DE4200352A1 - METHOD FOR APPLYING SUBSTANCES TO FIBER MATERIALS AND TEXTILE SUBSTRATES - Google Patents
METHOD FOR APPLYING SUBSTANCES TO FIBER MATERIALS AND TEXTILE SUBSTRATESInfo
- Publication number
- DE4200352A1 DE4200352A1 DE4200352A DE4200352A DE4200352A1 DE 4200352 A1 DE4200352 A1 DE 4200352A1 DE 4200352 A DE4200352 A DE 4200352A DE 4200352 A DE4200352 A DE 4200352A DE 4200352 A1 DE4200352 A1 DE 4200352A1
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- Germany
- Prior art keywords
- textile
- fluid
- fiber materials
- materials
- substances
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/79—Polyolefins
- D06P3/794—Polyolefins using dispersed dyes
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B19/00—Treatment of textile materials by liquids, gases or vapours, not provided for in groups D06B1/00 - D06B17/00
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B5/00—Forcing liquids, gases or vapours through textile materials to effect treatment, e.g. washing, dyeing, bleaching, sizing impregnating
- D06B5/12—Forcing liquids, gases or vapours through textile materials to effect treatment, e.g. washing, dyeing, bleaching, sizing impregnating through materials of definite length
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
- D06M11/76—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon oxides or carbonates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/005—Compositions containing perfumes; Compositions containing deodorants
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
- D06M23/10—Processes in which the treating agent is dissolved or dispersed in organic solvents; Processes for the recovery of organic solvents thereof
- D06M23/105—Processes in which the solvent is in a supercritical state
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M7/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made of other substances with subsequent freeing of the treated goods from the treating medium, e.g. swelling, e.g. polyolefins
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/90—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dyes dissolved in organic solvents or aqueous emulsions thereof
- D06P1/92—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dyes dissolved in organic solvents or aqueous emulsions thereof in organic solvents
- D06P1/928—Solvents other than hydrocarbons
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/94—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dyes dissolved in solvents which are in the supercritical state
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/02—Material containing basic nitrogen
- D06P3/04—Material containing basic nitrogen containing amide groups
- D06P3/043—Material containing basic nitrogen containing amide groups using dispersed dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/02—Material containing basic nitrogen
- D06P3/04—Material containing basic nitrogen containing amide groups
- D06P3/24—Polyamides; Polyurethanes
- D06P3/26—Polyamides; Polyurethanes using dispersed dyestuffs
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/34—Material containing ester groups
- D06P3/52—Polyesters
- D06P3/54—Polyesters using dispersed dyestuffs
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/40—Reduced friction resistance, lubricant properties; Sizing compositions
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Materials Engineering (AREA)
- Microbiology (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Biochemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Coloring (AREA)
Abstract
Description
Die Erfindung betrifft ein Verfahren zum Aufbringen von Substanzen auf Fasermaterialien und textile Substrate aus fluider Phase, bei dem als Fluid ein überkritisches Fluid oder ein verflüssigtes Gas oder eine verflüssigte Gasmischung verwendet wird. Dieses Aufbringen wird im folgenden als "Imprägnieren bzw. Imprägnierung" bezeichnet. Es werden dabei Substanzen verwendet, die die Verarbeitungs- und/oder die Gebrauchseigenschaften der Fasermaterialien bzw. der textilen Substrate modifizieren. Solche Substanzen werden im folgenden als "Wirkstoffe" bezeichnet.The invention relates to a method for applying substances Fiber materials and textile substrates from a fluid phase, in which as a fluid a supercritical fluid or a liquefied gas or a liquefied one Gas mixture is used. This application is referred to below as "impregnation or impregnation ". Substances are used that the processing and / or usage properties of the fiber materials or modify the textile substrates. Such substances will hereinafter referred to as "active ingredients".
Anwendungen überkritische Fluide in dem Sinne, daß Chemikalien (Wirkstoffe) auf ein Substrat aufgebracht werden, sind nur wenig bekannt. Hierbei handelt es sich um das Aufbringen von Dispersionsfarbstoffen auf Synthesefasern (DE 39 06 724 A1) oder von Wirkstoffen auf Thermoplaste (US 45 98 006).Applications of supercritical fluids in the sense that chemicals (active substances) Little are known to be applied to a substrate. This is about it concerns the application of disperse dyes on synthetic fibers (DE 39 06 724 A1) or of active ingredients on thermoplastics (US 45 98 006).
Aufgabe der vorliegenden Erfindung ist es, ein Verfahren aufzuzeigen, das unter Verwendung ökologisch unbedenklicher Mittel Fasermaterialien, textile Substrate oder Garne verschiedenster Art und Aufmachung unter Verwendung überkritischer Fluide bzw. verflüssigter Gase mit Wirkstoffen imprägniert und damit den Fasermaterialien, textilen Substraten oder Garnen eine gewünschte Eigenschaft zum Gebrauch und/oder der Verarbeitung verleiht (s. Ausführungsbeispiele). The object of the present invention is to demonstrate a method which using ecologically harmless fiber materials, textile All kinds of substrates or yarns and packaging using supercritical fluids or liquefied gases impregnated with active ingredients and thus the desired fiber materials, textile substrates or yarns Gives property for use and / or processing (s. Embodiments).
Bei dem erfindungsgemäßen Verfahren handelt es sich um die Verwendung überkritischer Fluide, auch als "superkritische Fluide oder überkritische bzw. superkritische Gase bezeichnet", bzw. von verflüssigten Gasen als Trägermedium (Fluid) für den das Fasermaterial bzw. auf das textile Substrat aufzubringenden Wirkstoff. Aus diesem Trägermedium läßt sich der Wirkstoff unter Variation der Verfahrensparameter (Druck, Temperatur) auf bzw. in den jeweiligen Fasermaterialien bzw. textilen Substraten abscheiden. Unter überkritischen Fluiden sind solche, ursprünglich gasförmigen oder flüssigen Systeme zu verstehen, die durch entsprechende Änderung des Druckes und Änderung der Temperatur über ihren kritischen Punkt gebracht werden. Hier nehmen solche fluiden Systeme besondere Löseeigenschaften an.The method according to the invention involves the use of supercritical ones Fluids, also called "supercritical fluids or supercritical or called supercritical gases ", or of liquefied gases as a carrier medium (Fluid) for the fiber material to be applied or onto the textile substrate Active ingredient. The active ingredient can be obtained from this carrier medium by varying the process parameters (pressure, temperature) on or in the deposit the respective fiber materials or textile substrates. Under supercritical Fluids are those that were originally gaseous or liquid Understand systems by changing the pressure accordingly and Change in temperature can be brought above its critical point. Here such fluid systems assume special dissolving properties.
Das Ziel der Erfindung wird dadurch erreicht, daß das zu imprägnierende Fasermaterial bzw. textile Substrat in einem Druckbehälter mit einem Gas oder Gasgemisch, das auf überkritische Bedingungen gebracht wird oder verflüssigt wird und das den Wirkstoff löst, in Kontakt gebracht wird und daß durch Variation der Druck-, Volumen- und/oder Temperaturbedingungen und/oder der Variation der Zusammensetzung des Fluids die Wirkstoffe in bzw. an dem zu behandelnden Fasermaterial bzw. textilen Substraten abgelagert werden und ihnen damit die gewünschten Eigenschaften verleihen.The aim of the invention is achieved in that the impregnated Fiber material or textile substrate in a pressure vessel with a gas or gas mixture which is brought to supercritical conditions or liquefied is and that dissolves the active ingredient, is brought into contact and that by varying the pressure, volume and / or temperature conditions and / or the variation of the composition of the fluid, the active substances in or on the to be treated fiber material or textile substrates and thereby give them the desired properties.
Ein für die Durchführung solcher Experimente geeignetes Apparatesystem ist schematisch in der beiliegenden Abb. 1 angeführt.An apparatus system suitable for carrying out such experiments is shown schematically in the attached Fig. 1.
Aus den nachstehend angeführten Ausführungsbeispielen wird ersichtlich, daß nach dem erfindungsgemäßen Verfahren alle textilen Materialien verschiedenster Konstitution effektiv mit Wirkstoffen versehen werden können. Ein besonderer Vorteil dieser Verfahrensweise liegt darin, daß eine gewünschte Endeigenschaft dem Textil, z. B. einer bereits konfektionierten Ware, "just- in-time" verliehen werden kann.It can be seen from the exemplary embodiments listed below that all textile materials of the most varied according to the inventive method Constitution can be effectively provided with active ingredients. A particular advantage of this procedure is that a desired Final property of the textile, e.g. B. an already assembled product, "just- can be awarded in-time ".
Aus der Auswahl erreichbarer Effekte seien einige beispielhaft angeführt. So können künstliche Duft- und Aromastoffen auf textilem Material aufgebracht werden (z. B. Duftnoten auf Seidenblumen). Es wird durch die erfindungsgemäßen Vorgehensweise an den textilen Materialien eine Depotwirkung für den Wirkstoff vermittelt, so daß über einen langen Zeitraum hinweg z. B. Duftstoffe von dem Textilgut (z. B. Schals, Taschentücher) abgegeben werden können.Some of the effects that can be achieved are given as examples. So artificial fragrances and aromas can be applied to textile material (e.g. fragrance notes on silk flowers). It is the inventive Procedure on the textile materials has a depot effect for the Active ingredient mediated so that over a long period of time, for. B. fragrances from the textile goods (e.g. scarves, handkerchiefs) can.
Andere Möglichkeiten, den Komfort von Bekleidungstextilien zu erhöhen, liegen in der Möglichkeit, etwa insektenabweichende Mittel in das Fasermaterial einzubringen, was besonders für Freizeitbekleidung interessant ist. Analog lassen sich UV-Absorber am Textil verankern. Dadurch etwa kann an Mützen, Hüten oder sonstiger Freizeitkleidung ein gewisser Sonnenschutz für den Benutzer als auch für das Fasermaterial eingearbeitet werden. Ein solcher lichtschützender Effekt kann simultan mit einer Färbung durchgeführt werden. Hierbei bewirkt der Zusatz eines hydrophoben Lichtschutzmittels außerdem, daß in Art einer Carrier-Färbung bei ansonsten gleichen Verfahrensbedingungen ein tieferer Farbton an der Ware erzielt wird.There are other ways to increase the comfort of clothing textiles in the possibility of using insect repellent in the fiber material to bring in what is particularly interesting for casual clothing. Similarly, UV absorbers can be anchored to the textile. This may help Hats, hats or other casual clothing a certain sun protection for the user as well as for the fiber material are incorporated. A such a light-protecting effect can be carried out simultaneously with a coloring will. The addition of a hydrophobic light stabilizer moreover, that in the manner of a carrier stain, otherwise the same Process conditions a deeper shade of the goods is achieved.
Darüber hinaus lassen sich etwa Bakterizide und Fungizide etc. aufbringen, was für den Einsatz in medizinischen Bereichen (Kliniken) genutzt werden kann, derart etwa daß Verbandsmaterial u. a. sterilisierend oder mit den Heilungsprozeß fördernden Wirkstoffen beladen werden. Ähnliches gilt ebenso für das Aufbringen etwa antibakterieller Wirkstoffe auf Wischtücher und -vliese etc. in solchen Fällen kommt die schon bei der Parfümierung angesprochene Depotwirkung zum Tragen. Im technischen Textilsektor können analog etwa Antifoulingmittel mit Langzeitwirkung am bzw. im Textil verankert werden.In addition, bactericides and fungicides etc. can be applied, what can be used for use in medical areas (clinics) can, such as that dressing material u. a. sterilizing or with the Active ingredients promoting the healing process are loaded. The same applies for applying antibacterial agents to wipes and fleece etc. in such cases comes the one already mentioned during the perfuming Depot effect to carry. In the technical textile sector, analog such as long-acting antifouling agents anchored on or in the textile will.
Als Vorteil des erfindungsgemäßen Verfahrens ist anzuführen, daß die Wirkstoffe (z. B. Spinnpräparation, Schlichten bzw. Avivagen) in besonders gleichmäßiger Verteilung auf Fasermaterialien bzw. die textilen Substrate aufgebracht werden kann, wodurch sich besondere Verarbeitungsvorteile ergeben.An advantage of the process according to the invention is that the active ingredients (e.g. spin finish, finishing or finishing) in particular even distribution on fiber materials or the textile substrates can be applied, which results in special processing advantages.
Als weitere Vorteile sind anzusehen:Further advantages are:
- - daß bei dem erfindungsgemäßen Verfahren kein Abwasser anfällt,That no waste water is produced in the process according to the invention,
- - daß bei Verwendung von CO₂ als Fluid das Fluid toxikologisch und ökologisch völlig unbdenklich ist,- That when using CO₂ as the fluid, the fluid toxicologically and ecologically is completely unthinkable
- - daß Fluid und behandeltes Substrat nach Beendigung des Imprägniervorgangs auf einfache Weise und vollständig voneinander zu trennen sind,- That fluid and treated substrate after completion of the impregnation process are easily and completely separated from each other,
- - daß das behandelte Substrat aus dem erfindungsgemäßen Prozeß gebrauchsfertig erhalten wird, daß z. B. keine Trocknung erforderlich ist,- That the treated substrate from the process of the invention ready for use is obtained that z. B. no drying is required,
- - daß nach dem vorliegenden Verfahren sehr kurze Behandlungszeiten resultieren,- That according to the present method, very short treatment times result,
- - daß das Fluid regeneriert und in einem Kreisprozeß zurückgewonnen und wieder eingesetzt werden kann,- That the fluid regenerates and recovered in a cycle and can be used again
- - daß überschüssig eingesetzte Wirkstoffe auf einfache Weise zurückgewonnen werden.- That excess active ingredients recovered in a simple manner will.
5,29 g PES-Echtheitsgewebe werden auf eine Hülse im Autoklaven gewickelt und der Autoklav mit 1,8 g 3-Phenylpropylacetat (Fa. Hüls) versehen. Es wird mit CO₂ bei 50 Grad befüllt, anschließend unter Rühren auf 120°C und 245 bar eine Stunde behandelt. Nach dem Expandieren wird das PES-Gewebe kurz mit Ethanol gespült. Das Gewebe entfaltet im verschlossenen Gefäß weiterhin den Duft des Riechstoffs (s. a. Differentialthermo-Analyse).5.29 g of PES fastness fabric are wound on a tube in an autoclave and provide the autoclave with 1.8 g of 3-phenylpropylacetate (from Hüls). It will be with Filled CO₂ at 50 degrees, then stirring to 120 ° C and 245 bar treated for an hour. After expanding, the PES fabric is briefly with Rinsed ethanol. The tissue continues to unfold in the closed vessel Fragrance of the fragrance (see also differential thermal analysis).
2,8 g Maulbeerseide, geeignet zur Erstellung von künstlichen Blumen wird analog zu obigem Beispiel imprägniert, aber nicht mit Ethanol abgewaschen. Das erhaltene Gewebe duftet intensiv nach Phenylpropylacetat. 2.8 g of mulberry silk, which is suitable for creating artificial flowers impregnated analogously to the example above, but not washed off with ethanol. The fabric obtained smells intensely of phenylpropylacetate.
PP-Gewebe wird im Autoklaven mit Butylhydroxyanisol (BHA), einem Alterungsschutz, bei 100°C und 250 bar CO₂ behandelt und anschließend äußerlich mit Ethanol abgespült. Chromatigraphische Analyse an Extrakten derartig behandelter Materialien zeigt die Anwesenheit von BHA an.PP fabric is autoclaved with butylated hydroxyanisole (BHA), an anti-aging product, treated at 100 ° C and 250 bar CO₂ and then externally with Rinsed off ethanol. Chromatographic analysis on extracts of such treated Materials indicates the presence of BHA.
2 g Gewebestreifen aus PE werden mit Dispersionsfarbstoff und 0,5% Lichtschutzmittel UV-Absorber Eusolex (®Merck) in den Autoklaven gegeben und 1 Min. bei 300 bar bei 120°C behandelt, wobei anschließend der CO₂-Druck in 5 bar-Schritten abgelassen wird. Die behandelten Proben zeigen neben einer höheren Tiefe eine um etwa 0,5 Einheiten verbesserte Echtheit im Xenonlichttest im Vergleich zu Färbungen ohne den Zusatz des hydrophoben Schutzmittels. Das erhaltene gefärbte Gewebe zeichnet sich nach visueller Abmusterung durch einen tieferen Farbton aus, als ein ohne UV-Absorber behandeltes Material.2 g fabric strips made of PE are mixed with disperse dye and 0.5% light stabilizer UV absorber Eusolex (®Merck) placed in the autoclave and 1 Min. At 300 bar at 120 ° C, then the CO₂ pressure in 5 bar steps is drained. The treated samples show next to one higher depth, authenticity improved by about 0.5 units in the xenon light test compared to dyeings without the addition of the hydrophobic Preservative. The dyed fabric obtained is visual Sampling by a deeper shade than one without a UV absorber treated material.
4 g Baumwollgarn werden mit Silikonöl, geeignet als textiles Schlichtemittel, in den Autoklaven gegeben und 5 Min. bei 250 bar CO₂-Druck und 80°C behandelt. Nach Entspannen des Gasdrucks wie im vorigen Beispiel und Entnahme des behandelten Garns weist es eine gleichmäßige Auflagerung des Silikonwirkstoffs auf und zeigt in Reibungsversuchen gegenüber dem unbehandelten Material ausgezeichnete Gleiteigenschaften. 4 g of cotton yarn are mixed with silicone oil, suitable as a textile sizing agent, in the Autoclaved and treated for 5 minutes at 250 bar CO₂ pressure and 80 ° C. To Relax the gas pressure as in the previous example and remove the treated one Yarn, it has an even layer of the silicone active ingredient and shows excellent in friction tests against the untreated material Sliding properties.
BezugszeichenlisteReference list
1 textiles Substrat
2 Färbehülse
3 Autoklav
4 Heizung
5 Rührwerk
6 Vorratstank
7 Absperrventil
8 Filter
9 Kompressor
10 Rückschlagventil
12 Leitung
14 Manometer
16 Eintrittsleistung
18 Austrittsleitung
20 Berstscheibe
22 Expansionsventil
24 Expansionsgefäß 1 textile substrate
2 dye tubes
3 autoclave
4 heating
5 agitator
6 storage tank
7 shut-off valve
8 filters
9 compressor
10 check valve
12 line
14 manometers
16 Entry benefit
18 outlet line
20 rupture disc
22 expansion valve
24 expansion vessel
Claims (10)
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4200352A DE4200352A1 (en) | 1992-01-09 | 1992-01-09 | METHOD FOR APPLYING SUBSTANCES TO FIBER MATERIALS AND TEXTILE SUBSTRATES |
EP93902152A EP0620875A1 (en) | 1992-01-09 | 1993-01-08 | Process for applying substances to fibre materials and textile substrates |
CZ941640A CZ164094A3 (en) | 1992-01-09 | 1993-01-08 | Method of applying substrates onto fibrous materials and textile materials |
PCT/EP1993/000020 WO1993014259A1 (en) | 1992-01-09 | 1993-01-08 | Process for applying substances to fibre materials and textile substrates |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4200352A DE4200352A1 (en) | 1992-01-09 | 1992-01-09 | METHOD FOR APPLYING SUBSTANCES TO FIBER MATERIALS AND TEXTILE SUBSTRATES |
Publications (1)
Publication Number | Publication Date |
---|---|
DE4200352A1 true DE4200352A1 (en) | 1993-08-19 |
Family
ID=6449253
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE4200352A Withdrawn DE4200352A1 (en) | 1992-01-09 | 1992-01-09 | METHOD FOR APPLYING SUBSTANCES TO FIBER MATERIALS AND TEXTILE SUBSTRATES |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP0620875A1 (en) |
CZ (1) | CZ164094A3 (en) |
DE (1) | DE4200352A1 (en) |
WO (1) | WO1993014259A1 (en) |
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4200498A1 (en) * | 1992-01-10 | 1993-07-15 | Amann & Soehne | PROCEDURE FOR APPOINTING AN AVIVAGE |
DE4404839A1 (en) * | 1994-02-16 | 1995-08-17 | Deutsches Textilforschzentrum | Coating or impregnating substrates with polar cpds., esp. dyes |
DE19937465A1 (en) * | 1999-08-07 | 2001-02-08 | Volkswagen Ag | Adhesive composition, comprises adhesive and solvent that at least partially comprises super-critical carbon dioxide. |
DE4238621C2 (en) * | 1992-11-16 | 2002-10-24 | Amann & Soehne | Device for treating textile goods |
DE4238622C2 (en) * | 1992-11-16 | 2002-10-24 | Amann & Soehne | Device for treating textile goods |
WO2004040057A1 (en) * | 2002-10-31 | 2004-05-13 | Uhde High Pressure Technologies Gmbh | Method for staining materials in compressed carbon dioxide |
DE4344021B4 (en) * | 1993-12-23 | 2006-06-29 | Deutsches Textilforschungszentrum Nord-West E.V. | Coloring of sized textile fabrics of synthetic fiber material in supercritical media |
DE102005045501A1 (en) * | 2005-09-23 | 2007-03-29 | Braun Gmbh | Wear and tear indicating dyestuff introducing method for toothbrush, involves supplying consumable-medium-mixture, which stays under pressure for predetermined application time, to toothbrush filaments or wear and tear part |
US8932409B2 (en) | 2012-11-01 | 2015-01-13 | Spectra Systems Corporation | Supercritical fluid cleaning of banknotes and secure documents |
US8961702B2 (en) | 2012-11-01 | 2015-02-24 | Spectra Systems Corporation. | Supercritical fluid cleaning of banknotes and secure documents |
DE102015221453A1 (en) | 2015-11-03 | 2017-05-04 | Evonik Degussa Gmbh | Process for impregnation |
US9676009B2 (en) | 2012-11-01 | 2017-06-13 | Specrra Systems Corporation | Supercritical fluid cleaning of banknotes and secure documents |
Families Citing this family (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0615561B1 (en) * | 1992-10-08 | 1996-05-08 | Amann & Söhne GmbH & Co. | Process for dyeing a substrate in a supercritical fluid |
EP0854952B1 (en) * | 1995-10-06 | 2001-08-29 | Amann & Söhne GmbH & Co. | Process for dyeing a textile substrate |
WO1997014843A1 (en) * | 1995-10-17 | 1997-04-24 | Amann & Söhne Gmbh & Co. | Process for dyeing a textile substrate in at least one supercritical fluid |
US5783082A (en) * | 1995-11-03 | 1998-07-21 | University Of North Carolina | Cleaning process using carbon dioxide as a solvent and employing molecularly engineered surfactants |
US5863298A (en) * | 1996-03-08 | 1999-01-26 | Battelle Memorial Institute | Method for sizing and desizing yarns with liquid and supercritical carbon dioxide solvent |
US5968654A (en) * | 1996-09-12 | 1999-10-19 | University Of Massachusetts Lowell | Modification of polymeric substrates using dense or liquified gases |
US6030663A (en) * | 1997-05-30 | 2000-02-29 | Micell Technologies, Inc. | Surface treatment |
US6287640B1 (en) | 1997-05-30 | 2001-09-11 | Micell Technologies, Inc. | Surface treatment of substrates with compounds that bind thereto |
US6344243B1 (en) | 1997-05-30 | 2002-02-05 | Micell Technologies, Inc. | Surface treatment |
US6165560A (en) * | 1997-05-30 | 2000-12-26 | Micell Technologies | Surface treatment |
GB9721588D0 (en) | 1997-10-10 | 1997-12-10 | Du Pont | Textile treatment |
JP2001519237A (en) | 1997-10-10 | 2001-10-23 | ユニオン・カーバイド・ケミカルズ・アンド・プラスティックス・テクノロジー・コーポレイション | Spray application of additive composition to sheet material |
GB9721586D0 (en) * | 1997-10-10 | 1997-12-10 | Unilever Plc | Textile treatment |
US6048369A (en) * | 1998-06-03 | 2000-04-11 | North Carolina State University | Method of dyeing hydrophobic textile fibers with colorant materials in supercritical fluid carbon dioxide |
US6261326B1 (en) | 2000-01-13 | 2001-07-17 | North Carolina State University | Method for introducing dyes and other chemicals into a textile treatment system |
US6676710B2 (en) | 2000-10-18 | 2004-01-13 | North Carolina State University | Process for treating textile substrates |
US8201564B2 (en) * | 2005-12-30 | 2012-06-19 | Philip Morris Usa Inc. | Cigarette filters |
ES2881958T3 (en) | 2017-06-22 | 2021-11-30 | Hbi Branded Apparel Entpr Llc | Fabric treatment compositions and methods |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2853066A1 (en) * | 1978-12-08 | 1980-06-26 | August Prof Dipl Phys D Winsel | Monomolecular or very thin coating prodn. on porous material - by contact with supercritical gas contg. solid or liq. coating material in soln. |
US4598006A (en) * | 1985-05-02 | 1986-07-01 | Hercules Incorporated | Method for impregnating a thermoplastic polymer |
DE4004111C2 (en) * | 1989-02-15 | 1999-08-19 | Deutsches Textilforschzentrum | Process for the pretreatment of textile fabrics or yarns |
DE3906724C2 (en) * | 1989-03-03 | 1998-03-12 | Deutsches Textilforschzentrum | Process for dyeing textile substrates |
DE3906737A1 (en) * | 1989-03-03 | 1990-09-13 | Deutsches Textilforschzentrum | Process for mercerising, causticising or scouring |
DE3906735C2 (en) * | 1989-03-03 | 1999-04-15 | Deutsches Textilforschzentrum | Bleaching process |
-
1992
- 1992-01-09 DE DE4200352A patent/DE4200352A1/en not_active Withdrawn
-
1993
- 1993-01-08 CZ CZ941640A patent/CZ164094A3/en unknown
- 1993-01-08 WO PCT/EP1993/000020 patent/WO1993014259A1/en not_active Application Discontinuation
- 1993-01-08 EP EP93902152A patent/EP0620875A1/en not_active Withdrawn
Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4200498A1 (en) * | 1992-01-10 | 1993-07-15 | Amann & Soehne | PROCEDURE FOR APPOINTING AN AVIVAGE |
DE4238621C2 (en) * | 1992-11-16 | 2002-10-24 | Amann & Soehne | Device for treating textile goods |
DE4238622C2 (en) * | 1992-11-16 | 2002-10-24 | Amann & Soehne | Device for treating textile goods |
DE4344021B4 (en) * | 1993-12-23 | 2006-06-29 | Deutsches Textilforschungszentrum Nord-West E.V. | Coloring of sized textile fabrics of synthetic fiber material in supercritical media |
DE4404839A1 (en) * | 1994-02-16 | 1995-08-17 | Deutsches Textilforschzentrum | Coating or impregnating substrates with polar cpds., esp. dyes |
DE19937465A1 (en) * | 1999-08-07 | 2001-02-08 | Volkswagen Ag | Adhesive composition, comprises adhesive and solvent that at least partially comprises super-critical carbon dioxide. |
DE10251136A1 (en) * | 2002-10-31 | 2004-05-19 | Uhde High Pressure Technologies Gmbh | Process for coloring materials in compressed carbon dioxide |
WO2004040057A1 (en) * | 2002-10-31 | 2004-05-13 | Uhde High Pressure Technologies Gmbh | Method for staining materials in compressed carbon dioxide |
DE102005045501A1 (en) * | 2005-09-23 | 2007-03-29 | Braun Gmbh | Wear and tear indicating dyestuff introducing method for toothbrush, involves supplying consumable-medium-mixture, which stays under pressure for predetermined application time, to toothbrush filaments or wear and tear part |
US8932409B2 (en) | 2012-11-01 | 2015-01-13 | Spectra Systems Corporation | Supercritical fluid cleaning of banknotes and secure documents |
US8961702B2 (en) | 2012-11-01 | 2015-02-24 | Spectra Systems Corporation. | Supercritical fluid cleaning of banknotes and secure documents |
US9676009B2 (en) | 2012-11-01 | 2017-06-13 | Specrra Systems Corporation | Supercritical fluid cleaning of banknotes and secure documents |
DE102015221453A1 (en) | 2015-11-03 | 2017-05-04 | Evonik Degussa Gmbh | Process for impregnation |
Also Published As
Publication number | Publication date |
---|---|
WO1993014259A1 (en) | 1993-07-22 |
CZ164094A3 (en) | 1994-11-16 |
EP0620875A1 (en) | 1994-10-26 |
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