DE4036787C2 - - Google Patents
Info
- Publication number
- DE4036787C2 DE4036787C2 DE19904036787 DE4036787A DE4036787C2 DE 4036787 C2 DE4036787 C2 DE 4036787C2 DE 19904036787 DE19904036787 DE 19904036787 DE 4036787 A DE4036787 A DE 4036787A DE 4036787 C2 DE4036787 C2 DE 4036787C2
- Authority
- DE
- Germany
- Prior art keywords
- biodegradation
- explosives
- water
- ammunition
- hydrolytic cleavage
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Revoked
Links
- 238000000034 method Methods 0.000 claims description 15
- 239000000843 powder Substances 0.000 claims description 9
- 239000002360 explosive Substances 0.000 claims description 7
- 239000003380 propellant Substances 0.000 claims description 7
- 238000006065 biodegradation reaction Methods 0.000 claims description 6
- 230000006378 damage Effects 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 4
- 238000003776 cleavage reaction Methods 0.000 claims description 4
- 230000003301 hydrolyzing effect Effects 0.000 claims description 4
- 230000007017 scission Effects 0.000 claims description 4
- 239000010865 sewage Substances 0.000 claims description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 239000002904 solvent Substances 0.000 claims description 2
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims 3
- 239000003513 alkali Substances 0.000 claims 1
- 239000004094 surface-active agent Substances 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 239000007789 gas Substances 0.000 description 6
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 5
- 229920002678 cellulose Polymers 0.000 description 5
- 239000001913 cellulose Substances 0.000 description 5
- 229910002651 NO3 Inorganic materials 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 241000894006 Bacteria Species 0.000 description 3
- 239000000020 Nitrocellulose Substances 0.000 description 3
- ZRALSGWEFCBTJO-UHFFFAOYSA-N anhydrous guanidine Natural products NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 238000002485 combustion reaction Methods 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 229920001220 nitrocellulos Polymers 0.000 description 3
- 238000007127 saponification reaction Methods 0.000 description 3
- 239000002351 wastewater Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical class O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 description 2
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Natural products CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000005474 detonation Methods 0.000 description 2
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 description 2
- 239000003337 fertilizer Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 238000006386 neutralization reaction Methods 0.000 description 2
- 150000002828 nitro derivatives Chemical class 0.000 description 2
- 150000002894 organic compounds Chemical class 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000004065 wastewater treatment Methods 0.000 description 2
- GWEHVDNNLFDJLR-UHFFFAOYSA-N 1,3-diphenylurea Chemical compound C=1C=CC=CC=1NC(=O)NC1=CC=CC=C1 GWEHVDNNLFDJLR-UHFFFAOYSA-N 0.000 description 1
- 239000002028 Biomass Substances 0.000 description 1
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 1
- 241000192041 Micrococcus Species 0.000 description 1
- -1 Na OH Substances 0.000 description 1
- 239000000006 Nitroglycerin Substances 0.000 description 1
- 241000589516 Pseudomonas Species 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical class NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- PZIMIYVOZBTARW-UHFFFAOYSA-N centralite Chemical compound C=1C=CC=CC=1N(CC)C(=O)N(CC)C1=CC=CC=C1 PZIMIYVOZBTARW-UHFFFAOYSA-N 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000005352 clarification Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000007257 deesterification reaction Methods 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 229960003711 glyceryl trinitrate Drugs 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 239000010808 liquid waste Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- 239000010841 municipal wastewater Substances 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000004886 process control Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 239000010801 sewage sludge Substances 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002910 solid waste Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D3/00—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances
- A62D3/02—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances by biological methods, i.e. processes using enzymes or microorganisms
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D3/00—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances
- A62D3/30—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances by reacting with chemical agents
- A62D3/35—Processes for making harmful chemical substances harmless or less harmful, by effecting a chemical change in the substances by reacting with chemical agents by hydrolysis
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F42—AMMUNITION; BLASTING
- F42B—EXPLOSIVE CHARGES, e.g. FOR BLASTING, FIREWORKS, AMMUNITION
- F42B33/00—Manufacture of ammunition; Dismantling of ammunition; Apparatus therefor
- F42B33/06—Dismantling fuzes, cartridges, projectiles, missiles, rockets or bombs
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D2101/00—Harmful chemical substances made harmless, or less harmful, by effecting chemical change
- A62D2101/06—Explosives, propellants or pyrotechnics, e.g. rocket fuel or napalm
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D2203/00—Aspects of processes for making harmful chemical substances harmless, or less harmful, by effecting chemical change in the substances
- A62D2203/02—Combined processes involving two or more distinct steps covered by groups A62D3/10 - A62D3/40
Landscapes
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Emergency Management (AREA)
- Business, Economics & Management (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Toxicology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Molecular Biology (AREA)
- Microbiology (AREA)
- Biomedical Technology (AREA)
- Biochemistry (AREA)
- General Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
- Processing Of Solid Wastes (AREA)
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19904036787 DE4036787A1 (de) | 1990-11-17 | 1990-11-17 | Vernichtung von explosivstoffen |
| CH316691A CH682459A5 (de) | 1990-11-17 | 1991-10-30 | Verfahren zum Vernichten von Explosivstoffen. |
| PL29241791A PL292417A1 (en) | 1990-11-17 | 1991-11-15 | Method of annihilating explosives |
| CS913473A CS347391A3 (en) | 1990-11-17 | 1991-11-15 | Process of explosives decomposition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19904036787 DE4036787A1 (de) | 1990-11-17 | 1990-11-17 | Vernichtung von explosivstoffen |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE4036787A1 DE4036787A1 (de) | 1992-05-21 |
| DE4036787C2 true DE4036787C2 (cs) | 1993-06-17 |
Family
ID=6418522
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19904036787 Granted DE4036787A1 (de) | 1990-11-17 | 1990-11-17 | Vernichtung von explosivstoffen |
Country Status (4)
| Country | Link |
|---|---|
| CH (1) | CH682459A5 (cs) |
| CS (1) | CS347391A3 (cs) |
| DE (1) | DE4036787A1 (cs) |
| PL (1) | PL292417A1 (cs) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2198154C2 (ru) * | 2001-03-13 | 2003-02-10 | Государственный научно-исследовательский институт химических продуктов | Способ переработки порохов |
| RU2227267C1 (ru) * | 2002-10-23 | 2004-04-20 | Военная академия Ракетных войск стратегического назначения им. Петра Великого | Способ уничтожения водных суспензий взрывчатых веществ нитраминового ряда щелочным гидролизом |
| US7442848B2 (en) | 2003-08-15 | 2008-10-28 | Perma-Fix Environmental Services, Inc. | Treatment of chemical agent hydrolysates |
| US8492607B2 (en) | 2003-08-15 | 2013-07-23 | Perma-Fix Environmental Services, Inc. | Treatment of chemical agent hydrolysates |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2210729C2 (ru) * | 1995-11-17 | 2003-08-20 | ЗЭ Энсайн-Бикфорд Кампани | Устройства, система, смесь и способы биологической ликвидации взрывчатых веществ |
| US5763736A (en) * | 1997-02-13 | 1998-06-09 | Oerlikon Contraves Pyrotec Ag | Method for the disposal of explosive material |
| US6051420A (en) * | 1997-05-21 | 2000-04-18 | Bechtel Bwxt Idaho, Llc | Method for the decontamination of soil containing solid organic explosives therein |
| GB9710869D0 (en) * | 1997-05-27 | 1997-07-23 | Grampian Pharm Ltd | Degradation of hazardous chemicals |
| US6080906A (en) * | 1997-09-18 | 2000-06-27 | Alliedsignal, Inc. | Demilitarization of chemical munitions |
| ES2131478B1 (es) * | 1997-10-27 | 2000-03-01 | Pastor Alicia Guijarro | Metodo para la transformacion de las sustancia explosivas en fertilizantes mediante un proceso que emplea koh (hidroxido potasico) como agente de hidrolisis. |
| AU1899599A (en) * | 1998-09-14 | 2000-04-03 | Allied-Signal Inc. | Demilitarization of chemical munitions |
| JP2003506164A (ja) * | 1999-08-06 | 2003-02-18 | ハネウェル インターナショナル，インコーポレーテッド | 化学剤加水分解物の処理 |
| US6603050B2 (en) * | 2000-02-23 | 2003-08-05 | Uxb International, Inc. | Destruction of energetic materials |
| US6543535B2 (en) | 2000-03-15 | 2003-04-08 | Exxonmobil Upstream Research Company | Process for stimulating microbial activity in a hydrocarbon-bearing, subterranean formation |
| US8092559B2 (en) | 2004-05-12 | 2012-01-10 | Luca Technologies, Inc. | Generation of hydrogen from hydrocarbon bearing materials |
| US7426960B2 (en) | 2005-05-03 | 2008-09-23 | Luca Technologies, Inc. | Biogenic fuel gas generation in geologic hydrocarbon deposits |
| US7416879B2 (en) | 2006-01-11 | 2008-08-26 | Luca Technologies, Inc. | Thermacetogenium phaeum consortium for the production of materials with enhanced hydrogen content |
| ES2259575B2 (es) * | 2006-03-31 | 2007-06-01 | Arturo Diaz De Barrionuevo | Proceso de eliminacion integral de productos de alto contenido energetico. |
| US7696132B2 (en) | 2006-04-05 | 2010-04-13 | Luca Technologies, Inc. | Chemical amendments for the stimulation of biogenic gas generation in deposits of carbonaceous material |
| US9004162B2 (en) | 2012-03-23 | 2015-04-14 | Transworld Technologies Inc. | Methods of stimulating acetoclastic methanogenesis in subterranean deposits of carbonaceous material |
| US12416024B2 (en) | 2018-03-29 | 2025-09-16 | Transworld Technologies Inc. | Biologically enhanced oil recovery methods |
| CN117776825A (zh) * | 2023-12-25 | 2024-03-29 | 一重集团大连工程技术有限公司 | 一种含能材料处理方法 |
-
1990
- 1990-11-17 DE DE19904036787 patent/DE4036787A1/de active Granted
-
1991
- 1991-10-30 CH CH316691A patent/CH682459A5/de not_active IP Right Cessation
- 1991-11-15 CS CS913473A patent/CS347391A3/cs unknown
- 1991-11-15 PL PL29241791A patent/PL292417A1/xx unknown
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2198154C2 (ru) * | 2001-03-13 | 2003-02-10 | Государственный научно-исследовательский институт химических продуктов | Способ переработки порохов |
| RU2227267C1 (ru) * | 2002-10-23 | 2004-04-20 | Военная академия Ракетных войск стратегического назначения им. Петра Великого | Способ уничтожения водных суспензий взрывчатых веществ нитраминового ряда щелочным гидролизом |
| US7442848B2 (en) | 2003-08-15 | 2008-10-28 | Perma-Fix Environmental Services, Inc. | Treatment of chemical agent hydrolysates |
| US8492607B2 (en) | 2003-08-15 | 2013-07-23 | Perma-Fix Environmental Services, Inc. | Treatment of chemical agent hydrolysates |
Also Published As
| Publication number | Publication date |
|---|---|
| DE4036787A1 (de) | 1992-05-21 |
| CS347391A3 (en) | 1992-08-12 |
| CH682459A5 (de) | 1993-09-30 |
| PL292417A1 (en) | 1992-08-24 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| OP8 | Request for examination as to paragraph 44 patent law | ||
| D2 | Grant after examination | ||
| 8363 | Opposition against the patent | ||
| 8331 | Complete revocation |