DE638302C - Molded detergents and cleaners - Google Patents
Molded detergents and cleanersInfo
- Publication number
- DE638302C DE638302C DE1930638302D DE638302DD DE638302C DE 638302 C DE638302 C DE 638302C DE 1930638302 D DE1930638302 D DE 1930638302D DE 638302D D DE638302D D DE 638302DD DE 638302 C DE638302 C DE 638302C
- Authority
- DE
- Germany
- Prior art keywords
- sulfuric acid
- salts
- substances
- parts
- alcohols
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
- C11D10/042—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on anionic surface-active compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/126—Acylisethionates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S516/00—Colloid systems and wetting agents; subcombinations thereof; processes of
- Y10S516/01—Wetting, emulsifying, dispersing, or stabilizing agents
- Y10S516/03—Organic sulfoxy compound containing
- Y10S516/04—Protein or carboxylic compound containing
Description
81.186.30-81.186.30-
Es ist bekannt, daß die Schwefelsäureester höher molekularer Alkohole in Wasser leicht löslich sind und stark netzende und schäumende Eigenschaften besitzen. Sie sind daher als Netz-, Reinigungs-, Schaum- upd Dispergiermittel für die Textil- und Lederindustrie vorgeschlagen worden.It is known that the sulfuric acid esters of higher molecular weight alcohols easily in water are soluble and have strong wetting and foaming properties. You are therefore as a wetting agent, cleaning agent, foam and dispersant has been proposed for the textile and leather industries.
Es wurde nun gefunden, daß sich die Möglichkeit der Anwendung dieser Stoffe nicht auf die Bereitung derartiger industrieller Behandlungsbäder in Form eines Badzusatzes als Lösung, Pulver oder Paste beschränkt. Gemäß der Erfindung gelangt man nämlich zu völlig neuartigen Wasch- und Reinigungsmitteln, welche beispielsweise den bekannten aus Fetten hergestellten Seifen im praktischenIt has now been found that the possibility the application of these substances to the preparation of such industrial treatment baths in the form of a bath additive as a solution, powder or paste. Indeed, according to the invention one arrives at to completely new detergents and cleaning agents, such as the well-known Soaps made from fats in practical terms
, Gebrauch nicht nur ebenbürtig, sondern sogar in mancher Hinsicht wesentlich überlegen sind, wenn man den wasserlöslichen Salzen, Use not only on par, but even significantly superior in some respects are when you consider the water soluble salts
ao der sauren Schwefelsäureester aus aliphatischen Alkoholen mit mehr als acht Kohlenstoffatomen im Molekül oder auch den Salzen der sauren Schwefelsäureester aus cycloaliphatischen Alkoholen oder Olefinen oder olefinischen Alkoholen mit mehr als acht Kohlenstoffatomen im Molekül die äußere Form von Stücken, Riegeln u.dgl. verleiht. Die genannten Salze können dabei für sich oder im Gemisch mit geringeren Mengen anderer Stoffe zur Anwendung gelangen. Ein besonderer Vorteil der Erfindung liegt darin, daß die erwähnten bestim'mten Substanzen nun auch dem Verbrauch im Haushalt zugänglich gemacht und damit einem neuen großen Verbraucherkreis zugeführt werden können. Die vorzüglichen Eigenschaften der erwähnten Estersalze, insbesondere ihre Unempfindlichkeit gegen die Härtebildner des Wassers, ihr Wasch- und Schaumvermögen sogar in Seewasser und ihre sonstigen vorzügliehen Eigenschaften kommen danach der Allgemeinheit in viel höherem Maße als bisher zugute.ao the acidic sulfuric acid esters from aliphatic alcohols with more than eight carbon atoms in the molecule or the salts of the acidic sulfuric acid esters from cycloaliphatic alcohols or olefins or olefinic alcohols with more than eight carbon atoms in the molecule gives the outer shape of pieces, bars and the like. The salts mentioned can be used alone or in a mixture with smaller amounts of other substances. A particular advantage of the invention lies in the fact that the specified substances mentioned can now also be made available for consumption in the household and can thus be supplied to a new, large group of consumers. The excellent properties of the ester salts mentioned, in particular their insensitivity to the hardness builders in water, their washing and foaming power even in sea water and their other excellent properties, are of much greater benefit to the general public than before.
Für die Zwecke der Erfindung lassen sich t. B. sehr vorteilhaft die sauren Schwefelsäureester von Oktyl-, Lauryl-, Cetyl-, Oktodecyl-, Oleylajkohol usw., die man beispielsweise durch Behandlung von Fettsäuren oder ihren Anhydriden oder Estern, wie pflanzlichen oder tierischen ölen und Fetten, mit Wasserstoff in Gegenwart von Katalysatoren oder durch Oxydation von Paraffinkohlenwasserstoffen erhalten hat, verwenden. Die Überführung der Alkohole in die sauren Schwefelsäureester kann je nach den gewünschten Endprodukten unter sehr verschiedenen Arbeitsbedingungen, z. B. unter Anwendung verschiedenartiger Sülfonierungsmittel, wie Schwefelsäure, Oleum, Chlorsulfonsäure u. dgl., gegebenenfalls in Gegenwart von Lösungsmitteln, ausgeführt werden. Evtl. nicht umgesetzte Anteile, z. B. Fettsäuren, Neutralfette, Paraffine u. dgl., können im Fertigprodukt enthalten sein. Als Salze der genannten sauren Schwefelsäure-For the purposes of the invention, t. B. very advantageous the acidic sulfuric acid esters of octyl, lauryl, cetyl, octodecyl, oleyl alcohol, etc., which can be obtained, for example, by treating fatty acids or their anhydrides or esters, such as vegetable or animal oils and fats, with hydrogen in the presence of Use catalysts or the oxidation of paraffinic hydrocarbons. The conversion of the alcohols into the acidic sulfuric acid esters can, depending on the desired end products, under very different working conditions, e.g. B. using various sulphonating agents such as sulfuric acid, oleum, chlorosulphonic acid and the like, optionally in the presence of solvents. Possibly unconverted portions, e.g. B. fatty acids, neutral fats, paraffins and the like, can be contained in the finished product. As salts of the acidic sulfuric acid
63S30263S302
ester kommen insbesondere die Natrium-, Kalium- und Ammoniumsalze sowie die Salze aus organischen Aminen usw., wie Methylamin,. Diäthanolamin, Pyridin u.dgl., in Betracht;':·, Die auf die genannte Weise erhaltlichen&i-n. die Form von Stücken, Riegeln, Stäben usvv* gebrachten Wasch- und Reinigungsmittel sind; für Toilettezwecke, z. B. Gesichts- oder Badeseifen, ferner für die Haushaltswäsche vorzüglieh, geeignet; sie zeigen in vielen Fällen neutrale Reaktion und greifen die Haut nicht oder nur wenig an. Sie können ihrerseits wieder -gestreckt sein mit den bekannten Seifen aus fettsauren Alkalien oder Seifenersatzprodukten in nicht überwiegender Menge. Ferner können sie Zusätze von Salzen aller Art oder von Wachsen, Fetten u. dgl. erhalten und mit Schutzkolloiden, z. B. Eiweißstoffen, Pflanzengummi, Stärke usw., verschnitten und auch gefärbt werden. Für viele Zwecke, besonders zur Lösung -von Fett, Harz usw., ist ein Zusatz von organischen Lösungsmitteln zweckmäßig. Zur Erzielung besonderer kosmetischer oder pharmazeutischer Wirkungen ag können die bekannten, für diese Zwecke bewährten Stoffe zugesetzt, werden, z. B. Glycerin, Geruchsstoffe, Teer, Schwefel, Nikotin usw.The sodium, potassium and ammonium salts as well as the salts come from esters organic amines, etc., such as methylamine. Diethanolamine, pyridine, etc., into consideration; ': ·, The & i-n obtainable in this way. the shape of pieces, bars, rods, etc. * brought washing and cleaning agents are; for toilet purposes, e.g. B. facial or bath soaps, also excellent and suitable for household linen; they show neutral in many cases Reaction and do not or only slightly attack the skin. For their part, they can be stretched with the familiar ones Soaps made from fatty acid alkalis or soap substitutes in not predominant quantities. They can also contain all kinds of salts or waxes, fats and the like and with protective colloids, e.g. B. proteins, vegetable gum, starch, etc., cut and also be colored. For many purposes, especially for dissolving fat, resin, etc., is an addition of organic solvents is advisable. To achieve special cosmetic or pharmaceutical effects ag can be the known, proven for these purposes Substances are added, e.g. B. glycerine, odorous substances, tar, sulfur, nicotine etc.
Man hat bereits vorgeschlagen, gewisse Sulfonierungsprodukte anderer Art üblichen Natronseifen in geringer Menge zuzusetzen und die so erhaltenen Produkte in Stücke zu pressen. Im vorliegenden Fall handelt es' sich, indessen nicht darum, mit geringfügigen Zusätzen versehene Seifen in geformte Stücke zu bringen, sondern darum, die Salze der sauren Schwefelsäureester aus aliphatischen Alkoholen usw. für sich allein in die den Verbrauchern von Seifen gewohnte Form1 zu bringen, sondern darum, die Salze der sauren Schwefelsäureester aus aliphatischen Alkoholen usw.. für sich allein in die den Verbrauchern von Seifen gewohnte Form zu bringen, wobei auch Gemische benutzt werden können, die neben den in überwiegender Menge vorliegenden Salzen der erwähnten Schwefelsäureester noch andere Stoffe enthalten.It has already been proposed to add small amounts of certain sulfonation products of other types to conventional soda soaps and to press the products thus obtained into pieces. In the present case, however, it is not a question of bringing soaps with insignificant additives into shaped pieces, but rather of bringing the salts of the acid sulfuric acid esters from aliphatic alcohols etc. into the form 1 that is familiar to consumers of soaps , but rather to bring the salts of acidic sulfuric acid esters from aliphatic alcohols, etc .. into the form familiar to the consumers of soaps, whereby mixtures can be used which, in addition to the predominantly present salts of the mentioned sulfuric acid esters, also contain other substances contain.
80 Gewichtsteile des Natriumsalzes des säuren Schwefelsäureesters des Cetylalkohols werden mit io Gewichtsteilen Stearinseife und 10 Gewichtsteilen Glycerin innig verarbeitet und in Formen gepreßt. Das Produkt eignet sich vorzüglich als Badeseife.80 parts by weight of the sodium salt of the acidic sulfuric acid ester of cetyl alcohol are intimately processed with 10 parts by weight of stearin soap and 10 parts by weight of glycerin and pressed into molds. The product is ideal as a bath soap.
Beispiel 2 ίο Teile kaltgerührte Kokosseife werdenExample 2 ίο parts are cold-stirred coconut soap
mit 25 Teilen einer etwa 80- bis 8 5 0/0 igen •sPaste des Natriumsalzes des Schwefelsäurefeters aus Dodecylen innig vermischt. Diewith 25 parts of an approximately 80 to 8 5 0/0 igen • Paste of the sodium salt of sulfuric acid from dodecylene intimately mixed. the
Mischung wird zu Riegeln geformt, und man H erhält so eine Wasch- und Badeseife, die sich i&^uich vorzügliche Schaumkraft und gutes * ileinigungsvermögen auszeichnet. Es empfehlt sich, der Mischung V2 ms τ % einer geeigneten alkalibeständigen Riechstoffkomposition zuzusetzen.The mixture is shaped into bars, and a washing and bathing soap is obtained, which is characterized by excellent foaming power and good cleaning power. It is advisable to add V2 ms τ % of a suitable alkali-resistant fragrance composition to the mixture.
55 Teile des neutralen Ammoniumsalzes des sauren Schwefelsäureesters aus Stearylalkohol und 25 Teile Ammoniumoleat werden mit 15 Teilen Wasser und 5 Teilen Cyclohexanol verknetet; man erhält ein Produkt, das wie Kernseife geformt werden kann und dessen Waschwirkung vorzüglich ist.55 parts of the neutral ammonium salt of the acid sulfuric acid ester from stearyl alcohol and 25 parts of ammonium oleate are mixed with 15 parts of water and 5 parts of cyclohexanol kneaded; a product is obtained which can be shaped like curd soap and whose washing effect is excellent.
Ein durch katalytisch© Reduktion von Kokosfettsäure erhaltlich.es iFettalkoholgemisch wird durch Behandlung- mit konzentrierter oder rauchender Schwefelsäure verestert und sodann mit Natronlauge neutralisiert. 1000 Teile der so erhaltenen Natriumsalze werden zusammen mit 0,2 Teilen-Titandioxyd, OjOi Teil einer wäßrigen Lösung von RhodaminBextra (vgl. Schultz, Farbstofftabellen 1931, Nr. 864) und 2 Teilen Citronellöl in der b.ei Seifen üblichen Weise piliert. Darauf wird das Gemisch in der Strangpresse gepreßt und sodann in der Schlagpendelpresse geformt. Man erhält schön gefärbte Toilettenseifenstücke, die auch in hartem Wasser oder Seewasser vorzügliche Schaumkraft zeigen.A mixture of fatty alcohols obtained through the catalytic reduction of coconut fatty acid is esterified by treatment with concentrated or fuming sulfuric acid and then neutralized with sodium hydroxide solution. 1000 parts of the sodium salts thus obtained are together with 0.2 parts of titanium dioxide, OjOi part of an aqueous solution of RhodaminBextra (see Schultz, color tables 1931, No. 864) and 2 parts of citronella oil piled in the usual way for soaps. The mixture is then put in the extruder pressed and then shaped in the hammer pendulum press. You get nicely colored toilet soap bars, which show excellent foaming power even in hard water or sea water.
Man kann dem Ausgangsmaterial auch noch Wachse,· Fette, Zucker, Glycerin oder andere Stoffe beimischen.You can also add waxes, fats, sugar, glycerine or add other substances.
Claims (1)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE638302T | 1930-04-08 |
Publications (1)
Publication Number | Publication Date |
---|---|
DE638302C true DE638302C (en) | 1936-11-13 |
Family
ID=34812936
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE1930638302D Expired DE638302C (en) | 1930-04-08 | 1930-04-08 | Molded detergents and cleaners |
Country Status (5)
Country | Link |
---|---|
US (1) | US1906484A (en) |
BE (1) | BE378069A (en) |
DE (1) | DE638302C (en) |
FR (1) | FR712913A (en) |
NL (1) | NL55394C (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE895815C (en) * | 1940-01-06 | 1953-11-05 | Basf Ag | laundry detergent |
DE1111761B (en) * | 1959-09-25 | 1961-07-27 | Shell Int Research | Toilet soap |
Families Citing this family (26)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2739130A (en) * | 1956-03-20 | Cleaning composition | ||
US2781320A (en) * | 1957-02-12 | All purpose | ||
US2603606A (en) * | 1952-07-15 | Alkyl sulfates | ||
US3057805A (en) * | 1962-10-09 | Synthetic detergent cake and process | ||
DE895289C (en) * | 1934-07-03 | 1953-11-02 | Bataafsche Petroleum | Process for preparing salts of acidic alkyl esters |
DE750286C (en) * | 1935-05-02 | 1945-01-03 | Kalle & Co Ag | Soap-free detergents |
US2508578A (en) * | 1944-05-05 | 1950-05-23 | Colgate Palmolive Peet Co | Combined soap and synthetic detergent bar |
BE482509A (en) * | 1947-05-16 | |||
US2494580A (en) * | 1947-05-24 | 1950-01-17 | Procter & Gamble | Detergent composition |
DE973122C (en) * | 1949-03-11 | 1959-12-03 | Hoechst Ag | Process for making shaped detergents |
US2749315A (en) * | 1951-04-28 | 1956-06-05 | Colgate Palmolive Co | Toilet detergent bar and process of preparing same |
US2865811A (en) * | 1952-05-02 | 1958-12-23 | Irval Cosmetics Inc | Hair straightener containing a kerating reducing agent, anionic wetting agent and water-soluble soap and method of using same |
US2991253A (en) * | 1952-08-20 | 1961-07-04 | Armour & Co | Solid soap composition |
US2781321A (en) * | 1953-05-12 | 1957-02-12 | Gen Aniline & Film Corp | All purpose detergent bar |
US3070547A (en) * | 1953-07-13 | 1962-12-25 | Procter & Gamble | Soap-synthetic bar |
US2894912A (en) * | 1954-09-21 | 1959-07-14 | Lever Brothers Ltd | Isethionate detergent bar |
US2988511A (en) * | 1955-03-31 | 1961-06-13 | Mills Victor | Nonsmearing detergent bar |
NL236056A (en) * | 1956-08-15 | |||
US3043778A (en) * | 1958-02-20 | 1962-07-10 | Lever Brothers Ltd | Soap bar compositions |
BE577250A (en) * | 1958-04-14 | |||
NL264887A (en) * | 1960-05-20 | |||
BE611781A (en) * | 1960-12-23 | |||
GB1314604A (en) * | 1970-08-18 | 1973-04-26 | Unilever Ltd | Soap-synthetic detergent tablets |
US4476055A (en) * | 1982-07-06 | 1984-10-09 | Westvaco Corporation | C21-Dicarboxylic acid isethionates as primary anionic surfactants |
US4514335A (en) * | 1982-07-06 | 1985-04-30 | Westvaco Corporation | C21 -Dicarboxylic acid isethionates as primary anionic surfactants |
US4571309A (en) * | 1983-07-20 | 1986-02-18 | Westvaco Corporation | C22 -Cycloaliphatic tricarboxylic acid derived isethionate esters and method of preparation |
-
0
- NL NL55394D patent/NL55394C/xx active
- BE BE378069D patent/BE378069A/xx unknown
-
1930
- 1930-04-08 DE DE1930638302D patent/DE638302C/en not_active Expired
-
1931
- 1931-03-09 FR FR712913D patent/FR712913A/en not_active Expired
- 1931-03-26 US US525603A patent/US1906484A/en not_active Expired - Lifetime
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE895815C (en) * | 1940-01-06 | 1953-11-05 | Basf Ag | laundry detergent |
DE1111761B (en) * | 1959-09-25 | 1961-07-27 | Shell Int Research | Toilet soap |
Also Published As
Publication number | Publication date |
---|---|
NL55394C (en) | |
US1906484A (en) | 1933-05-02 |
FR712913A (en) | 1931-10-15 |
BE378069A (en) |
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