DE4304491A1 - Use of hard fillers in radiation-curable lacquers, coatings and printing inks in order to increase the abrasion resistance - Google Patents

Use of hard fillers in radiation-curable lacquers, coatings and printing inks in order to increase the abrasion resistance

Info

Publication number
DE4304491A1
DE4304491A1 DE4304491A DE4304491A DE4304491A1 DE 4304491 A1 DE4304491 A1 DE 4304491A1 DE 4304491 A DE4304491 A DE 4304491A DE 4304491 A DE4304491 A DE 4304491A DE 4304491 A1 DE4304491 A1 DE 4304491A1
Authority
DE
Germany
Prior art keywords
radiation
coatings
abrasion resistance
printing inks
increase
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
DE4304491A
Other languages
German (de)
Inventor
Thomas Dr Walter
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Walter Thomas Dr 32049 Herford De
Original Assignee
Zeller and Gmelin GmbH and Co KG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zeller and Gmelin GmbH and Co KG filed Critical Zeller and Gmelin GmbH and Co KG
Priority to DE4304491A priority Critical patent/DE4304491A1/en
Publication of DE4304491A1 publication Critical patent/DE4304491A1/en
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • C09D167/06—Unsaturated polyesters having carbon-to-carbon unsaturation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
    • C08L71/02—Polyalkylene oxides
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/10—Printing inks based on artificial resins
    • C09D11/101—Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
    • C09D175/16—Polyurethanes having carbon-to-carbon unsaturated bonds having terminal carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/66—Additives characterised by particle size
    • C09D7/69—Particle size larger than 1000 nm
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
    • C08K3/013—Fillers, pigments or reinforcing additives

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Nanotechnology (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)
  • Paints Or Removers (AREA)

Abstract

The document describes the use of hard fillers in radiation-curable systems such as lacquers, coatings and printing inks in order to increase the abrasion resistance.

Description

Gegenstand der Erfindung ist die Verwendung gemäß Patentan­ spruch.The invention relates to the use according to Patentan say.

Im Rahmen der erfindungsgemäßen Verwendung werden strahlenhärt­ baren Systemen, worunter hier UV-härtbare und elektronen­ strahlhärtbare Systeme zu verstehen sind, pulverförmige harte Füllstoffe zugemischt.Within the scope of the use according to the invention, radiation-hardening takes place systems, including UV-curable and electrons radiation-curable systems are to be understood as powdery hard Fillers added.

Derartige strahlenhärtbare Systeme, bei denen es sich insbe­ sondere um strahlenhärtbare Lacke, Beschichtungen und Druck­ farben handelt, sind vorzugsweise auf Basis der in der Strah­ lenhärtungschemie bekannten Acrylsäureester (wie z. B. Polyu­ rethan-, Polyester-, Polyether- oder Epoxiacrylate), aber auch auf Basis der sogenannten ungesättigten Polyester oder auf Basis kationisch härtender Bindemittel, wie Epoxiverbindungen, cycloaliphatische Epoxiverbindungen, Vinylether oder -ester aufgebaut. Die pulverförmigen harten Füllstoffe erhöhen nun in den ausgehärteten Systemen die Abriebfestigkeit in be­ deutendem Ausmaß.Radiation-curable systems of this type, in particular especially radiation-curable paints, coatings and printing colors are preferably based on those in the beam oil curing chemistry known acrylic acid esters (such as Polyu rethane, polyester, polyether or epoxy acrylates), but also based on the so-called unsaturated polyester or Basis of cationically curing binders, such as epoxy compounds, cycloaliphatic epoxy compounds, vinyl ethers or -ester built. Increase the powdery hard fillers now in the cured systems the abrasion resistance in be significant extent.

Als pulverförmige Füllstoffe hierfür kommen insbesondere Quarz, synthetisches Siliciumdioxid, Basalt, Glasmehl, Glasku­ geln oder Glasfasern, Siliciumcarbid, Wolframcarbid oder Ko­ rund in Frage.Powdery fillers for this come in particular Quartz, synthetic silicon dioxide, basalt, glass powder, glass ku gel or glass fibers, silicon carbide, tungsten carbide or Ko round in question.

Diese Füllstoffe haben bevorzugt eine mittlere Teilchengröße im Bereich von 1 bis 50 µm, besonders bevorzugt im Bereich von 5 bis 20 µm. These fillers preferably have an average particle size in the range from 1 to 50 μm, particularly preferably in the range from 5 to 20 µm.  

Die Füllstoffe können für sich alleine oder in Mischung zum Einsatz gelangen.The fillers can be used alone or as a mixture Get involved.

Die Einsatzmengen dieser Füllstoffe betragen bevorzugt 1 bis 20 Gew.%, besonders bevorzugt 5 bis 10 Gew.%, bezogen auf die Gesamtformulierung.The amounts of these fillers used are preferably 1 to 20% by weight, particularly preferably 5 to 10% by weight, based on the Overall wording.

Hochabriebfeste Systeme der beschriebenen Art können zum Ein­ satz kommen insbesondere in folgenden Bereichen:Highly abrasion-resistant systems of the type described can be used come especially in the following areas:

  • 1. als Lack oder Beschichtung für Holz und Holzwerkstoffe, vorzugsweise bei Spanplatten, MDF (= mitteldichte Faser­ platten), Parkett oder Furnier;1. as a lacquer or coating for wood and wood-based materials, preferably with particle board, MDF (= medium density fiber panels), parquet or veneer;
  • 2. als Lack, Beschichtung oder Druckfarbe für Kunststoffe, insbesondere Thermoplaste, vorzugsweise Polycarbonat und PVC;2. as a varnish, coating or printing ink for plastics, in particular thermoplastics, preferably polycarbonate and PVC;
  • 3. als Lack, Beschichtung oder Druckfarbe für Papier und Karton.3. as a varnish, coating or printing ink for paper and Carton.

Dabei können diese Lacke und Beschichtungen als Ein- oder Mehrschichtsystem aufgebracht werden.These paints and coatings can be used as single or Multi-layer system can be applied.

Einsatzbereiche solcher derart beschichteter Hölzer oder Holz­ werkstoffe sind vorzugsweise Möbel, Möbelfronten, Arbeitsplat­ ten, Fußböden, Wandpaneele, Türen oder Treppen.Areas of application of such coated wood or wood Materials are preferably furniture, furniture fronts, work surfaces floors, floors, wall panels, doors or stairs.

Einsatzbereiche solcher derart beschichteter Kunststoffe sind vorzugsweise Platten oder Folien für Fußböden, Möbel, Möbel­ fronten, Schilder, Verglasungen, Profile, Autokarosserieteile, wie z. B. Kotflügel oder Stoßstangen, Koffer und weitere.Areas of application of such coated plastics are preferably sheets or foils for floors, furniture, furniture fronts, signs, glazing, profiles, car body parts, such as B. fenders or bumpers, suitcases and others.

Einsatzbereiche solcher derart beschichteter Papiere oder Kar­ tons sind vorzugsweise Dekorpapiere für die Holzwerkstoffindu­ strie, Verpackungen und weitere.Areas of application of such coated papers or cards tons are preferably decorative papers for wood-based materials strie, packaging and others.

Die erfindungsgemäß ausgestalteten Lacke und Beschichtungen können auf dem jeweiligen Substrat per Walz-, Gieß-, Spritz- oder Tauchlackierung appliziert werden. Entsprechende Druck­ farben können nach den gängigen und bekannten Druckverfahren wie Tief-, Flexo-, Offset-, Buch- oder Siebdruck aufgebracht werden.The lacquers and coatings designed according to the invention can be rolled, cast, sprayed on the respective substrate  or dip painting can be applied. Appropriate pressure colors can be printed using the usual and well-known printing processes such as gravure, flexo, offset, book or screen printing become.

Auf die beschriebene Weise lassen sich übliche strahlenhärt­ bare Systeme (Lacke, Beschichtungen und Druckfarben), die für eine Applikation im jeweiligen Einzelfall bestimmt sind, durch Zusatz der genannten Füllstoffe hinsichtlich ihrer Abriebfe­ stigkeit deutlich verbessern.Conventional radiation-curing can be carried out in the manner described systems (varnishes, coatings and printing inks) that are used for an application is determined in each individual case by Addition of the fillers mentioned with regard to their abrasion significantly improve stability.

Des weiteren erfolgt zu den erfindungsgemäß ausgestalteten Sy­ stemen vorzugsweise eine Zugabe von Hilfsstoffen (wie z. B. Mattierungsmittel, Antiabsetzmittel oder rheologische Zusatz­ stoffe), Additiven (wie z. B. Wachse, Slipadditive, Entschäu­ mer, Entlüfter, Dispergierhilfsmittel, Benetzungsmittel, Haft­ verbesserer und andere) oder organischen oder anorganischen farbgebenden Pigmenten.Furthermore, the Sy designed according to the invention takes place preferably add additives (such as e.g. Matting agent, anti-settling agent or rheological additive substances), additives (such as waxes, slip additives, defoaming mer, deaerator, dispersing agent, wetting agent, adhesive improvers and others) or organic or inorganic coloring pigments.

Die Einsatzmengen der harten Füllstoffe betragen insbesondere 1 bis 20 Gew.%, vorzugsweise 5 bis 10 Gew.%, bezogen auf die Gesamtformulierung. Der Anteil der strahlenhärtbaren Komponen­ te beträgt insbesondere 50 bis 95 Gew.%, vorzugsweise 60 bis 90 Gew.%, bezogen auf die Gesamtformulierung. Der Anteil der Hilfsstoffe beträgt insbesondere 0,5 bis 20 Gew.%, vorzugswei­ se 1 bis 15 Gew.%, bezogen auf die Gesamtformulierung. Der Anteil der Additive beträgt insbesondere 0,1 bis 5 Gew.%, vor­ zugsweise 0,5 bis 2 Gew.%, bezogen auf die Gesamtformulierung.The amounts of hard fillers used are in particular 1 to 20% by weight, preferably 5 to 10% by weight, based on the Overall wording. The proportion of radiation-curable components te is in particular 50 to 95% by weight, preferably 60 to 90% by weight, based on the overall formulation. The share of Auxiliaries are in particular 0.5 to 20% by weight, preferably two se 1 to 15% by weight, based on the total formulation. Of the The proportion of additives is in particular 0.1 to 5% by weight preferably 0.5 to 2% by weight, based on the total formulation.

Die Einarbeitung der harten Füllstoffe in das jeweilige strah­ lenhärtbare System erfolgt mit gängigen und bekannten Rühr- und Dispergieraggregaten, wie z. B. Flügelrührer, Dissolver, Kugel- oder Perlmühlen, Dreiwalzenstühle.Incorporation of the hard fillers into the respective jet oil-curable system is carried out with common and well-known stirring and dispersing units, such as. B. paddle stirrer, dissolver, Ball or pearl mills, three-roll mills.

Die nachstehenden Mengenangaben in den Ausführungsbeispielen beziehen sich auf Gewichtsprozent.The following quantities in the working examples refer to weight percent.

Die Lacke dieser Ausführungsbeispiele werden vorzugsweise mit einem Elektronenstrahler mit 175 KeV Beschleunigungsspannung bei einer Dosisleistung von 40 KGy gehärtet.The paints of these embodiments are preferably with an electron emitter with an acceleration voltage of 175 KeV hardened at a dose rate of 40 KGy.

Die vorstehenden Ausführungsbeispiele führen zu folgenden Re­ sultaten.The above embodiments lead to the following Re results.

Formulierung A: hochabriebfester, seidenmatter Gießlack für die Applikation auf Holz und Holzwerkstoffen.Formulation A: highly abrasion-resistant, silk-matt coating varnish for the application on wood and wood materials.

Formulierung B: hochabriebfester, matter Walzlack für die Ap­ plikation auf Holz und Holzwerkstoffen.Formulation B: highly abrasion-resistant, matt rolled lacquer for the ap application on wood and wood-based materials.

Formulierung D: abriebfester, seidenmatter Lack für die Walz­ applikation auf Papier und Karton.Formulation D: abrasion-resistant, silk-matt lacquer for the roller application on paper and cardboard.

Formulierung C: hochabriebfester Lack für die Walzapplikation auf Polycarbonat und auf PVC, tiefziehfähig.Formulation C: highly abrasion-resistant lacquer for roller application on polycarbonate and on PVC, thermoformable.

Durch die erfindungsgemäße Mitverwendung der harten Füllstoffe in den strahlenhärtenden Systemen läßt sich die Abriebfestig­ keit strahlengehärteter Lacke, Beschichtungen oder Druckfarben in nicht vorhersehbarer Weise signifikant erhöhen. Dieser Ef­ fekt wird noch besonders verstärkt, wenn die harten Füllstoffe durch geeignete Mittel, die ihr Absetzen im strahlenhärtbaren System verhindern, stabilisiert werden.By using the hard fillers according to the invention The abrasion resistance can be fixed in the radiation-curing systems radiation-hardened paints, coatings or printing inks  increase significantly in an unpredictable way. This ef fect is especially enhanced when the hard fillers by suitable means that prevent them from settling in the radiation-curable Prevent system from being stabilized.

Durch die erfindungsgemäße Verwendung harter Füllstoffe lassen sich besonders vorteilhafte Eigenschaften an den ausgehärteten Systemen erzielen. So ergibt z. B. die Abriebfestigkeitsprü­ fung nach DIN 53 799, Teil 4.6 mittels Taber abraser (Schleif­ papier mit 180er-Körnung, 500 g Belastung) eines gebräuchli­ chen UV-Lackes auf Parkett (Schichtdicke 70 µm) einen Abrieb­ wert von 200 Umdrehungen; dieselbe Prüfung eines Lackes nach Ausführungsbeispiel A ergibt jedoch 2500 Umdrehungen, also eine mehr als 10fach höhere Abriebfestigkeit.By using hard fillers according to the invention particularly advantageous properties of the cured Systems. So z. B. the abrasion resistance test to DIN 53 799, part 4.6 using a Taber abrasive (grinding paper with 180 grit, 500 g load) of a common Chen UV varnish on parquet (layer thickness 70 µm) an abrasion worth 200 revolutions; same test of a paint Embodiment A, however, gives 2500 revolutions, so more than 10 times higher abrasion resistance.

Claims (4)

1. Verwendung von pulverförmigen harten Füllstoffen in strah­ lenhärtbaren Lacken, Beschichtungen und Druckfarben zur Erhö­ hung der Abriebfestigkeit.1. Use of powdered hard fillers in jet oil-curable varnishes, coatings and printing inks to increase abrasion resistance. 2. Verwendung gemäß Anspruch 1, dadurch gekennzeichnet, daß der pulverförmige harte Füllstoff ausgewählt ist aus Quarz, synthetischem Siliciumdioxid, Basalt, Glasmehl, Glaskugeln, Glasfasern, Siliciumcarbid, Wolframcarbid oder Korund oder deren Mischungen.2. Use according to claim 1, characterized in that the powdery hard filler is selected from quartz, synthetic silicon dioxide, basalt, glass powder, glass balls, Glass fibers, silicon carbide, tungsten carbide or corundum or their mixtures. 3. Verwendung nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, daß der oder die pulverförmigen harten Füll­ stoffe eine mittlere Teilchengröße im Bereich von 1 bis 50 µm aufweisen.3. Use according to one of the preceding claims, characterized characterized in that the powdered hard filler substances have an average particle size in the range from 1 to 50 μm exhibit. 4. Verwendung nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, daß der oder die pulverförmigen harten Füll­ stoffe in einer Menge von 1 bis 20 Gew.%, bezogen auf die Gesamtformulierung, eingesetzt werden.4. Use according to any one of the preceding claims, characterized characterized in that the powdered hard filler substances in an amount of 1 to 20% by weight, based on the Overall formulation, can be used.
DE4304491A 1993-02-15 1993-02-15 Use of hard fillers in radiation-curable lacquers, coatings and printing inks in order to increase the abrasion resistance Withdrawn DE4304491A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DE4304491A DE4304491A1 (en) 1993-02-15 1993-02-15 Use of hard fillers in radiation-curable lacquers, coatings and printing inks in order to increase the abrasion resistance

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE4304491A DE4304491A1 (en) 1993-02-15 1993-02-15 Use of hard fillers in radiation-curable lacquers, coatings and printing inks in order to increase the abrasion resistance

Publications (1)

Publication Number Publication Date
DE4304491A1 true DE4304491A1 (en) 1994-08-18

Family

ID=6480472

Family Applications (1)

Application Number Title Priority Date Filing Date
DE4304491A Withdrawn DE4304491A1 (en) 1993-02-15 1993-02-15 Use of hard fillers in radiation-curable lacquers, coatings and printing inks in order to increase the abrasion resistance

Country Status (1)

Country Link
DE (1) DE4304491A1 (en)

Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2338959A (en) * 1998-07-03 2000-01-12 Wood Limited E Abrasion resistant floor coating composition
DE19927949A1 (en) * 1999-06-18 2000-12-21 Delo Industrieklebstoffe Gmbh Cationic curing composition, its use and process for the preparation of cured polymer compositions
US6291078B1 (en) 1997-10-22 2001-09-18 Mannington Mills, Inc. Surface coverings containing aluminum oxide
WO2002081579A2 (en) * 2000-12-08 2002-10-17 Ppg Industries Ohio, Inc. Coating compositions providing improved mar and scratch resistance and methods of using the same
EP1250395A2 (en) * 1999-12-09 2002-10-23 Valspar Sourcing, Inc. Abrasion resistant coatings
US6555216B2 (en) 1997-02-20 2003-04-29 Mannington Mill, Inc. Contrasting gloss surface coverings optionally containing dispersed wear-resistant particles and methods of making the same
WO2003062336A1 (en) * 2002-01-24 2003-07-31 Plastlac S.R.L. Paint, particularly for plastic materials, and painting method using said paint
WO2006127196A2 (en) * 2005-04-25 2006-11-30 Ppg Industries Ohio, Inc. Coating compositions providing improved mar and scratch resistance and methods of using the same
WO2007042398A1 (en) * 2005-10-07 2007-04-19 Airbus Deutschland Gmbh Polyurethane lacquers as abrasion-resistant coatings
DE102007052575A1 (en) * 2007-11-03 2009-05-07 Märzhäuser Wetzlar GmbH & Co. KG Protective layer of hard-anodized microscopic aluminum workpieces, comprises a composite-lacquer reinforced with a filler, and a hard-anodized layer that is colored black
US7678425B2 (en) 2003-03-06 2010-03-16 Flooring Technologies Ltd. Process for finishing a wooden board and wooden board produced by the process
EP2670803A1 (en) 2011-02-02 2013-12-11 Ashland Licensing And Intellectual Property, LLC Scratch resistant gelcoat
EP2147157B1 (en) 2007-04-20 2015-04-08 Center for Abrasives and Refractories Research & Development C.A.R.R.D. GmbH Anti abrasion layer
EP1454763B2 (en) † 2003-03-06 2016-06-08 Flooring Technologies Ltd. Decorative coating of a plate of wooden material
EP2158095B1 (en) 2007-05-27 2017-04-12 Thomas Schneider Planar element, and method for the production thereof
RU2715839C1 (en) * 2019-07-19 2020-03-03 Федеральное государственное автономное образовательное учреждение высшего образования "Северный (Арктический) федеральный университет имени М. В. Ломоносова" Organomineral disperse paintwork material
EP3998314A1 (en) * 2020-10-29 2022-05-18 Potters Industries, LLC Protective coating for wood products and method of making the same

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3966572A (en) * 1975-02-11 1976-06-29 Union Carbide Corporation Photocurable low gloss coatings containing silica and acrylic acid
US4003868A (en) * 1971-12-08 1977-01-18 Union Carbide Corporation Ink or coating compositions of low volatility

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4003868A (en) * 1971-12-08 1977-01-18 Union Carbide Corporation Ink or coating compositions of low volatility
US3966572A (en) * 1975-02-11 1976-06-29 Union Carbide Corporation Photocurable low gloss coatings containing silica and acrylic acid

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
KNITTEL: Lehrbuch der Lacke und Beschichtungen, 1974, S. 434 *

Cited By (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6555216B2 (en) 1997-02-20 2003-04-29 Mannington Mill, Inc. Contrasting gloss surface coverings optionally containing dispersed wear-resistant particles and methods of making the same
US7384697B2 (en) 1997-02-20 2008-06-10 Mannington Mills, Inc. Surface coverings containing aluminum oxide
US6291078B1 (en) 1997-10-22 2001-09-18 Mannington Mills, Inc. Surface coverings containing aluminum oxide
GB2338959A (en) * 1998-07-03 2000-01-12 Wood Limited E Abrasion resistant floor coating composition
DE19927949A1 (en) * 1999-06-18 2000-12-21 Delo Industrieklebstoffe Gmbh Cationic curing composition, its use and process for the preparation of cured polymer compositions
US6420450B1 (en) 1999-06-18 2002-07-16 Delo Industrieklebstoffe Gmbh & Co. Kg Cationically hardening mass, the use thereof and process for preparing hardened polymer masses
EP1250395A4 (en) * 1999-12-09 2005-06-08 Valspar Sourcing Inc Abrasion resistant coatings
EP1250395A2 (en) * 1999-12-09 2002-10-23 Valspar Sourcing, Inc. Abrasion resistant coatings
US8258225B2 (en) 2000-12-08 2012-09-04 Ppg Industries Ohio, Inc Coating compositions providing improved mar and scratch resistance and methods of using the same
WO2002081579A2 (en) * 2000-12-08 2002-10-17 Ppg Industries Ohio, Inc. Coating compositions providing improved mar and scratch resistance and methods of using the same
WO2002081579A3 (en) * 2000-12-08 2003-05-08 Ppg Ind Ohio Inc Coating compositions providing improved mar and scratch resistance and methods of using the same
CN100494297C (en) * 2002-01-24 2009-06-03 普勒斯特利克有限责任公司 Paint, particularly for plastic, and painting method using said paint
WO2003062336A1 (en) * 2002-01-24 2003-07-31 Plastlac S.R.L. Paint, particularly for plastic materials, and painting method using said paint
US7846248B2 (en) 2002-01-24 2010-12-07 Plastlac S.R.L. Paint, particularly for plastic materials, and painting method using said paint
EP1454763B2 (en) † 2003-03-06 2016-06-08 Flooring Technologies Ltd. Decorative coating of a plate of wooden material
US7678425B2 (en) 2003-03-06 2010-03-16 Flooring Technologies Ltd. Process for finishing a wooden board and wooden board produced by the process
US8016969B2 (en) 2003-03-06 2011-09-13 Flooring Technologies Ltd. Process for finishing a wooden board and wooden board produced by the process
WO2006127196A2 (en) * 2005-04-25 2006-11-30 Ppg Industries Ohio, Inc. Coating compositions providing improved mar and scratch resistance and methods of using the same
AU2006249589B2 (en) * 2005-04-25 2010-02-18 Ppg Industries Ohio, Inc. Coating compositions providing improved mar and scratch resistance and methods of using the same
WO2006127196A3 (en) * 2005-04-25 2007-03-15 Ppg Ind Ohio Inc Coating compositions providing improved mar and scratch resistance and methods of using the same
WO2007042398A1 (en) * 2005-10-07 2007-04-19 Airbus Deutschland Gmbh Polyurethane lacquers as abrasion-resistant coatings
RU2457150C2 (en) * 2005-10-07 2012-07-27 Эйрбас Оперейшнз Гмбх Polyurethane lacquers as wear-protective coatings
US9694901B2 (en) 2005-10-07 2017-07-04 Airbus Operations Gmbh Aircraft landing flap
EP2147157B1 (en) 2007-04-20 2015-04-08 Center for Abrasives and Refractories Research & Development C.A.R.R.D. GmbH Anti abrasion layer
EP2158095B1 (en) 2007-05-27 2017-04-12 Thomas Schneider Planar element, and method for the production thereof
EP2562004B1 (en) 2007-05-27 2019-11-06 Thomas Schneider Planar element and method for the production thereof
DE102007052575A1 (en) * 2007-11-03 2009-05-07 Märzhäuser Wetzlar GmbH & Co. KG Protective layer of hard-anodized microscopic aluminum workpieces, comprises a composite-lacquer reinforced with a filler, and a hard-anodized layer that is colored black
EP2670803A1 (en) 2011-02-02 2013-12-11 Ashland Licensing And Intellectual Property, LLC Scratch resistant gelcoat
RU2715839C1 (en) * 2019-07-19 2020-03-03 Федеральное государственное автономное образовательное учреждение высшего образования "Северный (Арктический) федеральный университет имени М. В. Ломоносова" Organomineral disperse paintwork material
EP3998314A1 (en) * 2020-10-29 2022-05-18 Potters Industries, LLC Protective coating for wood products and method of making the same
US11795341B2 (en) 2020-10-29 2023-10-24 Potters Industries, Llc Protective coating for wood products and method of making same

Similar Documents

Publication Publication Date Title
DE4304491A1 (en) Use of hard fillers in radiation-curable lacquers, coatings and printing inks in order to increase the abrasion resistance
EP2861432B1 (en) Method for printing panels
DE4238380B4 (en) Process for coating substrate materials with a glossy coating
EP3046778B1 (en) Thermo transfer films for the dry lacquering of surfaces
DE4323914A1 (en) Pearlescent pigment preparation
DE19845496A1 (en) Radiation-curable varnish, printing ink or coatings with improved hardness, abrasion resistance and scratch resistance contains hard particles, e.g. of aluminum oxide, in the nanometer size range
DE2505650C3 (en) Coating agent based on polymerizable acrylic compounds with improved flowability
DE202004005921U1 (en) Metallic printing ink for finishing prints
DE102010063554A1 (en) High gloss surface by HotCoating
WO2001014482A1 (en) Method for producing scratch resistant, weatherproof coatings
EP3990287A1 (en) Method for producing at least one substrate material provided with a printed pattern
WO2010112511A1 (en) Adhesion promoter for painting and printing
DE102013002457A1 (en) Use of surface material comprising polyethylene terephthalate-film, whose both surfaces are etched with trichloroacetic acid, additional precipitated silicic acid used during etching, for covering the melamine resin laminates
DE102021125055A1 (en) Process for the production of mechanically robust colorant-containing coatings
DE2947597B1 (en) Processes for making films or films
DE4426831A1 (en) Abrasion-resistant, radiation-cured coating materials e.g. for wood
DE1621820B1 (en) Method of priming wood
JP2017025254A (en) Coating composition for woody building material and woody building material
EP0770100A1 (en) Radiation-hardened paints and uses thereof to produce matt coating films
AT390620B (en) PAINTING AGENTS
WO2021160469A1 (en) Method for producing at least one substrate material provided with a printed pattern
EP2260161B1 (en) Coated wooden floor panel
DE19529987A1 (en) Prodn. of highly abrasion resistant lacquer coatings - with wear-reducing agent, pref. metal oxide, applied before or after the lacquer
DE10334008A1 (en) Process for coating carrier materials with different degrees of gloss and subsequently produced carrier material
EP2788126B1 (en) Method for producing a coat system, coat system and use thereof

Legal Events

Date Code Title Description
OP8 Request for examination as to paragraph 44 patent law
8127 New person/name/address of the applicant

Owner name: WALTER, THOMAS, DR., 32049 HERFORD, DE

8130 Withdrawal