DE58956C - Process for the production of a carbon electrode from individual carbon plates - Google Patents

Process for the production of a carbon electrode from individual carbon plates

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Publication number
DE58956C
DE58956C DENDAT58956D DE58956DA DE58956C DE 58956 C DE58956 C DE 58956C DE NDAT58956 D DENDAT58956 D DE NDAT58956D DE 58956D A DE58956D A DE 58956DA DE 58956 C DE58956 C DE 58956C
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DE
Germany
Prior art keywords
carbon
plates
production
individual
electrode
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DENDAT58956D
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German (de)
Original Assignee
SOCIETE ELECTRO-METALLURGIQUE FRANCAISE, Direktor A. MASSE in Paris, 43 Rue St. Georges
Publication of DE58956C publication Critical patent/DE58956C/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25CPROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C7/00Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells
    • C25C7/02Electrodes; Connections thereof

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Discharge Heating (AREA)

Description

KAISERLICHESIMPERIAL

PATENTAMTPATENT OFFICE

PATENTSCHRIFTPATENT LETTERING

KLASSE 40: Hüttenwesen.CLASS 40: Metallurgy.

Patentirt im Deutschen Reiche vom 11. April i8gö ab.Patented in the German Empire on April 11th, 1874.

Die Erfindung betrifft ein Verfahren zur Herstellung von positiven Elektroden bei elektrometallurgischen Apparaten, welche aus einer Anzahl von. Kohlenplatten bestehen, die so fest mit einander verbunden sind, dafs sie während der Benutzung allen zerstörenden Einflüssen widerstehen.The invention relates to a method for producing positive electrodes in electrometallurgical Apparatus consisting of a number of. Coal plates are made that way are firmly connected to each other so that they are destructive to all during use Resist the influences.

Die bisher in elektrometallurgischen Apparaten angewendeten Kohlenelektroden bestehen entweder aus einzelnen auf einander gelegten Kohlenplatten, welche auf mechanische Weise fest auf einander geprefst werden, oder aus einem einzigen massiven Stück Kohle.The carbon electrodes previously used in electrometallurgical apparatus consist of either from individual carbon plates placed on top of one another, which are mechanically firmly pressed together, or from a single solid piece of coal.

Bei der ersteren Art der aus Platten zusammengesetzten Elektrode ereignet es sich häufig, dafs durch die hohe Temperatur, der sie ausgesetzt, sowie durch andere Einflüsse, denen sie unterworfen sind, einzelne Platten in verschiedener Länge abbrechen, diese Stücke in den Schmelzkessel, in . den die Elektrode eintaucht, fallen, dadurch Kurzschlufs verursachen und somit die elektrische Einwirkung hemmen; aufserdem ist auch der elektrische Contact solcher Platten ein unvollkommener.In the former type of composite electrode, it occurs often, that due to the high temperature to which it is exposed, as well as due to other influences, to which they are subject to break off individual panels of various lengths, these pieces in the melting pot, in. that the electrode is immersed, fall, thereby causing a short circuit and thus the electrical effect inhibit; In addition, the electrical contact of such plates is imperfect.

Eine derartig beschädigte Elektrode functionirt mangelhaft und unregelmäfsig, so dafs sie durch eine neue ersetzt werden mufs, die häufig in sehr kurzer Zeit denselben Störungen unterliegt. Such a damaged electrode functions poorly and irregularly, so that it passes through a new one must be replaced, which is often subject to the same malfunctions in a very short time.

Bei den Elektroden, die aus einem einzigen massiven Stück Kohle hergestellt sind, ergiebt sich der Uebelstand, dafs die kleinen, oft unmerkbaren Querrisse, die sich in dicken Stücken der Retortenkohle stets befinden, bei hohen Temperaturgraden immer die Veranlassung des Abbrechens der Kohle werden.In the case of electrodes, which are made from a single solid piece of carbon, yields the inconvenience that the small, often imperceptible transverse cracks, which are in thick pieces the retort carbon are always located, at high temperatures always the cause of the Breaking off the coal will be.

Das neue Verfahren besteht nun darin, eine Anzahl dünner Platten auf einander zu legen und in der Art zusammenzukitten, dafs die oben erwähnten Uebelstände beseitigt werden.The new method now consists in laying a number of thin plates on top of one another and to cement them together in such a way that the abovementioned evils are removed.

Diese einzelnen Platten werden aus pulverisirter Retortenkohle in bekannter Weise hergestellt und nach dem Trocknen bezw. Brennen derselben in beliebiger Anzahl mittelst einer geeigneten Paste mit einander zu einer compacten, massiven Kohlen-Elektrode verbunden.These individual plates are made from pulverized retort carbon in a known manner and after drying respectively. Burn them in any number by means of one suitable paste connected to one another to form a compact, solid carbon electrode.

Eine solche sehr gute Paste stellt man her aus Fruchtzuckersyrup mit einem Zusatz von ca. ίο pCt. Dextrin oder arabischem Gummi. Auch eignet sich eine Mischung von heifsem Theer und fein gepulvertem Koks sehr gut für einen derartigen Kitt.Such a very good paste is made from fructose syrup with the addition of approx. ίο pCt. Dextrin or gum arabic. A mixture of hot tar and finely powdered coke is also very suitable for such a putty.

Je nachdem man nun eine Elektrode von gröfserer oder kleinerer Oberfläche herstellen will, werden eine Anzahl Kohlenplatten mit dazwischengebrachtem Kitt in ein gufseisernes Gefäfs gebracht und dieses in einem hierzu geeigneten Ofen einer ganz allmälig sich steigernden Hitze bis zur Rothglut ausgesetzt. Die Abkühlung mufs ebenfalls eine allmälige sein.Depending on whether you now produce an electrode with a larger or smaller surface want, a number of carbon plates with putty in between are put into a cast-iron one Brought a vessel and place it in a suitable oven very gradually exposed to increasing heat up to red embers. The cooling must also be gradual be.

Nach dem Erkalten ist jeder dieser Plattenbündel zu einem festen, compacten Kohlenstück zusammengeschmolzen und eine vollständig fehlerfreie Kohlen-Elektrode für metallurgische Zwecke hergestellt.After cooling, each of these bundles of plates is a solid, compact piece of coal melted together and a completely flawless carbon electrode for metallurgical Purposes.

Sollte sich in einer einzelnen Platte ein Querrifs befinden, so kann doch auf keinen Fall ein Stück abfallen, da einestheils der Rifs durch die Paste ausgefüllt wird und aufserdem alle Seitenflächen der einen Platte mit denen der anderen Platten mittelst des Kittes verbunden sind. Es ist durch diese Verbindungsart auch zugleich ein vollständig guter elektrischer Contact zwischen den einzelnen Platten, welche die Elektroden bilden, hergestellt.If there is a transverse rifle in a single plate, it cannot apply to any If a piece falls off, the riff is partly filled by the paste, and also all side surfaces of one plate connected to those of the other plates by means of cement are. This type of connection also makes it a completely good electrical one at the same time Contact established between the individual plates that form the electrodes.

Claims (1)

Patent-Anspruch:Patent claim: Verfahren zur Herstellung einer zusammenhängenden Kohlen-Elektrode aus einzelnen Kohlenplatten, darin bestehend, dafs eine Anzahl Kohlenplatten mit einem aus kohlenstoffhaltigen Substanzen bestehenden Kitt bestrichen, auf einander gelegt und einer allmälig bis zur Rothglühhitze sich steigernden Wärmeeinwirkung unterworfen werden.Process for the production of a coherent carbon electrode from individual Carbon plates consisting of a number of carbon plates with one made of carbonaceous Substances existing putty coated, placed on top of each other and one gradually until the red glow heat increasing exposure to heat. Hierzu ι Blatt Zeichnungen.For this purpose ι sheet of drawings.
DENDAT58956D Process for the production of a carbon electrode from individual carbon plates Expired - Lifetime DE58956C (en)

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2523253A (en) * 1945-09-10 1950-09-19 Harshaw Chem Corp Electrodeposition anode
US2728109A (en) * 1952-06-06 1955-12-27 Savoie Electrodes Refract Method of making cathodic electrodes for electrolysis furnaces
US2758964A (en) * 1952-08-12 1956-08-14 Aluminum Co Of America Continuous electrode and method of making the same
US2764539A (en) * 1952-08-21 1956-09-25 Frank H Morse Carbon electrodes
US2952592A (en) * 1955-06-08 1960-09-13 Montedison Spa Multicell closed circuit furnace and fused salt electrolysis process for aluminium production from aluminium oxide
US2959526A (en) * 1954-05-25 1960-11-08 Kaiser Aluminium Chem Corp Continuous electrode electrical furnace
US3029194A (en) * 1954-01-19 1962-04-10 Varda Giuseppe De Furnace and process for the electrolysis of aluminum
DE3103044A1 (en) * 1981-01-30 1982-08-26 Fried. Krupp Gmbh, 4300 Essen ELECTRODE ARRANGEMENT FOR PREFERRED THREE-PHASE ARC FURNACES

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2523253A (en) * 1945-09-10 1950-09-19 Harshaw Chem Corp Electrodeposition anode
US2728109A (en) * 1952-06-06 1955-12-27 Savoie Electrodes Refract Method of making cathodic electrodes for electrolysis furnaces
US2758964A (en) * 1952-08-12 1956-08-14 Aluminum Co Of America Continuous electrode and method of making the same
US2764539A (en) * 1952-08-21 1956-09-25 Frank H Morse Carbon electrodes
US3029194A (en) * 1954-01-19 1962-04-10 Varda Giuseppe De Furnace and process for the electrolysis of aluminum
US2959526A (en) * 1954-05-25 1960-11-08 Kaiser Aluminium Chem Corp Continuous electrode electrical furnace
US2952592A (en) * 1955-06-08 1960-09-13 Montedison Spa Multicell closed circuit furnace and fused salt electrolysis process for aluminium production from aluminium oxide
DE3103044A1 (en) * 1981-01-30 1982-08-26 Fried. Krupp Gmbh, 4300 Essen ELECTRODE ARRANGEMENT FOR PREFERRED THREE-PHASE ARC FURNACES

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