DE669724C - Process for the production of fire-retardant coatings on wood or other combustible substances of vegetable origin - Google Patents

Process for the production of fire-retardant coatings on wood or other combustible substances of vegetable origin

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Publication number
DE669724C
DE669724C DESCH109446D DESC109446D DE669724C DE 669724 C DE669724 C DE 669724C DE SCH109446 D DESCH109446 D DE SCH109446D DE SC109446 D DESC109446 D DE SC109446D DE 669724 C DE669724 C DE 669724C
Authority
DE
Germany
Prior art keywords
mixture
wood
cement
fire
vegetable origin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DESCH109446D
Other languages
German (de)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GERTRUDE SCHLESS GEB WINKLER
Original Assignee
GERTRUDE SCHLESS GEB WINKLER
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by GERTRUDE SCHLESS GEB WINKLER filed Critical GERTRUDE SCHLESS GEB WINKLER
Priority to DESCH109446D priority Critical patent/DE669724C/en
Application granted granted Critical
Publication of DE669724C publication Critical patent/DE669724C/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5076Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with masses bonded by inorganic cements
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/06Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to wood
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D1/00Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
    • C09D1/06Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances cement
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/70Additives characterised by shape, e.g. fibres, flakes or microspheres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00Processes for applying liquids or other fluent materials
    • B05D1/02Processes for applying liquids or other fluent materials performed by spraying
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2601/00Inorganic fillers
    • B05D2601/20Inorganic fillers used for non-pigmentation effect
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D5/00Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Ceramic Engineering (AREA)
  • Structural Engineering (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Aftertreatments Of Artificial And Natural Stones (AREA)

Description

Verfahren zur Herstellung feuerhemmender Überzüge auf Holz oder anderen brennbaren Stoffen pflanzlichen Ursprungs Seitdem die Gefahr besteht, daß im Krieg-, durch Brandbomben die Dachstühle der Häuser in Brand gesetzt und dadurch ganze Stadtviertel eingeäschert werden, hat man seine besondere Aufmerksamkeit darauf gerichtet, besonders die Holzkonstruktionen in den Dachstühlen gegen Entflammung durch Brandbomhen zu schützen.Process for making fire retardant coatings on wood or others combustible substances of vegetable origin Since then there has been a danger that The roof trusses of the houses were set on fire by incendiary bombs and entire districts as a result being cremated, special attention has been paid to it, especially the wooden structures in the roof trusses against fire caused by fire bombs protection.

Es sind eine große Menge chemischer Mittel zum Imprägnieren des Dachgestühles vorgeschlagen worden, die aber zum Teil ziemlich teuer sind .und, soweit sie billiger sind, den Nachteil aufweisen, daß sie wegen ihrer Hygroskopizität das Holz unerwünscht feucht machen.There are a large amount of chemical agents used to impregnate the roof stalls have been proposed, but some of them are quite expensive. And, to the extent that they are cheaper are, have the disadvantage that they are undesirable because of their hygroscopicity of the wood make it moist.

Die sehr einfache und billige Methode, die Entflammbarkeit durch einen übierzug mit Zement, Mörtel o. dgl. herabzusetzen, befriedigt deshalb nicht, weil :diese Materialien am Holz nicht dauernd haften.The very simple and cheap way to reduce the flammability by a Abierzug with cement, mortar o. The like. Reduce is not satisfactory because : these materials do not permanently adhere to the wood.

Es wurde nun ,gefunden, daß es gelingt, auf dem Holz einen haftenden Überzug mit Zement ,als Hauptbiestandteil zu schaffen, wenn man den Zement mit einem Fasierstoff, im Interesse der Unverbrennbarkeit natürlich in erster Linie mit einem anorganischen Faserstoff, mischt und dieses Gemisch mit einem erheblichen Überdruck auf Holz aufbringt. Die Aufbringung erfolgt mit einem Spritzapparat, aus dem naturgemäß die Elemente zu beseitigen sind, die den Durchtritt des etwas groben Gemisches von Asbest und Zement erschweren. Der Überzug darf das Holz nicht hermetisch gegen die Außenluft abschließen, weil häufig das Holz noch arbeitet, außerdem ein fast hermetischer Abschluß zu Fäulnisierscheinun;gen führen kann, wenn :doch an irgendeiner Stelle Feuchtigkeit eingedrungen ist.It has now been found that it is possible to create an adhesive on the wood Coating with cement, as the main component to create when you use the cement with one Fiber, in the interests of incombustibility, of course, primarily with one inorganic fiber, and this mixture mixes with a considerable excess pressure applies to wood. The application takes place with a spray gun, from which naturally the elements to be eliminated are preventing the passage of the somewhat coarse mixture of Asbestos and cement make it difficult. The coating must not be hermetically sealed against the wood Shut off outside air because the wood is often still working, and an almost hermetic one Closure can lead to signs of putrefaction if: at some point Moisture has penetrated.

Um eine ,gewisse Porosität des überzug!es zu ,gewährleisten, wird deshalbi dem Asbest-Zement-Gemisch noch feinkörniger Quarz beigegeben. Ein solches Gemisch besteht z. B. aus 15 Teilen Asbest, z o Teilen Quarz, 7 5 Teilen Zement und r oo Teilen Wasser.To ensure a certain porosity of the coating, fine-grained quartz is added to the asbestos-cement mixture. Such a mixture consists e.g. B. from 15 parts asbestos, zo parts quartz, 75 parts cement and r oo parts water.

Man hat die Möglichkeit, die Zusammensetzung, des Gemisches: in weiten Grenzen zu variieren, jie nach dem Zweck, der erreicht werden soll.One has the possibility of the composition, of the mixture: to a large extent To vary limits depending on the purpose to be achieved.

Dia es möglich ist, für. die Mischung den billigen kurzfaserigen Asbest zu benutzen, stellen sich die Kosten für die überzielung dies Dach;gestüihls mit der Spritzpistole ziemlich niedrig.Dia it is possible for. a mix cheap short-fiber asbestos to use, the costs for the overarching of this roof; stüihls with the spray gun pretty low.

Natürlich lrönnen nach dem Verfahren der Erfindung auch Bauhölzer, Grubenhölzer, Platten aufs Schilf, Torf usw. von vornherein mit diesem flammenhemmenden Überzug versehen werden, in welchem Falle die sonst grauweiße Mischung mit igeeigneten Farbstoffen versetzt werden kann.Of course, according to the method of the invention, construction timbers, Pit wood, slabs on reeds, peat, etc. with this flame-retardant from the start A coating can be provided, in which case the otherwise gray-white mixture with suitable ones Dyes can be added.

Auch in Bengwerken kann gemäß dem Verfahren der Erfindung .eine überziehuug der Kohlenflöze mit dem Asbest-Zement-Quarz-Gemisch vorgenommen werden, um die Feuersgefahr herabzusetzen. Die Schutzschicht muß etwa eine Dicke von 3 rnm besitzen, um die brennbaren Stoffe pflanzlichen Ursprungs, also etwa einen Dachstuhl oder ein. Kolhlenflö,z, dauernd gegen Entflamm`un,g zu schützen.A coating can also be used in benches according to the method of the invention the coal seams are made with the asbestos-cement-quartz mixture to reduce the risk of fire to belittle. The protective layer must have a thickness of about 3 mm, around the combustible substances of vegetable origin, such as a roof structure or a. To protect the Kolhlenflö, z, against inflammation, g at all times.

Da das Material der Schutzschicht b"' Anstreichen -oder Anspritzen leicht von einer geneigten Oberfläche abfließt, so daß die Schicht an der einen Stelle zu dünm, an der anderen überflüssig dickt wird, wird die Schutzschicht in mindestens zwei Schichte von :einer Gesamtschichtdieke von etwa 3 mm bei einem Betriebsdruck von 3 bis ¢ Atm. mit Spritzapparaten aufgespritzt.Since the material of the protective layer b "'painting or gating easily drains from an inclined surface, leaving the layer on one Where there is too thin a place where it is unnecessarily thick, the protective layer becomes in at least two layers of: a total layer thickness of about 3 mm at an operating pressure from 3 to ¢ Atm. sprayed on with spray guns.

Weist nun die Schutzschicht stets die gleiche Farbe auf, so ist @es schnver zu kontrollieren, ob, sie überall gleichmäßig ge-,deckt hat. Deswegen wird gemäß .der Erfindung ein jeweils verschieden gefärbtes Ge- misch ,aufgespritzt, so daß genau geprüft . werden kann, ob die neue Schicht die zuvor aufgetragene überall bedeckt. Zum Bleispiel wird die für die erste Schicht benutzte Mischung schwarz gefärbt wind die zweite rötlich, während man der dritten den natürlichen hellgrauen Ton der Mischung lassen kann. Verschwindet unter der ersten Schicht völlig der Dachstuhl: und die schwarze Schicht wieder unter der rötlichen bzw. die rötliche unter der grauweißen, so hat mann die Sicherheit, daß die Schutzschicht in der notwendigen Stärke :aufgetragen ist. -Ältere Dachkonstruktionen sowie auch Kohlenschichten sind meist mit Staub, b@zw. Sand überdeckt, die :die Aufspritzum;g eines gut haftenden, Faserstoff -enthaltenden Überzuges erschweren. In diesem Falle ist es not-1v:endig, zunächst :eine Schicht aus einem Gemisch von Zement und Quarz allein, aufzubringen. Beispielsweise mischt man 75 Teile Portlandzement mit 25 Teilen Quarzmehl und i oo Teilen Wasser zu einer Zementmilch, die man aufspritzt oder aufpinselt und mit einer groben Bürste einreibt, damit der Staub mit der Zementmilch abgebunden wird.If the protective layer always has the same color, it must be checked quickly whether it has covered evenly everywhere. Therefore, according to .the invention, a respectively different colored overall is mixed, sprayed, so that closely examined. whether the new layer covers the previously applied everywhere. For example, the mixture used for the first layer is colored black and the second is reddish, while the third can be left the natural light gray tone of the mixture. If the roof structure disappears completely under the first layer: and the black layer again under the reddish or the reddish under the greyish-white, you can be sure that the protective layer has been applied in the necessary thickness. - Older roof structures as well as layers of coal are mostly covered with dust, b @ zw. Sand covers that: make it difficult to spray a well-adhering, fiber-containing coating. In this case it is necessary, first of all: to apply a layer of a mixture of cement and quartz alone. For example, 75 parts of Portland cement are mixed with 25 parts of quartz flour and 100 parts of water to form a cement milk, which is sprayed or brushed on and rubbed in with a coarse brush so that the dust is bound with the cement milk.

Man hat bereits. einmal vorgeschlagen, dekorativ wirkende überzüge, die u. a. auch feuerhemmend- wirkten, auf brennbaren Stoffen herzustellen durch Aufspritzen eines Gemisches, das hauptsächlich größere Teilchen des glitzernden Schiefersteins Algolith enthielt und daneben die verschiedensten Füllstoffe, wie Kieselgur, Kalkstein, B,imsistein, auch Asbest und die mannigfaltigsten Bindemittel, wie Leim, Kautschuk, Asphalt, Gips, 4ärunter auch Zement.One already has. once suggested, decorative coatings, which i.a. also fire-retardant, produced on flammable materials Spraying a mixture that consists mainly of larger particles of the glitter Slate stone contained algolith and next to it various fillers, such as Kieselguhr, limestone, B, imsistein, also asbestos and the most diverse binders, such as glue, rubber, asphalt, gypsum, including cement.

Weder hat man den Asbest in größeren Mengen verwandt, noch empfohlen, ihn gerade mit Zement ;als Bindemittel zusammen. anzu:-wenden. Auch weicht dieser ;ältere Vorschlag insofern von dem Verfahren vorliegender Erfindung ab, als Bindemittel und Füllstoff getrennt auf die Unterlagen aufgebracht werden sollen. Es kann dann niemals, besonders auf Holz, die feste Haftung erreicht werden, die bei dem Verfahren vorliegender Erfindung erstrebt und für die zu herreichende Wirkung notwendig ist.Asbestos has not been used in large quantities, nor has it been recommended him just with cement; as a binding agent together. to: -use. Also this gives way ; Older proposal insofar from the method of the present invention as a binder and filler are to be applied separately to the substrates. It can then never, especially on wood, the firm adhesion that can be achieved in the process strives for the present invention and is necessary for the effect to be achieved.

Claims (3)

PATENTANSPRÜCHE; i. Verfahren zur Herstellung feuerhemmender üb:erziige auf Holz oder anderen brennbaren Stoffen pflanzlichen Ursprungs unter Benutzung zementhaltiger Mischungen, dadurch gekennzeichnet, :daß ein spritzbares Gemisch aus Zement - als Hauptbestandteil -, Asbest, Kieselsaure und Wasser in mindestens zwei Schichten von einer Gesamtschichtdicke von etwa 3 mim ,auf die zu schützende Oberfläche mit Hilfe von Spritzapparaten bei einem Betriebsdruck von 3 bis 4. Atm. aufgespritzt wird. PATENT CLAIMS; i. Method of making fire retardant compounds on wood or other combustible substances of vegetable origin in use cementitious mixtures, characterized in that: that a sprayable mixture from cement - as the main component -, asbestos, silica and water in at least two layers with a total thickness of about 3 mm on the one to be protected Surface with the help of spray guns at an operating pressure of 3 to 4 atm. is sprayed on. 2. Verfahren Dach Anspruch i, dadurch gekennzeichnet, daß das Gemisch in drei jeweils verschieden gefärbten Lagen von etwa je i mm Dicke aufgespritzt wird. 2. The method roof claim i, characterized in that the Mixture sprayed on in three differently colored layers, each about 1 mm thick will. 3. Verfahren nach Anspruch i und 2, dadurch gekennzeichnet, daß die zu überziehenden Stoffe, falls sie mit -einer Staubschicht bedeckt sind, zunächst mit einem wäßrigen Gemisch von Zement und Quarz alleineingerieben werden, bevor das Aufspritzen des Asbest-Zement-Gemisaheserfolgt.3. The method according to claim i and 2, characterized in that the to be coated Substances, if they are covered with a layer of dust, first with an aqueous one Mixture of cement and quartz alone must be rubbed in before spraying the Asbestos-cement mixture is done.
DESCH109446D 1936-03-11 1936-03-11 Process for the production of fire-retardant coatings on wood or other combustible substances of vegetable origin Expired DE669724C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DESCH109446D DE669724C (en) 1936-03-11 1936-03-11 Process for the production of fire-retardant coatings on wood or other combustible substances of vegetable origin

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DESCH109446D DE669724C (en) 1936-03-11 1936-03-11 Process for the production of fire-retardant coatings on wood or other combustible substances of vegetable origin

Publications (1)

Publication Number Publication Date
DE669724C true DE669724C (en) 1939-01-02

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Application Number Title Priority Date Filing Date
DESCH109446D Expired DE669724C (en) 1936-03-11 1936-03-11 Process for the production of fire-retardant coatings on wood or other combustible substances of vegetable origin

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DE (1) DE669724C (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2945300A1 (en) * 1979-11-09 1981-05-21 Chemische Fabrik Kalk GmbH, 5000 Köln Coating for wood impregnated with hygroscopic fire retardant salt - consists of sodium or potassium water glass soln. or cement

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2945300A1 (en) * 1979-11-09 1981-05-21 Chemische Fabrik Kalk GmbH, 5000 Köln Coating for wood impregnated with hygroscopic fire retardant salt - consists of sodium or potassium water glass soln. or cement

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