DE3445815A1 - LAMINATE FILM AND COMPRESSIBLE DISPENSER MADE FROM IT - Google Patents
LAMINATE FILM AND COMPRESSIBLE DISPENSER MADE FROM ITInfo
- Publication number
- DE3445815A1 DE3445815A1 DE19843445815 DE3445815A DE3445815A1 DE 3445815 A1 DE3445815 A1 DE 3445815A1 DE 19843445815 DE19843445815 DE 19843445815 DE 3445815 A DE3445815 A DE 3445815A DE 3445815 A1 DE3445815 A1 DE 3445815A1
- Authority
- DE
- Germany
- Prior art keywords
- layer
- polyester
- adhesive
- paper
- polyethylene terephthalate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000005001 laminate film Substances 0.000 title claims description 4
- -1 polyethylene terephthalate Polymers 0.000 claims description 24
- 229910052751 metal Inorganic materials 0.000 claims description 23
- 239000002184 metal Substances 0.000 claims description 23
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 22
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 22
- 239000000853 adhesive Substances 0.000 claims description 18
- 230000001070 adhesive effect Effects 0.000 claims description 18
- 239000011888 foil Substances 0.000 claims description 18
- 229920000728 polyester Polymers 0.000 claims description 17
- 229920001283 Polyalkylene terephthalate Polymers 0.000 claims description 9
- 229920001577 copolymer Polymers 0.000 claims description 7
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 4
- 239000005977 Ethylene Substances 0.000 claims description 4
- 239000010410 layer Substances 0.000 description 46
- 238000010521 absorption reaction Methods 0.000 description 11
- 239000000606 toothpaste Substances 0.000 description 8
- 239000004698 Polyethylene Substances 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- 229920000573 polyethylene Polymers 0.000 description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
- 230000004888 barrier function Effects 0.000 description 6
- 239000000796 flavoring agent Substances 0.000 description 6
- 235000019634 flavors Nutrition 0.000 description 6
- 229910052760 oxygen Inorganic materials 0.000 description 6
- 239000001301 oxygen Substances 0.000 description 6
- 229920003023 plastic Polymers 0.000 description 5
- 239000004033 plastic Substances 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 229940034610 toothpaste Drugs 0.000 description 5
- 239000012790 adhesive layer Substances 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 230000032683 aging Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 229920001707 polybutylene terephthalate Polymers 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 229920001169 thermoplastic Polymers 0.000 description 2
- 239000012815 thermoplastic material Substances 0.000 description 2
- 239000004416 thermosoftening plastic Substances 0.000 description 2
- 239000000341 volatile oil Substances 0.000 description 2
- 238000003466 welding Methods 0.000 description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 230000003446 memory effect Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 229920001281 polyalkylene Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
- B32B15/09—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising polyesters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/16—Articles comprising two or more components, e.g. co-extruded layers
- B29C48/18—Articles comprising two or more components, e.g. co-extruded layers the components being layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B1/00—Layered products having a non-planar shape
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B15/12—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of paper or cardboard
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/20—Layered products comprising a layer of metal comprising aluminium or copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/10—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of paper or cardboard
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D35/00—Pliable tubular containers adapted to be permanently or temporarily deformed to expel contents, e.g. collapsible tubes for toothpaste or other plastic or semi-liquid material; Holders therefor
- B65D35/02—Body construction
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2367/00—Polyesters, e.g. PET, i.e. polyethylene terephthalate
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2439/00—Containers; Receptacles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2439/00—Containers; Receptacles
- B32B2439/40—Closed containers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2597/00—Tubular articles, e.g. hoses, pipes
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Laminated Bodies (AREA)
- Tubes (AREA)
- Wrappers (AREA)
- Cartons (AREA)
Description
Die vorliegende Erfindung betrifft Behälter und insbesondere zusammendrückbare Spender, deren Behälterteil aus laminierten Wänden gebildet ist, wobei in allen dafür anfälligen Bereichen des Behälters Produktpermeation und -absorption sowie Sauerstoffabsorption im wesentlichen unterdrückt werden.The present invention relates to containers and, more particularly, to collapsible dispensers, the container portion of which is composed of Laminated walls is formed, with product permeation in all areas of the container that are prone to this and absorption as well as oxygen absorption are substantially suppressed.
Im Verpackungsbereich sind aus Metall oder Kunststoff bestehende zusammendrückbar Tuben seit langem bekannt. Tuben aus extrudiertem Metall sind brüchig und längererIn the packaging sector, compressible tubes made of metal or plastic have long been known. Extruded metal tubes are brittle and longer
Gebrauch führt nicht selten zu Wandbrüchen, so daß die 15Use not infrequently leads to wall breaks, so that the 15th
Ware aus einer anderen Stelle als der im wesentlichen starren Spenderöffnung austritt. Von den bekannten Metalltuben sind Aluminiumtuben, die wahrscheinlich am wenigsten brüchig sind, in ihrem Anwendungsbereich eingeschränkt, daGoods emerge from a point other than the essentially rigid dispenser opening. From the well-known metal tubes Aluminum tubes, which are likely to be the least fragile, are limited in their scope because of this
es bis heute nicht möglich war, auf ihre Innenflächen 20it has not been possible to date to 20
einen wirklich befriedigenden Überzug aufzubringen, wenn es erforderlich war, einen Angriff und Korrosion des Metalls durch alkalische oder saure Inhaltsstoffe und eine Verunreinigung des Inhalts durch die Reaktionsprodukte zuto apply a really satisfactory coating when it was required an attack and corrosion of the metal by alkaline or acidic ingredients and a Contamination of the contents by the reaction products
verhindern. Abgesehen von der relativ brüchigen Natur 25impede. Apart from the relatively fragile nature 25
einer Metalltube kommt hinzu, daß die genannte innere Beschichtung eine zusätzliche Herstellungsstufe erfordert, die notwendigerweise den Preis des fertigen Artikels erhöht.a metal tube is added to that said inner tube Coating requires an additional manufacturing stage, which necessarily increases the price of the finished item elevated.
Tuben aus Polyethylen und anderen Kunststoffen werden zur Verpackung vieler Materialien verwendet. Es wurde jedoch beobachtet, daß bestimmte Waren nach einiger Zeit in solchen Behältern verderben. Kunststoff wie beispielsweiseTubes made from polyethylene and other plastics are used to package many materials. It did, however observed that certain goods spoil after a while in such containers. Plastic such as
Polyethylen ist in gewissem Ausmaß permeabel, wenn er in 35Polyethylene is permeable to some extent when put in 35
den für tubenförmige Behälter verwendeten Wandstärken eingesetzt wird. Die in den meisten Zahnpasten zur Geschmacksverleihung enthaltenen essentiellen Öle nehmen volumenmäßig während der Lagerung des Behälters ab, wodurch die Zahnpasta weniger schmackhaft wird. Weiterhin absorbiert die Wand des Plastikbehälters mit der Zeit Sauerstoff und schließlich wird das Produkt zersetzt, was bei fluoridhaltigen Zahnpasten in der Tat beobachtet wurde.the wall thicknesses used for tubular containers is used. Take the essential oils found in most toothpastes for flavoring in volume during storage of the container, making the toothpaste less tasty. Farther the wall of the plastic container will absorb oxygen over time and eventually the product will decompose, which has indeed been observed with toothpastes containing fluoride.
Dementsprechend wurde vorgeschlagen, eine Sperrschicht aus einer relativ dünnen Metallfolie zwischen der Ware und dem Tubenkörper aus Polyethylen anzuordnen, um den genannten Verlust an essentiellen Ölen und die Absorption von Sauerstoff zu verhindern. Gemäß einem Vorschlag bildet die Metallsperrschicht eine Zwischenschicht zwischen Lagen aus Polyethylen; durch Erhitzen mit oder ohne geeigneten Klebstoffen wird ein Laminat hergestellt. Obwohl eine Struktur dieses allgemeinen Typs einen Teil der Produktpermeation und der Sauerstoffabsorption durch den Tubenkörper verhindert, insbesondere dann, wenn die innere thermoplastische Schicht ein Copolymer aus einem Olefin und einem eine polare Gruppe enthaltenden Monomer ist, das mit diesem copolymerisierbar ist, bleibt dennoch die Möglichkeit, daß die Ware verdirbt, wenn auch in viel geringerem Ausmaß.Accordingly, it has been proposed to place a barrier layer of a relatively thin metal foil between the goods and to arrange the tube body made of polyethylene, in order to avoid the mentioned loss of essential oils and the absorption to prevent oxygen. According to one proposal, the metal barrier layer forms an intermediate layer between layers of polyethylene; a laminate is made by heating with or without suitable adhesives. Although a structure of this general type does some of the product permeation and oxygen absorption through Prevents the tube body, especially if the inner thermoplastic layer is a copolymer of a Olefin and a polar group-containing monomer copolymerizable therewith still remains the possibility of the goods spoiling, albeit to a much lesser extent.
Ein Nachteil der Polyolefinoberflache liegt in der mangelnden Eignung der Oberfläche für die Annahme von Druck- und Dekorationsmaterialien. Außerdem zeigt das Polyolefin einen Gedächtniseffekt; d.h., es bleibt nach dem Drücken nicht zusammengedrückt, was bei Zahnpastatuben ein besonderer Nachteil ist. Um diesen Mangel an Zusammendrückbarkeit zu beheben, muß die Metallschicht relativ dick sein, so daß ihre Zusammendrückbarkeit auf den Kunststoff übertragen wird.A disadvantage of the polyolefin surface is the lack of it Suitability of the surface for the acceptance of printing and decoration materials. In addition, the polyolefin shows a memory effect; i.e., it does not remain compressed after pressing, which is a special thing with toothpaste tubes Disadvantage is. To remedy this lack of compressibility, the metal layer must be relatively thick so that their compressibility is transferred to the plastic.
— O ~- O ~
Aufgabe der Erfindung ist es daher, zur Überwindung der genannten Nachteile einen zusammendrückbaren Spender
vorzuschlagen, der in seinem Behälterbereich laminierte Wände aufweist.
5The object of the invention is therefore to propose a compressible dispenser, which has laminated walls in its container area, in order to overcome the disadvantages mentioned.
5
Zur Lösung dieser Aufgabe wird ein tubenförmiger Behälter vorgeschlagen, dessen Körper mehrere miteinander verbundene Schichten aufweist, wobei eine dieser Schichten, etwa eine Metallfolie, eine Sperrschicht gegen Produktdurchtritt und Sauerstoffabsorption bildet und eine weitere Schicht aus einem Polyalkylenmaterial wie Polyethylenterephthalat oder Polybutylenterephthalat oder einem Copolymer mit einer geringen Menge an einer anderen Dicarbonsäure besteht, wobei Dichte, Schmelzpunkt und Kristallinität variabel sind. Die letztere Schicht bildet die Innenschicht und vorzugsweise die Außenschicht, wobei zwischen diesen verschiedene weitere Laminatschichten angeordnet sind.A tube-shaped container is used to solve this problem proposed whose body has several interconnected layers, one of these layers, for example a metal foil that forms a barrier layer against product penetration and oxygen absorption and another Layer of a polyalkylene material such as polyethylene terephthalate or polybutylene terephthalate or a Copolymer with a small amount of another dicarboxylic acid, with density, melting point and Crystallinity are variable. The latter layer forms the inner layer and preferably the outer layer, wherein between these various further laminate layers are arranged.
Diese weiteren Schichten umfassen Papier und geeignete Kleb- und Bindemittel, z.B. ein Copolymer aus Ethylen und Acrylsäure.These additional layers include paper and suitable adhesives and binders such as a copolymer of ethylene and acrylic acid.
Der erfindungsgemäße zusammendrückbare Spender kann aus der erfindungsgemäßen Laminatfolie mit konventionellen und bekannten Apparaten hergestellt werden. Beispiele für eine solche Apparatur und ein solches Verfahren können aus der US-PS 3 832 9 64 entnommen werden, auf die hiermit Bezug genommen wird.The compressible dispenser according to the invention can be made from the laminate film according to the invention with conventional and known apparatus. Examples of such an apparatus and method can be found in US Pat. No. 3,832,964, to which reference is hereby made.
Gegenstand der Erfindung ist es auch, ein Verfahren zur Herstellung laminierter Tuben zu schaffen, bei dem ein Tubenkörper aus einer Sperrschicht und einem darauf laminierten Polyester hergestellt wird; der laminierte Tubenkörper wird dann auf einem Formteil mit einem auch auf diesem befindlichen Barrierenteil zusammengebracht.The invention also provides a method for producing laminated tubes in which a tube body is made from a barrier layer and a polyester laminated thereon; the laminated one The tube body is then brought together on a molded part with a barrier part also located thereon.
Im folgenden wird die Erfindung anhand von Figuren näher erläutert:The invention is explained in more detail below with reference to figures:
Es zeigen:Show it:
Figur 1 einen Querschnitt durch ein Stück einer erfindungsgemäßen Laminatfolie,FIG. 1 shows a cross section through a piece of a laminate film according to the invention,
Figur 2 eine Seitenansicht eines erfindungsgemäßenFigure 2 is a side view of an inventive
zusammendrückbaren Spenders, bei dem ein Teil der Behälterwand entfernt ist, um die Laminatstruktur sichtbar zu machen.collapsible dispenser with part of the container wall removed to form the laminate structure to make visible.
In Figur 1 ist ein Querschnitt durch eine Schichtfolie 10 gezeigt, um die Komponenten des sandwichartigen Aufbaues zu zeigen, die die Laminatkonfiguration bilden.In FIG. 1, a cross section through a layer film 10 is shown in order to cover the components of the sandwich-like structure to show that make up the laminate configuration.
Die unterste Schicht 11 ist ein Polyester. Die darüber 20The bottom layer 11 is a polyester. The one above 20
befindliche zweite Schicht 12 ist eine Klebstoffschicht,located second layer 12 is an adhesive layer,
die die Polyesterschicht 11 mit der dritten Schicht 13, die eine Metallfolie wie eine Aluminiumfolie ist, verbindet. Die vierte Schicht 14 ist eine weitere Klebstoff schicht, die klebend die andere Seite der Metall-25 which is the polyester layer 11 with the third layer 13, which is a metal foil such as an aluminum foil, connects. The fourth layer 14 is another layer of adhesive that is adhesively bonded to the other side of the metal 25
folienschicht 13 an einer Papierschicht 15 befestigt.film layer 13 attached to a paper layer 15.
Die oberste Schicht 16 besteht wiederum aus einem Polyester.The top layer 16 in turn consists of a polyester.
Der erfindungsgemäße thermoplastische Polyester umfaßt Polyalkylenterephthalate wie Polyethylenterephthalat und Polybutylenterephthalat.The thermoplastic polyester of the present invention includes Polyalkylene terephthalates such as polyethylene terephthalate and polybutylene terephthalate.
Geeignete Polyesterharze sind im Hinblick auf die Verwendung für Behälter in der US-PS 3 152 515 und der US-PSSuitable polyester resins for use in containers are disclosed in U.S. Patent 3,152,515 and U.S. Patent
197 326 beschrieben. In diesen Patenten ist z.B. als ein Polyester Polyethylenterephthalat beschrieben. Auf diese Patente wird hiermit Bezug genommen.197 326 described. For example, polyethylene terephthalate is described as a polyester in these patents. To this Patents are hereby incorporated by reference.
Erfindungsgemäß können die Klebstoffe ein Copolymer aus Ethylen und Acrylsäure oder Methacrylsäure oder Natrium- oder Zinksalze desselben in einem Verdünner sein.According to the invention, the adhesives can be a copolymer of ethylene and acrylic acid or methacrylic acid or sodium or zinc salts thereof in a thinner.
Die Metallfolie ist vorzugsweise Aluminiumfolie. 10The metal foil is preferably aluminum foil. 10
Die Papierschicht ist vorzugsweise Packpapier.The paper layer is preferably wrapping paper.
Die jeweilige Dicke der Schichten liegt im Bereich von:The respective thickness of the layers is in the range of:
^ 12,7 ,u bis 76,2 ,u, vorzugsweise 25,4 ,u für die Polyethylenterephthalatschicht 11,^ 12.7, u to 76.2, u, preferably 25.4, u for the polyethylene terephthalate layer 11
ausreichende Dicke, um Haftung zu gewährleisten, für die Klebstoffschicht 12,sufficient thickness to ensure adhesion for the adhesive layer 12,
12,7/U bis 50,8/U, vorzugsweise 25,4 ,u für die Metallfolienschicht 13,12.7 / U to 50.8 / U, preferably 25.4, u for the metal foil layer 13,
ausreichende Dicke, um Haftung zu gewährleisten, für die Klebstoffschicht 14,sufficient thickness to ensure adhesion for the adhesive layer 14,
38,1/U bis 63,5 ,u, vorzugsweise 50,8,U für die Papierschicht
15 und
2^ 88,9/U bis 127, 0,u, vorzugsweise 101,6,u für die Polyethylen-terephthalatschicht
16.38.1 / U to 63.5, u, preferably 50.8, U for the paper layer 15 and
2 ^ 88.9 / U to 127.0, u, preferably 101.6, u for the polyethylene terephthalate layer 16.
Die oberste Polyethylenterephthalatschicht 16 haftet auf der Papierschicht 15 durch Anwendung von genügend Wärme und Druck auf die Anordnung. Falls die Anwendung von Wärme und Druck nicht angemessen ist, wird ein geeigneter Klebstoff eingesetzt.The uppermost polyethylene terephthalate layer 16 is adhered to the paper layer 15 by applying sufficient heat and pressure on the arrangement. If the application of heat and pressure is inadequate, an appropriate one is used Adhesive used.
Figur 2 zeigt ein Beispiel eines zusammendrückbaren Behälters aus der Laminatstruktur, bei dem wie in FigurFIG. 2 shows an example of a collapsible container made of the laminate structure in which, as in FIG
1 die Schichten gezeigt sind, wobei die Schicht 11 die innerste Schicht ist und die anderen Schichten aus denselben Materialien in derselben Reihenfolge wie in Figur 11 the layers are shown, with layer 11 being the innermost layer and the other layers being the same Materials in the same order as in Figure 1
5- gezeigt bestehen.5- consist shown.
Durch den erfindungsgemäßen zu s aminen drückbar en Behälter werden die genannten Nachteile aus dem Stand der Technik überwunden. Der laminierte Behälterkörper und das laminierte Schulterstück 2 0 verhindern völlig die Produktpermeation und die Sauerstoffabsorption; dieses äußerst erstrebenswerte Resultat wird unter Verwendung preisgünstiger Materialien erzielt, die vorzugsweise auf die in FigurBy means of the container according to the invention which can be pressed to form amines the disadvantages mentioned from the prior art are overcome. The laminated container body and the laminated one Shoulder piece 2 0 completely prevent product permeation and oxygen absorption; this extremely desirable The result is achieved using inexpensive materials, which are preferably based on those shown in FIG
2 gezeigte Weise zu einem Laminat vereinigt werden.2 can be combined to form a laminate.
Die Außenschicht aus einem Polyethylenterephthalat bes.teht aus einem thermoplastischen Material, das bei der Seitennahtbildungsstufe schweißbar ist und daß der Papier- und der Metallfolienzwischenschicht angemessenen Schutz bietet. Die Nahtbildung bei einer zusammendrückbaren Zahnpastatube des hier offenbarten allgemeinen Typs ist in der US-PS 3 295 725 beschrieben.The outer layer made of a polyethylene terephthalate bes.teht consists of a thermoplastic material that is used in the side seam formation stage is weldable and that the paper and metal foil interlayers have adequate protection offers. Seam formation in a compressible tube of toothpaste of the general type disclosed herein is shown in FIG U.S. Patent 3,295,725.
Die Außenschicht aus Polyalkylenterephthalat und PapierThe outer layer made of polyalkylene terephthalate and paper
kann weggelassen werden, wenn die Sperrschichtfolie 25can be omitted if the barrier film 25
ausreichende Dicke aufweist, um Beschädigungen zu widerstehen; in diesem Fall wird ein thermoplastisches Material in den überlappenden Nahtbereich beim Verschweißen desselben eingeführt.has sufficient thickness to withstand damage; in this case a thermoplastic material is used in the overlapping seam area during welding same introduced.
Weiterhin kann bei einem dreilagigen Laminat aus Papier, Metallfolie und einem Polyalkylenterephthalat die Außenschicht aus Papier sein. Da die äußere und die innere Schicht vorzugsweise dieselben sind, werden die Faltkanten der hergestellten Tuben auf bequeme Weise wärmever-Furthermore, in the case of a three-layer laminate made of paper, metal foil and a polyalkylene terephthalate, the outer layer be made of paper. Since the outer and inner layers are preferably the same, the fold edges become of the tubes produced in a convenient way
schweißt. Ein geeigneter Klebstoff kann verwendet werden, wenn Wärmeschweißen nicht möglich ist. Diese Modifizierung gilt zusätzlich zu den oben genannten vierlagigen Laminaten aus, von außen nach innen, Polyalkylenterephthalat, Papier, Metallfolie und Polyalkylenterephthalat; oder Polyalkylenterephthalat, Metallfolie, Papier und Polyalkylenterephthalat. Wenn nötig, können geeignete Klebstoffe zwischen den Schichten eingesetzt werden. Ähnliche Strukturen können für das Schulterstück, die Kappe, den Hals, diewelds. A suitable adhesive can be used if heat welding is not possible. This modification applies in addition to the above-mentioned four-layer laminates made of, from the outside in, polyalkylene terephthalate, Paper, metal foil and polyalkylene terephthalate; or polyalkylene terephthalate, metal foil, paper and polyalkylene terephthalate. Appropriate adhesives can be used between the layers if necessary. Similar structures can for the shoulder piece, the cap, the neck, the
"Ό Kolbenstange, den Kolben und für den Aufbau der Spenderventile solcher Behälter verwendet werden, insbesondere in Verbindung mit den inneren Teilen, die der im Behälter befindlichen Zahnpasta ausgesetzt sind, und auch hier können natürlich, wenn erforderlich, geeignete Klebstoffe"Ό piston rod, the piston and for the construction of the dispenser valves such containers can be used, particularly in connection with the internal parts that form the inside of the container the toothpaste that is in place, and of course, if necessary, suitable adhesives can also be used here
Ί5 verwendet werden.Ί5 can be used.
Verschiede Modifikationen der Erfindung wurden offenbart, die neben anderen zum erfindungsgemäßen Konzept gehören. Wenn das erfindungsgemäße Material als Folie auf die Innenflächen der Trommeln aus Fasermaterial aufgebracht wird, die zur Lagerung der aromatisierten Zahnpasten verwendet werden, dann verlangsamt das erfindungsgemäße Material den Verlust an Geschmacksstoffen in den Trommeln und erhöht dadurch die Lagerfähigkeit.Various modifications of the invention have been disclosed which, among others, belong to the inventive concept. If the material according to the invention as a film on the Inner surfaces of the drums made of fiber material are applied, which are used to store the flavored toothpastes are used, the inventive material slows down the loss of flavor in the drums and thereby increases the shelf life.
Das Polyethylenterephthalat (PET) ist besonders geeignet, da es eine sehr niedrige Geschmackstoffabsorption zeigt, wie aus den folgenden Tabellen ersichtlich ist, in denen PET mit Polyethylen verglichen wird, wobei die Dicken der Schichten oder Überzüge gleich sind:The polyethylene terephthalate (PET) is particularly suitable because it shows a very low flavor absorption, as can be seen from the following tables, in which PET is compared to polyethylene, the thicknesses the layers or coatings are the same:
Tabelle I
5 Table I.
5
Absorption von Geschmackstoffen aus einer Zahnpasta (Alterungsbedingung; 1 Woche bei Raumtemperatur)Absorption of flavors from a toothpaste (Aging condition; 1 week at room temperature)
PET 0,1PET 0.1
pet Aluminisiert (11/2-2 ohm) 0,0pet aluminized (11 / 2-2 ohm) 0.0
PET Aluminisiert (2 - 3 ohm) 0,0PET aluminized (2 - 3 ohms) 0.0
Nylon-6,6 0,5Nylon-6.6 0.5
Polyethylen 2,4Polyethylene 2.4
(Alterungsbedingung: 2 Wochen bei Raumtemperatur) (Aging condition: 2 weeks at room temperature)
PET · 0,0PET x 0.0
PET Aluminisiert (1 1/2 - 2 ohm) 0,0PET aluminized (1 1/2 - 2 ohm) 0.0
PET Aluminisiert (2 - 3 ohm) 0,0PET aluminized (2 - 3 ohms) 0.0
Nylon 6,6 0,2Nylon 6.6 0.2
Polyethylen 1,0Polyethylene 1.0
- Leerseite- Blank page
Claims (14)
befestigt ist.4. Foil according to claim 3, characterized in that the first layer (11) made of polyethylene terephthalate on the metal foil (13) with an adhesive (12)
is attached.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US56700183A | 1983-12-30 | 1983-12-30 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE3445815A1 true DE3445815A1 (en) | 1985-07-11 |
Family
ID=24265344
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19843445815 Withdrawn DE3445815A1 (en) | 1983-12-30 | 1984-12-15 | LAMINATE FILM AND COMPRESSIBLE DISPENSER MADE FROM IT |
Country Status (29)
| Country | Link |
|---|---|
| JP (1) | JPS60220748A (en) |
| KR (1) | KR910009525B1 (en) |
| AR (1) | AR240277A1 (en) |
| AT (1) | AT386563B (en) |
| AU (1) | AU578649B2 (en) |
| BE (1) | BE901405A (en) |
| BR (1) | BR8406756A (en) |
| CA (1) | CA1222687A (en) |
| CH (1) | CH665998A5 (en) |
| DE (1) | DE3445815A1 (en) |
| DK (1) | DK618184A (en) |
| ES (1) | ES289620U (en) |
| FR (1) | FR2557503B1 (en) |
| GB (2) | GB2151986B (en) |
| GR (1) | GR82563B (en) |
| IE (1) | IE56191B1 (en) |
| IN (1) | IN162574B (en) |
| IT (1) | IT1206800B (en) |
| MA (1) | MA20314A1 (en) |
| MX (1) | MX167222B (en) |
| MY (1) | MY101476A (en) |
| NL (1) | NL8403942A (en) |
| NO (1) | NO163763C (en) |
| NZ (1) | NZ210619A (en) |
| PH (1) | PH20919A (en) |
| PT (1) | PT79722A (en) |
| SE (1) | SE463868B (en) |
| ZA (1) | ZA849957B (en) |
| ZW (1) | ZW22284A1 (en) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61130041A (en) * | 1984-11-28 | 1986-06-17 | ポリプラスチックス株式会社 | Manufacture of molded shape having excellent size stability |
| JPS61130046A (en) * | 1984-11-28 | 1986-06-17 | ポリプラスチックス株式会社 | Manufacture of laminated film |
| IN165840B (en) * | 1984-12-28 | 1990-01-20 | Colgate Palmolive Co | |
| US4951841A (en) * | 1984-12-28 | 1990-08-28 | Colgate-Palmolive Company | Dispensing container made from an ethylene vinyl alcohol containing laminated material and the material therefor |
| US4728564A (en) * | 1985-02-05 | 1988-03-01 | Kuraray Co., Ltd. | Sheet-like structures and process for producing the same |
| DE3689142T2 (en) * | 1985-11-08 | 1994-04-28 | Nippon Steel Corp | Containers made from materials with an oxygen-removing effect. |
| JP2873461B2 (en) * | 1988-11-18 | 1999-03-24 | 大日本印刷株式会社 | Tube container |
| DE3933066A1 (en) * | 1989-10-04 | 1991-04-18 | Pkl Verpackungssysteme Gmbh | FILM COMPOSITION, ESPECIALLY FOR PACKAGING PURPOSES |
| NZ231049A (en) * | 1989-10-18 | 1992-02-25 | Michael David Latimer | Sound-insulating and fire-retardant sheet material |
| ZA91924B (en) * | 1990-02-26 | 1992-10-28 | Colgate Palmolive Co | Collapsible laminated tube for dentifrice |
| JP2020033060A (en) * | 2018-08-30 | 2020-03-05 | 株式会社吉野工業所 | Tube container |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3152515A (en) * | 1959-02-04 | 1964-10-13 | Polaroid Corp | Liquid-carrying containers |
| US3260777A (en) * | 1962-12-07 | 1966-07-12 | American Can Co | Method of making a collapsible container structure |
| US3900644A (en) * | 1973-03-20 | 1975-08-19 | United Merchants & Mfg | Heat resistant laminate |
| US3980107A (en) * | 1975-05-08 | 1976-09-14 | Champion International Corporation | Helically wound tubular wall material |
| CA1080105A (en) * | 1976-02-20 | 1980-06-24 | William A. Anderton | Metal protecting lead/plastic laminate |
| JPS53133570A (en) * | 1977-04-28 | 1978-11-21 | Kyodo Printing Co Ltd | Manufacturing method of compound tube |
| CA1153069A (en) * | 1979-03-16 | 1983-08-30 | Oscar E. Seiferth | Food receptacle for microwave cooking |
| US4322003A (en) * | 1980-03-26 | 1982-03-30 | Ludlow Corporation | Laminate with heat-sealable polyester foil and package |
| US4608285A (en) * | 1983-12-29 | 1986-08-26 | Colgate-Palmolive Company | Laminated substrate and collapsible dispensing container made therefrom |
| DE3445798A1 (en) * | 1983-12-30 | 1985-07-11 | Colgate-Palmolive Co., New York, N.Y. | FLUOROPOLYMER LAMINATE FILM AND COMPRESSIBLE DISPENSER MADE FROM THIS |
| US4659408A (en) * | 1984-05-29 | 1987-04-21 | American Can Company | Multi-layer sheet structure, method of making same and containers made therefrom |
-
1984
- 1984-12-15 DE DE19843445815 patent/DE3445815A1/en not_active Withdrawn
- 1984-12-17 IN IN943/DEL/84A patent/IN162574B/en unknown
- 1984-12-18 SE SE8406432A patent/SE463868B/en not_active IP Right Cessation
- 1984-12-18 NZ NZ210619A patent/NZ210619A/en unknown
- 1984-12-19 AT AT0402384A patent/AT386563B/en not_active IP Right Cessation
- 1984-12-20 PT PT79722A patent/PT79722A/en unknown
- 1984-12-20 CH CH6154/84A patent/CH665998A5/en not_active IP Right Cessation
- 1984-12-20 DK DK618184A patent/DK618184A/en not_active Application Discontinuation
- 1984-12-20 ZA ZA849957A patent/ZA849957B/en unknown
- 1984-12-21 GR GR82563A patent/GR82563B/en unknown
- 1984-12-21 GB GB08432398A patent/GB2151986B/en not_active Expired
- 1984-12-21 ZW ZW222/84A patent/ZW22284A1/en unknown
- 1984-12-24 NL NL8403942A patent/NL8403942A/en not_active Application Discontinuation
- 1984-12-27 JP JP59281865A patent/JPS60220748A/en active Pending
- 1984-12-27 IT IT8449360A patent/IT1206800B/en active
- 1984-12-28 ES ES1984289620U patent/ES289620U/en active Pending
- 1984-12-28 BE BE0/214259A patent/BE901405A/en not_active IP Right Cessation
- 1984-12-28 MX MX203919A patent/MX167222B/en unknown
- 1984-12-28 NO NO845266A patent/NO163763C/en unknown
- 1984-12-28 PH PH31669A patent/PH20919A/en unknown
- 1984-12-28 MA MA20538A patent/MA20314A1/en unknown
- 1984-12-28 BR BR8406756A patent/BR8406756A/en unknown
- 1984-12-28 IE IE3351/84A patent/IE56191B1/en not_active IP Right Cessation
- 1984-12-28 CA CA000471142A patent/CA1222687A/en not_active Expired
- 1984-12-29 KR KR1019840008558A patent/KR910009525B1/en active IP Right Grant
- 1984-12-31 FR FR8420106A patent/FR2557503B1/en not_active Expired
-
1985
- 1985-01-02 AR AR299162A patent/AR240277A1/en active
- 1985-01-02 AU AU37262/85A patent/AU578649B2/en not_active Ceased
-
1987
- 1987-01-26 GB GB08701596A patent/GB2184395B/en not_active Expired
- 1987-09-30 MY MYPI87002439A patent/MY101476A/en unknown
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