DE410969C - Process for the preparation of derivatives of nuclear mercured phenols - Google Patents
Process for the preparation of derivatives of nuclear mercured phenolsInfo
- Publication number
- DE410969C DE410969C DES58634D DES0058634D DE410969C DE 410969 C DE410969 C DE 410969C DE S58634 D DES58634 D DE S58634D DE S0058634 D DES0058634 D DE S0058634D DE 410969 C DE410969 C DE 410969C
- Authority
- DE
- Germany
- Prior art keywords
- phenols
- mercured
- nuclear
- derivatives
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000002989 phenols Chemical class 0.000 title claims description 4
- 238000000034 method Methods 0.000 title claims description 3
- 238000002360 preparation method Methods 0.000 title claims description 3
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical class [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 claims description 6
- 150000002731 mercury compounds Chemical class 0.000 claims 1
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 5
- 230000007935 neutral effect Effects 0.000 description 5
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 235000010265 sodium sulphite Nutrition 0.000 description 3
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 229930003836 cresol Natural products 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 229910000474 mercury oxide Inorganic materials 0.000 description 1
- UKWHYYKOEPRTIC-UHFFFAOYSA-N mercury(ii) oxide Chemical compound [Hg]=O UKWHYYKOEPRTIC-UHFFFAOYSA-N 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- CYGSXDXRHXMAOV-UHFFFAOYSA-N o-cresol hydrogen sulfate Chemical compound CC1=CC=CC=C1OS(O)(=O)=O CYGSXDXRHXMAOV-UHFFFAOYSA-N 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic Table
- C07F3/10—Mercury compounds
- C07F3/12—Aromatic substances containing mercury
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
Verfahren zur Herstellung von Derivaten kernmercurierter Phenole. Es wurde gefunden, daß sich die komplexen Pihenolmercurichloride, -sulfate und andere Salze sowie auch die Phenolmercurioxyde mit sauren oder neutralen Sulfiten zu den entsprechenden Phenolmercurisulfiten umsetzen lassen. Die Phenolmercurisulfite sind farblose, in Wasser leicht lösliche kristallinische Pulver, «-elche durch konzentrierte Säure unter Absprengung von schwefliger Säure zersetzt werden. Beim Erhitzen bräunen sie sich unter Zersetzung. Einen scharfen Schmelzpunkt zeigen diese Verbindungen nicht. Durch Kohlensäure werden die Sulfitverbindungen nicht zersetzt. Diese Sulfitverbindungen waren bisher nicht bekannt, sie haben eine besondere Bedeutung, weil ihre Salze leicht in Wasser löslich sind und sich ohne Zersetzung durch Eindampfen gewinnen lassen. Die Salze der Phenolmercurisulfite besitzen starke fungizidc Wirkung.Process for the preparation of derivatives of nuclear mercured phenols. It has been found that the complex Pihenolmercurichloride, sulfates and others Salts as well as the phenol mercurioxides with acidic or neutral sulfites to the let the corresponding phenol mercuric sulfites react. The phenol mercuric sulfites are colorless crystalline powders, readily soluble in water, "-which by concentrated Acid can be decomposed with splitting off of sulphurous acid. Brown when heated they are decomposing. These compounds show a sharp melting point not. The sulphite compounds are not decomposed by carbonic acid. These sulfite compounds were not previously known, they have a special meaning because of their salts are easily soluble in water and can be obtained by evaporation without decomposition permit. The salts of the phenol mercuric sulphites have a strong fungicidal effect.
Beispiele. I . In eine Suspension von I g kg Mercuriphenoloxyd in Wasser werden 15 kg neutrales Natriumsulfit eingetragen. Es tritt nach kurzer Zeit schon bei gewöhnlicher Temperatur eine völlige Auflösung ein. Die erhaltene Lösung von Mercuriphenolsulfitnatrium wird eingedampft. a. 3ä kg Mercurikresolsulfat werden mit 2o kg neutralem Natriumsulfit und Wasserbei mäßiger Hitze bis zur völligen Lösung behandelt. Die klare Lösung wird im Vakuum eingedampft.Examples. I. 1 5 kg of neutral sodium sulfite are added to a suspension of 1 g kg of mercuriphenol oxide in water. Complete dissolution occurs after a short time, even at normal temperature. The resulting solution of sodium mercuriphenolsulfite is evaporated. a. 3 kg of mercuric cresol sulfate are treated with 20 kg of neutral sodium sulfite and water at moderate heat until they are completely dissolved. The clear solution is evaporated in vacuo.
3. Io kg Kresol werden mit z5 kg Quecksilberoxyd und iookg Wasser unter Zusatz von iol Natronlauge von .1o° B6 unter Rühren erwärmt. Nach beendigter Mercurierung wird filtriert und das Filtrat mit i 5 kg neutralem Natriumsulfit zur Trockne gebracht.3. 10 kg of cresol are mixed with 5 kg of mercury oxide and 1 ookg of water heated with the addition of iol sodium hydroxide solution of .1o ° B6 with stirring. After finished Mercury is filtered and the filtrate with i 5 kg of neutral sodium sulfite to Brought dry.
Arbeitet man mit saurem schwefligsaurem Natron statt mit neutralem Sulfit, so wird freies Mercurikresolsulfit ausgeschieden, welches auf Zusatz von Alkali in Lösung geht und beim Eindampfen ebenfalls Mercurikresolsulfitnatrium liefert.If you work with acid sulphurous soda instead of neutral Sulphite, free mercuricresol sulphite is excreted, which is due to the addition of The alkali goes into solution and, on evaporation, also supplies sodium mercuric cresol sulfite.
a. 35k"- Mercurikresolnatrium werden mit 15 kg entwässertem Natriumsulfit innig vermahlen. Auf Zusatz von Wasser bildet sich aus der Mischung Mercurikresolnatriumsulfit.a. 35k "-sodium mercuricresol are thoroughly ground with 15 kg of dehydrated sodium sulfite. Upon addition of water, sodium mercuricresol is formed from the mixture.
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DES58634D DE410969C (en) | 1922-01-13 | 1922-01-13 | Process for the preparation of derivatives of nuclear mercured phenols |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DES58634D DE410969C (en) | 1922-01-13 | 1922-01-13 | Process for the preparation of derivatives of nuclear mercured phenols |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE410969C true DE410969C (en) | 1925-03-21 |
Family
ID=7492687
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DES58634D Expired DE410969C (en) | 1922-01-13 | 1922-01-13 | Process for the preparation of derivatives of nuclear mercured phenols |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE410969C (en) |
-
1922
- 1922-01-13 DE DES58634D patent/DE410969C/en not_active Expired
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