DE3573108D1 - Process for the preparation of anhydrous carboxylic acids from alcohols - Google Patents
Process for the preparation of anhydrous carboxylic acids from alcoholsInfo
- Publication number
- DE3573108D1 DE3573108D1 DE8585110204T DE3573108T DE3573108D1 DE 3573108 D1 DE3573108 D1 DE 3573108D1 DE 8585110204 T DE8585110204 T DE 8585110204T DE 3573108 T DE3573108 T DE 3573108T DE 3573108 D1 DE3573108 D1 DE 3573108D1
- Authority
- DE
- Germany
- Prior art keywords
- group
- atom
- sec
- carboxylic acids
- methanol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000001735 carboxylic acids Chemical class 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 150000001298 alcohols Chemical class 0.000 title 1
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 6
- 125000004432 carbon atom Chemical group C* 0.000 abstract 3
- 229910052698 phosphorus Inorganic materials 0.000 abstract 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 2
- 229910052799 carbon Inorganic materials 0.000 abstract 2
- 125000004437 phosphorous atom Chemical group 0.000 abstract 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract 1
- 125000002877 alkyl aryl group Chemical group 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 125000003710 aryl alkyl group Chemical group 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 125000004429 atom Chemical group 0.000 abstract 1
- 229910002091 carbon monoxide Inorganic materials 0.000 abstract 1
- 150000001244 carboxylic acid anhydrides Chemical class 0.000 abstract 1
- 238000006555 catalytic reaction Methods 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 239000002815 homogeneous catalyst Substances 0.000 abstract 1
- 239000003446 ligand Substances 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 150000002895 organic esters Chemical class 0.000 abstract 1
- 125000004430 oxygen atom Chemical group O* 0.000 abstract 1
- 239000011574 phosphorus Substances 0.000 abstract 1
- 229910052703 rhodium Inorganic materials 0.000 abstract 1
- 239000010948 rhodium Substances 0.000 abstract 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C53/00—Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
- B01J31/1875—Phosphinites (R2P(OR), their isomeric phosphine oxides (R3P=O) and RO-substitution derivatives thereof)
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2495—Ligands comprising a phosphine-P atom and one or more further complexing phosphorus atoms covered by groups B01J31/1845 - B01J31/1885, e.g. phosphine/phosphinate or phospholyl/phosphonate ligands
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
- C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/54—Preparation of carboxylic acid anhydrides
- C07C51/56—Preparation of carboxylic acid anhydrides from organic acids, their salts, their esters or their halides, e.g. by carboxylation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/822—Rhodium
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
- Steroid Compounds (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US64147784A | 1984-08-16 | 1984-08-16 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE3573108D1 true DE3573108D1 (en) | 1989-10-26 |
Family
ID=24572567
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE8585110204T Expired DE3573108D1 (en) | 1984-08-16 | 1985-08-14 | Process for the preparation of anhydrous carboxylic acids from alcohols |
Country Status (12)
| Country | Link |
|---|---|
| EP (1) | EP0173170B1 (OSRAM) |
| JP (1) | JPS6157243A (OSRAM) |
| KR (1) | KR860001781A (OSRAM) |
| AT (1) | ATE46497T1 (OSRAM) |
| AU (1) | AU587581B2 (OSRAM) |
| CA (1) | CA1248549A (OSRAM) |
| DE (1) | DE3573108D1 (OSRAM) |
| FI (1) | FI89352C (OSRAM) |
| MX (1) | MX162712A (OSRAM) |
| NO (1) | NO161908C (OSRAM) |
| YU (1) | YU130585A (OSRAM) |
| ZA (2) | ZA856210B (OSRAM) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3429180A1 (de) * | 1984-08-08 | 1986-02-20 | Hoechst Ag, 6230 Frankfurt | Verfahren zur herstellung von essigsaeureanhydrid und ggf. essigsaeure |
| DE3823645C1 (OSRAM) * | 1988-07-13 | 1989-11-30 | Hoechst Ag | |
| JPH0578274A (ja) * | 1991-03-22 | 1993-03-30 | Dalian Kagaku Kogyo Kofun Yugenkoshi | 酢酸の製造法 |
| GB9802027D0 (en) * | 1998-01-31 | 1998-03-25 | Bp Chem Int Ltd | Chemical process |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4179403A (en) * | 1977-12-19 | 1979-12-18 | Shell Oil Company | Resin-ligand-metal complex compositions |
| NL8020079A (nl) * | 1979-02-12 | 1980-12-31 | Exxon Research Engineering Co | Werkwijze ter bereiding van aldehyden. |
| CA1237728A (en) * | 1984-07-20 | 1988-06-07 | Anthony G. Abatjoglou | Production of carboxylic acids from alcohols using rhodium complex catalysts |
| DE3429180A1 (de) * | 1984-08-08 | 1986-02-20 | Hoechst Ag, 6230 Frankfurt | Verfahren zur herstellung von essigsaeureanhydrid und ggf. essigsaeure |
| US4563309A (en) * | 1984-08-16 | 1986-01-07 | Union Carbide Corporation | Production of carboxylic anhydrides from methyl carboxlyates using rhodium complex catalysts |
-
1985
- 1985-08-09 CA CA000488454A patent/CA1248549A/en not_active Expired
- 1985-08-14 EP EP85110204A patent/EP0173170B1/en not_active Expired
- 1985-08-14 DE DE8585110204T patent/DE3573108D1/de not_active Expired
- 1985-08-14 AT AT85110204T patent/ATE46497T1/de not_active IP Right Cessation
- 1985-08-15 MX MX206307A patent/MX162712A/es unknown
- 1985-08-15 FI FI853130A patent/FI89352C/fi not_active IP Right Cessation
- 1985-08-15 NO NO853230A patent/NO161908C/no unknown
- 1985-08-15 AU AU46226/85A patent/AU587581B2/en not_active Ceased
- 1985-08-15 ZA ZA856210A patent/ZA856210B/xx unknown
- 1985-08-15 JP JP60178683A patent/JPS6157243A/ja active Granted
- 1985-08-15 YU YU01305/85A patent/YU130585A/xx unknown
- 1985-08-15 ZA ZA856212A patent/ZA856212B/xx unknown
- 1985-08-16 KR KR1019850005894A patent/KR860001781A/ko not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| ATE46497T1 (de) | 1989-10-15 |
| JPH0338257B2 (OSRAM) | 1991-06-10 |
| FI89352B (fi) | 1993-06-15 |
| NO161908B (no) | 1989-07-03 |
| AU587581B2 (en) | 1989-08-24 |
| NO161908C (no) | 1989-10-11 |
| MX162712A (es) | 1991-06-17 |
| JPS6157243A (ja) | 1986-03-24 |
| EP0173170A1 (en) | 1986-03-05 |
| FI853130A0 (fi) | 1985-08-15 |
| ZA856212B (en) | 1986-04-30 |
| EP0173170B1 (en) | 1989-09-20 |
| NO853230L (no) | 1986-02-17 |
| CA1248549A (en) | 1989-01-10 |
| FI853130L (fi) | 1986-02-17 |
| YU130585A (en) | 1987-12-31 |
| ZA856210B (en) | 1986-04-30 |
| AU4622685A (en) | 1986-02-20 |
| KR860001781A (ko) | 1986-03-22 |
| FI89352C (fi) | 1993-09-27 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8363 | Opposition against the patent | ||
| 8365 | Fully valid after opposition proceedings | ||
| 8339 | Ceased/non-payment of the annual fee |