DE3462945D1 - Process and apparatus for the cooling and liquefaction of at least a low boiling point gas, such as natural gas - Google Patents
Process and apparatus for the cooling and liquefaction of at least a low boiling point gas, such as natural gasInfo
- Publication number
- DE3462945D1 DE3462945D1 DE8484400906T DE3462945T DE3462945D1 DE 3462945 D1 DE3462945 D1 DE 3462945D1 DE 8484400906 T DE8484400906 T DE 8484400906T DE 3462945 T DE3462945 T DE 3462945T DE 3462945 D1 DE3462945 D1 DE 3462945D1
- Authority
- DE
- Germany
- Prior art keywords
- liquefaction
- gas
- cooling
- boiling point
- low boiling
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 title 2
- 238000009835 boiling Methods 0.000 title 1
- 238000001816 cooling Methods 0.000 title 1
- 239000007789 gas Substances 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- 239000003345 natural gas Substances 0.000 title 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
- F25J1/0243—Start-up or control of the process; Details of the apparatus used; Details of the refrigerant compression system used
- F25J1/0257—Construction and layout of liquefaction equipments, e.g. valves, machines
- F25J1/0262—Details of the cold heat exchange system
- F25J1/0264—Arrangement of heat exchanger cores in parallel with different functions, e.g. different cooling streams
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/0002—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the fluid to be liquefied
- F25J1/0022—Hydrocarbons, e.g. natural gas
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/003—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
- F25J1/0047—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using an "external" refrigerant stream in a closed vapor compression cycle
- F25J1/0052—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using an "external" refrigerant stream in a closed vapor compression cycle by vaporising a liquid refrigerant stream
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/003—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
- F25J1/0047—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using an "external" refrigerant stream in a closed vapor compression cycle
- F25J1/0052—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using an "external" refrigerant stream in a closed vapor compression cycle by vaporising a liquid refrigerant stream
- F25J1/0055—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using an "external" refrigerant stream in a closed vapor compression cycle by vaporising a liquid refrigerant stream originating from an incorporated cascade
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
- F25J1/0211—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a multi-component refrigerant [MCR] fluid in a closed vapor compression cycle
- F25J1/0214—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a multi-component refrigerant [MCR] fluid in a closed vapor compression cycle as a dual level refrigeration cascade with at least one MCR cycle
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
- F25J1/0243—Start-up or control of the process; Details of the apparatus used; Details of the refrigerant compression system used
- F25J1/0279—Compression of refrigerant or internal recycle fluid, e.g. kind of compressor, accumulator, suction drum etc.
- F25J1/0292—Refrigerant compression by cold or cryogenic suction of the refrigerant gas
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
- F25J1/0243—Start-up or control of the process; Details of the apparatus used; Details of the refrigerant compression system used
- F25J1/0279—Compression of refrigerant or internal recycle fluid, e.g. kind of compressor, accumulator, suction drum etc.
- F25J1/0295—Shifting of the compression load between different cooling stages within a refrigerant cycle or within a cascade refrigeration system
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2210/00—Processes characterised by the type or other details of the feed stream
- F25J2210/06—Splitting of the feed stream, e.g. for treating or cooling in different ways
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2220/00—Processes or apparatus involving steps for the removal of impurities
- F25J2220/60—Separating impurities from natural gas, e.g. mercury, cyclic hydrocarbons
- F25J2220/62—Separating low boiling components, e.g. He, H2, N2, Air
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2220/00—Processes or apparatus involving steps for the removal of impurities
- F25J2220/60—Separating impurities from natural gas, e.g. mercury, cyclic hydrocarbons
- F25J2220/64—Separating heavy hydrocarbons, e.g. NGL, LPG, C4+ hydrocarbons or heavy condensates in general
Landscapes
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Mechanical Engineering (AREA)
- Thermal Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Separation By Low-Temperature Treatments (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR8307620A FR2545589B1 (fr) | 1983-05-06 | 1983-05-06 | Procede et appareil de refroidissement et liquefaction d'au moins un gaz a bas point d'ebullition, tel que par exemple du gaz naturel |
Publications (1)
Publication Number | Publication Date |
---|---|
DE3462945D1 true DE3462945D1 (en) | 1987-05-07 |
Family
ID=9288670
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE8484400906T Expired DE3462945D1 (en) | 1983-05-06 | 1984-05-03 | Process and apparatus for the cooling and liquefaction of at least a low boiling point gas, such as natural gas |
Country Status (13)
Country | Link |
---|---|
US (1) | US4539028A (de) |
EP (1) | EP0125980B1 (de) |
JP (1) | JPH0627618B2 (de) |
AU (1) | AU560904B2 (de) |
CA (1) | CA1226206A (de) |
DE (1) | DE3462945D1 (de) |
ES (1) | ES8502536A1 (de) |
FR (1) | FR2545589B1 (de) |
IN (1) | IN161272B (de) |
MY (1) | MY101481A (de) |
NO (1) | NO159683C (de) |
OA (1) | OA07764A (de) |
SU (1) | SU1627097A3 (de) |
Families Citing this family (36)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2180921B (en) * | 1985-09-25 | 1990-01-24 | Sanyo Electric Co | Refrigeration system |
US4911741A (en) * | 1988-09-23 | 1990-03-27 | Davis Robert N | Natural gas liquefaction process using low level high level and absorption refrigeration cycles |
FR2681859B1 (fr) * | 1991-09-30 | 1994-02-11 | Technip Cie Fse Etudes Const | Procede de liquefaction de gaz naturel. |
US5271231A (en) * | 1992-08-10 | 1993-12-21 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Method and apparatus for gas liquefaction with plural work expansion of feed as refrigerant and air separation cycle embodying the same |
US5615561A (en) * | 1994-11-08 | 1997-04-01 | Williams Field Services Company | LNG production in cryogenic natural gas processing plants |
FR2743140B1 (fr) * | 1995-12-28 | 1998-01-23 | Inst Francais Du Petrole | Procede et dispositif de liquefaction en deux etapes d'un melange gazeux tel qu'un gaz naturel |
US5657643A (en) * | 1996-02-28 | 1997-08-19 | The Pritchard Corporation | Closed loop single mixed refrigerant process |
US5746066A (en) * | 1996-09-17 | 1998-05-05 | Manley; David B. | Pre-fractionation of cracked gas or olefins fractionation by one or two mixed refrigerant loops and cooling water |
US6659730B2 (en) * | 1997-11-07 | 2003-12-09 | Westport Research Inc. | High pressure pump system for supplying a cryogenic fluid from a storage tank |
US6446465B1 (en) * | 1997-12-11 | 2002-09-10 | Bhp Petroleum Pty, Ltd. | Liquefaction process and apparatus |
US6119479A (en) | 1998-12-09 | 2000-09-19 | Air Products And Chemicals, Inc. | Dual mixed refrigerant cycle for gas liquefaction |
MY117548A (en) | 1998-12-18 | 2004-07-31 | Exxon Production Research Co | Dual multi-component refrigeration cycles for liquefaction of natural gas |
US6471694B1 (en) | 2000-08-09 | 2002-10-29 | Cryogen, Inc. | Control system for cryosurgery |
US7004936B2 (en) * | 2000-08-09 | 2006-02-28 | Cryocor, Inc. | Refrigeration source for a cryoablation catheter |
US6347532B1 (en) | 1999-10-12 | 2002-02-19 | Air Products And Chemicals, Inc. | Gas liquefaction process with partial condensation of mixed refrigerant at intermediate temperatures |
FR2821351B1 (fr) * | 2001-02-26 | 2003-05-16 | Technip Cie | Procede de recuperation d'ethane, mettant en oeuvre un cycle de refrigeration utilisant un melange d'au moins deux fluides refrigerants, gaz obtenus par ce procede, et installation de mise en oeuvre |
US6640586B1 (en) * | 2002-11-01 | 2003-11-04 | Conocophillips Company | Motor driven compressor system for natural gas liquefaction |
US20080006053A1 (en) * | 2003-09-23 | 2008-01-10 | Linde Ag | Natural Gas Liquefaction Process |
DE102004011481A1 (de) * | 2004-03-09 | 2005-09-29 | Linde Ag | Verfahren zum Verflüssigen eines Kohlenwasserstoff-reichen Stromes |
US7727228B2 (en) | 2004-03-23 | 2010-06-01 | Medtronic Cryocath Lp | Method and apparatus for inflating and deflating balloon catheters |
US8491636B2 (en) | 2004-03-23 | 2013-07-23 | Medtronic Cryopath LP | Method and apparatus for inflating and deflating balloon catheters |
CN100344872C (zh) * | 2004-06-11 | 2007-10-24 | 中国科学院理化技术研究所 | 高真空深冷水汽捕集器 |
KR101301024B1 (ko) * | 2004-06-23 | 2013-08-29 | 엑손모빌 업스트림 리서치 캄파니 | 혼합 냉매 액화 공정 |
US8206345B2 (en) | 2005-03-07 | 2012-06-26 | Medtronic Cryocath Lp | Fluid control system for a medical device |
WO2008049821A2 (en) * | 2006-10-23 | 2008-05-02 | Shell Internationale Research Maatschappij B.V. | Method and apparatus for liquefying hydrocarbon streams |
WO2008058926A2 (en) * | 2006-11-14 | 2008-05-22 | Shell Internationale Research Maatschappij B.V. | Method and apparatus for cooling a hydrocarbon stream |
DE102007006370A1 (de) * | 2007-02-08 | 2008-08-14 | Linde Ag | Verfahren zum Verflüssigen eines Kohlenwasserstoff-reichen Stromes |
AU2009316236B2 (en) * | 2008-11-17 | 2013-05-02 | Woodside Energy Limited | Power matched mixed refrigerant compression circuit |
FR2957407B1 (fr) * | 2010-03-15 | 2012-08-17 | Inst Francais Du Petrole | Procede de liquefaction d'un gaz naturel avec des melanges refrigerants contenant au moins un hydrocarbure insature |
US9562717B2 (en) | 2010-03-25 | 2017-02-07 | The University Of Manchester | Refrigeration process |
WO2013096464A1 (en) * | 2011-12-20 | 2013-06-27 | Conocophillips Company | Liquefying natural gas in a motion environment |
CN103322769B (zh) * | 2012-03-20 | 2015-07-08 | 中国海洋石油总公司 | 一种基荷型天然气液化工厂的级联式液化系统 |
DE102013016695A1 (de) * | 2013-10-08 | 2015-04-09 | Linde Aktiengesellschaft | Verfahren zum Verflüssigen einer Kohlenwasserstoff-reichen Fraktion |
WO2016094168A1 (en) * | 2014-12-12 | 2016-06-16 | Dresser-Rand Company | System and method for liquefaction of natural gas |
RU2601670C1 (ru) * | 2015-07-22 | 2016-11-10 | Федеральное Государственное Автономное Образовательное Учреждение Высшего Профессионального Образования "Дальневосточный Федеральный Университет" (Двфу) | Холодильная машина |
US11262123B2 (en) | 2017-12-15 | 2022-03-01 | Saudi Arabian Oil Company | Process integration for natural gas liquid recovery |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2292203A1 (fr) * | 1974-11-21 | 1976-06-18 | Technip Cie | Procede et installation pour la liquefaction d'un gaz a bas point d'ebullition |
FR2471566B1 (fr) * | 1979-12-12 | 1986-09-05 | Technip Cie | Procede et systeme de liquefaction d'un gaz a bas point d'ebullition |
FR2499226B1 (fr) * | 1981-02-05 | 1985-09-27 | Air Liquide | Procede et installation de liquefaction d'un gaz |
-
1983
- 1983-05-06 FR FR8307620A patent/FR2545589B1/fr not_active Expired
-
1984
- 1984-04-24 IN IN347/DEL/84A patent/IN161272B/en unknown
- 1984-04-26 US US06/604,049 patent/US4539028A/en not_active Expired - Lifetime
- 1984-04-27 AU AU27460/84A patent/AU560904B2/en not_active Ceased
- 1984-05-02 CA CA000453353A patent/CA1226206A/en not_active Expired
- 1984-05-03 DE DE8484400906T patent/DE3462945D1/de not_active Expired
- 1984-05-03 EP EP84400906A patent/EP0125980B1/de not_active Expired
- 1984-05-04 SU SU843737939A patent/SU1627097A3/ru active
- 1984-05-04 ES ES532222A patent/ES8502536A1/es not_active Expired
- 1984-05-04 NO NO841803A patent/NO159683C/no not_active IP Right Cessation
- 1984-05-04 OA OA58289A patent/OA07764A/xx unknown
- 1984-05-07 JP JP59090837A patent/JPH0627618B2/ja not_active Expired - Fee Related
-
1987
- 1987-09-30 MY MYPI87002502A patent/MY101481A/en unknown
Also Published As
Publication number | Publication date |
---|---|
US4539028A (en) | 1985-09-03 |
AU560904B2 (en) | 1987-04-16 |
EP0125980B1 (de) | 1987-04-01 |
EP0125980A3 (en) | 1984-12-27 |
EP0125980A2 (de) | 1984-11-21 |
AU2746084A (en) | 1984-11-08 |
FR2545589B1 (fr) | 1985-08-30 |
NO841803L (no) | 1984-11-07 |
IN161272B (de) | 1987-11-07 |
CA1226206A (en) | 1987-09-01 |
NO159683B (no) | 1988-10-17 |
MY101481A (en) | 1991-11-18 |
ES532222A0 (es) | 1985-01-01 |
JPS6099982A (ja) | 1985-06-03 |
NO159683C (no) | 1989-01-25 |
JPH0627618B2 (ja) | 1994-04-13 |
OA07764A (fr) | 1985-08-30 |
FR2545589A1 (fr) | 1984-11-09 |
SU1627097A3 (ru) | 1991-02-07 |
ES8502536A1 (es) | 1985-01-01 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
8364 | No opposition during term of opposition |