DE571026C - Process for the reversal development of photosensitive halogen silver layers without intermediate exposure - Google Patents

Process for the reversal development of photosensitive halogen silver layers without intermediate exposure

Info

Publication number
DE571026C
DE571026C DEI40458D DEI0040458D DE571026C DE 571026 C DE571026 C DE 571026C DE I40458 D DEI40458 D DE I40458D DE I0040458 D DEI0040458 D DE I0040458D DE 571026 C DE571026 C DE 571026C
Authority
DE
Germany
Prior art keywords
intermediate exposure
silver layers
reversal development
development
halogen silver
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DEI40458D
Other languages
German (de)
Inventor
Dr Eduard Schloemann
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IG Farbenindustrie AG
Original Assignee
IG Farbenindustrie AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IG Farbenindustrie AG filed Critical IG Farbenindustrie AG
Priority to DEI40458D priority Critical patent/DE571026C/en
Application granted granted Critical
Publication of DE571026C publication Critical patent/DE571026C/en
Expired legal-status Critical Current

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Description

Verfahren zur Umkehrentwicklung lichtempfindlicher Halogensilberschichten ohne Zwischenbelichtung Es ist bekannt, bei der photographischen Umkehrentwicklung die Zwischenbelichtung vor der zweiten Entwicklung zu vermeiden, indem man nach dem Herauslösen des durch die erste Entwicklung hervorgerufenen Silberbildes die Bildschicht mit Lösungen von Schwefelalkalien behandelt. Diese Lösungen haben den Nachteil, daß sie stark nach Schwefelwasserstoff riechen.Process for the reverse development of photosensitive halogen silver layers without intermediate exposure It is known in photographic reversal development avoid the intermediate exposure before the second development by looking after the removal of the silver image caused by the first development Image layer treated with solutions of alkaline sulfur. These solutions have the Disadvantage that they smell strongly of hydrogen sulfide.

Wie gefunden wurde, kann die Alkalisulfidlösung zur Hervorrufung des Umkehrbildes ersetzt werden durch einen alkalischen, geringe Mengen geruchloser Schwefelverbindungen enthaltenden Entwickler. Während die bekannten alkalischen Entwickler ohne Zwischenbelichtung erst nach mindestens 20 Minuten eine Schwärzung des Halogensilbers herbeiführen, ruft der mit geringen Mengen von Schwefelverbindungen, z. B. Thiosinamin, versetzte alkalische Entwickler bereits nach einer Minute das Silberbild hervor. Für sich allein wären die Schwefelverbindungen in der geringen; Konzentration nicht imstande, das flalo,gensilher zu schwärzen.As has been found, the alkali sulfide solution can cause the Reversal image can be replaced by an alkaline, small amount of odorless Developer containing sulfur compounds. While the well-known alkaline Developers without intermediate exposure only blacken after at least 20 minutes bring about the halogen silver, calls with small amounts of sulfur compounds, z. B. thiosinamine, alkaline developers offset that after just one minute Silver picture emerges. On their own the sulfur compounds would be in the slightest; Concentration unable to blacken the flalo, gensilher.

Als geruchlose Schwefelverbindungen eignen sich außer dem bereits erwähnten Thiosinamin noch Thioharnstoff und andere Schwefelverbindungen, die geeignet sind, Schwefelsilberkeime zu bilden. Beispiel iooo ccin des an sich bekannten Metolhydrochinonentwicklers, wie er in der Praxis der Umkehrentwicklung für die erste Negativentwicklung Verwendung findet, werden mit 0,5 g Thiosinainin versetzt. Das nach der Behandlung mit dem aus Bichromat und Schwefelsäure bestehenden Umkehrbad in der Schicht zurückbleibende Halogensilber wird durch die geruchlose Lösung in weniger als einer Minute geschwärzt. Der Farbton des Silberbildes ähnelt sehr dem Ton eines mit reinen Schwefelalkalien hervorgerufenen Bildes.In addition to the already mentioned thiosinamine, thiourea and other sulfur compounds which are suitable for forming sulfur-silver nuclei are also suitable as odorless sulfur compounds. Example 10000 ccin of the metolhydroquinone developer known per se, as it is used in the practice of reverse development for the first negative development, are mixed with 0.5 g of thiosinainine. The halogen silver remaining in the layer after treatment with the reversal bath consisting of bichromate and sulfuric acid is blackened in less than a minute by the odorless solution. The color tone of the silver picture is very similar to the tone of a picture produced with pure alkaline sulfur.

Der' für das Verfahren erforderliche Entwickler kann auch in fester Form unter Zusatz des Thiosinamins oder einer entsprechenden geruchlosen Schwefelverbindung in den Handel gebracht werden.The developer required for the process can also work in solid Form with the addition of thiosinamine or a corresponding odorless sulfur compound be put on the market.

Claims (1)

PATENTANSPRUCH Verfahren zur Umkehrentwicklung lichtempfindlicher Halogensilberschichten ohne Zwischenbelichtung, dadurch gekennzeichnet, daß nach dem Herauslösen des Silberbildes die zweite Entwicklung mit Hilfe eines alkalischen, geringe Mengen von geruchlosen Schwefelverbindungen, insbesondere Thiosinamin, enthaltenden Entwicklers vorgenommen wird.PATENT CLAIM Process for reverse development more light-sensitive Halogen silver layers without intermediate exposure, characterized in that according to the removal of the silver image, the second development with the help of an alkaline, Containing small amounts of odorless sulfur compounds, especially thiosinamine Developer is made.
DEI40458D 1931-01-18 1931-01-18 Process for the reversal development of photosensitive halogen silver layers without intermediate exposure Expired DE571026C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DEI40458D DE571026C (en) 1931-01-18 1931-01-18 Process for the reversal development of photosensitive halogen silver layers without intermediate exposure

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEI40458D DE571026C (en) 1931-01-18 1931-01-18 Process for the reversal development of photosensitive halogen silver layers without intermediate exposure

Publications (1)

Publication Number Publication Date
DE571026C true DE571026C (en) 1933-03-01

Family

ID=7190314

Family Applications (1)

Application Number Title Priority Date Filing Date
DEI40458D Expired DE571026C (en) 1931-01-18 1931-01-18 Process for the reversal development of photosensitive halogen silver layers without intermediate exposure

Country Status (1)

Country Link
DE (1) DE571026C (en)

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