DE59220C - Process for the preparation of nitrated fuchsine and methyl violet - Google Patents
Process for the preparation of nitrated fuchsine and methyl violetInfo
- Publication number
- DE59220C DE59220C DENDAT59220D DE59220DA DE59220C DE 59220 C DE59220 C DE 59220C DE NDAT59220 D DENDAT59220 D DE NDAT59220D DE 59220D A DE59220D A DE 59220DA DE 59220 C DE59220 C DE 59220C
- Authority
- DE
- Germany
- Prior art keywords
- fuchsine
- nitrated
- preparation
- methyl violet
- dyes
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- NIKFYOSELWJIOF-UHFFFAOYSA-O Fuchsine Chemical compound Cl.C1=C(N)C(C)=CC(C(=C2C=CC(=[NH2+])C=C2)C=2C=CC(N)=CC=2)=C1 NIKFYOSELWJIOF-UHFFFAOYSA-O 0.000 title claims description 6
- JFTBTTPUYRGXDG-UHFFFAOYSA-N Methyl violet Chemical compound Cl.C1=CC(=NC)C=CC1=C(C=1C=CC(=CC=1)N(C)C)C1=CC=C(N(C)C)C=C1 JFTBTTPUYRGXDG-UHFFFAOYSA-N 0.000 title claims description 5
- 238000000034 method Methods 0.000 title claims description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid group Chemical class S(O)(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 3
- 239000000975 dye Substances 0.000 description 11
- VEXZGXHMUGYJMC-UHFFFAOYSA-N HCl Chemical class Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- UIIMBOGNXHQVGW-UHFFFAOYSA-M NaHCO3 Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- VXMKYRQZQXVKGB-CWWHNZPOSA-N Tannin Chemical compound O([C@H]1[C@H]([C@@H]2OC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)O[C@H]([C@H]2O)O1)O)C(=O)C1=CC(O)=C(O)C(O)=C1 VXMKYRQZQXVKGB-CWWHNZPOSA-N 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 235000018553 tannin Nutrition 0.000 description 2
- 229920001864 tannin Polymers 0.000 description 2
- 239000001648 tannin Substances 0.000 description 2
- CIGATVLAEMOWGZ-UHFFFAOYSA-N Benzyl violet 4B Chemical compound [Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C=CC(=CC=2)N(C)C)C=CC=1N(CC)CC1=CC=C(S(O)(=O)=O)C=C1 CIGATVLAEMOWGZ-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 210000002268 Wool Anatomy 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 230000000875 corresponding Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- 230000036633 rest Effects 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 239000001187 sodium carbonate Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B11/00—Diaryl- or thriarylmethane dyes
- C09B11/04—Diaryl- or thriarylmethane dyes derived from triarylmethanes, i.e. central C-atom is substituted by amino, cyano, alkyl
- C09B11/10—Amino derivatives of triarylmethanes
- C09B11/12—Amino derivatives of triarylmethanes without any OH group bound to an aryl nucleus
- C09B11/20—Preparation from other triarylmethane derivatives, e.g. by substitution, by replacement of substituents
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
Description
KAISERLICHESIMPERIAL
PATENTAMT.PATENT OFFICE.
Das Verfahren beruht auf der Beobachtung, dafs Farbstoffe von werthvollen Eigenschaften entstehen, wenn Fuchsin und Methylviolett mit einer Mischung von Salpeter- und Schwefelsäure behandelt werden.The process rests on the observation that dyes have valuable properties arise when fuchsine and methyl violet with a mixture of nitric and sulfuric acids be treated.
Man verfährt folgendermafsen:Proceed as follows:
40,47 kg krystallisirtes Methyl violett werden in 200 bis 250 kg Schwefelsäure von 66° B. gelöst. Zu der auf o° erkalteten Lösung wird langsam ein gleichfalls abgekühltes Gemisch von 10 kg 36 procentiger Salpetersäure und 20 bis 30 kg concentrirter Schwefelsäure unter Umrühren hinzugefügt. Nach mehrstündigem Stehen wird mit Wasser auf 4000 1 verdünnt, die Säure mit Natron oder kohlensaurer Magnesia neutralisirt und die ausgeschiedene Base auf Filtern gesammelt und ausgewaschen.40.47 kg of crystallized methyl turn violet dissolved in 200 to 250 kg sulfuric acid of 66 ° B. To the solution cooled to o ° slowly a likewise cooled mixture of 10 kg of 36 percent nitric acid and Add 20 to 30 kg of concentrated sulfuric acid while stirring. After several hours Standing is diluted to 4000 l with water, the acid with sodium bicarbonate or carbonate Magnesia neutralized and the precipitated base collected on filters and washed out.
Das salzsaure Salz wird erhalten, wenn man die teigförmige Masse mit 116 oder 1 20 kg gewöhnlicher Salzsäure anrührt und dann trocknet. Der so erhaltene Farbstoff bildet ein bronzeglänzendes Pulver, das sich leicht in Wasser löst; derselbe färbt Wolle, Seide, sowie mit Gerbstoff gebeizte Baumwolle violettblau.The hydrochloric acid salt is obtained if the dough-like mass is 116 or 1 20 kg more common Stirring hydrochloric acid and then drying. The dye obtained in this way forms a shiny bronze Powder that easily dissolves in water; the same dyes wool, silk, as well as with Tannin-stained cotton violet blue.
Das krystallisirte Methylviolett kann in obigem Beispiel durch 39 kg gewöhnliches Methyl violett oder durch eine entsprechende Menge Benzylviolett ersetzt werden.The crystallized methyl violet can in the above example be made violet by 39 kg of ordinary methyl or replaced by an appropriate amount of benzyl violet.
Die entsprechenden Farbstoffe sind dem soeben beschriebenen ganz ähnlich.The corresponding dyes are very similar to the one just described.
33,75 kg Fuchsin oder 32 kg Rosanilin werden genau wie unter Beispiel I. angegeben behandelt. 33.75 kg of fuchsine or 32 kg of rosaniline are treated exactly as given in Example I.
Der nitrirte Farbstoff, der die Textilfaser granatroth färbt, wird am geeignetsten in Form von Paste verwendet.The nitrided dye, which dyes the textile fiber garnet-red, is most suitably shaped used by paste.
Beispiel III.Example III.
Wird in den angeführten Beispielen die Menge Salpetersäure verdoppelt, so entstehen weiter nitrirte Farbstoffe, die sämmtlich in Wasser schwerer löslich sind und deren Nuance etwas schwärzer ist. Im Ganzen besitzen diese höher nitrirten Farbstoffe ähnliche Eigenschaften wie die zuerst beschriebenen.If the amount of nitric acid is doubled in the examples given, more is produced nitrated dyes, all of which are less soluble in water, and their shade somewhat is blacker. On the whole, these more highly nitrated dyes have properties similar to the first described.
Ein besonderer Vorzug der sämmtlichen erwähnten Farbstoffe besteht darin, dafs dieselben die mit Gerbstoff gebeizte vegetabilische Faser nur an den gebeizten Stellen färben, nicht aber an den ungeheizten, so dafs die durch Aetzdruck (Enlevage) erzielten Zeichnungen schön weifs auf dem gefärbten Grunde erscheinen. Die erhaltenen Färbungen sind ebenso echt gegen Licht und Seife, wie die der nicht nitrirten Farbstoffe.A particular advantage of all the dyes mentioned is that they are dye the vegetable fibers stained with tannin only in the stained areas, but not on the unheated ones, so that the drawings obtained by etching (Enlevage) are beautiful white appear on the colored ground. The dyeings obtained are also fast against Light and soap, like those of the non-nitrided dyes.
Claims (1)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE59220C true DE59220C (en) |
Family
ID=333454
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DENDAT59220D Expired - Lifetime DE59220C (en) | Process for the preparation of nitrated fuchsine and methyl violet |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE59220C (en) |
-
0
- DE DENDAT59220D patent/DE59220C/en not_active Expired - Lifetime
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