DE60217156D1 - Verfahren zur züchtung einer mcraly-beschichtung und ein mit mcraly-beschichteter gegenstand - Google Patents
Verfahren zur züchtung einer mcraly-beschichtung und ein mit mcraly-beschichteter gegenstandInfo
- Publication number
- DE60217156D1 DE60217156D1 DE60217156T DE60217156T DE60217156D1 DE 60217156 D1 DE60217156 D1 DE 60217156D1 DE 60217156 T DE60217156 T DE 60217156T DE 60217156 T DE60217156 T DE 60217156T DE 60217156 D1 DE60217156 D1 DE 60217156D1
- Authority
- DE
- Germany
- Prior art keywords
- mcraly
- breating
- coated object
- coating
- mcraly coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C26/00—Coating not provided for in groups C23C2/00 - C23C24/00
- C23C26/02—Coating not provided for in groups C23C2/00 - C23C24/00 applying molten material to the substrate
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C24/00—Coating starting from inorganic powder
- C23C24/08—Coating starting from inorganic powder by application of heat or pressure and heat
- C23C24/10—Coating starting from inorganic powder by application of heat or pressure and heat with intermediate formation of a liquid phase in the layer
-
- C—CHEMISTRY; METALLURGY
- C30—CRYSTAL GROWTH
- C30B—SINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
- C30B13/00—Single-crystal growth by zone-melting; Refining by zone-melting
-
- C—CHEMISTRY; METALLURGY
- C30—CRYSTAL GROWTH
- C30B—SINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
- C30B29/00—Single crystals or homogeneous polycrystalline material with defined structure characterised by the material or by their shape
- C30B29/10—Inorganic compounds or compositions
- C30B29/52—Alloys
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/922—Static electricity metal bleed-off metallic stock
- Y10S428/923—Physical dimension
- Y10S428/924—Composite
- Y10S428/926—Thickness of individual layer specified
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/922—Static electricity metal bleed-off metallic stock
- Y10S428/9335—Product by special process
- Y10S428/939—Molten or fused coating
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12771—Transition metal-base component
- Y10T428/12861—Group VIII or IB metal-base component
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12771—Transition metal-base component
- Y10T428/12861—Group VIII or IB metal-base component
- Y10T428/12937—Co- or Ni-base component next to Fe-base component
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12771—Transition metal-base component
- Y10T428/12861—Group VIII or IB metal-base component
- Y10T428/12944—Ni-base component
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Mechanical Engineering (AREA)
- Inorganic Chemistry (AREA)
- Turbine Rotor Nozzle Sealing (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP01122818A EP1295969A1 (de) | 2001-09-22 | 2001-09-22 | Verfahren zur Züchtung einer MCrAlY-Beschichtung und damit beschichteter Gegenstand |
EP01122818 | 2001-09-22 | ||
PCT/IB2002/003595 WO2003035946A1 (en) | 2001-09-22 | 2002-09-06 | Method of growing a mcraly-coating and an article coated with the mcraly-coating |
Publications (2)
Publication Number | Publication Date |
---|---|
DE60217156D1 true DE60217156D1 (de) | 2007-02-08 |
DE60217156T2 DE60217156T2 (de) | 2007-10-04 |
Family
ID=8178707
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE60217156T Expired - Lifetime DE60217156T2 (de) | 2001-09-22 | 2002-09-06 | Verfahren zur züchtung einer mcraly-beschichtung und ein mit mcraly-beschichteter gegenstand |
Country Status (5)
Country | Link |
---|---|
US (1) | US7014923B2 (de) |
EP (2) | EP1295969A1 (de) |
JP (1) | JP4205586B2 (de) |
DE (1) | DE60217156T2 (de) |
WO (1) | WO2003035946A1 (de) |
Families Citing this family (49)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1426458B1 (de) * | 2002-12-06 | 2008-03-12 | ALSTOM Technology Ltd | Verfahren zur örtlichen Abscheidung einer MCrAlY - Beschichtung |
US7316850B2 (en) * | 2004-03-02 | 2008-01-08 | Honeywell International Inc. | Modified MCrAlY coatings on turbine blade tips with improved durability |
EP1674662A1 (de) * | 2004-12-23 | 2006-06-28 | Siemens Aktiengesellschaft | Elektrolyt für die Abscheidung einer Legierung und Verfahren zur elektrolytischen Abscheidung |
FR2914319B1 (fr) * | 2007-03-30 | 2009-06-26 | Snecma Sa | Barriere thermique deposee directement sur superalliages monocristallins. |
EP2294235A1 (de) * | 2008-05-20 | 2011-03-16 | Siemens Aktiengesellschaft | Zweilagige mcralx-schicht mit unterschiedlichen kobalt- und nickelgehalten |
EP2206805A1 (de) * | 2009-01-08 | 2010-07-14 | Siemens Aktiengesellschaft | MCrAIX-Schicht mit unterschiedlichen Chrom- und Aluminiumgehalten |
EP2317078B2 (de) | 2009-11-02 | 2021-09-01 | Ansaldo Energia IP UK Limited | Abrasive einkristalline Turbinenschaufel |
EP2330349B1 (de) | 2009-12-01 | 2018-10-24 | Siemens Aktiengesellschaft | Pilotverbrenner für einen Gasturbinenmotor, Verbrenner und Gasturbinenmotor |
CN101824652B (zh) * | 2010-05-06 | 2012-05-30 | 中国科学院宁波材料技术与工程研究所 | 铝镍钴磁体的制备方法 |
US9249491B2 (en) | 2010-11-10 | 2016-02-02 | General Electric Company | Components with re-entrant shaped cooling channels and methods of manufacture |
US8387245B2 (en) | 2010-11-10 | 2013-03-05 | General Electric Company | Components with re-entrant shaped cooling channels and methods of manufacture |
US8673397B2 (en) | 2010-11-10 | 2014-03-18 | General Electric Company | Methods of fabricating and coating a component |
US8727727B2 (en) | 2010-12-10 | 2014-05-20 | General Electric Company | Components with cooling channels and methods of manufacture |
US8753071B2 (en) | 2010-12-22 | 2014-06-17 | General Electric Company | Cooling channel systems for high-temperature components covered by coatings, and related processes |
US8533949B2 (en) | 2011-02-14 | 2013-09-17 | General Electric Company | Methods of manufacture for components with cooling channels |
US8528208B2 (en) | 2011-04-11 | 2013-09-10 | General Electric Company | Methods of fabricating a coated component using multiple types of fillers |
US8601691B2 (en) | 2011-04-27 | 2013-12-10 | General Electric Company | Component and methods of fabricating a coated component using multiple types of fillers |
US9216491B2 (en) | 2011-06-24 | 2015-12-22 | General Electric Company | Components with cooling channels and methods of manufacture |
US9327384B2 (en) | 2011-06-24 | 2016-05-03 | General Electric Company | Components with cooling channels and methods of manufacture |
US9206696B2 (en) | 2011-08-16 | 2015-12-08 | General Electric Company | Components with cooling channels and methods of manufacture |
US9249672B2 (en) | 2011-09-23 | 2016-02-02 | General Electric Company | Components with cooling channels and methods of manufacture |
US20130086784A1 (en) | 2011-10-06 | 2013-04-11 | General Electric Company | Repair methods for cooled components |
US20130101761A1 (en) * | 2011-10-21 | 2013-04-25 | General Electric Company | Components with laser cladding and methods of manufacture |
CN102352508B (zh) * | 2011-11-09 | 2012-10-31 | 唐山瑞兆激光技术机械修复有限公司 | Trt机组零部件激光熔覆用铁基合金粉末 |
KR20140102203A (ko) * | 2011-11-10 | 2014-08-21 | 알스톰 테크놀러지 리미티드 | 고온 열 차단벽 코팅부 |
US9249670B2 (en) | 2011-12-15 | 2016-02-02 | General Electric Company | Components with microchannel cooling |
US9435208B2 (en) | 2012-04-17 | 2016-09-06 | General Electric Company | Components with microchannel cooling |
US9243503B2 (en) | 2012-05-23 | 2016-01-26 | General Electric Company | Components with microchannel cooled platforms and fillets and methods of manufacture |
DE102013109116A1 (de) | 2012-08-27 | 2014-03-27 | General Electric Company (N.D.Ges.D. Staates New York) | Bauteil mit Kühlkanälen und Verfahren zur Herstellung |
US8974859B2 (en) | 2012-09-26 | 2015-03-10 | General Electric Company | Micro-channel coating deposition system and method for using the same |
CN102877060A (zh) * | 2012-09-26 | 2013-01-16 | 孙晓冰 | 镁合金表面激光熔覆耐磨耐腐蚀涂层用amr合金粉 |
US9242294B2 (en) | 2012-09-27 | 2016-01-26 | General Electric Company | Methods of forming cooling channels using backstrike protection |
US9238265B2 (en) | 2012-09-27 | 2016-01-19 | General Electric Company | Backstrike protection during machining of cooling features |
US9562436B2 (en) | 2012-10-30 | 2017-02-07 | General Electric Company | Components with micro cooled patterned coating layer and methods of manufacture |
US9200521B2 (en) | 2012-10-30 | 2015-12-01 | General Electric Company | Components with micro cooled coating layer and methods of manufacture |
US9003657B2 (en) | 2012-12-18 | 2015-04-14 | General Electric Company | Components with porous metal cooling and methods of manufacture |
CN104451655B (zh) * | 2013-09-13 | 2018-02-16 | 中国科学院金属研究所 | 抗高温材料用表面合金涂层复合材料、涂层及其制备方法 |
US9278462B2 (en) | 2013-11-20 | 2016-03-08 | General Electric Company | Backstrike protection during machining of cooling features |
US9476306B2 (en) | 2013-11-26 | 2016-10-25 | General Electric Company | Components with multi-layered cooling features and methods of manufacture |
EP2886225B1 (de) * | 2013-12-23 | 2017-06-07 | Ansaldo Energia IP UK Limited | Ausscheidungsgehärteten Gamma-Prime-Superlegierung auf Nickelbasis zur Verwendung in Verfahren zur Herstellung pulverbasierter Additive |
CN104862693B (zh) * | 2015-04-24 | 2018-04-06 | 燕山大学 | 一种拉丝机塔轮的激光熔覆修复方法 |
CN106702371A (zh) * | 2015-07-15 | 2017-05-24 | 昆山鑫昌泰模具科技有限公司 | 提高h13热锻模寿命的激光熔覆技术 |
KR101753094B1 (ko) * | 2015-08-25 | 2017-07-04 | 한국기계연구원 | 절삭 가공성, 내산화성 및 심미성이 우수한 Co-Cr계 치과용 합금 |
CN112105755B (zh) * | 2018-04-24 | 2023-06-06 | 欧瑞康表面处理解决方案股份公司普费菲孔 | 包含MCrAl-X涂覆层的涂层 |
CN110747377B (zh) * | 2019-11-15 | 2020-11-10 | 清华大学 | 一种高铬镍基高温合金及其制备方法与应用 |
CN110835756A (zh) * | 2019-11-18 | 2020-02-25 | 南昌大学 | 一种单晶高温合金基体上外延生长MCrAlY单晶涂层的制备方法 |
CN113564587A (zh) * | 2021-08-18 | 2021-10-29 | 沈阳大陆激光先进制造技术创新有限公司 | 一种激光复合制造炉卷辊抗高温氧化、防压入结瘤功能层合金材料及工艺方法 |
DE102021213329A1 (de) * | 2021-11-26 | 2023-06-01 | Siemens Energy Global GmbH & Co. KG | Kobaltbasislegierung mit hohem Anteil an Aluminium, Pulver, Verfahren und Bauteile |
CN114645241B (zh) * | 2022-03-04 | 2023-04-18 | 北京航空航天大学 | 一种具有复合结构热障涂层的制备方法 |
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US3528861A (en) * | 1968-05-23 | 1970-09-15 | United Aircraft Corp | Method for coating the superalloys |
US3754903A (en) * | 1970-09-15 | 1973-08-28 | United Aircraft Corp | High temperature oxidation resistant coating alloy |
US3676085A (en) * | 1971-02-18 | 1972-07-11 | United Aircraft Corp | Cobalt base coating for the superalloys |
US4152223A (en) * | 1977-07-13 | 1979-05-01 | United Technologies Corporation | Plasma sprayed MCrAlY coating and coating method |
US4313760A (en) * | 1979-05-29 | 1982-02-02 | Howmet Turbine Components Corporation | Superalloy coating composition |
US4346137A (en) * | 1979-12-19 | 1982-08-24 | United Technologies Corporation | High temperature fatigue oxidation resistant coating on superalloy substrate |
USRE32121E (en) * | 1981-08-05 | 1986-04-22 | United Technologies Corporation | Overlay coatings for superalloys |
US4585481A (en) * | 1981-08-05 | 1986-04-29 | United Technologies Corporation | Overlays coating for superalloys |
US4419416A (en) * | 1981-08-05 | 1983-12-06 | United Technologies Corporation | Overlay coatings for superalloys |
US4743514A (en) * | 1983-06-29 | 1988-05-10 | Allied-Signal Inc. | Oxidation resistant protective coating system for gas turbine components, and process for preparation of coated components |
US4643782A (en) * | 1984-03-19 | 1987-02-17 | Cannon Muskegon Corporation | Single crystal alloy technology |
DE3740478C1 (de) * | 1987-11-28 | 1989-01-19 | Asea Brown Boveri | Hochtemperatur-Schutzschicht |
US4758480A (en) * | 1987-12-22 | 1988-07-19 | United Technologies Corporation | Substrate tailored coatings |
US5232789A (en) * | 1989-03-09 | 1993-08-03 | Mtu Motoren- Und Turbinen-Union Muenchen Gmbh | Structural component with a protective coating having a nickel or cobalt basis and method for making such a coating |
US5312584A (en) * | 1992-02-18 | 1994-05-17 | General Motors Corporation | Moldless/coreless single crystal castings of nickel-aluminide |
US5304039A (en) * | 1992-07-30 | 1994-04-19 | General Electric Company | Method for providing an extension on an end of an article and extended article |
EP0786017B1 (de) * | 1994-10-14 | 1999-03-24 | Siemens Aktiengesellschaft | Schutzschicht zum schutz eines bauteils gegen korrosion, oxidation und thermische überbeanspruchung sowie verfahren zu ihrer herstellung |
US5900170A (en) | 1995-05-01 | 1999-05-04 | United Technologies Corporation | Containerless method of producing crack free metallic articles by energy beam deposition with reduced power density |
DE19624056A1 (de) * | 1996-06-17 | 1997-12-18 | Abb Research Ltd | Nickel-Basis-Superlegierung |
DE19624055A1 (de) * | 1996-06-17 | 1997-12-18 | Abb Research Ltd | Nickel-Basis-Superlegierung |
EP0861927A1 (de) * | 1997-02-24 | 1998-09-02 | Sulzer Innotec Ag | Verfahren zum Herstellen von einkristallinen Strukturen |
DE69821945T2 (de) * | 1998-11-10 | 2005-07-14 | Alstom Technology Ltd | Gasturbineteil |
-
2001
- 2001-09-22 EP EP01122818A patent/EP1295969A1/de not_active Withdrawn
-
2002
- 2002-09-06 JP JP2003538439A patent/JP4205586B2/ja not_active Expired - Fee Related
- 2002-09-06 EP EP02762676A patent/EP1442163B1/de not_active Expired - Lifetime
- 2002-09-06 WO PCT/IB2002/003595 patent/WO2003035946A1/en active IP Right Grant
- 2002-09-06 US US10/490,337 patent/US7014923B2/en not_active Expired - Fee Related
- 2002-09-06 DE DE60217156T patent/DE60217156T2/de not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
EP1295969A1 (de) | 2003-03-26 |
US20040244676A1 (en) | 2004-12-09 |
EP1442163A1 (de) | 2004-08-04 |
JP4205586B2 (ja) | 2009-01-07 |
US7014923B2 (en) | 2006-03-21 |
WO2003035946A1 (en) | 2003-05-01 |
EP1442163B1 (de) | 2006-12-27 |
DE60217156T2 (de) | 2007-10-04 |
JP2005506458A (ja) | 2005-03-03 |
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