DE3632975C2 - - Google Patents
Info
- Publication number
- DE3632975C2 DE3632975C2 DE3632975A DE3632975A DE3632975C2 DE 3632975 C2 DE3632975 C2 DE 3632975C2 DE 3632975 A DE3632975 A DE 3632975A DE 3632975 A DE3632975 A DE 3632975A DE 3632975 C2 DE3632975 C2 DE 3632975C2
- Authority
- DE
- Germany
- Prior art keywords
- methanol
- methyl chloride
- solution
- hcl
- aqueous
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 87
- NEHMKBQYUWJMIP-UHFFFAOYSA-N chloromethane Chemical compound ClC NEHMKBQYUWJMIP-UHFFFAOYSA-N 0.000 claims description 48
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 39
- 229940050176 methyl chloride Drugs 0.000 claims description 24
- 229910000041 hydrogen chloride Inorganic materials 0.000 claims description 23
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 claims description 23
- 238000006243 chemical reaction Methods 0.000 claims description 9
- 238000004519 manufacturing process Methods 0.000 claims description 9
- 238000004821 distillation Methods 0.000 claims description 8
- 239000008346 aqueous phase Substances 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 7
- 239000007791 liquid phase Substances 0.000 claims description 6
- 239000000047 product Substances 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 239000003054 catalyst Substances 0.000 claims description 4
- NEHMKBQYUWJMIP-NJFSPNSNSA-N chloro(114C)methane Chemical compound [14CH3]Cl NEHMKBQYUWJMIP-NJFSPNSNSA-N 0.000 claims description 4
- 239000007795 chemical reaction product Substances 0.000 claims description 3
- 238000000926 separation method Methods 0.000 claims description 3
- 239000012071 phase Substances 0.000 claims description 2
- YSVZGWAJIHWNQK-UHFFFAOYSA-N [3-(hydroxymethyl)-2-bicyclo[2.2.1]heptanyl]methanol Chemical compound C1CC2C(CO)C(CO)C1C2 YSVZGWAJIHWNQK-UHFFFAOYSA-N 0.000 claims 1
- 238000001816 cooling Methods 0.000 claims 1
- 238000003786 synthesis reaction Methods 0.000 description 4
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000002253 acid Substances 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/38—Separation; Purification; Stabilisation; Use of additives
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR8514552A FR2587995B1 (fr) | 1985-10-01 | 1985-10-01 | Procede de demethanolisation des solutions residuaires de la reaction de synthese du chlorure de methyle |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE3632975A1 DE3632975A1 (de) | 1987-04-02 |
| DE3632975C2 true DE3632975C2 (en, 2012) | 1991-02-28 |
Family
ID=9323430
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19863632975 Granted DE3632975A1 (de) | 1985-10-01 | 1986-09-29 | Verfahren zum entfernen von methanol aus den bei der synthese von methylchlorid anfallenden rueckstandsloesungen |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US4808761A (en, 2012) |
| JP (1) | JPS6284032A (en, 2012) |
| BE (1) | BE905524A (en, 2012) |
| CA (1) | CA1260503A (en, 2012) |
| DE (1) | DE3632975A1 (en, 2012) |
| ES (1) | ES2002515A6 (en, 2012) |
| FR (1) | FR2587995B1 (en, 2012) |
| GB (1) | GB2181132B (en, 2012) |
| IT (1) | IT1197473B (en, 2012) |
| NL (1) | NL191514C (en, 2012) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2619729B1 (fr) * | 1987-08-27 | 1991-06-21 | Atochem | Procede d'elimination du chlore |
| EP2403628B1 (en) * | 2009-03-05 | 2017-09-27 | Blue Cube IP LLC | Method for the hydrochlorination of alkanols to alkyl halides |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2153170A (en) * | 1936-08-22 | 1939-04-04 | Standard Oil Dev Co | Process for producing alkyl halides |
| US3432561A (en) * | 1966-03-28 | 1969-03-11 | Baird Chem Ind | Preparation of alkyl chlorides by the reaction of alkyl alcohols with phosphorus trichloride |
| US3527820A (en) * | 1967-10-19 | 1970-09-08 | Melle Bezons | Production of alkyl chlorides containing from 3 to 6 carbon atoms |
| JPS5231842B2 (en, 2012) * | 1973-10-06 | 1977-08-17 | ||
| FR2270224A1 (en) * | 1974-05-08 | 1975-12-05 | Du Pont | Continuous methyl chloride prepn - from methanol and hydrochloric acid without requiring catalyst |
| US3981938A (en) * | 1974-07-08 | 1976-09-21 | The Dow Chemical Company | Method for producing dry alkyl halides |
-
1985
- 1985-10-01 FR FR8514552A patent/FR2587995B1/fr not_active Expired
-
1986
- 1986-09-05 IT IT21620/86A patent/IT1197473B/it active
- 1986-09-22 NL NL8602392A patent/NL191514C/xx not_active IP Right Cessation
- 1986-09-29 DE DE19863632975 patent/DE3632975A1/de active Granted
- 1986-09-30 CA CA000519464A patent/CA1260503A/fr not_active Expired
- 1986-09-30 GB GB8623465A patent/GB2181132B/en not_active Expired
- 1986-09-30 BE BE0/217233A patent/BE905524A/fr not_active IP Right Cessation
- 1986-10-01 JP JP61234244A patent/JPS6284032A/ja active Granted
- 1986-10-01 US US06/914,077 patent/US4808761A/en not_active Expired - Lifetime
- 1986-10-01 ES ES8602341A patent/ES2002515A6/es not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| NL191514B (nl) | 1995-04-18 |
| FR2587995A1 (fr) | 1987-04-03 |
| ES2002515A6 (es) | 1988-08-16 |
| US4808761A (en) | 1989-02-28 |
| GB2181132A (en) | 1987-04-15 |
| CA1260503A (fr) | 1989-09-26 |
| NL8602392A (nl) | 1987-05-04 |
| FR2587995B1 (fr) | 1987-12-11 |
| IT8621620A0 (it) | 1986-09-05 |
| BE905524A (fr) | 1987-03-30 |
| DE3632975A1 (de) | 1987-04-02 |
| IT1197473B (it) | 1988-11-30 |
| NL191514C (nl) | 1995-08-21 |
| JPS6284032A (ja) | 1987-04-17 |
| JPH0156053B2 (en, 2012) | 1989-11-28 |
| GB2181132B (en) | 1989-09-13 |
| GB8623465D0 (en) | 1986-11-05 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| OP8 | Request for examination as to paragraph 44 patent law | ||
| D2 | Grant after examination | ||
| 8364 | No opposition during term of opposition |