DE409690C - Process for the production of emulsions from saponifiable or unsaponifiable oils or fats - Google Patents
Process for the production of emulsions from saponifiable or unsaponifiable oils or fatsInfo
- Publication number
- DE409690C DE409690C DED40987D DED0040987D DE409690C DE 409690 C DE409690 C DE 409690C DE D40987 D DED40987 D DE D40987D DE D0040987 D DED0040987 D DE D0040987D DE 409690 C DE409690 C DE 409690C
- Authority
- DE
- Germany
- Prior art keywords
- emulsions
- alcohols
- fats
- production
- saponifiable
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000839 emulsion Substances 0.000 title claims description 11
- 239000003925 fat Substances 0.000 title claims description 9
- 238000004519 manufacturing process Methods 0.000 title claims description 8
- 239000003921 oil Substances 0.000 title claims description 7
- 238000000034 method Methods 0.000 title claims description 6
- 150000001298 alcohols Chemical class 0.000 claims description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 239000010426 asphalt Substances 0.000 claims description 2
- 239000003077 lignite Substances 0.000 claims description 2
- 239000003995 emulsifying agent Substances 0.000 claims 1
- 235000019197 fats Nutrition 0.000 description 6
- 239000002480 mineral oil Substances 0.000 description 5
- 235000019198 oils Nutrition 0.000 description 5
- 230000008901 benefit Effects 0.000 description 4
- 150000002191 fatty alcohols Chemical class 0.000 description 4
- 239000003513 alkali Substances 0.000 description 3
- 239000000314 lubricant Substances 0.000 description 3
- 239000000344 soap Substances 0.000 description 3
- 239000001993 wax Substances 0.000 description 3
- 210000002268 wool Anatomy 0.000 description 3
- 239000000203 mixture Substances 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000010775 animal oil Substances 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 239000012170 montan wax Substances 0.000 description 1
- 239000003883 ointment base Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 235000019871 vegetable fat Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
- C09K23/38—Alcohols, e.g. oxidation products of paraffins
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/02—Water
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/40—Fatty vegetable or animal oils
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/40—Fatty vegetable or animal oils
- C10M2207/404—Fatty vegetable or animal oils obtained from genetically modified species
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Colloid Chemistry (AREA)
Description
Verfahren zur Herstellung von Emulsionen aus verseifbaren oder unverseifbaren Ölen oder Fetten.Process for the preparation of emulsions from saponifiable or unsaponifiable Oils or fats.
Die nach dem Verfahren des Hauptpatents gewonnenen Montanalkohole sind, wie der Erfinder neuerdings gefunden hat, in ausgesprochenem Maße hydrophil. Man kann von dieser neuen Beobachtung nach verschiedenen Richtungen vorteilhaft Anwendung machen. Beispielsweise kann eine Lösung von Montanalkoholen in Mineralölen beliebiger Beschaffenheit mit Wasser versetzt und zu einer haltbaren Emulsion verbunden werden. The mining alcohols obtained by the process of the main patent are, as the inventor recently found, extremely hydrophilic. One can benefit from this new observation in various directions Make application. For example, a solution of montan alcohols in mineral oils mixed with water of any consistency and combined to form a durable emulsion will.
Ebenso kann man tierische oder pflanzliche Öle oder Fette mittels derMontanalkohrole mit Wasser haltbar emulgieren. Derartige Emulsionen sind je nach Art des angewandten Öls und je nach Menge der Montanalkohole und des inkorporierten Wassers als konsistente Schmiermittel, Salbengrundlagen oder emulgierte Öle verwendbar.You can also use animal or vegetable oils or fats Emulsify the Montanalkohrole with water for a long time. Such emulsions are dependent on Type of oil used and depending on the amount of montan alcohol and the amount incorporated Water can be used as consistent lubricants, ointment bases or emulsified oils.
Als Beispiel für die Herstellung eines Starrfettes diene folgende Vorschrift: In 45 Teilen Petroleumrückständen, welche zwischen I j und -200 erstarren, werden unter Erwärmen 5 kg rohe Montanalkohole aufgelöst und in diese Lösung 50 kg Wasser eingerührt. Das Ganze läßt man unter Rühren erkalten. Es entstehen 100 kg eines den üblichen Anforderungen entsprechenden Starrfettes mit einem Tropfpunkt von + 540 Bekanntlich bestanden Starrfette bisher aus einer Lösung von Alkali-und Erdalkaliseifen in Mineralölen und wiesen außerdem einen bestimmten Gehalt an Wasser auf. Bei diesen gewöhnlichen Starrfetten konnte es leicht vorkommen, daß das für die Seifenbildung verwendete Alkali oderErdalkali nicht vollkommen in Reaktion trat, so daß die erzeugten Schmiermittel gelegentlich nicht neutral sind. The following serve as an example of the production of a rigid fat Regulation: In 45 parts of petroleum residues, which solidify between I j and -200, 5 kg of raw montan alcohols are dissolved with heating and 50 kg of water stirred in. The whole thing is allowed to cool while stirring. There are 100 kg of a rigid fat with one dropping point that meets the usual requirements von + 540 It is well known that rigid fats consisted of a solution of alkali and alkali Alkaline earth soaps in mineral oils and also had a certain amount of water on. With these common rigid fats, it could easily happen that for the alkali used or alkaline earth did not react completely, so that the lubricants produced are occasionally not neutral.
Außerdem bedingt die Seife eine leichtere Verharzbarkeit und einen unerwünschten Gehalt an anorganischen Stoffen. Demgegenüber bedeuten die nach vorliegendem Verfahren erzeugten Starrfette einen technik schen Fortschritt, indem sie keinerlei Seifen enthalten und vollkommen neutral sind.In addition, the soap is easier to resinify and has a undesired content of inorganic substances. In contrast, mean according to the present Process produced rigid fats a technical advance by not using any Contain soaps and are completely neutral.
Dies trifft z. B. für die nach einem älteren Schweizer Patent herstellbaren wäßrigen Emulsionen von verseiftem Montanwachs nicht zu, die, sowohl an sich wie auch mit Mineralölen oder anderen Kohlenwasserstoffen verdünn, naturgemäß stets stark alkalisch reagieren.This applies e.g. B. for those manufacturable according to an older Swiss patent aqueous emulsions of saponified montan wax do not, both per se and also diluted with mineral oils or other hydrocarbons, of course always react strongly alkaline.
Für den gleichen Zweck, wie ihn die vorliegende Erfindung verfolgt, sind bereits früher gewisse andere Wachsalkohole vorgeschlagen worden, so z B. Wollfettalkohole. For the same purpose as pursued by the present invention, Certain other wax alcohols have been proposed earlier, such as wool fatty alcohols.
Ein älteres deutsches Patent beschreibt u. a. die Herstellung von Schmiermitteln aus einem Gemisch von Wolifettalkoholen und Mineralölen. Dieses Gemisch soll zur Emulsion mit Wasser geeignet sein. Es konnte aber aus der Verwendung von Wollfettalkoholen zur Herstellung von Mineralölemulsionen nicht ohne weiteres auf die Verwendbarkeit der Montanalkohole geschlossen werden. Dies geht u. a. auch daraus hervor, daß die Montanalkohole bisher für diesen Zweck praktisch noch nicht verwendet worden sind, trotzdem sie an sich seit mehr als 20 Jahren der Fachwelt bekannt sind.An earlier German patent describes, inter alia. the manufacture of Lubricants made from a mixture of woli fatty alcohols and mineral oils. This mixture should be suitable for emulsion with water. But it could be from the use of wool fatty alcohols for the production of mineral oil emulsions not easily the usability of the montan alcohols can be concluded. This is inter alia. even it emerges from this that the montan alcohols have not yet been used in practice for this purpose have been used in spite of the fact that they have been used in the professional world for more than 20 years are known.
Die Montanalkohole sind in bezug auf ihre wasserbindende Eigenschaft den Wollfettalkoholen ebenso wie allen anderen Wachsalkoholen überlegen und ihre Verwendung zur Herstellung von Ölemulsionen bietet dauer einen technischen Vorteil. Außerdem sind die Montanalkohole aus dem in großen Mengen im Inlande erzeugbaren Braunkohlenbitumen zu gewinnen, während andere Wachsalkohole einschließlich der VVoUfettalkoPholle nur in geringen Mengen oder sogar gar nicht aus heimischen Quellen verfügbar und daher sehr kostspielig sind. Die Verwendung der Montanalkohole für die Herstellung von Emulsionen bietet also geg-enüber anderen Wachsalkoholen sowohl technische als auch wirtschaftliche Vorteile. The montan alcohols are with regard to their water-binding property Superior to wool fatty alcohols as well as all other wax alcohols and theirs Use for the production of oil emulsions offers a permanent technical advantage. In addition, the montan alcohols are produced domestically from the in large quantities Lignite bitumen while other waxy alcohols including the VVoUfettalkoPholle only in small quantities or not at all from domestic sources available and therefore very expensive. The use of montan alcohols for the production of emulsions offers both, compared to other wax alcohols technical as well as economic advantages.
Die nach vorliegendem Verfahren erzeugten Emulsionen können z. B. auch für pharmazeutische und kosmetische Zwecke Verwendung finden und bieten als solche besonderen Vorteil, weil sie auch aus dünnflüssigen, leicht resorbierbaren Ölen in Formziemlich fester Pasten hergestellt werden können. Für die Herstellung solcher Pasten geht man vorteilhaft von gereinigten, d. h. destillierten oder raffinierten Montanalkoholen aus. The emulsions produced by the present process can, for. B. can also be used for pharmaceutical and cosmetic purposes and are offered as such special advantage because they are also made of thin, easily absorbable Oils in the form of fairly solid pastes can be made. For the production Such pastes are advantageously cleaned, i.e. H. distilled or refined Montan alcohols from.
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DED40987D DE409690C (en) | 1921-12-31 | 1921-12-31 | Process for the production of emulsions from saponifiable or unsaponifiable oils or fats |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DED40987D DE409690C (en) | 1921-12-31 | 1921-12-31 | Process for the production of emulsions from saponifiable or unsaponifiable oils or fats |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE409690C true DE409690C (en) | 1925-02-17 |
Family
ID=7045815
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DED40987D Expired DE409690C (en) | 1921-12-31 | 1921-12-31 | Process for the production of emulsions from saponifiable or unsaponifiable oils or fats |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE409690C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE767571C (en) * | 1937-12-01 | 1952-12-08 | Minimax A G | Process for stabilizing fire-extinguishing foam produced by mechanical means |
-
1921
- 1921-12-31 DE DED40987D patent/DE409690C/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE767571C (en) * | 1937-12-01 | 1952-12-08 | Minimax A G | Process for stabilizing fire-extinguishing foam produced by mechanical means |
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