
Authority
DE
Germany
Prior art keywords
hydration
rhodium
aromatic amines
carriers
dioxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE90106800T
Other languages
English (en)
Other versions
DE69003570T2 (de
Inventor
Richard John Jenkins
Robert Alexander Treskot
Gamini Ananda Vedage
James Ferguson White
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Air Products and Chemicals Inc
Original Assignee
Air Products and Chemicals Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Air Products and Chemicals Inc filed Critical Air Products and Chemicals Inc
Application granted granted Critical
Publication of DE69003570D1 publication Critical patent/DE69003570D1/de
Publication of DE69003570T2 publication Critical patent/DE69003570T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/464—Rhodium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/68—Preparation of compounds containing amino groups bound to a carbon skeleton from amines, by reactions not involving amino groups, e.g. reduction of unsaturated amines, aromatisation, or substitution of the carbon skeleton
    • C07C209/70—Preparation of compounds containing amino groups bound to a carbon skeleton from amines, by reactions not involving amino groups, e.g. reduction of unsaturated amines, aromatisation, or substitution of the carbon skeleton by reduction of unsaturated amines
    • C07C209/72—Preparation of compounds containing amino groups bound to a carbon skeleton from amines, by reactions not involving amino groups, e.g. reduction of unsaturated amines, aromatisation, or substitution of the carbon skeleton by reduction of unsaturated amines by reduction of six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
DE90106800T 1989-04-11 1990-04-09 Hydrierung aromatischer Amine unter Benützung von Rhodium auf Titandioxyd- oder Zirkoniumdioxydträger. Expired - Fee Related DE69003570T2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US07/336,184 US5026914A (en) 1989-04-11 1989-04-11 Hydrogenation of aromatic amines using rhodium on titania or zirconia support

Publications (2)

Publication Number Publication Date
DE69003570D1 true DE69003570D1 (de) 1993-11-04
DE69003570T2 DE69003570T2 (de) 1994-03-10

Family

ID=23314935

Family Applications (1)

Application Number Title Priority Date Filing Date
DE90106800T Expired - Fee Related DE69003570T2 (de) 1989-04-11 1990-04-09 Hydrierung aromatischer Amine unter Benützung von Rhodium auf Titandioxyd- oder Zirkoniumdioxydträger.

Country Status (5)

Country Link
US (1) US5026914A (de)
EP (1) EP0392435B1 (de)
JP (1) JPH02290834A (de)
CA (1) CA2013812A1 (de)
DE (1) DE69003570T2 (de)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5380946A (en) * 1993-07-30 1995-01-10 Monsanto Company Process for preparing p-nitroaromatic amides and products thereof
DE4328007A1 (de) * 1993-08-20 1995-02-23 Huels Chemische Werke Ag Katalysator zur Herstellung von Bis-Para-aminocyclohexylmethan mit niedrigem Anteil an trans-trans-Isomer durch Hydrierung von Methylendiamin
US5973207A (en) * 1993-09-27 1999-10-26 Air Products And Chemicals, Inc. Hydrogenation of meta-toluenediamine
US5545756A (en) * 1994-09-14 1996-08-13 Air Products And Chemicals, Inc. Hydrogenation of aromatic amines using mixed metal oxide support
KR100717490B1 (ko) * 1999-03-26 2007-05-14 가부시키가이샤 시세이도 티탄실리카 복합체 및 그것을 배합한 화장료
DE10231119A1 (de) 2002-07-10 2004-02-05 Degussa Ag Verfahren zur Selektivitätserhöhung der Hydrierung von 4,4'-Diaminodiphenylmethan zu 4,4'-Diaminodicyclohexylmethan in Gegenwart eines N-Alkyl-4,4'-Diaminodiphenylmethans
US7038088B2 (en) * 2004-05-19 2006-05-02 Air Products And Chemicals, Inc. Hydrogenation of highly contaminated methylenedianiline
DE102004061608A1 (de) * 2004-12-17 2006-07-06 Basf Ag Verfahren zur Herstellung von 1,2-Diamino-3-methylcyclohexan und/oder 1,2-Diamino-4-methylcyclohexan
DE102008002002A1 (de) 2008-05-27 2009-12-03 Evonik Degussa Gmbh Chlor armes mehrstufiges Verfahren zur Herstellung von cycloaliphatischen Diisocyanaten
KR101847161B1 (ko) * 2011-05-04 2018-04-09 에스케이바이오텍 주식회사 광학적으로 순수한 (ｓ)-사이클로헥실아미노산 유도체의 제조 방법
TWI534131B (zh) 2014-11-27 2016-05-21 財團法人工業技術研究院 氫化４，４’－二胺基二苯甲烷的觸媒與方法
JP7059289B2 (ja) * 2017-09-01 2022-04-25 エヌ・イーケムキャット株式会社 核水添反応用触媒
US11964259B2 (en) 2019-12-31 2024-04-23 Industrial Technology Research Institute Catalyst composition for hydrogenating 4,4′-methylenedianiline derivatives and method for preparing 4,4′-methylene bis(cyclohexylamine) derivatives using the same

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2079404A (en) * 1934-09-19 1937-05-04 Du Pont Catalyst preparation
US2606928A (en) * 1947-11-18 1952-08-12 Du Pont Preparation of amino alicyclic compounds
US2511028A (en) * 1947-12-04 1950-06-13 Du Pont 4-[(para-aminophenyl) alkyl] cyclo-hexylamine
US2606924A (en) * 1949-06-09 1952-08-12 Du Pont Bis (4-aminocyclohexyl)-methane
US2606925A (en) * 1949-12-15 1952-08-12 Du Pont Ruthenium catalyzed hydrogenation process for obtaining aminocyclohexyl compounds
US3636108A (en) * 1965-12-23 1972-01-18 Du Pont Catalytic hydrogenation of aromatic nitrogen containing compounds over alkali moderated ruthenium
US3591635A (en) * 1968-09-25 1971-07-06 Upjohn Co Catalytic hydrogenation process for preparing di(4 - aminocyclohexyl) methane
US3644522A (en) * 1969-04-04 1972-02-22 Du Pont Catalytic hydrogenation of nitrogen containing compounds over supported ruthenium catalysts
US3697449A (en) * 1970-12-14 1972-10-10 Du Pont Alkali moderation of supported ruthenium catalysts
US3856862A (en) * 1973-06-25 1974-12-24 Upjohn Co Process for hydrogenation of di(4-aminophenyl)methane with a rhodium catalyst
US4218308A (en) * 1976-05-26 1980-08-19 Toa Nenryo Kogyo Kabushiki Kaisha Hydrogenation catalyst
DE2630562C2 (de) * 1976-07-07 1984-01-12 Bayer Ag, 5090 Leverkusen Verfahren zur katalytischen Hydrierung von Perfluoralkyl-substituierten Anilinen
US4233183A (en) * 1979-02-06 1980-11-11 Hitachi Shipbuilding & Engineering Co., Ltd. Process for producing plate-shaped denitrating catalyst
US4376724A (en) * 1980-04-14 1983-03-15 Showa Denko Kabushiki Kaisha Rhodium catalyst and method for preparing the same
CA1204785A (en) * 1981-06-01 1986-05-20 Gary F. Allen Process for the catalytic hydrogenation of di (4- aminophenyl) methane
US4459372A (en) * 1982-08-25 1984-07-10 Uop Inc. Surface-metallated refractory inorganic oxides, method of their preparation and catalyst supported on the oxides
US4754070A (en) * 1986-01-23 1988-06-28 Air Products And Chemicals, Inc. Hydrogenation of methylenedianiline to produce bis(para-aminocyclohexyl)methane
US4960941A (en) * 1988-03-30 1990-10-02 Air Products And Chemicals, Inc. Hydrogenation of aromatic amines to produce their ring hydrogenated counterparts

Also Published As

Publication number Publication date
EP0392435A1 (de) 1990-10-17
DE69003570T2 (de) 1994-03-10
EP0392435B1 (de) 1993-09-29
US5026914A (en) 1991-06-25
CA2013812A1 (en) 1990-10-11
JPH02290834A (ja) 1990-11-30

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Legal Events

Date Code Title Description
8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee