DE60020915D1 - Polymere Kompositmembran und Verfahren zu ihrer Herstellung - Google Patents

Polymere Kompositmembran und Verfahren zu ihrer Herstellung

Info

Publication number
DE60020915D1
DE60020915D1 DE60020915T DE60020915T DE60020915D1 DE 60020915 D1 DE60020915 D1 DE 60020915D1 DE 60020915 T DE60020915 T DE 60020915T DE 60020915 T DE60020915 T DE 60020915T DE 60020915 D1 DE60020915 D1 DE 60020915D1
Authority
DE
Germany
Prior art keywords
preparation
composite membrane
polymer composite
polymer
membrane
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE60020915T
Other languages
English (en)
Other versions
DE60020915T2 (de
Inventor
Hiroshi Akita
Masao Ichikawa
Masaru Iguchi
Hiroyuki Oyanagi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Honda Motor Co Ltd
Original Assignee
Honda Motor Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Honda Motor Co Ltd filed Critical Honda Motor Co Ltd
Publication of DE60020915D1 publication Critical patent/DE60020915D1/de
Application granted granted Critical
Publication of DE60020915T2 publication Critical patent/DE60020915T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D67/00Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0002Organic membrane manufacture
    • B01D67/0006Organic membrane manufacture by chemical reactions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D67/00Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0002Organic membrane manufacture
    • B01D67/0009Organic membrane manufacture by phase separation, sol-gel transition, evaporation or solvent quenching
    • B01D67/0011Casting solutions therefor
    • B01D67/00111Polymer pretreatment in the casting solutions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D67/00Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0081After-treatment of organic or inorganic membranes
    • B01D67/0093Chemical modification
    • B01D67/00931Chemical modification by introduction of specific groups after membrane formation, e.g. by grafting
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D69/00Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/12Composite membranes; Ultra-thin membranes
    • B01D69/125In situ manufacturing by polymerisation, polycondensation, cross-linking or chemical reaction
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D71/00Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06Organic material
    • B01D71/38Polyalkenylalcohols; Polyalkenylesters; Polyalkenylethers; Polyalkenylaldehydes; Polyalkenylketones; Polyalkenylacetals; Polyalkenylketals
    • B01D71/381Polyvinylalcohol
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment
    • C08F8/34Introducing sulfur atoms or sulfur-containing groups
    • C08F8/36Sulfonation; Sulfation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20Manufacture of shaped structures of ion-exchange resins
    • C08J5/22Films, membranes or diaphragms
    • C08J5/2206Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
    • C08J5/2275Heterogeneous membranes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/86Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90Selection of catalytic material
    • H01M4/92Metals of platinum group
    • H01M4/925Metals of platinum group supported on carriers, e.g. powder carriers
    • H01M4/926Metals of platinum group supported on carriers, e.g. powder carriers on carbon or graphite
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/1016Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018Polymeric electrolyte materials
    • H01M8/102Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1023Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having only carbon, e.g. polyarylenes, polystyrenes or polybutadiene-styrenes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/1016Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018Polymeric electrolyte materials
    • H01M8/1039Polymeric electrolyte materials halogenated, e.g. sulfonated polyvinylidene fluorides
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/1016Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018Polymeric electrolyte materials
    • H01M8/1041Polymer electrolyte composites, mixtures or blends
    • H01M8/1053Polymer electrolyte composites, mixtures or blends consisting of layers of polymers with at least one layer being ionically conductive
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/1016Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018Polymeric electrolyte materials
    • H01M8/1069Polymeric electrolyte materials characterised by the manufacturing processes
    • H01M8/1081Polymeric electrolyte materials characterised by the manufacturing processes starting from solutions, dispersions or slurries exclusively of polymers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/1016Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018Polymeric electrolyte materials
    • H01M8/1069Polymeric electrolyte materials characterised by the manufacturing processes
    • H01M8/1086After-treatment of the membrane other than by polymerisation
    • H01M8/1088Chemical modification, e.g. sulfonation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2323/00Details relating to membrane preparation
    • B01D2323/30Cross-linking
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2325/00Details relating to properties of membranes
    • B01D2325/26Electrical properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2325/00Details relating to properties of membranes
    • B01D2325/36Hydrophilic membranes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2810/00Chemical modification of a polymer
    • C08F2810/20Chemical modification of a polymer leading to a crosslinking, either explicitly or inherently
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2329/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Derivatives of such polymer
    • C08J2329/02Homopolymers or copolymers of unsaturated alcohols
    • C08J2329/04Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2381/00Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen, or carbon only; Polysulfones; Derivatives of such polymers
    • C08J2381/06Polysulfones; Polyethersulfones
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00Electrolytes
    • H01M2300/0017Non-aqueous electrolytes
    • H01M2300/0065Solid electrolytes
    • H01M2300/0082Organic polymers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/86Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90Selection of catalytic material
    • H01M4/92Metals of platinum group
    • H01M4/921Alloys or mixtures with metallic elements
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/1004Fuel cells with solid electrolytes characterised by membrane-electrode assemblies [MEA]
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/1009Fuel cells with solid electrolytes with one of the reactants being liquid, solid or liquid-charged
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Manufacturing & Machinery (AREA)
  • General Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Energy (AREA)
  • Sustainable Development (AREA)
  • Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Materials Engineering (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Transplantation (AREA)
  • Composite Materials (AREA)
  • Fuel Cell (AREA)
DE60020915T 1999-09-20 2000-09-19 Polymere Kompositmembran und Verfahren zu ihrer Herstellung Expired - Lifetime DE60020915T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP26511599 1999-09-20
JP26511599 1999-09-20

Publications (2)

Publication Number Publication Date
DE60020915D1 true DE60020915D1 (de) 2005-07-28
DE60020915T2 DE60020915T2 (de) 2006-05-11

Family

ID=17412832

Family Applications (1)

Application Number Title Priority Date Filing Date
DE60020915T Expired - Lifetime DE60020915T2 (de) 1999-09-20 2000-09-19 Polymere Kompositmembran und Verfahren zu ihrer Herstellung

Country Status (3)

Country Link
US (1) US6523699B1 (de)
EP (1) EP1085051B1 (de)
DE (1) DE60020915T2 (de)

Families Citing this family (72)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100403754B1 (ko) * 2001-06-19 2003-10-30 송민규 연료전지용 복합 고분자 전해질 막, 이의 제조방법 및이를 포함하는 연료전지
US7318972B2 (en) 2001-09-07 2008-01-15 Itm Power Ltd. Hydrophilic polymers and their use in electrochemical cells
DE10205852A1 (de) * 2002-02-13 2003-08-21 Creavis Tech & Innovation Gmbh Elektrolytmembran mit Diffusionsbarriere, diese umfassende Membranelektrodeneinheiten, Verfahren zur Herstellung und spezielle Verwendungen
GB0204028D0 (en) 2002-02-20 2002-04-03 Stamford Memory Polymers Ltd Method of photoelectrolysis
DE10392357B4 (de) * 2002-03-07 2015-03-12 Ube Industries, Ltd. Elektrolytmembran, Verfahren zu deren Herstellung sowie Elektrolyt-Membran-Elektroden-Baugruppen und Brennstoffzellen mit einer solchen Elektrolytmembran
US7824820B2 (en) * 2002-03-07 2010-11-02 Nitto Denko Corporation Electrolyte film and solid polymer fuel cell using the same
EP1518290A4 (de) * 2002-05-13 2009-12-02 Polyfuel Inc Ionenleitende blockcopolymere
US20050244696A1 (en) * 2002-09-20 2005-11-03 Hidekazu Kuromatsu Proton conducting polymer film and method for production thereof
US7115333B2 (en) 2003-02-07 2006-10-03 Gas Technology Institute High temperature composite proton exchange membranes
KR100509298B1 (ko) * 2003-05-31 2005-08-22 한국과학기술연구원 무기질 박막이 코팅된 직접메탄올 연료전지용 복합고분자 전해질막의 제조 방법
US20060024546A1 (en) * 2003-06-12 2006-02-02 Mc Research & Innovation Corp And Mer Corporation Fullerene-based electrolyte for fuel cells
CA2529013A1 (en) * 2003-06-12 2004-12-23 Materials And Electrochemical Research (Mer) Corporation Fullerene-based electrolyte for fuel cells
US7176247B1 (en) 2003-06-27 2007-02-13 The United States Of America As Represented By The Secretary Of The Army Interpenetrating polymer network
US20050042489A1 (en) * 2003-07-11 2005-02-24 Kenji Fukuta Laminate useful as a membrane-electrode assembly for fuel cells, production process therefor and a fuel cell provided with the laminate
US6962959B2 (en) * 2003-08-28 2005-11-08 Hoku Scientific, Inc. Composite electrolyte with crosslinking agents
JP2005108604A (ja) * 2003-09-30 2005-04-21 Canon Inc 膜電極接合体、その製造方法および固体高分子型燃料電池
US20050211624A1 (en) * 2004-03-23 2005-09-29 Vane Leland M Hydrophilic cross-linked polymeric membranes and sorbents
KR100562050B1 (ko) * 2004-03-30 2006-03-17 한국화학연구원 가교된 폴리비닐알콜계 신규 고분자막 및 이의 제조방법
US7041191B2 (en) * 2004-05-27 2006-05-09 Institute Of Nuclear Energy Research Method for manufacturing membrane electrode assembly of fuel cell by printing processes
KR100658739B1 (ko) 2004-06-30 2006-12-15 삼성에스디아이 주식회사 연료전지용 고분자 전해질막 및 그 제조방법
KR100637486B1 (ko) * 2004-06-30 2006-10-20 삼성에스디아이 주식회사 연료전지용 전해질막 및 이를 포함하는 연료전지
KR100639284B1 (ko) * 2004-07-21 2006-10-30 가부시끼가이샤 도시바 양성자 전도성 고체 전해질, 양성자 전도성 막, 연료전지용 전극, 막 전극 조립품 및 연료 전지
US20060147789A1 (en) * 2004-10-07 2006-07-06 More Energy Ltd., Gas blocking anode for a direct liquid fuel cell
KR101135479B1 (ko) * 2005-01-26 2012-04-13 삼성에스디아이 주식회사 연료전지용 고분자 전해질막, 이의 제조방법, 및 이를포함하는 연료전지 시스템
US7459487B2 (en) * 2005-02-16 2008-12-02 The University Of Hong Kong Polymer composite membrane and method of making the same
EP1885777A2 (de) * 2005-06-01 2008-02-13 Polyfuel, Inc. Vernetztes, ionenleitfähiges copolymer
CN101501917A (zh) * 2005-06-01 2009-08-05 复合燃料公司 包含离子导电侧基的离子导电聚合物
KR100668339B1 (ko) 2005-06-18 2007-01-12 삼성전자주식회사 이온 교환성 혼합물 및 그의 제조방법
JP2008544473A (ja) 2005-06-27 2008-12-04 アイティーエム パワー(リサーチ)リミティド 膜電極接合体
TW200810197A (en) * 2006-08-15 2008-02-16 Univ Chang Gung Method for producing composite solid polymer electrolyte (SPE)
WO2009027993A1 (en) * 2007-08-29 2009-03-05 Council Of Scientific & Industrial Research Proton conducting polymer electrolyte membrane useful in polymer electrolyte fuel cells
US9142835B2 (en) * 2007-11-20 2015-09-22 Sekisui Specialty Chemicals America, Llc Separator film for batteries including oxidation resistant vinyl alcohol copolymer
JP5557430B2 (ja) * 2008-04-11 2014-07-23 日東電工株式会社 プロトン伝導性高分子電解質膜およびその製造方法ならびにそれを用いた膜−電極接合体および高分子電解質型燃料電池
EP2276095B1 (de) * 2008-05-08 2014-02-12 Nitto Denko Corporation Elektrolytfilm für eine feststoffpolymer-brennstoffzelle und herstellungsverfahren dafür
US7897693B2 (en) * 2008-05-09 2011-03-01 Gm Global Technology Operations, Inc. Proton conductive polymer electrolytes and fuel cells
US8008404B2 (en) * 2008-05-09 2011-08-30 GM Global Technology Operations LLC Composite membrane
US7888433B2 (en) * 2008-05-09 2011-02-15 Gm Global Technology Operations, Inc. Sulfonated-polyperfluoro-cyclobutane-polyphenylene polymers for PEM fuel cell applications
US7897692B2 (en) * 2008-05-09 2011-03-01 Gm Global Technology Operations, Inc. Sulfonated perfluorocyclobutane block copolymers and proton conductive polymer membranes
US7985805B2 (en) * 2008-05-09 2011-07-26 GM Global Technology Operations LLC Polyelectrolyte membranes comprised of blends of PFSA and sulfonated PFCB polymers
US8030405B2 (en) * 2008-05-09 2011-10-04 GM Global Technology Operations LLC Blended PEM's with elastomers for improved mechanical durability
US7897691B2 (en) * 2008-05-09 2011-03-01 Gm Global Technology Operations, Inc. Proton exchange membranes for fuel cell applications
US7976730B2 (en) * 2008-08-25 2011-07-12 GM Global Technology Operations LLC Blends of low equivalent molecular weight PFSA ionomers with Kynar 2751
US8003732B2 (en) * 2008-08-25 2011-08-23 GM Global Technology Operations LLC Gradient reinforced proton exchange membrane
US9139669B2 (en) 2009-03-24 2015-09-22 W. L. Gore & Associates, Inc. Expandable functional TFE copolymer fine powder, the expandable functional products obtained therefrom and reaction of the expanded products
US8658707B2 (en) 2009-03-24 2014-02-25 W. L. Gore & Associates, Inc. Expandable functional TFE copolymer fine powder, the expanded functional products obtained therefrom and reaction of the expanded products
US20100280200A1 (en) * 2009-03-24 2010-11-04 Poddar Tarun K Water Permeable Fluoropolymer Articles
US20110045381A1 (en) * 2009-08-18 2011-02-24 Gm Global Technology Operations, Inc. Hydrocarbon PEM Membranes with Perfluorosulfonic Acid Groups for Automotive Fuel Cells
WO2011025259A2 (ko) 2009-08-25 2011-03-03 주식회사 코오롱 연료전지용 고분자 전해질막 및 그 제조방법
US8053530B2 (en) * 2009-08-26 2011-11-08 GM Global Technology Operations LLC Polyelectrolyte membranes made of poly(perfluorocyclobutanes) with pendant perfluorosulfonic acid groups and blends with poly(vinylidene fluoride)
US8852823B2 (en) * 2009-08-26 2014-10-07 GM Global Technology Operations LLC Sodium stannate additive to improve the durability of PEMS for H2/air fuel cells
US20110053008A1 (en) * 2009-08-28 2011-03-03 Gm Global Technology Operations, Inc. Water vapor transfer membrane and paper integrated assembly
US8058352B2 (en) * 2009-08-28 2011-11-15 GM Global Technology Operations LLC Perfluorocyclobutane based water vapor transfer membranes
US8354201B2 (en) * 2009-08-28 2013-01-15 GM Global Technology Operations LLC Fuel cell with spatially non-homogeneous ionic membrane
US20110053009A1 (en) * 2009-08-28 2011-03-03 Gm Global Technology Operations, Inc. Customized water vapor transfer membrane layered structure
US7972732B2 (en) * 2009-08-28 2011-07-05 GM Global Technology Operations LLC Perfluorocyclobutane based water vapor transfer membranes with side chain perfluorosulfonic acid moieties
US8048963B2 (en) * 2009-08-31 2011-11-01 GM Global Technology Operations LLC Ion exchange membrane having lamellar morphology and process of making the same
US8409765B2 (en) * 2009-08-31 2013-04-02 GM Global Technology Operations LLC Co(II)tetramethoxyphenylporphyrin additive to PFSA PEMS for improved fuel cell durability
US8252712B2 (en) * 2009-11-13 2012-08-28 GM Global Technology Operations LLC Polymer dispersant addition to fuel cell electrode inks for improved manufacturability
US20110159404A1 (en) * 2009-12-29 2011-06-30 Gm Global Technology Operations, Inc. Polyolefin Support to Prevent Dielectric Breakdown in PEMS
US20110159405A1 (en) * 2009-12-30 2011-06-30 Gm Global Technology Operations, Inc. Hydrophilic Polyelectrolyte Membranes Containing Poly(Vinyl Acetate) and Poly(Vinyl Alcohol)
US20110165497A1 (en) * 2010-01-06 2011-07-07 Gm Global Technology Operations, Inc. Method for Mitigating Fuel Cell Chemical Degradation
US7989512B1 (en) 2010-03-17 2011-08-02 GM Global Technology Operations LLC Polyelectrolyte membranes derived from soluble perfluorocyclobutane polymers with sulfonyl chloride groups
US8044146B1 (en) 2010-04-16 2011-10-25 GM Global Technology Operations LLC Combination of main-chain and side-chain sulfonation of PFCB-6F high-temperature fuel cell membranes
US8735021B2 (en) 2010-04-16 2014-05-27 GM Global Technology Operations LLC Cobalt(II) tetramethoxyphenylporphyrin (CoTMPP) ionomer stabilization to prevent electrode degradation
US8609739B2 (en) 2011-02-17 2013-12-17 GM Global Technology Operations LLC Poly(perfluorocyclobutane) ionomer with phosphonic acid groups for high temperature fuel cells
KR101307893B1 (ko) * 2011-04-25 2013-09-13 아주대학교산학협력단 폴리비닐계 공중합체, 상기를 포함하는 도판트, 및 상기 도판트를 포함하는 전도성 고분자 복합체
US20140051812A1 (en) * 2012-08-15 2014-02-20 Brian Burmaster Polymeric surface oxidation using peracids
KR102092943B1 (ko) 2014-01-29 2020-04-14 삼성전자주식회사 전기 흡착 탈이온 장치용 전극 조성물, 및 이를 포함하는 전기 흡착 탈이온 장치용 전극
KR102422983B1 (ko) 2014-05-15 2022-07-19 암테크 리서치 인터내셔널 엘엘씨 공유 가교 결합된 겔 전해질
WO2018021495A1 (ja) * 2016-07-29 2018-02-01 日本合成化学工業株式会社 樹脂組成物及びその用途、並びに樹脂組成物の製造方法
CN106823856B (zh) * 2017-03-21 2020-10-30 亚美滤膜(南通)有限公司 亲水性多孔聚烯烃材料及其亲水性改性处理方法
US20210269572A1 (en) * 2018-06-25 2021-09-02 University Of Florida Research Foundation, Incorporated Improving the mechanical integrity of polysulfonic acids

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5742765A (en) 1980-08-29 1982-03-10 C I Kasei Co Ltd Water absorbing resin and preparation of the same
US4361632A (en) 1981-05-22 1982-11-30 Kimberly-Clark Corporation Alkaline battery, composite separator therefor
US4505998A (en) 1981-07-10 1985-03-19 The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration Alkaline battery containing a separator of a cross-linked copolymer of vinyl alcohol and unsaturated carboxylic acid
EP0082355B1 (de) * 1981-12-21 1986-06-11 Aligena Ag Semipermeable Membranen aus modifizierten Polystyrolen, Verfahren zu ihrer Herstellung und ihre Verwendung
IL70415A (en) * 1982-12-27 1987-07-31 Aligena Ag Semipermeable encapsulated membranes,their manufacture and their use
US4708981A (en) 1985-12-11 1987-11-24 Uop Inc. Water insoluble proton conducting polymers
JPS6354903A (ja) * 1986-08-26 1988-03-09 Agency Of Ind Science & Technol パ−ベ−パレ−シヨン用分離膜
US5039421A (en) * 1989-10-02 1991-08-13 Aligena Ag Solvent stable membranes
CA2085549A1 (en) 1991-12-25 1993-06-26 Noboru Nakano Fuel cell and electrolyte membrane therefor
JP3203778B2 (ja) 1992-07-16 2001-08-27 凸版印刷株式会社 エッチング方法
JP3150897B2 (ja) 1996-02-20 2001-03-26 信越化学工業株式会社 スルホン酸変性ポリビニルアルコールの製造方法
US5643689A (en) 1996-08-28 1997-07-01 E.C.R.-Electro-Chemical Research Ltd. Non-liquid proton conductors for use in electrochemical systems under ambient conditions
JP2001081220A (ja) * 1999-09-20 2001-03-27 Honda Motor Co Ltd 高分子複合膜、その製造方法、ならびに高分子固体電解質膜

Also Published As

Publication number Publication date
EP1085051A1 (de) 2001-03-21
DE60020915T2 (de) 2006-05-11
EP1085051B1 (de) 2005-06-22
US6523699B1 (en) 2003-02-25

Similar Documents

Publication Publication Date Title
DE60020915D1 (de) Polymere Kompositmembran und Verfahren zu ihrer Herstellung
DE69840251D1 (de) Festpolymerelektrolyt und Verfahren zur Herstellung
DE69910511D1 (de) Polybutene-1 (co)polymere und verfahren zu ihrer herstellung
DE69920419D1 (de) Semipermeable verbundmembran, verfahren zu ihrer herstellung und verfahren zur reinigung von wasser mit hilfe derselben
DE60014734D1 (de) Bioabbaubare Verbundfaser und Verfahren zu ihrer Herstellung
DE69939959D1 (de) Polymer, Verfahren zu seiner Herstellung und Zusammensetzung
DE69934463D1 (de) Cellulosischer Verbundwerkstoff und Verfahren zu dessen Herstellung
DE60022039D1 (de) Wärmestabile polymere, verfahren zu ihrer herstellung und gegenstände daraus
DE69727366D1 (de) Tastaturfolie und Verfahren zu ihrer Herstellung
DE60027126D1 (de) Verfahren zur herstellung von polyesterblockcopolymeren, polyesterblockcopolymer-zusammensetzungen und verfahren zu ihrer herstellung
DE60125461D1 (de) Poröse Hohlfasermembranen und Verfahren zu ihrer Herstellung
DE69825038D1 (de) Polypropylen copolymer legierung, verfahren zu ihrer herstellung und verwendungen der legierung
DE69917194D1 (de) Thermoplastische Polyvinylalkoholfasern und Verfahren zu ihrer Herstellung
DE69712172D1 (de) Propiophenonderivate und Verfahren zu ihrer Herstellung
DE60031033D1 (de) Organisch-anorganischer Verbundwerkstoff und Verfahren zu seiner Herstellung
DE60016900D1 (de) Biologische abbaubare und wärmeempfindliche polyphosphazene und verfahren zu ihrer herstellung
DE69915224D1 (de) Kieselsäure-Magnesiumfluoridhydrat-Komposit enthaltende Sole und Verfahren zu deren Herstellung
DE60116793D1 (de) Kompositgranulatzusätze für polyolefin, verfahren zu ihrer herstellung und diese enthaltende zusammensetzung
DE60028771D1 (de) Wässrige polyamidharzdispersion und verfahren zu ihrer herstellung
DE60024801D1 (de) Polyurethanharnstofffasern und verfahren zu ihrer herstellung
ATE342288T1 (de) Buten-1-(co)polymere und verfahren zu ihrer herstellung
DE60013040D1 (de) Verbundkunststofffolie und Verfahren zu ihrer Herstellung
ATE217831T1 (de) Bearbeitete holzwerkstoffe, daraus hergestellte holzverbundprodukte und verfahren zu ihrer herstellung
DE10294093D2 (de) Sulfinatgruppen enthaltende Oligomere und Polymere und Verfahren zu ihrer Herstellung
DE69605374D1 (de) Fluorhaltige Polymerlegierung, Verfahren zu ihrer Herstellung und Verfahren zur Formung

Legal Events

Date Code Title Description
8364 No opposition during term of opposition