DE65316C - Process for the preparation of α-oxyuvitic acid - Google Patents

Process for the preparation of α-oxyuvitic acid

Info

Publication number
DE65316C
DE65316C DENDAT65316D DE65316DA DE65316C DE 65316 C DE65316 C DE 65316C DE NDAT65316 D DENDAT65316 D DE NDAT65316D DE 65316D A DE65316D A DE 65316DA DE 65316 C DE65316 C DE 65316C
Authority
DE
Germany
Prior art keywords
acid
oxyuvitic
cresol
temperatures
cooh
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DENDAT65316D
Other languages
German (de)
Original Assignee
Dr. F. von heyden nachfolger in Radebeul bei Dresden
Publication of DE65316C publication Critical patent/DE65316C/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C65/00Compounds having carboxyl groups bound to carbon atoms of six—membered aromatic rings and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
    • C07C65/01Compounds having carboxyl groups bound to carbon atoms of six—membered aromatic rings and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups containing hydroxy or O-metal groups
    • C07C65/03Compounds having carboxyl groups bound to carbon atoms of six—membered aromatic rings and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups containing hydroxy or O-metal groups monocyclic and having all hydroxy or O-metal groups bound to the ring
    • C07C65/05Compounds having carboxyl groups bound to carbon atoms of six—membered aromatic rings and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups containing hydroxy or O-metal groups monocyclic and having all hydroxy or O-metal groups bound to the ring o-Hydroxy carboxylic acids

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Description

Sättigt man das erhitzte Kresolsalz mit Kohlensäure statt im Druckgefäfs bei gewöhnlichem Druck, so erhält man eine geringere Ausbeute an Oxyuvitinsäure.If you saturate the heated cresol salt with carbonic acid instead of the ordinary in a pressure vessel Pressure, a lower yield of oxyuvitic acid is obtained.

Die Säure wird zur Herstellung von Farbstoffen benutzt.The acid is used to make dyes.

Pa teντ-Anspruch:Pa teντ claim:

Verfahren zur Darstellung von α - Oxyuvitinsäure durch Einwirkung von Kohlensäure auf Kresol-Alkali- oder Erdalkalisalze bei Temperaturen über i6d° C.Process for the preparation of α - oxyuvitic acid by the action of carbonic acid Cresol alkali or alkaline earth salts at temperatures above i6d ° C.

Claims (1)

KAISERLICHESIMPERIAL PATENTAMT.PATENT OFFICE. ■rV -·ι' .· y:'' ■> ■ rV - · ι '. · Y : ''■> ■ ' ''' " ' f f ■ ''''"'ff ■■'■■ ' Die α - Oxyuvitinsäure wurde bisher bei Laboratoriumsversuchen aus Amidouvitinsa'ure mittelst salpetriger Säure und aus Sulfouvitinsäure durch die Kalischmelze erhalten. Die Darstellung dieser Säure in grofsem Mafsstabe für technische Zwecke gelingt durch Einwirkung von Kohlensäure auf ο - Kresol-Alkali oder -Erdalkali bei Temperaturen über 1600C. Während sich bei Temperaturen unter 1600C. bekanntlich o-KresolmonocarbonsäureThe α-oxyuvitic acid has hitherto been obtained in laboratory experiments from amidouvitic acid by means of nitrous acid and from sulfouvitic acid by smelting potash. The representation of this acid in grofsem Mafsstabe for technical purposes can be achieved by the action of carbon dioxide on ο - cresol or alkali -Erdalkali at temperatures over 160 0 C. While at temperatures below 160 0 C. known o-Kresolmonocarbonsäure (Ο (2) (3) :(Ο (2) (3): C6H^-CH3-OH-COOHC 6 H ^ -CH 3 -OH-COOH bildet, entsteht über i6o° C. ein Gemisch dieser Säure mit α - Oxyuvitinsäureforms, a mixture of these arises above 160 ° C Acid with α-oxyuvitic acid C6H2- CH3-OH- COOH- C&OH,C 6 H 2 - CH 3 -OH- COOH- C&OH, bei Temperaturen über 2100 C. dagegen nur die letztere.at temperatures above 210 ° C., on the other hand, only the latter. Der Procefs wird vortheilhaft folgendermafsen ausgeführt: In einem Druckkessel wird zu trockenem, auf ca. 220 ° C. erhitzten Kresolkalium trockene Kohlensäure bis zur Sättigung eingeprefst. Man läfst hierauf erkalten und löst das Reactionsproduct in Wasser. · Salzsäure fällt aus der Lösung a - Oxyuvitinsäure vom Schmelzpunkt ca. 290° C. Von etwa noch beigemengter Kresotinsäure reinigt man sie durch partielles Fällen der Lösung eines Salzes der Säure. Bei diesem Procefs kann das ο - Kresolkalium durch ein anderes Alkalioder Erdalkalisalz des o-Kresols ersetzt werden.The process is advantageously carried out as follows: In a pressure vessel, dry carbonic acid, heated to about 220 ° C., is injected into cresol potassium until saturation. It is then allowed to cool and the reaction product is dissolved in water. · Hydrochloric acid falls from the solution a - oxyuvitic acid with a melting point of approx. 290 ° C. Any cresotinic acid that may still be added is purified by partially precipitating the solution of a salt of the acid. In this process, the ο -cresol potassium can be replaced by another alkali or alkaline earth salt of the o-cresol.
DENDAT65316D Process for the preparation of α-oxyuvitic acid Expired - Lifetime DE65316C (en)

Publications (1)

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DE65316C true DE65316C (en)

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ID=339120

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DENDAT65316D Expired - Lifetime DE65316C (en) Process for the preparation of α-oxyuvitic acid

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DE (1) DE65316C (en)

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