DE60230271D1 - Integriertes verfahren zur synthese von alkoholen und ethern aus alkanen - Google Patents

Integriertes verfahren zur synthese von alkoholen und ethern aus alkanen

Info

Publication number
DE60230271D1
DE60230271D1 DE60230271T DE60230271T DE60230271D1 DE 60230271 D1 DE60230271 D1 DE 60230271D1 DE 60230271 T DE60230271 T DE 60230271T DE 60230271 T DE60230271 T DE 60230271T DE 60230271 D1 DE60230271 D1 DE 60230271D1
Authority
DE
Germany
Prior art keywords
bromide
metal
reactor
converter
ethers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE60230271T
Other languages
English (en)
Inventor
Xiao Ping Zhou
Ivan Marc Lorkovic
Galen D Stucky
Peter C Ford
Jeffrey H Sherman
Philip Grosso
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
University of California
GRT Inc
Original Assignee
University of California
GRT Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by University of California, GRT Inc filed Critical University of California
Priority claimed from PCT/US2002/018775 external-priority patent/WO2003000635A1/en
Application granted granted Critical
Publication of DE60230271D1 publication Critical patent/DE60230271D1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/09—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis
    • C07C29/12—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of esters of mineral acids
    • C07C29/124—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of esters of mineral acids of halides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/10—Preparation of halogenated hydrocarbons by replacement by halogens of hydrogen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/24—Synthesis of the oxirane ring by splitting off HAL—Y from compounds containing the radical HAL—C—C—OY
    • C07D301/26—Y being hydrogen
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
DE60230271T 2001-06-20 2002-06-13 Integriertes verfahren zur synthese von alkoholen und ethern aus alkanen Expired - Lifetime DE60230271D1 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US09/886,078 US6472572B1 (en) 2001-06-20 2001-06-20 Integrated process for synthesizing alcohols and ethers from alkanes
US09/951,570 US6462243B1 (en) 2001-06-20 2001-09-11 Integrated process for synthesizing alcohols and ethers from alkanes
PCT/US2002/018775 WO2003000635A1 (en) 2001-06-20 2002-06-13 Integrated process for synthesizing alcohols and ethers from alkanes

Publications (1)

Publication Number Publication Date
DE60230271D1 true DE60230271D1 (de) 2009-01-22

Family

ID=25388329

Family Applications (1)

Application Number Title Priority Date Filing Date
DE60230271T Expired - Lifetime DE60230271D1 (de) 2001-06-20 2002-06-13 Integriertes verfahren zur synthese von alkoholen und ethern aus alkanen

Country Status (8)

Country Link
US (4) US6472572B1 (de)
EP (2) EP1435349B1 (de)
AT (2) ATE417031T1 (de)
CY (2) CY1109035T1 (de)
DE (1) DE60230271D1 (de)
DK (2) DK1404636T3 (de)
ES (2) ES2371944T3 (de)
PT (2) PT1404636E (de)

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US20080275284A1 (en) 2004-04-16 2008-11-06 Marathon Oil Company Process for converting gaseous alkanes to liquid hydrocarbons
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US7674941B2 (en) 2004-04-16 2010-03-09 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons
US7244867B2 (en) * 2004-04-16 2007-07-17 Marathon Oil Company Process for converting gaseous alkanes to liquid hydrocarbons
US8173851B2 (en) * 2004-04-16 2012-05-08 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons
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WO2005110953A1 (en) * 2004-04-30 2005-11-24 Shell Internationale Research Maatschappij B.V. Derivatives of alcohols and olefins
US20060138948A1 (en) * 2004-12-27 2006-06-29 Quantum Paper, Inc. Addressable and printable emissive display
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US20090270655A1 (en) * 2005-03-28 2009-10-29 Howard Lam-Ho Fong Conversion of Alkylhalides Into Alcohol Alkoxylates
US20060229228A1 (en) * 2005-04-11 2006-10-12 Zachary John Anthony Komon Method of making alkoxylates
US20060229475A1 (en) * 2005-04-11 2006-10-12 Weiss Michael J Synthesis of hydroxylated hydrocarbons
AU2012200173B2 (en) * 2006-02-03 2013-10-24 Grt, Inc. Continuous process for converting natural gas to liquid hydrocarbons
BRPI0707490A2 (pt) 2006-02-03 2011-05-03 Grt Inc separação de gases leves de halogênios
EP2457887A1 (de) 2006-02-03 2012-05-30 GRT, Inc. Kontinuierliches Verfahren zur Umwandlung von Erdgas in flüssige Kohlenwasserstoffe
US20090163749A1 (en) * 2006-03-20 2009-06-25 Microvast Technologies, Ltd. Conversion of methane into c3˜c13 hydrocarbons
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CN101284232B (zh) * 2007-04-13 2013-01-16 微宏动力系统（湖州）有限公司 甲烷溴氧化制溴甲烷及其转化制碳氢化合物的催化剂
CN101284756A (zh) * 2007-04-13 2008-10-15 微宏科技（湖州）有限公司 碳氢化合物中HBr的净化方法
KR20100027141A (ko) 2007-05-24 2010-03-10 지알티, 인코포레이티드 가역적으로 할로겐화수소를 흡수 및 방출할 수 있는 존 반응기
US8282810B2 (en) 2008-06-13 2012-10-09 Marathon Gtf Technology, Ltd. Bromine-based method and system for converting gaseous alkanes to liquid hydrocarbons using electrolysis for bromine recovery
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US7812201B2 (en) 2008-10-01 2010-10-12 Targa Resources, Inc. Process and catalyst for converting alkanes
US20110152546A1 (en) 2009-12-17 2011-06-23 Sumitomo Chemical Company, Limited Process for producing olefin oxide
US8575403B2 (en) 2010-05-07 2013-11-05 Celanese International Corporation Hydrolysis of ethyl acetate in ethanol separation process
US8198495B2 (en) 2010-03-02 2012-06-12 Marathon Gtf Technology, Ltd. Processes and systems for the staged synthesis of alkyl bromides
US8367884B2 (en) 2010-03-02 2013-02-05 Marathon Gtf Technology, Ltd. Processes and systems for the staged synthesis of alkyl bromides
US9024083B2 (en) 2010-07-09 2015-05-05 Celanese International Corporation Process for the production of ethanol from an acetic acid feed and a recycled ethyl acetate feed
US8846988B2 (en) 2010-07-09 2014-09-30 Celanese International Corporation Liquid esterification for the production of alcohols
US8859827B2 (en) 2011-11-18 2014-10-14 Celanese International Corporation Esterifying acetic acid to produce ester feed for hydrogenolysis
US8710279B2 (en) 2010-07-09 2014-04-29 Celanese International Corporation Hydrogenolysis of ethyl acetate in alcohol separation processes
WO2012148509A1 (en) 2011-04-26 2012-11-01 Celanese International Corporation Process for producing ethanol using a stacked bed reactor
US9272970B2 (en) 2010-07-09 2016-03-01 Celanese International Corporation Hydrogenolysis of ethyl acetate in alcohol separation processes
US8664454B2 (en) 2010-07-09 2014-03-04 Celanese International Corporation Process for production of ethanol using a mixed feed using copper containing catalyst
US8815050B2 (en) 2011-03-22 2014-08-26 Marathon Gtf Technology, Ltd. Processes and systems for drying liquid bromine
US8592635B2 (en) 2011-04-26 2013-11-26 Celanese International Corporation Integrated ethanol production by extracting halides from acetic acid
US9073816B2 (en) 2011-04-26 2015-07-07 Celanese International Corporation Reducing ethyl acetate concentration in recycle streams for ethanol production processes
US8907141B2 (en) 2011-04-26 2014-12-09 Celanese International Corporation Process to recover alcohol with secondary reactors for esterification of acid
US9000233B2 (en) 2011-04-26 2015-04-07 Celanese International Corporation Process to recover alcohol with secondary reactors for hydrolysis of acetal
US8754268B2 (en) 2011-04-26 2014-06-17 Celanese International Corporation Process for removing water from alcohol mixtures
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US8895786B2 (en) 2011-08-03 2014-11-25 Celanese International Corporation Processes for increasing alcohol production
US8802908B2 (en) 2011-10-21 2014-08-12 Marathon Gtf Technology, Ltd. Processes and systems for separate, parallel methane and higher alkanes' bromination
US8853468B2 (en) 2011-11-18 2014-10-07 Celanese International Corporation Vapor esterification method to produce ester feed for hydrogenolysis
US8748673B2 (en) 2011-11-18 2014-06-10 Celanese International Corporation Process of recovery of ethanol from hydrogenolysis process
US8829249B2 (en) 2011-11-18 2014-09-09 Celanese International Corporation Integrated esterification and hydrogenolysis process for producing ethanol
US8829251B2 (en) 2011-11-18 2014-09-09 Celanese International Corporation Liquid esterification method to produce ester feed for hydrogenolysis
US9024089B2 (en) 2011-11-18 2015-05-05 Celanese International Corporation Esterification process using extractive separation to produce feed for hydrogenolysis
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US8927790B2 (en) 2011-12-15 2015-01-06 Celanese International Corporation Multiple vapor feeds for hydrogenation process to produce alcohol
US9193641B2 (en) 2011-12-16 2015-11-24 Gtc Technology Us, Llc Processes and systems for conversion of alkyl bromides to higher molecular weight hydrocarbons in circulating catalyst reactor-regenerator systems
US8975451B2 (en) 2013-03-15 2015-03-10 Celanese International Corporation Single phase ester feed for hydrogenolysis
WO2015091871A1 (en) * 2013-12-20 2015-06-25 Solvay Sa Process for manufacturing an epoxide
CN105709751B (zh) * 2014-12-04 2018-02-09 中国石油化工股份有限公司 一种溴甲烷制二甲醚催化剂及其制备方法和应用
US11236031B2 (en) 2020-02-12 2022-02-01 Saudi Arabian Oil Company Integrated process for the production of isononanol and gasoline and diesel blending components
US11542447B2 (en) 2021-03-09 2023-01-03 Saudi Arabian Oil Company Integrated process for the production of isononanol and stable / lubricating gasoline and diesel blending components

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Also Published As

Publication number Publication date
CY1112382T1 (el) 2015-12-09
US6465696B1 (en) 2002-10-15
EP1435349B1 (de) 2011-08-10
DK1435349T3 (da) 2011-11-14
US6403840B1 (en) 2002-06-11
US6472572B1 (en) 2002-10-29
US6462243B1 (en) 2002-10-08
EP1435349A2 (de) 2004-07-07
ES2321489T3 (es) 2009-06-08
ATE417031T1 (de) 2008-12-15
ATE519724T1 (de) 2011-08-15
EP1435349A3 (de) 2004-08-04
EP2060552A2 (de) 2009-05-20
EP2060552A3 (de) 2010-05-26
PT1435349E (pt) 2011-11-21
ES2371944T3 (es) 2012-01-11
DK1404636T3 (da) 2009-04-14
CY1109035T1 (el) 2014-07-02
PT1404636E (pt) 2009-03-18

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Legal Events

Date Code Title Description
8327 Change in the person/name/address of the patent owner

Owner name: GRT, INC., SANTA BARBARA, CALIF., US

Owner name: THE REGENTS OF THE UNIVERSITY OF CALIFORNIA, O, US

8364 No opposition during term of opposition