DE590165C - Process for the production of emulsions - Google Patents
Process for the production of emulsionsInfo
- Publication number
- DE590165C DE590165C DE1928590165D DE590165DD DE590165C DE 590165 C DE590165 C DE 590165C DE 1928590165 D DE1928590165 D DE 1928590165D DE 590165D D DE590165D D DE 590165DD DE 590165 C DE590165 C DE 590165C
- Authority
- DE
- Germany
- Prior art keywords
- emulsions
- mixture
- production
- esters
- substances
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000839 emulsion Substances 0.000 title claims description 13
- 238000004519 manufacturing process Methods 0.000 title claims description 5
- 238000000034 method Methods 0.000 title description 3
- 150000002148 esters Chemical class 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 7
- 239000000126 substance Substances 0.000 claims description 6
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 2
- 239000000194 fatty acid Substances 0.000 claims description 2
- 229930195729 fatty acid Natural products 0.000 claims description 2
- 150000004665 fatty acids Chemical class 0.000 claims description 2
- 238000006467 substitution reaction Methods 0.000 claims description 2
- 230000004048 modification Effects 0.000 claims 1
- 238000012986 modification Methods 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- -1 ethylene glycol monooxystearic acid ester Chemical class 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 239000005662 Paraffin oil Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 150000005846 sugar alcohols Polymers 0.000 description 2
- 239000001993 wax Substances 0.000 description 2
- 239000004375 Dextrin Substances 0.000 description 1
- 229920001353 Dextrin Polymers 0.000 description 1
- 239000001293 FEMA 3089 Substances 0.000 description 1
- 239000001828 Gelatine Substances 0.000 description 1
- 239000004264 Petrolatum Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 229940088990 ammonium stearate Drugs 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- JPNZKPRONVOMLL-UHFFFAOYSA-N azane;octadecanoic acid Chemical compound [NH4+].CCCCCCCCCCCCCCCCCC([O-])=O JPNZKPRONVOMLL-UHFFFAOYSA-N 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 235000020247 cow milk Nutrition 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 235000019425 dextrin Nutrition 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 235000013310 margarine Nutrition 0.000 description 1
- 239000003264 margarine Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 229940049964 oleate Drugs 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- 229940066842 petrolatum Drugs 0.000 description 1
- 235000019271 petrolatum Nutrition 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229940114930 potassium stearate Drugs 0.000 description 1
- ANBFRLKBEIFNQU-UHFFFAOYSA-M potassium;octadecanoate Chemical compound [K+].CCCCCCCCCCCCCCCCCC([O-])=O ANBFRLKBEIFNQU-UHFFFAOYSA-M 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 229940099259 vaseline Drugs 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/06—Emulsions
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Dispersion Chemistry (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Colloid Chemistry (AREA)
Description
Verfahren zur Herstellung von Emulsionen Zusatz zum Patent 551 403 Vorliegende Erfindung betrifft ein Verfahren zur Herstellung von Emulsionen, wie es in dem Hauptpatent 551 403 beschrieben ist. Dieses letztere besteht darin, die Ester mehrwertiger - Alkohole, welche mindestens eine freie Hydroxylgruppe lenthalten, mit höhermolekularen Fettsäuren in Gegenwart alkalisch reagierender Stoffe mit Wasser oder wäßrigen Lösungen zu emulgieren.Process for the production of emulsions Addition to patent 551,403 The present invention relates to a method for preparing emulsions such as it is described in the main patent 551,403. This latter consists in the Esters of polyhydric alcohols which contain at least one free hydroxyl group, with higher molecular weight fatty acids in the presence of alkaline substances with water or to emulsify aqueous solutions.
Statt der mehrwertigen Alkohole kann man auch beliebige Derivate derselben, insbesondere die ätherartigen Polyverbindungen, verwenden, und zwar entweder solche mit gleichen oder ungleichartigen Alkoholradikalen (vgl. Patent 582 106). Instead of the polyhydric alcohols, any derivatives can also be used the same, especially the ethereal poly compounds, use either those with the same or dissimilar alcohol radicals (see patent 582 106).
Vorliegende Erfindung geht nun noch einen Schritt weiter, indem sie statt der dort genannten Ester die entsprechenden Ester der Oxy- und ungesättigten Fettsäuren oder ihrer Substitutionsprodukte in Mischung mit etwa 5 bis I2 0/0 seifenartiger Stoffe, bezogen auf die Estermenge, verwendet. The present invention now goes a step further by providing instead of the esters mentioned there, the corresponding esters of the oxy and unsaturated Fatty acids or their substitution products in a mixture with about 5 to I2 0/0 soap-like Substances based on the amount of ester used.
Ein Vorteil der Verwendung dieser Stoffe beruht u. a. darin, daß man bei prozentual gleicher Verwendung von Emulsionsmitbeln Wünschen nach Veränderung der Konsistenz der Emulsionen in weiten Grenzen Rechnung tragen kann. One advantage of using these substances is based inter alia. in that With the same percentage of emulsion agents being used, one wishes for a change can take into account the consistency of the emulsions within wide limits.
Beispiel I Eine Mischung aus IO 10 % Äthylenglykot monooxystearinsäureester, 10% Vaseline, 5% Paraffinöl, 0,5% Kaliumstearat und 74, 0/o Wasser wird auf 70° erhitzt und dann kaltgerührt. Man erhält eine haltbare, weiße, homogen verreibbare, salbenartige Emulsion von Schmalzkonsistenz. Example I A mixture of 10% ethylene glycol monooxystearic acid ester, 10% petrolatum, 5% paraffin oil, 0.5% potassium stearate and 74.0 / o water is brought to 70 ° heated and then stirred cold. A durable, white, homogeneously rubable, ointment-like emulsion of lard consistency.
Beispiel 2 Eine Mischung aus 10% Glycerinmonoölsäureester, 100/0 Glycerin, I20/o Paraffinöl, 1% Traiäthanolaminoleat und 67% Wasser wird ebenso behandelt wie die Mischung in Beispiel 1. Es ergibt sich Zein dickflüssiger Krem, der sich mit Wasser zu leichtflüssigen Emulsionen verdünnen läßt. Example 2 A mixture of 10% glycerol monooleic acid ester, 100/0 Glycerine, 120% paraffin oil, 1% traiethanol amine oleate and 67% water are also treated like the mixture in Example 1. The result is a thick cream that is can be diluted with water to form easily flowing emulsions.
Beispiel 3 Eine Mischung aus 8% Propylenglykolmonolinolensäureester, 200/0 Vaseline, 5% Olivenöl, I % Ammoniumstearat und 660/o Wasser wird in gleicher Weise behandelt wie die Mischung in Beispiel 1. Es ergibt sich eine weiße, dickflüssige Emulsion von guter Beständigkeit. Example 3 A mixture of 8% propylene glycol monolinolenic acid ester, 200/0 vaseline, 5% olive oil, 1% ammonium stearate and 660 / o water is used in the same Treated wisely like the mixture in example 1. The result is a white, thick emulsion of good persistence.
Wie auch die Beispiele zeigen, lassen sich mit den angegebenen Emulsionsmitteln die verschiedensten Stoffe in emulsoiden Zustand überführen, z. B. Wachse, Harze, Fette, Öle aller Art. Auch kann man den Emulsionen Kolloide, wie Gelatine, Leim, Gummi, Dextrin, Kieselsäure, einverleiben oder ihnen natürliche Emulsionen, z. B. Kuhmilch, zusetzen. As the examples also show, the specified emulsifiers can be used convert a wide variety of substances into an emulsoid state, e.g. B. waxes, resins, Fats, oils of all kinds. Colloids such as gelatine, glue, Gum, dextrin, silica, or natural emulsions, e.g. B. Add cow's milk.
Auch können feste Stoffe, wie Ruß oder Zinkoxyd, zugesetzt werden.Solid substances such as carbon black or zinc oxide can also be added.
Die Emulsionen eignen sich zu kosmetischein und pharmazeutischen Zwecken, zur Herstellung von Margarine und anderen, zur Nahrung geeigneten Emulsionen, als Schmiermittel, zur Herstellung von Schuhkreme und Bohnerwachs. The emulsions are useful for cosmetic and pharmaceutical purposes Purposes, for the production of margarine and other emulsions suitable for food, as a lubricant, for the production of shoe polish and floor wax.
Es hat sich ferner gezeigt, daß die obengenannten Ester infolge ihrer lemulgierenden Wirkung sich sehr gut für Wasch- und Reinigungszwecke eignen, wofür man ihnen besondere Zusätze,-wie Borsäure, Terpentinöl usw., zugeben kann. It has also been shown that the above-mentioned esters as a result of their emulsifying effect are very suitable for washing and cleaning purposes, for which you can add special additives, such as boric acid, turpentine oil, etc.
Auch kann man sie mit Vorteil als Uberfettungsmittel für Seifen benutzen. They can also be used to advantage as superfatting agents for soaps.
Ferner eignen sich die mittels der Ester hergestellten Emulsionen zum Benetzen, Imprägnieren, Weich- und Geschmeidigmachen von Faserstoffen, Leder, Kunststoffen, Papier und anderen Materialien und zur Erzeugung matter Überzüge. The emulsions produced by means of the esters are also suitable for wetting, impregnating, softening and softening fibers, leather, Plastics, paper and other materials and for producing matt coatings.
Claims (1)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE590165T | 1928-02-15 |
Publications (1)
Publication Number | Publication Date |
---|---|
DE590165C true DE590165C (en) | 1933-12-27 |
Family
ID=6572708
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE1928590165D Expired DE590165C (en) | 1928-02-15 | 1928-02-15 | Process for the production of emulsions |
Country Status (1)
Country | Link |
---|---|
DE (1) | DE590165C (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2422486A (en) * | 1945-05-24 | 1947-06-17 | Vanderbilt Co R T | Emulsifying and whipping agents |
-
1928
- 1928-02-15 DE DE1928590165D patent/DE590165C/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2422486A (en) * | 1945-05-24 | 1947-06-17 | Vanderbilt Co R T | Emulsifying and whipping agents |
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