DE445099C - Process for the preparation of as an emulsifying agent u. Usable products - Google Patents

Process for the preparation of as an emulsifying agent u. Usable products

Info

Publication number
DE445099C
DE445099C DEB106742D DEB0106742D DE445099C DE 445099 C DE445099 C DE 445099C DE B106742 D DEB106742 D DE B106742D DE B0106742 D DEB0106742 D DE B0106742D DE 445099 C DE445099 C DE 445099C
Authority
DE
Germany
Prior art keywords
saponification
paraffin
content
amount
oxidation product
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DEB106742D
Other languages
German (de)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IG Farbenindustrie AG
Original Assignee
IG Farbenindustrie AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IG Farbenindustrie AG filed Critical IG Farbenindustrie AG
Priority to DEB106742D priority Critical patent/DE445099C/en
Application granted granted Critical
Publication of DE445099C publication Critical patent/DE445099C/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
    • C09K23/38—Alcohols, e.g. oxidation products of paraffins
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/129—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of thirty or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/04—Groups 2 or 12
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2060/00—Chemical after-treatment of the constituents of the lubricating composition
    • C10N2060/04—Oxidation, e.g. ozonisation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)

Description

P A T E N T A N S P R U C H: Weiterbildung des Verfahrens des Hauptpatentes 438I80 zur Gewinnung von als Emulgierungsmittel u. dgl. verwendbaren Produkten, dadurch gekennzeichnet, daß hier die Oxydationsprodukte der Paraffinkohlenwasserstoffe mit anderen basischen Mitteln ganz oder teilweise verseift werden. P A T E N T A N S P R U C H: Further development of the process of the main patent 438I80 for the production of products that can be used as emulsifying agents and the like, characterized in that here the oxidation products of the paraffin hydrocarbons be wholly or partially saponified with other basic agents.

Claims (1)

Verfahren zur Herstellung von als Emulgierungsmittel u. dgl. verwendbaren Produkten.Process for producing those useful as emulsifying agents and the like Products. Zusatz zum Patent 438 I80. Addition to patent 438 I80. In dem Hauptpatent 438 I80 ist ein Ver fahren zur Gewinnung von als Emulgierungsmittel u. dgl. verwendbaren Produkten mit einem hohen Gehalt an Unverseifbarem beschrieben, das darin besteht, daß Oxydationsprodukte von festen Paraffinkohlenwasserstoffen mit Alkalihydroxyd verseift werden. In the main patent 438 I80 is a process for the extraction of than Emulsifying agents and the like usable products having a high content of unsaponifiables described, which consists in the oxidation products of solid paraffin hydrocarbons saponified with alkali hydroxide. Es wurde nun gefunden, daß zu dieser Verseifung sich statt der Alkalihydroxyde vorteilhaft auch andere basisch wirkende Mittel, wie z. B. Alkalikarbonate, Erdalkalihydroxyde, Ammoniak usw., verwenden lassen. Man kann hierbei unter Druck arbeiten und ferner das Verseifungsmittel in beliebiger Weise, z. B. in fester Form, in Lösung, in gasförmigem Zustand usw., zur Einwirkung bringen. Gegebenenfalls ist es zweckmäßig, vor dem Zusammengeben sowohl das Oxydationsprodukt als auch das Verseifungsmittel zu erwärmen.It has now been found that this saponification takes place instead of alkali metal hydroxides other basic agents such. B. Alkali carbonates, alkaline earth hydroxides, Let ammonia, etc., be used. You can work under pressure here and further the saponifying agent in any manner, e.g. B. in solid form, in solution, in gaseous form State, etc., to act. It may be useful to do this before Combine both the oxidation product and the saponifying agent to heat. Beispiel I. Example I. Ein Oxydationsprodukt von Paraffin mit einem Gehalt von etwa 55 bis 6o Prozent Unverseifbarem wird bei I20° unter Rühren mit der Hälfte der aus der Verseifungszahl berechneten Menge calcinierter Soda versetzt. Unter Gasentwicklung wird eine klare Schmelze erhalten, die in warmem Wasser außerordentlich leicht kolloidal löslich ist Beispiel 2. An oxidation product of paraffin with a content of about 55 to 60 percent of unsaponifiable material is extracted at 120 ° while stirring with half of the amount Saponification number calculated amount of calcined soda added. Under gas evolution a clear melt is obtained, which is extremely slightly colloidal in warm water Example 2 is soluble. Ein Oxydationsprodukt von Paraffin mit einem Gehalt von 40 bis 45 Prozent Unverseifbarem wird mit der aus der Verseifungszahl errechneten Menge an gelöschtem Kalk bei 120 bis I300 verrührt. Unter Schäumen tritt klare Lösung ein. An oxidation product of paraffin with a content of 40 to 45 Percent of unsaponifiable matter is calculated from the amount of saponification slaked lime stirred at 120 to I300. A clear solution occurs with foaming. Man kann aus dem Verseifungsprodukt durch Verschmelzen mit einem Maschinenöl leicht konsistente Maschinenfette erhalten. One can from the saponification product by fusing with one Machine oil to obtain slightly consistent machine greases. Beispiel 3. Example 3. Ein Oxydationsprodukt von Paraffin mit einem Gehalt von 40 bis 45 Prozent Unverseifbarem wird mit der Hälfte der aus der Verseifungszahl errechneten Menge 2oprozentigem Ammoniakwasser im Rührautoklaven bei IOO° verseift. Man erhält eine klare Schmelze, die sich in warmem Wasser restlos kolloidal auflöst. An oxidation product of paraffin with a content of 40 to 45 Percent of unsaponifiable matter is calculated with half that from the saponification number Amount of 2% ammonia water saponified in a stirred autoclave at 100 °. You get a clear melt that dissolves completely colloidally in warm water.
DEB106742D 1922-10-07 1922-10-07 Process for the preparation of as an emulsifying agent u. Usable products Expired DE445099C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DEB106742D DE445099C (en) 1922-10-07 1922-10-07 Process for the preparation of as an emulsifying agent u. Usable products

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEB106742D DE445099C (en) 1922-10-07 1922-10-07 Process for the preparation of as an emulsifying agent u. Usable products

Publications (1)

Publication Number Publication Date
DE445099C true DE445099C (en) 1927-06-03

Family

ID=6991708

Family Applications (1)

Application Number Title Priority Date Filing Date
DEB106742D Expired DE445099C (en) 1922-10-07 1922-10-07 Process for the preparation of as an emulsifying agent u. Usable products

Country Status (1)

Country Link
DE (1) DE445099C (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE871047C (en) * 1943-03-22 1953-03-19 Henkel & Cie Gmbh Process for the production of lubricating oil emulsions
DE879274C (en) * 1943-03-22 1953-06-11 Henkel & Cie Gmbh Process for the production of lubricating oil emulsions

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE871047C (en) * 1943-03-22 1953-03-19 Henkel & Cie Gmbh Process for the production of lubricating oil emulsions
DE879274C (en) * 1943-03-22 1953-06-11 Henkel & Cie Gmbh Process for the production of lubricating oil emulsions

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