DE37333C - Process for the preparation of magnesium phosphates by means of sulphurous acid using the same twice - Google Patents
Process for the preparation of magnesium phosphates by means of sulphurous acid using the same twiceInfo
- Publication number
- DE37333C DE37333C DENDAT37333D DE37333DA DE37333C DE 37333 C DE37333 C DE 37333C DE NDAT37333 D DENDAT37333 D DE NDAT37333D DE 37333D A DE37333D A DE 37333DA DE 37333 C DE37333 C DE 37333C
- Authority
- DE
- Germany
- Prior art keywords
- magnesium
- sulphurous acid
- lime
- solution
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- LSNNMFCWUKXFEE-UHFFFAOYSA-N sulfonic acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 title claims description 6
- GVALZJMUIHGIMD-UHFFFAOYSA-H Magnesium phosphate tribasic Chemical class [Mg+2].[Mg+2].[Mg+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O GVALZJMUIHGIMD-UHFFFAOYSA-H 0.000 title claims description 5
- 239000004137 magnesium phosphate Substances 0.000 title description 3
- 235000010994 magnesium phosphates Nutrition 0.000 title description 3
- 238000002360 preparation method Methods 0.000 title description 2
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims description 8
- 235000015450 Tilia cordata Nutrition 0.000 claims description 8
- 235000011941 Tilia x europaea Nutrition 0.000 claims description 8
- 239000004571 lime Substances 0.000 claims description 8
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 4
- CSNNHWWHGAXBCP-UHFFFAOYSA-L mgso4 Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims description 4
- ZLNQQNXFFQJAID-UHFFFAOYSA-L Magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims description 2
- VTHJTEIRLNZDEV-UHFFFAOYSA-L Magnesium hydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 2
- 230000000875 corresponding Effects 0.000 claims description 2
- 239000010440 gypsum Substances 0.000 claims description 2
- 229910052602 gypsum Inorganic materials 0.000 claims description 2
- 239000001095 magnesium carbonate Substances 0.000 claims description 2
- 239000011776 magnesium carbonate Substances 0.000 claims description 2
- 229910000021 magnesium carbonate Inorganic materials 0.000 claims description 2
- 239000000347 magnesium hydroxide Substances 0.000 claims description 2
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 2
- 239000000395 magnesium oxide Substances 0.000 claims description 2
- 229910052943 magnesium sulfate Inorganic materials 0.000 claims description 2
- 235000019341 magnesium sulphate Nutrition 0.000 claims description 2
- JESHZQPNPCJVNG-UHFFFAOYSA-L magnesium;sulfite Chemical compound [Mg+2].[O-]S([O-])=O JESHZQPNPCJVNG-UHFFFAOYSA-L 0.000 claims description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 2
- 235000021317 phosphate Nutrition 0.000 claims 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 claims 2
- 239000001226 triphosphate Substances 0.000 claims 2
- 235000011178 triphosphate Nutrition 0.000 claims 2
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 claims 2
- QORWJWZARLRLPR-UHFFFAOYSA-H Tricalcium phosphate Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 claims 1
- 239000001506 calcium phosphate Substances 0.000 claims 1
- 229910000389 calcium phosphate Inorganic materials 0.000 claims 1
- 235000011010 calcium phosphates Nutrition 0.000 claims 1
- 239000007800 oxidant agent Substances 0.000 claims 1
- 238000000926 separation method Methods 0.000 claims 1
- 239000006228 supernatant Substances 0.000 claims 1
- NUJOXMJBOLGQSY-UHFFFAOYSA-N Manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K [O-]P([O-])([O-])=O Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 229960002261 magnesium phosphate Drugs 0.000 description 2
- 229910000157 magnesium phosphate Inorganic materials 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 238000007664 blowing Methods 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 229910000460 iron oxide Inorganic materials 0.000 description 1
- 235000013980 iron oxide Nutrition 0.000 description 1
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000010414 supernatant solution Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B9/00—Fertilisers based essentially on phosphates or double phosphates of magnesium
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Fertilizers (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
Description
KAISERLICHESIMPERIAL
PATENTAMT.PATENT OFFICE.
PATENTSCHRIFTPATENT LETTERING
. KLASSE 16: Düngerbereitung.. CLASS 16: Fertilizer preparation.
Patentirt im Deutschen Reiche vom 19. Januar 1886 ab.Patented in the German Empire on January 19, 1886.
Um Magnesiumphosphat darzustellen, bringt man Kalkphosphat durch schweflige Säure in Lösung und setzt eine dem gelösten Kalk entsprechende Menge Magnesiumsulfat zu und darauf nach der Filtration so viel Magnesiumoxyd, -Carbonat oder -Hydroxyd,' dafs gerade Magnesiumphosphat ausgefällt wird.In order to produce magnesium phosphate, lime phosphate is brought in by means of sulphurous acid Solution and adds an amount of magnesium sulphate corresponding to the dissolved lime and thereupon, after filtration, enough magnesium oxide, carbonate or hydroxide, just enough Magnesium phosphate is precipitated.
Die überstehende Lösung des Magnesiumsulfits wird in geeigneter Weise (durch Einblasen von Luft, durch Eisenoxyde oder Braunstein etc.) wieder in Sulfat übergeführt und zum Ueberführen des Kalkes einer zweiten Portion Kalkphosphat in Gyps benutzt. Auf diese Weise gelingt es, die angewendete schweflige Säure zweimal zu benutzen.The supernatant solution of the magnesium sulfite is removed in a suitable manner (by blowing in from air, through iron oxides or manganese dioxide, etc.) converted back into sulfate and a second portion of lime phosphate is used to convert the lime into gypsum. on In this way it is possible to use the sulphurous acid applied twice.
Claims (1)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE37333C true DE37333C (en) |
Family
ID=313094
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DENDAT37333D Expired - Lifetime DE37333C (en) | Process for the preparation of magnesium phosphates by means of sulphurous acid using the same twice |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE37333C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE927153C (en) * | 1943-06-19 | 1955-05-02 | Theodor Dr Schmidt | Process for the production of calcium magnesium phosphates |
-
0
- DE DENDAT37333D patent/DE37333C/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE927153C (en) * | 1943-06-19 | 1955-05-02 | Theodor Dr Schmidt | Process for the production of calcium magnesium phosphates |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE37333C (en) | Process for the preparation of magnesium phosphates by means of sulphurous acid using the same twice | |
| DE2436124A1 (en) | Iron polysulphate soln. for treating pulp waste - prepd. by oxidising ferrous sulphate soln. in presence of sulphuric acid | |
| DE566834C (en) | Process for the production of concentrated fertilizers | |
| DE84954C (en) | ||
| DE156356C (en) | ||
| DE463720C (en) | Process for the production of ammonium sulphate and magnesium sulphite from magnesium sulphate, ammonia and sulphurous acid | |
| DE453118C (en) | Process for the production of solutions suitable for the manufacture of ammonium sulphate and alkali sulphate or their double salts | |
| DE253553C (en) | ||
| DE533857C (en) | Process for the preparation of fertilizers consisting essentially of alkali metal phosphates | |
| DE575319C (en) | Production of potassium nitrate with simultaneous production of chlorammonium from potassium chloride, nitric acid and ammonia | |
| DE204063C (en) | ||
| DE555581C (en) | Process for the production of ammonium sulphate nitrate | |
| DE397473C (en) | Process for utilizing the sulphurous acid occurring in the exhaust gases of the chemical industry for the purpose of obtaining high-quality phosphates | |
| DE649365C (en) | Production of alkali hydroxide solutions by causticizing the carbonates in an aqueous solution with lime | |
| DE1667672B2 (en) | PROCESS FOR THE USE OF SO DEEP 2 FROM THE EXHAUST GASES FROM SULFUR ACID PRODUCTION | |
| DE307101C (en) | ||
| DE337217C (en) | ||
| AT62216B (en) | Process for the simultaneous production of ammonium phosphate and ammonium nitrate. | |
| DE494839C (en) | Obtaining a basic copper sulfate particularly suitable for the production of copper oxide ammonia cellulose solutions for the production of rayon | |
| DE204476C (en) | ||
| DE331637C (en) | Process for the extraction of huettenfaehigem zinc oxide from gypsum-containing precipitates | |
| DE299004C (en) | ||
| DE81347C (en) | ||
| DE116419C (en) | ||
| DE285617C (en) |