DE45620C - Process for the preparation of concentrated chlorine gas from dilute chlorine gas mixtures - Google Patents
Process for the preparation of concentrated chlorine gas from dilute chlorine gas mixturesInfo
- Publication number
- DE45620C DE45620C DENDAT45620D DE45620DA DE45620C DE 45620 C DE45620 C DE 45620C DE NDAT45620 D DENDAT45620 D DE NDAT45620D DE 45620D A DE45620D A DE 45620DA DE 45620 C DE45620 C DE 45620C
- Authority
- DE
- Germany
- Prior art keywords
- chlorine gas
- chlorine
- preparation
- dilute
- concentrated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- KZBUYRJDOAKODT-UHFFFAOYSA-N chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 title claims description 10
- 239000000203 mixture Substances 0.000 title claims description 6
- 238000000034 method Methods 0.000 title claims description 4
- 238000002360 preparation method Methods 0.000 title claims 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N HCl Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- 238000010438 heat treatment Methods 0.000 claims description 6
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 4
- CSNNHWWHGAXBCP-UHFFFAOYSA-L mgso4 Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims description 4
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 4
- 229910052943 magnesium sulfate Inorganic materials 0.000 claims description 2
- 235000019341 magnesium sulphate Nutrition 0.000 claims description 2
- 239000010446 mirabilite Substances 0.000 claims description 2
- 239000001103 potassium chloride Substances 0.000 claims description 2
- 235000011164 potassium chloride Nutrition 0.000 claims description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 2
- 239000011780 sodium chloride Substances 0.000 claims description 2
- 235000002639 sodium chloride Nutrition 0.000 claims description 2
- RSIJVJUOQBWMIM-UHFFFAOYSA-L sodium sulfate decahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].[O-]S([O-])(=O)=O RSIJVJUOQBWMIM-UHFFFAOYSA-L 0.000 claims description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L MgCl2 Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims 2
- 229910001629 magnesium chloride Inorganic materials 0.000 claims 1
- 235000011147 magnesium chloride Nutrition 0.000 claims 1
- 239000000460 chlorine Substances 0.000 description 12
- 229910052801 chlorine Inorganic materials 0.000 description 11
- ZAMOUSCENKQFHK-UHFFFAOYSA-N chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 11
- 238000010521 absorption reaction Methods 0.000 description 5
- 239000007789 gas Substances 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000005755 formation reaction Methods 0.000 description 3
- ZKQDCIXGCQPQNV-UHFFFAOYSA-N Calcium hypochlorite Chemical compound [Ca+2].Cl[O-].Cl[O-] ZKQDCIXGCQPQNV-UHFFFAOYSA-N 0.000 description 2
- 238000005660 chlorination reaction Methods 0.000 description 2
- -1 chlorine-calcium Chemical compound 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-N Carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- QWPPOHNGKGFGJK-UHFFFAOYSA-N Hypochlorous acid Chemical class ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 description 1
- MFSIEROJJKUHBQ-UHFFFAOYSA-N O.[Cl] Chemical compound O.[Cl] MFSIEROJJKUHBQ-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B7/00—Halogens; Halogen acids
- C01B7/01—Chlorine; Hydrogen chloride
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paper (AREA)
Description
KAISERLICHESIMPERIAL
PATENTAMT.PATENT OFFICE.
Bekanntlich verbindet sich das Chlorgas mit gut gekühltem Wasser zu einer krystallinischen Verbindung, Chlorhydrat genannt, welches angeblich die Formel Cl2 + 10 H2O besitzt und daher 27,7 pCt. Chlor enthält.As is well known, the chlorine gas combines with well-cooled water to form a crystalline compound, called chlorohydrate, which supposedly has the formula Cl 2 + 10 H 2 O and therefore 27.7 pCt. Contains chlorine.
Erfinder benutzen nun die Eigenschaft des Chlors, dieses Hydrat zu bilden, um das Chlorgas aus Gasgemischen jeder Art abzuscheiden. Das Chlorhydrat soll zur Chlorentwickelung für Chlorirungen, Darstellung von Bleichflüssigkeiten, von Chlorkalk und anderen unterchlorigsauren Salzen Verwendung finden.Inventors now use the property of chlorine to form this hydrate to produce the chlorine gas separated from gas mixtures of any kind. The chlorine hydrate is supposed to develop chlorine for Chlorination, representation of bleaching liquids, of chlorinated lime and other hypochlorous acids Salts are used.
Zur Abscheidung des Chlors und Bildung des Chlorhydrats haben wir folgenden Apparat construirt. Das Gasgemisch wird durch eine gröfsere Anzahl flacher Tröge geleitet, wie sie in Fig. ι im Längsschnitt, Fig. 2 im Querschnitt und Fig. 3 im Grundrifs skizzirt sind. Jeder dieser Tröge wird bis circa zur Hälfte mit Wasser gefüllt, welches durch ein Röhrensystem C, in dem eine stark abgekühlte Chlor-• calciumlösung circulirt, bis nahe zu seinem Gefrierpunkte abgekühlt wird. Die von den Chlorentwicklern herströmenden, gut gekühlten Gase treten bei der abgebildeten Stellung der Hähne durch ein Zweigrohr Z des Chlorzuleitungsrohres, welches unter das Flüssigkeitsniveau W taucht, in den ersten Absorptionstrog ein. Die nicht absorbirten Gase entweichen durch die Röhre H in den zweiten und aus diesem in einen dritten, vierten und fünften Absorptionstrog. Das Chlorgas löst sich zunächst im gekühlten Wasser auf, indem sich ein bei o° gesättigtes Chlorwasser bildet, und hierauf beginnt bei weiterer Zufuhr von Chlor eine successive Abscheidung des gelblichgrünen, krystallinischen Körpers, des Chlorhydrats. Zur Beobachtung und Ueberwachung dieses Processes ist in jeden Kasten ein Glasfenster S eingesetzt, und sobald der ganze Inhält des Troges zu einem breiartigen Magma erstarrt ist und keine sichtbare Absorption des Chlorgases mehr stattfindet, wird dieser Trog durch Oerfnen des Hahnes E und Schliefsen der Hähne Z und H ausgeschaltet. We have constructed the following apparatus for the separation of the chlorine and the formation of the hydrochloride. The gas mixture is passed through a larger number of flat troughs, as they are sketched in Fig. 1 in longitudinal section, Fig. 2 in cross section and Fig. 3 in outline. Each of these troughs is about half filled with water, which is cooled down to near its freezing point through a system of tubes C, in which a strongly cooled chlorine-calcium solution circulates. The well-cooled gases flowing from the chlorine generators enter the first absorption trough through a branch pipe Z of the chlorine feed pipe, which dips below the liquid level W , when the taps are in the position shown. The unabsorbed gases escape through the tube H into the second and from this into a third, fourth and fifth absorption trough. The chlorine gas first dissolves in the cooled water, in that a chlorine water saturated at 0 ° is formed, and then, with further addition of chlorine, a successive separation of the yellowish-green, crystalline body, the hydrochloride, begins. To observe and monitor this process, a glass window S is placed in each box, and as soon as the entire contents of the trough has solidified into a pulpy magma and there is no visible absorption of the chlorine gas, this trough is opened by opening the valve E and closing the valve Z and H switched off.
Zur Erzielung concentrirten Chlorgases wird das Chlorhydrat in denselben Trögen zersetzt. Zunächst wird zu diesem Zwecke die Kühlung unterbrochen und die Kammer durch Oeffhen des Hahnes F mit den Chlorirungsgefäfsen (Chlorkalkkammern etc.) in Verbindung gesetzt. Durch Erwärmen wird nun die Zersetzung des Chlorhydrats eingeleitet, welche unter Entwickelung eines lebhaften Stromes von reinem Chlorgas von statten geht. Die Erwärmung kann nun geschehen durch Einleiten von Dampf durch die Röhre D oder durch Erhitzen des Troges von aufsen vermittelst eines Wasserbades , oder endlich durch quer durch den Kasten gehende Heizröhren. Sobald das Chlor durch Erwärmen bis auf 40 bis 500 fast vollständig ausgetrieben ist, wird der Trog wieder abgekühlt und wieder in den Betrieb eingeschaltet, und zwar zweckmäfsig so, dafs die neu einzuschaltenden Absorptionsgefäfse jeweilen am Ende des Systems angefügt werden.In order to obtain concentrated chlorine gas, the hydrochloride is decomposed in the same troughs. For this purpose the cooling is first interrupted and the chamber is connected to the chlorination vessels (chlorinated lime chambers, etc.) by opening the tap F. The decomposition of the hydrochloride is then initiated by heating, which proceeds with the development of a lively stream of pure chlorine gas. The heating can now be done by introducing steam through the tube D or by heating the trough from the outside by means of a water bath, or finally by heating tubes going across the box. As soon as the chlorine is almost completely expelled by heating up to 40 to 50 0 , the trough is cooled down again and put back into operation, expediently in such a way that the new absorption vessels to be switched on are added at the end of the system.
Die oben beschriebene Methode erlaubt nicht nur, auf billige und zweckmäfsige Weise das Chlor aus Gasgemischen mit Luft und Salzsäure abzuscheiden und zu verwerthen, sondern auch aus Mischungen mit Kohlensäure, was nach den anderen Methoden fast undurchführ-The method described above not only allows, in a cheap and expedient way, that Separate and utilize chlorine from gas mixtures with air and hydrochloric acid, rather also from mixtures with carbon dioxide, which is almost impracticable according to the other methods.
bar ist; denn es verhindert, wie wir gefunden haben, weder Salzsäure noch Kohlensäure die Bildung des Chlorhydrats.is bar; for it prevents, as we have found, neither hydrochloric acid nor carbonic acid Formation of the chlorohydrate.
An Stelle von Wasser von o° lassen sich zur Absorption des Chlors bezw. zur Bildung des Chlorhydrats nach dem beschriebenen Verfahren auch ebenso stark gekühlte wässerige Lösungen von Kochsalz, Glaubersalz, Chlormagnesium, Chlorkalium, Magnesiumsulfat oder verdünnte Salz- oder Schwefelsäure benutzen.Instead of water from o °, you can use the Absorption of the chlorine or for the formation of the chlorohydrate by the process described also strongly chilled aqueous solutions of common salt, Glauber's salt, chlorine magnesium, Use potassium chloride, magnesium sulphate or diluted hydrochloric or sulfuric acid.
Claims (1)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE45620C true DE45620C (en) |
Family
ID=320776
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DENDAT45620D Expired - Lifetime DE45620C (en) | Process for the preparation of concentrated chlorine gas from dilute chlorine gas mixtures |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE45620C (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2392930A1 (en) * | 1976-09-07 | 1978-12-29 | Asahi Glass Co Ltd | PURIFICATION OF CHLORINE BY FORMING CHLORINE HYDRATE CRYSTALS |
| WO2007134720A1 (en) * | 2006-05-23 | 2007-11-29 | Bayer Materialscience Ag | Process for preparing chlorine from hydrogen chloride and oxygen |
| JP2021057169A (en) * | 2019-09-30 | 2021-04-08 | 日本電子株式会社 | Sample chip workbench and retainer |
-
0
- DE DENDAT45620D patent/DE45620C/en not_active Expired - Lifetime
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2392930A1 (en) * | 1976-09-07 | 1978-12-29 | Asahi Glass Co Ltd | PURIFICATION OF CHLORINE BY FORMING CHLORINE HYDRATE CRYSTALS |
| WO2007134720A1 (en) * | 2006-05-23 | 2007-11-29 | Bayer Materialscience Ag | Process for preparing chlorine from hydrogen chloride and oxygen |
| JP2021057169A (en) * | 2019-09-30 | 2021-04-08 | 日本電子株式会社 | Sample chip workbench and retainer |
| US11679489B2 (en) | 2019-09-30 | 2023-06-20 | Jeol Ltd. | Sample chip worktable and retainer |
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