DE3625280A1 - Purifier for drinking water plants - Google Patents

Purifier for drinking water plants

Info

Publication number
DE3625280A1
DE3625280A1 DE19863625280 DE3625280A DE3625280A1 DE 3625280 A1 DE3625280 A1 DE 3625280A1 DE 19863625280 DE19863625280 DE 19863625280 DE 3625280 A DE3625280 A DE 3625280A DE 3625280 A1 DE3625280 A1 DE 3625280A1
Authority
DE
Germany
Prior art keywords
cleaner according
drinking water
iron
manganese
anion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
DE19863625280
Other languages
German (de)
Other versions
DE3625280C2 (en
Inventor
Des Erfinders Auf Nennung Verzicht
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
TEVAN CHEMIE B.V., GORINCHEM, NL
Original Assignee
Feldmann Hagen
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Feldmann Hagen filed Critical Feldmann Hagen
Priority to DE19863625280 priority Critical patent/DE3625280A1/en
Publication of DE3625280A1 publication Critical patent/DE3625280A1/en
Application granted granted Critical
Publication of DE3625280C2 publication Critical patent/DE3625280C2/de
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F5/00—Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents
    • C02F5/08—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/53—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone involving the removal of at least part of the materials of the treated article, e.g. etching, drying of hardened concrete
    • C04B41/5315—Cleaning compositions, e.g. for removing hardened cement from ceramic tiles
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/60—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only artificial stone
    • C04B41/72—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only artificial stone involving the removal of part of the materials of the treated articles, e.g. etching
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
    • C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
    • C23G1/08—Iron or steel
    • C23G1/088—Iron or steel solutions containing organic acids

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Water Supply & Treatment (AREA)
  • Environmental & Geological Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Detergent Compositions (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The purifier for drinking water plants is intended to dissolve lime, fat and other usual contaminants and iron- and/or manganese-containing encrustations. It has a package composed of two part-packages, of which one for the normal sediment has a mixture, packed liquid-tightly, of water-soluble, but solid, organic and/or inorganic acids and/or acid salts in powder or granule form and the other for the iron- and manganese-containing encrustations has ascorbic acid, citric acid and/or a disinfecting and/or deodorising active component in solid form which slowly releases peroxide oxygen and contains the active peroxo group in the form of a chemical compound or a stable adduct, and which purifier contains a compound which is not considered to be a foreign substance according to the water supply standards in the drinking water of drinking water supply plants or wells.

Description

Die Erfindung betrifft einen Reiniger gemäß dem Oberbe­ griff des Hauptanspruchs.The invention relates to a cleaner according to the Oberbe gripped the main claim.

Solche Reiniger liegen in zwei verschiedenen Formen vor. Zum einen werden für den normalen Schmutz und die normalen Ablagerungen flüssige Säuren eingesetzt, die in Kanistern angeliefert werden. Entweder wird diesen flüssigen Säuren als Wirkstoff eine eisen- und/oder manganlösende Verbin­ dung kurz vor der Anwendung zugesetzt, oder aber es wird diese Verbindung zeitlich danach zum Reinigen der Trink­ wasseranlagen eingesetzt.Such cleaners come in two different forms. Firstly, for normal dirt and normal Deposits of liquid acids are used in canisters to be delivered. Either this will be liquid acids as an active ingredient, an iron and / or manganese dissolving compound added shortly before use, or else it will this connection timed afterwards for cleaning the drinking water systems used.

Von Nachteil sind die hohen Transportkosten infolge des hohen Gewichtanteils von Wasser. Wird beispielsweise Was­ serstoffperoxyd als Reiniger verwendet, ist ein normaler Versand nicht möglich, weil es sich um eine recht gefähr­ liche Verbindung handelt. Des weiteren sind diese flüssi­ gen Reiniger nur für den beschränkten Einsatz bei norma­ ler Verschmutzung geeignet. Zum Lösen eisen- und/oder man­ ganhaltiger Ablagerungen und Verockerungen ist ein geson­ dert zu beziehender Wirkstoff erforderlich; dieser kann dem flüssigen Wirkstoff nicht schon vor dem Transport zu­ gemischt werden, weil er nach kurzer Zeit von dem Reini­ ger zersetzt wird.The high transport costs due to the high weight of water. For example, What Use of peroxide as a cleaner is normal Shipping not possible because it is quite dangerous connection. Furthermore, they are liquid gene cleaner only for limited use at norma Suitable for pollution. To solve iron and / or one Complete deposits and blockages is a separate active substance to be obtained is required; this can the liquid active ingredient before transport be mixed, because after a short time the Reini is decomposed.

Der Erfindung liegt die Aufgabe zugrunde, einen zum billi­ gen und einfachen Versand geeigneten Reiniger bereitzustel­ len, der auch für mangan- und/oder eisenhaltige Ablagerun­ gen und Verockerungen einsetzbar ist.The invention has for its object one for billi suitable and easy shipping to provide suitable cleaners len, also for manganese and / or ferrous deposits conditions and blockages can be used.

Diese Aufgabe wird erfindungsgemäß durch den Gegenstand des Anspruches 1 gelöst. Nach Lehre der Erfindung wird zum Versand eine Abpackung, bestehend aus zwei Teilpackungen verwendet, von denen die eine ein flüssigkeitsdichtes Be­ hältnis darstellt, das mit einer festen anorganischen Säure und/oder einem sauren Salz in Pulver- oder Granulat­ form gefüllt ist. Die zweite Teilpackung enthält die eben­ falls einen Feststoff enthaltende Wirkomponente für eisen­ und manganhaltige Verockerungen in Trinkwasseranlagen. Mit dieser, da kein Wasser enthaltenden und daher leichten Ab­ packung ist ein billiger und einfacher Transport eines Rei­ nigungsmittels beispielsweise durch die Post zu einem Be­ steller möglich, der darüber hinaus mit dem Einsatzgebiet für den Reiniger nicht auf normale Verschmutzung beschränkt ist, sondern im Bedarfsfalle auch schwerlösliche eisen- und/ oder manganhaltige Verockerungen relativ schnell und einfach ablösen kann. Je nach Ausbildung der zweiten Wirkkomponen­ te ist zugleich eine desinfizierende und/oder desodorieren­ de Wirkung erforderlichenfalls möglich.This object is achieved by the subject of claim 1 solved. According to the teaching of the invention Dispatch of a package consisting of two partial packages used, one of which is a liquid-tight Be Ratio represents that with a solid inorganic Acid and / or an acid salt in powder or granules  form is filled. The second part pack contains them if an active component containing a solid for iron and manganese-containing blockages in drinking water systems. With this, since no water-containing and therefore easy from pack is a cheap and easy transportation of a rei cleaning agent, for example, by post to a Be possible, who is also involved with the area of application for the cleaner not limited to normal soiling but, if necessary, also poorly soluble iron and / or manganese-containing blockages relatively quickly and easily can replace. Depending on the formation of the second active components te is also a disinfectant and / or deodoriser de Effect possible if necessary.

Zweckmäßige Ausgestaltungen und Weiterbildungen der Er­ findung sind in den Unteransprüchen gekennzeichnet.Appropriate refinements and developments of the Er invention are characterized in the subclaims.

BeispieleExamples

1. Ein Trinkwasserbehälter von 1000 m3 Volumen, dessen was­ serbenetzte Flächen aus Beton bestanden, war mit einer ca. 0.5 bis 1 mm dicken Schicht aus Eisenoxidhydrat und Mangan-IV-oxid inkrustiert. Wenige Sekunden nach Auf­ sprühen einer wässrigen Lösung der erfindungsgemäßen Mischung entfärbte sich der ursprünglich tief schwarz­ braune Belag und konnte leicht abgewaschen werden.1. A drinking water container with a volume of 1000 m 3 , the surface of which was wetted with concrete, was incrusted with an approximately 0.5 to 1 mm thick layer of iron oxide hydrate and manganese IV oxide. A few seconds after spraying on an aqueous solution of the mixture according to the invention, the originally deep black-brown coating discolored and could be easily washed off.

2. Eine Rohrleitung aus Eisen mit einer Nennweite von 1 Zoll und einer Gesamtlänge von 20 Metern war durch Anlagerun­ gen von Calciumcarbonat und Mangan-IV-oxid fast völlig verstopft. Durch Spülen mit einer wässrigen Lösung der erfindungsgemäßen Mischung konnte der Rohrquerschnitt wieder völlig freigelegt werden. 2. An iron pipe with a nominal size of 1 inch and a total length of 20 meters was due to annexation calcium carbonate and manganese IV oxide almost completely clogged. By rinsing with an aqueous solution of mixture according to the invention could the pipe cross section be completely exposed again.  

3. Eine Sprühkammer von 30 m3 Rauminhalt hatte auf den Wänden und auf allen Einbauten einen 2 bis 3 mm dicken Belag von sulfidhaltigem Eisenoxid. Durch Einsatz einer wässri­ gen Lösung der erfindungsgemäßen Mischung konnte eine Entkrustierung ohne störenden Schwefelwasserstoffgeruch vorgenommen werden.3. A spray chamber with a volume of 30 m 3 had a 2 to 3 mm thick coating of sulfide-containing iron oxide on the walls and on all internals. By using an aqueous solution of the mixture according to the invention, decrusting could be carried out without an annoying odor of hydrogen sulfide.

4. Die erfindungsgemäße Mischung hat eine deutliche Abtö­ tungswirkung auf Mikroorganismen, wie z.B. Algen, stark geruchsbildende Pilze und/oder Bakterien. Teile eines offenen Filterbeckens, die durch Schleimbildner stark kontaminiert waren, konnten durch den Einsatz einer wäss­ rigen Lösung der erfindungsgemäßen Mischung sauber und geruchlos gemacht werden.4. The mixture according to the invention has a clear kill effect on microorganisms, e.g. Algae, strong odor-causing fungi and / or bacteria. Parts of a open filter basin, strongly affected by slime formers were contaminated by using an aq clean solution of the mixture according to the invention clean and be made odorless.

Claims (12)

1. Reiniger für Trinkwasseranlagen für normale Ablage­ rungen wie Kalk, Fett und sonstige normale Verschmutzung sowie eisen- und/oder manganhaltige Verockerungen, ge­ kennzeichnet durch eine Abpackung, be­ stehend aus zwei Teilpackungen, von den die eine für die normale Ablagerung eine flüssigkeitsdicht verpackte Mischung aus wasserlöslichen, jedoch festen organischen und/oder an­ organischen Säuren und/oder sauren Salzen in pulverisierter oder granulierter Form und die andere für die eisen- und manganhaltigen Verockerungen Ascorbinsäure, Zitronensäure und/oder eine desinfizierende und/oder desodorierende Wirk­ komponente in fester Form aufweist, die Peroxid-Sauerstoff langsam abgibt und die wirksame Peroxo-Gruppe in Form einer chemischen Verbindung oder eines stabilen Addukts enthält, und/der eine nicht als Fremdstoff gemäß den Wasservorsor­ gungsnormen im Trinkwasser der Trinkwasserversorgungsanlage bzw. Brunnen geltende Verbindung enthält.1.Cleaner for drinking water systems for normal deposits such as lime, grease and other normal soiling as well as iron and / or manganese-containing blockages, characterized by a package consisting of two partial packages, one of which is a liquid-tight mixture for normal storage from water-soluble, but solid organic and / or organic acids and / or acidic salts in powdered or granular form and the other for the iron and manganese-containing constipations ascorbic acid, citric acid and / or a disinfectant and / or deodorant active component in solid form , which slowly releases peroxide oxygen and contains the effective peroxo group in the form of a chemical compound or a stable adduct, and / which contains a compound that is not considered a foreign substance according to the water precautionary standards in the drinking water of the drinking water supply system or well. 2. Reiniger nach Anspruch 1, dadurch ge­ kennzeichnet, daß sie als aktive Komponente das Anion Peroxoborat mit Natrium, Kalium, Ammonium, Calcium oder Magnesium als Kation und in Form des Mono- bis Tetrahy­ drats oder das Kation Eisen-II mit Sulfat oder Chlorid als Anion enthält.2. Cleaner according to claim 1, characterized ge indicates that it is an active component the anion peroxoborate with sodium, potassium, ammonium, calcium or magnesium as a cation and in the form of the mono- to tetrahy  drats or the cation iron-II with sulfate or chloride as Contains anion. 3. Reiniger nach Anspruch 1 oder 2, dadurch gekennzeichnet, daß sie als aktive Komponen­ te Harnstoffperhydrat enthält.3. Cleaner according to claim 1 or 2, characterized characterized as being active components contains urea perhydrate. 4. Reiniger nach einem der Ansprüche 1 bis 3, da­ durch gekennzeichnet, daß sie als Ra­ dikalbildner das Anion Peroxomonosulfat mit den möglichen Kationen Natrium, Kalium und Ammonium enthält.4. Cleaner according to one of claims 1 to 3, because characterized in that it is called Ra dical former the anion peroxomonosulfate with the possible Cations contain sodium, potassium and ammonium. 5. Reiniger nach einem der Ansprüche 1 bis 4, da­ durch gekennzeichnet, daß sie als Ra­ dikalbildner das Anion Peroxodisulfat mit den möglichen Ka­ tionen Natrium, Kalium und Ammonium enthält.5. Cleaner according to one of claims 1 to 4, there characterized in that it is called Ra dical former the anion peroxodisulfate with the possible Ka contains sodium, potassium and ammonium. 6. Reiniger nach einem der Ansprüche 1 bis 5, da­ durch gekennzeichnet, daß sie als Ra­ dikalbildner das Anion Perchlorat mit den möglichen Kationen Natrium, Kalium und Ammonium enthält.6. Cleaner according to one of claims 1 to 5, there characterized in that it is called Ra dical former the anion perchlorate with the possible cations Contains sodium, potassium and ammonium. 7. Reiniger nach einem der Ansprüche 1 bis 6, da­ durch gekennzeichnet, daß sie die als Radikalbildner verwendeten Stoffe in einer Konzentration von 0,1 bis 1 Gew.%, vorzugsweise 0,2 Gew.%, enthält.7. Cleaner according to one of claims 1 to 6, there characterized in that they are the as Radical formers used substances in a concentration of Contains 0.1 to 1% by weight, preferably 0.2% by weight. 8. Reiniger nach einem der Ansprüche 1 bis 7, da­ durch gekennzeichnet, daß sie 0,1 bis 2 Gew.% von oxidationsbeständigen Tensiden enthält.8. Cleaner according to one of claims 1 to 7, there characterized by being 0.1 to Contains 2% by weight of oxidation-resistant surfactants. 9. Reiniger nach einem der Ansprüche 1 bis 8, da­ durch gekennzeichnet, daß sie als Ge­ rüstbildner Polyaldehydocarbonsäuren, Phosphate und Sulfate enthält. 9. Cleaner according to one of claims 1 to 8, there characterized in that it as Ge scaffolders polyaldehydocarboxylic acids, phosphates and sulfates contains.   10. Reiniger nach einem der Ansprüche 1 bis 9, da­ durch gekennzeichnet, daß die festen organischen oder anorganischen Säuren und/oder Salze in wässriger Lösung auf einen ph-Wert von 5,5 oder kleiner einstellbar sind.10. Cleaner according to one of claims 1 to 9, there characterized by that the fixed organic or inorganic acids and / or salts in aqueous solution to a pH of 5.5 or less are adjustable. 11. Reiniger nach einem der Ansprüche 1 bis 10, dadurch gekennzeichnet, daß bei Verwendung von Eisen-II-Sulfat für die normale Ablagerung dieses in einer einzigen Packung zusammen mit den anderen, die eisen- und manganhaltigen Verockerungen ablösenden Wirkstoffen gemischt sein kann.11. Cleaner according to one of claims 1 to 10, characterized in that at Use of ferrous sulfate for normal deposition this in a single pack with the others, relieving the iron and manganese-containing blockages Active ingredients can be mixed. 12. Reiniger nach Anspruch 11, dadurch ge­ kennzeichnet, daß die einzige Teilpackung flüssigkeitsdicht von der Umgebungsluft abgetrennt ist.12. Cleaner according to claim 11, characterized ge indicates that the only partial pack is separated from the ambient air in a liquid-tight manner.
DE19863625280 1986-07-25 1986-07-25 Purifier for drinking water plants Granted DE3625280A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DE19863625280 DE3625280A1 (en) 1986-07-25 1986-07-25 Purifier for drinking water plants

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19863625280 DE3625280A1 (en) 1986-07-25 1986-07-25 Purifier for drinking water plants

Publications (2)

Publication Number Publication Date
DE3625280A1 true DE3625280A1 (en) 1988-02-04
DE3625280C2 DE3625280C2 (en) 1992-04-02

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Family Applications (1)

Application Number Title Priority Date Filing Date
DE19863625280 Granted DE3625280A1 (en) 1986-07-25 1986-07-25 Purifier for drinking water plants

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0456272A1 (en) * 1990-05-11 1991-11-13 Heimo Wessollek Cleaning agent for drinking water installations
DE4015201A1 (en) * 1990-05-11 1991-11-14 Heimo Wessollek CLEANER FOR DRINKING WATER SYSTEMS
WO1993002973A1 (en) * 1991-08-05 1993-02-18 Trawöger, Werner Anti-fouling agent for wet surfaces
DE102017125010A1 (en) * 2017-10-25 2019-04-25 CHT Germany GmbH Process for removing manganese oxide deposits from textile surfaces
WO2019081290A1 (en) 2017-10-25 2019-05-02 CHT Germany GmbH Method for removing manganese oxide deposits from textile surfaces

Citations (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1016241B (en) * 1952-01-30 1957-09-26 Zampoli & Brogi Process for the solidification of hydrogen peroxide
US3303104A (en) * 1963-12-12 1967-02-07 Lever Brothers Ltd Compositions containing discoloration inhibitors
US3399760A (en) * 1966-11-01 1968-09-03 Valentine Hechler Package and method of packaging
DE1546096A1 (en) * 1965-10-28 1970-02-05 Borg Holding Ag Process for removing copper-containing deposits from iron and steel surfaces
DE2040546C (en) * 1972-06-29 Feldmann, Hagen, 8000 München Aqueous solution of an aliphatic carboxylic acid to remove ocher deposits or deposits
DE2518880A1 (en) * 1974-04-30 1975-11-20 Ciba Geigy Ag METHODS AND MEANS TO PREVENT ALKALINE STONE
US3968048A (en) * 1975-02-14 1976-07-06 The Drackett Company Drain cleaning compositions
AT330930B (en) * 1973-04-13 1976-07-26 Henkel & Cie Gmbh PROCESS FOR THE PRODUCTION OF SOLID, SPILLABLE DETERGENTS OR CLEANING AGENTS WITH A CONTENT OF CALCIUM BINDING SUBSTANCES
DE2629081A1 (en) * 1976-06-29 1978-01-12 Peroxid Chemie Gmbh GERMIZIDES MEDIUM
DE2827571A1 (en) * 1977-06-27 1979-01-11 Akzo Gmbh DETERGENT COMPOSITION BASED ON ALKALICARBONATE
DE2901852A1 (en) * 1979-01-18 1980-07-31 Wurster & Dietz Maschf Sorting unit for timber boards - selects according to width and thickness using conveyor which carries boards over row of boxes
DE2904152A1 (en) * 1978-02-28 1980-08-14 Klaus Dipl Chem Dr Hoffmann Oxygen-releasing compsn. for fish:ponds - contg. sodium perborate mono:hydrate and potassium permanganate finely dispersed in polyethylene glycol as binding agent
US4221660A (en) * 1976-11-26 1980-09-09 Sterling Drug Inc. Method for disinfecting
US4234442A (en) * 1978-07-14 1980-11-18 Akzo N.V. Feed unit of a detergent composition based on alkali carbonate
EP0064647A1 (en) * 1981-04-28 1982-11-17 Amf Incorporated Filter media, method for oxidizing and removing soluble iron, method for removing and inactivating microorganisms, and particulate filter aid
DE3244443A1 (en) * 1982-12-01 1984-06-07 Rainer 7888 Rheinfelden Späne HYDROPEROXIDE CONTAINING AQUEOUS MINERAL ACID PREPARATIONS
DE3125452C2 (en) * 1981-06-29 1985-09-12 Degussa Ag, 6000 Frankfurt Process for detoxifying and lowering the COD and the BOD in continuous wastewater streams with changing contents of various oxidizable ingredients with hydrogen peroxide
DE3538131A1 (en) * 1984-10-26 1986-05-07 UHT Umwelt- und Hygienetechnik GmbH, 4800 Bielefeld Solution process and solvent for sparingly soluble carbonates

Patent Citations (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2040546C (en) * 1972-06-29 Feldmann, Hagen, 8000 München Aqueous solution of an aliphatic carboxylic acid to remove ocher deposits or deposits
DE1016241B (en) * 1952-01-30 1957-09-26 Zampoli & Brogi Process for the solidification of hydrogen peroxide
US3303104A (en) * 1963-12-12 1967-02-07 Lever Brothers Ltd Compositions containing discoloration inhibitors
DE1546096A1 (en) * 1965-10-28 1970-02-05 Borg Holding Ag Process for removing copper-containing deposits from iron and steel surfaces
US3399760A (en) * 1966-11-01 1968-09-03 Valentine Hechler Package and method of packaging
AT330930B (en) * 1973-04-13 1976-07-26 Henkel & Cie Gmbh PROCESS FOR THE PRODUCTION OF SOLID, SPILLABLE DETERGENTS OR CLEANING AGENTS WITH A CONTENT OF CALCIUM BINDING SUBSTANCES
DE2518880A1 (en) * 1974-04-30 1975-11-20 Ciba Geigy Ag METHODS AND MEANS TO PREVENT ALKALINE STONE
US3968048A (en) * 1975-02-14 1976-07-06 The Drackett Company Drain cleaning compositions
DE2629081A1 (en) * 1976-06-29 1978-01-12 Peroxid Chemie Gmbh GERMIZIDES MEDIUM
US4221660A (en) * 1976-11-26 1980-09-09 Sterling Drug Inc. Method for disinfecting
DE2827571A1 (en) * 1977-06-27 1979-01-11 Akzo Gmbh DETERGENT COMPOSITION BASED ON ALKALICARBONATE
DE2904152A1 (en) * 1978-02-28 1980-08-14 Klaus Dipl Chem Dr Hoffmann Oxygen-releasing compsn. for fish:ponds - contg. sodium perborate mono:hydrate and potassium permanganate finely dispersed in polyethylene glycol as binding agent
US4234442A (en) * 1978-07-14 1980-11-18 Akzo N.V. Feed unit of a detergent composition based on alkali carbonate
DE2901852A1 (en) * 1979-01-18 1980-07-31 Wurster & Dietz Maschf Sorting unit for timber boards - selects according to width and thickness using conveyor which carries boards over row of boxes
EP0064647A1 (en) * 1981-04-28 1982-11-17 Amf Incorporated Filter media, method for oxidizing and removing soluble iron, method for removing and inactivating microorganisms, and particulate filter aid
DE3125452C2 (en) * 1981-06-29 1985-09-12 Degussa Ag, 6000 Frankfurt Process for detoxifying and lowering the COD and the BOD in continuous wastewater streams with changing contents of various oxidizable ingredients with hydrogen peroxide
DE3244443A1 (en) * 1982-12-01 1984-06-07 Rainer 7888 Rheinfelden Späne HYDROPEROXIDE CONTAINING AQUEOUS MINERAL ACID PREPARATIONS
EP0113060A1 (en) * 1982-12-01 1984-07-11 R. Späne GmbH & Co. KG Method of eliminating manganese deposits from water works installations
DE3538131A1 (en) * 1984-10-26 1986-05-07 UHT Umwelt- und Hygienetechnik GmbH, 4800 Bielefeld Solution process and solvent for sparingly soluble carbonates

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0456272A1 (en) * 1990-05-11 1991-11-13 Heimo Wessollek Cleaning agent for drinking water installations
DE4015201A1 (en) * 1990-05-11 1991-11-14 Heimo Wessollek CLEANER FOR DRINKING WATER SYSTEMS
WO1993002973A1 (en) * 1991-08-05 1993-02-18 Trawöger, Werner Anti-fouling agent for wet surfaces
DE102017125010A1 (en) * 2017-10-25 2019-04-25 CHT Germany GmbH Process for removing manganese oxide deposits from textile surfaces
WO2019081290A1 (en) 2017-10-25 2019-05-02 CHT Germany GmbH Method for removing manganese oxide deposits from textile surfaces

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DE3625280C2 (en) 1992-04-02

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