DE509399C - Process for the production of artificial horsehair - Google Patents
Process for the production of artificial horsehairInfo
- Publication number
- DE509399C DE509399C DESCH82312D DESC082312D DE509399C DE 509399 C DE509399 C DE 509399C DE SCH82312 D DESCH82312 D DE SCH82312D DE SC082312 D DESC082312 D DE SC082312D DE 509399 C DE509399 C DE 509399C
- Authority
- DE
- Germany
- Prior art keywords
- production
- glutin
- luster
- horsehair
- machine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims description 13
- 238000004519 manufacturing process Methods 0.000 title claims description 7
- SYUXAJSOZXEFPP-UHFFFAOYSA-N glutin Natural products COc1c(O)cc2OC(=CC(=O)c2c1O)c3ccccc3OC4OC(CO)C(O)C(O)C4O SYUXAJSOZXEFPP-UHFFFAOYSA-N 0.000 claims description 10
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 9
- 150000003839 salts Chemical class 0.000 claims description 9
- 239000002932 luster Substances 0.000 claims description 8
- 239000004927 clay Substances 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 239000003292 glue Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 229920002955 Art silk Polymers 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- 239000001828 Gelatine Substances 0.000 description 2
- RJKFOVLPORLFTN-LEKSSAKUSA-N Progesterone Chemical compound C1CC2=CC(=O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H](C(=O)C)[C@@]1(C)CC2 RJKFOVLPORLFTN-LEKSSAKUSA-N 0.000 description 2
- 238000007792 addition Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000004043 dyeing Methods 0.000 description 2
- 229920000159 gelatin Polymers 0.000 description 2
- 235000019322 gelatine Nutrition 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 1
- DCXXMTOCNZCJGO-UHFFFAOYSA-N Glycerol trioctadecanoate Natural products CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 229940037003 alum Drugs 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/45—Oxides or hydroxides of elements of Groups 3 or 13 of the Periodic Table; Aluminates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/15—Proteins or derivatives thereof
- D06M15/155—Treatment in the presence of salts derived from amphoteric metal hydroxides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Description
Verfahren zur Herstellung von künstlichen Roßhaar Unter den verschiedensten Bezeichnungen finden sich seit längerer Zeit Erzeugnisse ini Handel, die das natürliche Roßhaar ersetzen sollen. Es sind dies in der Hauptsache Proilukte aus fier Industrie der künstlichen Seide. Kunstseide und KunstseHeroßhaar führen in diesem Fall ihren Ursprung .auf das gleiche Ausgangsmaterial zurück.Process for the production of artificial horsehair Among the most diverse For a long time, names have been found in products in trade that denote the natural To replace horsehair. These are mainly products from industry of artificial silk. Artificial silk and synthetic herringbone hair lead in this case Origin. To the same starting material.
Eine zweite Art Roßhaarersatz bilden die mit Visco;s,e überzogenen Fäden aus Baumwolle un l anderen Textilmaterialien.A second type of horsehair substitute are those coated with Visco; s, e Threads of cotton and other textile materials.
Das sogenannte Eisengarn, auch Glanzgarn genannt, wird häufig ebenfalls als künstliches Roßhaar bezeichnet und ist als dritte Gruppe in der Reihe dieser Produkte zu betrachten.The so-called iron yarn, also called glossy yarn, is also often used referred to as artificial horsehair and is the third group in this series Products to look at.
Eisengarn wird hergestellt durch Imprägnieren von Baumwolle im Strang und nachfolgendes Lüstrieren. Hauptbestandteil der Appreturmasse ist Stärke, die Zusätze von Seife, Wachs, Stearin, Paraffin, öl u. dgl. erhält.Iron yarn is made by impregnating cotton in a strand and subsequent lusting. The main component of the finishing mass is starch, which Additions of soap, wax, stearin, paraffin, oil and the like.
Stärke füllt den Faden, Ö:1 und die anderen Beimengungen bedingen Glanz. Gleichzeitig soll auch die Gleitfähigkeit vor der Lüstrermaschine erhöht werden, um ein Verbrennen des Fadens zu verhüten. (Deutscher Färberkalender 192;, Seite 55 bis 85).Strength fills the thread, Ö: 1 and the other additions Shine. At the same time, the sliding ability in front of the luster machine should also be increased to prevent the thread from burning. (German Färberkalender 192 ;, Pages 55 to 85).
Das vorliegende Verfahren ist gekennzeichnet durch die Verwendung von Glutin in Verbindung mit Tonerdesalzen.The present method is characterized by the use of glutin in connection with clay salts.
An sich ist die Kombination Glutin-Toner@de nicht neu. Sie stellt ein seit langem bekanntes Appreturmittel dar. Aus der Fach-Literatur ergibt sich aber eindeutig, daß Ton.-erdesalze in diesem Fall .-dazu dienen, Glutin zu »härten«, es wasserunlöslich zu machen. Immer wieder kehrt in den Patentschriften und in der einschlägigen Literatur die Bezeichnung »härten« wieder. (Dr. K i ß41 i n g , %Ionographien aus dein Gebiet der Fettchemie, Band 2, Leim und Gelatine, Seite 13,4, von »Härtungsversuchen und Härtungsproblemen«.) Gerade diese Eigenschaft der Tonerdesalze, zu härten, ist aber für die Ausführung des vorliegenden Verfahrens belanglos. Es darf nicht einmal so viel Tonerde zugesetzt werden, daß eine vollständige Fällung (Härtung) des Glutims eintritt; die Glutinlösung darf nur viskoaser werden. Es ist nicht beabsichtigt, das Glutin zu härten, schon deshalb, weil dadurch der Endzweck, einen brauchbaren Textilfaden zu erhalten, der, veredelt, den vielfachen Manipulationen industrieller Färbereimethoden einwandfrei standhält, überhaupt nicht zu erreichen ist. Das Reaktionsprodukt lutin-Tonerde ist eben nur relativ wasserfest, oder, um sich eines Ausdrucks in dem obenerwähuten Kißlingschen Werk zu bedienen, nur »sogenannt wasserfest«. »Alaun fällt Leim als durchscheinende farblose Masse«. (A n d e s Fabrikation der Papierstoffwaren, Seite 98.) Diese glasige Masse auf dem Faden mit der Lüstriermasch ine trocken gebürstet ist ungemein quellungsfähig und in diesem Zustand durchaus nicht widerstandsfähig. Tonerdeverbindungen als härtende Substanz im hisherigen Sinne-der Fachliteratur für das beänspruchte Verfahren benutzen zu wollen, wäre also durchaus@zwecklos.In itself, the combination of Glutin-Toner @ de is nothing new. She poses a finishing agent that has been known for a long time. The technical literature shows but clearly that clay - earth salts in this case - serve to "harden" glutin, to make it insoluble in water. Again and again in the patent specifications and in the relevant literature the term "harden" again. (Dr. K i ß41 i n g,% ionographs from your area of fat chemistry, Volume 2, glue and gelatine, page 13.4, of »Hardening tests and hardening problems «.) It is precisely this property of the alumina salts of hardening that is but irrelevant for the execution of the present procedure. It may not even be so much clay is added that a complete precipitation (hardening) of the glutime entry; the glutin solution should only become viscous. It is not intended to harden the glow, if only because it is the ultimate end, a useful one To obtain textile thread that, refines, the multiple manipulations of industrial Flawlessly withstands dyeing methods, cannot be achieved at all. The reaction product Lutin clay is only relatively waterproof, or to express yourself in to use the above-mentioned Kißling work, only "so-called waterproof". "Alum glue falls as a translucent, colorless mass «. (A n d s production of paper goods, Page 98.) Dry-brushed this glassy mass on the thread with a luster machine is extremely capable of swelling and in this state it is by no means resistant. Alumina compounds as a hardening substance in the traditional sense of the specialist literature for what is claimed To want to use a procedure would therefore be @ pointless.
Wesentlich ist, daß nicht gehärtet, also das Glutin nicht vollständiggefällt wird.It is essential that it is not hardened, i.e. the glowin does not completely precipitate will.
Im umgekehrten Falle treten trotz Behandlung der Bürsten der Lü.striermaschine mit Paraffin und Fett beim Bürsten sofort Verbrennungen ein, die derart stark sein können, daß sich ein intensiver Geruch nach verbranntem Horn bemerkbar macht.In the opposite case, this occurs despite the treatment of the brushes of the ventilation machine with paraffin and grease when brushing immediately burns that are so severe that an intense odor of burnt horn becomes noticeable.
Die Erhöhung der Viskosität der Glutinlösung durch geeignete Zusätze ist schon deshalb nötig, weil durch die rasch rotierenden Bürsten der Lüstriermaschine höhere Wärmegrade auftreten, andererseits »die Viskosität einer Glutinlösung« bei einer Erhöhung -der Temperatur von 21 auf 31' C um etwa iooo % sinkt (Band 2 der Monographien aus dem Gebiet der Fettchemie, Seite 6).Increasing the viscosity of the glutin solution through suitable additives is necessary because of the rapidly rotating brushes of the luster machine higher degrees of warmth occur, on the other hand "the viscosity of a glutin solution" an increase in temperature from 21 to 31 ° C by about 100% (Volume 2 of the Monographs from the field of oleochemistry, page 6).
Soll -der mit Glutin-Tonerde lüstrierte Faden für die Zwecke der Färberei und andere Zwecke hinreichend widerstandsfähig gemacht werden, so bedarf @es der Weiterbehandlung nach anderen Verfahren.Should -the thread luscious with glutinous clay for the purposes of dyeing and other purposes are made sufficiently resistant, @es need that Further treatment according to other procedures.
Beispiel Garn in Strangform wird mit einer Glutinlösung :imprägniert, nach dem Ausquetschen mit einer Tonerdeverbindung behandelt und noch feucht auf der Lüstriermaschine trockengebürstet.Example yarn in strand form is impregnated with a glutin solution: Treated with an alumina compound after squeezing and still moist the luster machine dry-brushed.
Der Arbeitsvorgang kann auch in umgekehrter Reihenfolge stattfinden, derart, daß das Garn zuerst mit dem Tonerdesalz und dann mit der G.lutinlö.sung imprägniert wird.The work process can also take place in reverse order, in such a way that the yarn is first washed with the alumina salt and then with the G.lutin solution is impregnated.
Die Lösungen von Tonerdesalzen und umgekehrt von Glutin können weiter erst auf der Lüstriermaschine auf .das Garn aufgetragen werden.The solutions of alumina salts and vice versa of glutin can continue can only be applied to the yarn on the luster machine.
Erwähnt muß werden, daß die zahlreichen Qualitätsdifferenzen, die sich bei .den im Handel befindlichen Sorten von Glutin in Form von Leim und Gelatine zeigen -Unterschiede, die auf Verunreinigungen und die durch sie bedingten Strukturverschiedenheiten der sich hildendenGele zurückzuführen sind -, naturgemäß auch Verschiedenheiten im Endresultat .des ausgeübten Verfahrens bedingen.It must be mentioned that the numerous quality differences that the types of glutin available on the market in the form of glue and gelatine show differences based on impurities and the structural differences caused by them can be traced back to the gels that are formed - naturally also differences in the end result of the procedure carried out.
Claims (3)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DESCH82312D DE509399C (en) | 1927-04-05 | 1927-04-05 | Process for the production of artificial horsehair |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DESCH82312D DE509399C (en) | 1927-04-05 | 1927-04-05 | Process for the production of artificial horsehair |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE509399C true DE509399C (en) | 1930-10-08 |
Family
ID=7442498
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DESCH82312D Expired DE509399C (en) | 1927-04-05 | 1927-04-05 | Process for the production of artificial horsehair |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE509399C (en) |
-
1927
- 1927-04-05 DE DESCH82312D patent/DE509399C/en not_active Expired
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