DE3778805D1 - Verfahren zur herstellung eines methanreichen gases aus kohle. - Google Patents

Verfahren zur herstellung eines methanreichen gases aus kohle.

Info

Publication number
DE3778805D1
DE3778805D1 DE8787201683T DE3778805T DE3778805D1 DE 3778805 D1 DE3778805 D1 DE 3778805D1 DE 8787201683 T DE8787201683 T DE 8787201683T DE 3778805 T DE3778805 T DE 3778805T DE 3778805 D1 DE3778805 D1 DE 3778805D1
Authority
DE
Germany
Prior art keywords
methane
coal
producing
rich gas
rich
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE8787201683T
Other languages
English (en)
Inventor
Giacomo Bruno
Luigi Carvani
Giovanni Passoni
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Eni Tecnologie SpA
Snam SpA
Original Assignee
Snam SpA
Eniricerche SpA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Snam SpA, Eniricerche SpA filed Critical Snam SpA
Application granted granted Critical
Publication of DE3778805D1 publication Critical patent/DE3778805D1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/02Fixed-bed gasification of lump fuel
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C9/00Aliphatic saturated hydrocarbons
    • C07C9/02Aliphatic saturated hydrocarbons with one to four carbon atoms
    • C07C9/04Methane
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L3/00Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/06Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
    • C10L3/08Production of synthetic natural gas
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L5/00Solid fuels
    • C10L5/02Solid fuels such as briquettes consisting mainly of carbonaceous materials of mineral or non-mineral origin
    • C10L5/04Raw material of mineral origin to be used; Pretreatment thereof
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L9/00Treating solid fuels to improve their combustion
    • C10L9/10Treating solid fuels to improve their combustion by using additives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0903Feed preparation
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913Carbonaceous raw material
    • C10J2300/093Coal
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953Gasifying agents
    • C10J2300/0956Air or oxygen enriched air
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953Gasifying agents
    • C10J2300/0959Oxygen
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953Gasifying agents
    • C10J2300/0973Water
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0983Additives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0983Additives
    • C10J2300/0986Catalysts
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/16Integration of gasification processes with another plant or parts within the plant
    • C10J2300/1678Integration of gasification processes with another plant or parts within the plant with air separation
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/18Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/1807Recycle loops, e.g. gas, solids, heating medium, water
DE8787201683T 1986-09-10 1987-09-07 Verfahren zur herstellung eines methanreichen gases aus kohle. Expired - Lifetime DE3778805D1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT21661/86A IT1197477B (it) 1986-09-10 1986-09-10 Processo per ottenere una miscela gassosa ad alto contenuto di metano dal carbone

Publications (1)

Publication Number Publication Date
DE3778805D1 true DE3778805D1 (de) 1992-06-11

Family

ID=11184987

Family Applications (1)

Application Number Title Priority Date Filing Date
DE8787201683T Expired - Lifetime DE3778805D1 (de) 1986-09-10 1987-09-07 Verfahren zur herstellung eines methanreichen gases aus kohle.

Country Status (8)

Country Link
EP (1) EP0259927B1 (de)
CN (1) CN1017702B (de)
AU (1) AU585732B2 (de)
CA (1) CA1332108C (de)
DE (1) DE3778805D1 (de)
ES (1) ES2032813T3 (de)
IT (1) IT1197477B (de)
ZA (1) ZA876637B (de)

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IT1289003B1 (it) * 1996-10-16 1998-09-25 Tomadini Gino & C Procedimento perfezionato di gassificazione di combustibili e relativo dispositivo gassificatore
US8114176B2 (en) 2005-10-12 2012-02-14 Great Point Energy, Inc. Catalytic steam gasification of petroleum coke to methane
US7922782B2 (en) 2006-06-01 2011-04-12 Greatpoint Energy, Inc. Catalytic steam gasification process with recovery and recycle of alkali metal compounds
CN105062563A (zh) 2007-08-02 2015-11-18 格雷特波因特能源公司 负载催化剂的煤组合物,制造方法和用途
WO2009086377A2 (en) 2007-12-28 2009-07-09 Greatpoint Energy, Inc. Catalytic gasification process with recovery of alkali metal from char
US8123827B2 (en) 2007-12-28 2012-02-28 Greatpoint Energy, Inc. Processes for making syngas-derived products
WO2009086407A2 (en) 2007-12-28 2009-07-09 Greatpoint Energy, Inc. Steam generating slurry gasifier for the catalytic gasification of a carbonaceous feedstock
US7897126B2 (en) 2007-12-28 2011-03-01 Greatpoint Energy, Inc. Catalytic gasification process with recovery of alkali metal from char
CN101959996B (zh) 2008-02-29 2013-10-30 格雷特波因特能源公司 用于气化作用的颗粒状组合物及其制备和连续转化
US8114177B2 (en) 2008-02-29 2012-02-14 Greatpoint Energy, Inc. Co-feed of biomass as source of makeup catalysts for catalytic coal gasification
WO2009111345A2 (en) 2008-02-29 2009-09-11 Greatpoint Energy, Inc. Catalytic gasification particulate compositions
WO2009111332A2 (en) 2008-02-29 2009-09-11 Greatpoint Energy, Inc. Reduced carbon footprint steam generation processes
US8652222B2 (en) 2008-02-29 2014-02-18 Greatpoint Energy, Inc. Biomass compositions for catalytic gasification
US8297542B2 (en) 2008-02-29 2012-10-30 Greatpoint Energy, Inc. Coal compositions for catalytic gasification
US8286901B2 (en) 2008-02-29 2012-10-16 Greatpoint Energy, Inc. Coal compositions for catalytic gasification
US7926750B2 (en) 2008-02-29 2011-04-19 Greatpoint Energy, Inc. Compactor feeder
US8709113B2 (en) 2008-02-29 2014-04-29 Greatpoint Energy, Inc. Steam generation processes utilizing biomass feedstocks
US8192716B2 (en) 2008-04-01 2012-06-05 Greatpoint Energy, Inc. Sour shift process for the removal of carbon monoxide from a gas stream
CA2718295C (en) 2008-04-01 2013-06-18 Greatpoint Energy, Inc. Processes for the separation of methane from a gas stream
US7955403B2 (en) * 2008-07-16 2011-06-07 Kellogg Brown & Root Llc Systems and methods for producing substitute natural gas
CN102159687B (zh) 2008-09-19 2016-06-08 格雷特波因特能源公司 使用炭甲烷化催化剂的气化方法
KR101256288B1 (ko) 2008-09-19 2013-04-23 그레이트포인트 에너지, 인크. 탄소질 공급원료의 기체화 방법
WO2010033850A2 (en) 2008-09-19 2010-03-25 Greatpoint Energy, Inc. Processes for gasification of a carbonaceous feedstock
WO2010048493A2 (en) 2008-10-23 2010-04-29 Greatpoint Energy, Inc. Processes for gasification of a carbonaceous feedstock
KR101290423B1 (ko) * 2008-12-30 2013-07-29 그레이트포인트 에너지, 인크. 촉매된 석탄 미립자의 제조 방법
KR101290453B1 (ko) 2008-12-30 2013-07-29 그레이트포인트 에너지, 인크. 촉매된 탄소질 미립자의 제조 방법
US8268899B2 (en) 2009-05-13 2012-09-18 Greatpoint Energy, Inc. Processes for hydromethanation of a carbonaceous feedstock
CA2759961C (en) * 2009-05-13 2013-12-17 Greatpoint Energy, Inc. Processes for hydromethanation of a carbonaceous feedstock
WO2010132551A2 (en) 2009-05-13 2010-11-18 Greatpoint Energy, Inc. Processes for hydromethanation of a carbonaceous feedstock
WO2011034889A1 (en) * 2009-09-16 2011-03-24 Greatpoint Energy, Inc. Integrated hydromethanation combined cycle process
WO2011049858A2 (en) 2009-10-19 2011-04-28 Greatpoint Energy, Inc. Integrated enhanced oil recovery process
WO2011049861A2 (en) 2009-10-19 2011-04-28 Greatpoint Energy, Inc. Integrated enhanced oil recovery process
CN102079685B (zh) * 2009-11-26 2014-05-07 新奥科技发展有限公司 两级气化炉煤气化制甲烷的方法
CN102639435A (zh) 2009-12-17 2012-08-15 格雷特波因特能源公司 整合的强化采油方法
WO2011106285A1 (en) 2010-02-23 2011-09-01 Greatpoint Energy, Inc. Integrated hydromethanation fuel cell power generation
US8652696B2 (en) 2010-03-08 2014-02-18 Greatpoint Energy, Inc. Integrated hydromethanation fuel cell power generation
AU2011248701B2 (en) 2010-04-26 2013-09-19 Greatpoint Energy, Inc. Hydromethanation of a carbonaceous feedstock with vanadium recovery
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CA2806673A1 (en) 2010-08-18 2012-02-23 Greatpoint Energy, Inc. Hydromethanation of a carbonaceous feedstock
KR101543136B1 (ko) 2010-11-01 2015-08-07 그레이트포인트 에너지, 인크. 탄소질 공급원료의 히드로메탄화
US8800498B2 (en) * 2010-12-30 2014-08-12 Kellogg Brown & Root Llc Systems and methods for exchanging heat in a gasification system
CA2827916C (en) 2011-02-23 2016-06-21 Greatpoint Energy, Inc. Hydromethanation of a carbonaceous feedstock with nickel recovery
US9127221B2 (en) 2011-06-03 2015-09-08 Greatpoint Energy, Inc. Hydromethanation of a carbonaceous feedstock
WO2013052553A1 (en) 2011-10-06 2013-04-11 Greatpoint Energy, Inc. Hydromethanation of a carbonaceous feedstock
KR101576781B1 (ko) 2012-10-01 2015-12-10 그레이트포인트 에너지, 인크. 응집된 미립자 저등급 석탄 공급원료 및 그의 용도
KR101646890B1 (ko) 2012-10-01 2016-08-12 그레이트포인트 에너지, 인크. 응집된 미립자 저등급 석탄 공급원료 및 그의 용도
WO2014055365A1 (en) 2012-10-01 2014-04-10 Greatpoint Energy, Inc. Use of contaminated low-rank coal for combustion
WO2014055353A1 (en) 2012-10-01 2014-04-10 Greatpoint Energy, Inc. Agglomerated particulate low-rank coal feedstock and uses thereof
CN103881755B (zh) * 2014-03-31 2017-01-11 新奥科技发展有限公司 一种原料制备装置及方法
US10464872B1 (en) 2018-07-31 2019-11-05 Greatpoint Energy, Inc. Catalytic gasification to produce methanol
US10344231B1 (en) 2018-10-26 2019-07-09 Greatpoint Energy, Inc. Hydromethanation of a carbonaceous feedstock with improved carbon utilization
US10435637B1 (en) 2018-12-18 2019-10-08 Greatpoint Energy, Inc. Hydromethanation of a carbonaceous feedstock with improved carbon utilization and power generation
US10618818B1 (en) 2019-03-22 2020-04-14 Sure Champion Investment Limited Catalytic gasification to produce ammonia and urea

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US3689240A (en) * 1971-03-18 1972-09-05 Exxon Research Engineering Co Production of methane rich gases
AU537070B2 (en) * 1979-08-06 1984-06-07 Swanson, Rollan Dr. Converting coal to gaseous hydrocarbons and volatile distillates
DE3268510D1 (en) * 1981-06-05 1986-02-27 Exxon Research Engineering Co An integrated catalytic coal devolatilisation and steam gasification process

Also Published As

Publication number Publication date
EP0259927B1 (de) 1992-05-06
AU585732B2 (en) 1989-06-22
EP0259927A1 (de) 1988-03-16
AU7823887A (en) 1988-03-17
ES2032813T3 (es) 1993-03-01
IT8621661A0 (it) 1986-09-10
CN1017702B (zh) 1992-08-05
IT1197477B (it) 1988-11-30
CA1332108C (en) 1994-09-27
ZA876637B (en) 1988-07-27
CN87106233A (zh) 1988-03-30

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