DE3371981D1 - Catalyzed aldol condensations - Google Patents

Catalyzed aldol condensations

Info

Publication number
DE3371981D1
DE3371981D1 DE8383105450T DE3371981T DE3371981D1 DE 3371981 D1 DE3371981 D1 DE 3371981D1 DE 8383105450 T DE8383105450 T DE 8383105450T DE 3371981 T DE3371981 T DE 3371981T DE 3371981 D1 DE3371981 D1 DE 3371981D1
Authority
DE
Germany
Prior art keywords
aldol condensations
catalyzed aldol
catalyzed
condensations
aldol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DE8383105450T
Other languages
German (de)
English (en)
Inventor
Walter Thomas Reichle
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Union Carbide Corp
Original Assignee
Union Carbide Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Union Carbide Corp filed Critical Union Carbide Corp
Application granted granted Critical
Publication of DE3371981D1 publication Critical patent/DE3371981D1/de
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/007—Mixed salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/16—Clays or other mineral silicates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F7/00—Compounds of aluminium
    • C01F7/78—Compounds containing aluminium, with or without oxygen or hydrogen, and containing two or more other elements
    • C01F7/784—Layered double hydroxide, e.g. comprising nitrate, sulfate or carbonate ions as intercalating anions
    • C01F7/785—Hydrotalcite
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C45/72—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction of compounds containing >C = O groups with the same or other compounds containing >C = O groups
    • C07C45/74—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction of compounds containing >C = O groups with the same or other compounds containing >C = O groups combined with dehydration
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/16—Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Geology (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Compounds Of Iron (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
DE8383105450T 1982-06-02 1983-06-01 Catalyzed aldol condensations Expired DE3371981D1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US06/384,212 US4476324A (en) 1982-06-02 1982-06-02 Catalyzed aldol condensations

Publications (1)

Publication Number Publication Date
DE3371981D1 true DE3371981D1 (en) 1987-07-16

Family

ID=23516459

Family Applications (1)

Application Number Title Priority Date Filing Date
DE8383105450T Expired DE3371981D1 (en) 1982-06-02 1983-06-01 Catalyzed aldol condensations

Country Status (5)

Country Link
US (1) US4476324A (enExample)
EP (1) EP0095783B1 (enExample)
JP (1) JPS58219139A (enExample)
CA (1) CA1203071A (enExample)
DE (1) DE3371981D1 (enExample)

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DE3573536D1 (en) * 1984-05-28 1989-11-16 Mitsui Petrochemical Ind Alkali metal-carrying substance, and its use as catalyst
FR2599275B1 (fr) * 1986-06-03 1988-11-10 Centre Nat Rech Scient Catalyseurs a base d'argile du type smectite, leur procede d'obtention et leur application a l'acylation d'hydrocarbures aromatiques.
US4704478A (en) * 1986-06-25 1987-11-03 Union Carbide Corporation Process for the condensation of ketones
US4701562A (en) * 1986-06-25 1987-10-20 Union Carbide Corporation Process for the condensation of aldehydes
EP0318099A3 (en) * 1987-11-25 1989-11-15 Union Carbide Corporation Monoalkylene glycol production using mixed metal framework compositions
US4902660A (en) * 1988-02-26 1990-02-20 Phillips Petroleum Company Catalyst for oxidation of carbon monoxide
US4911904A (en) * 1988-02-26 1990-03-27 Phillips Petroleum Company Catalytic oxidation of carbon monoxide
US5202496A (en) * 1989-04-18 1993-04-13 Aristech Chemical Corporation Method of making isophorne
US5153156A (en) * 1989-04-18 1992-10-06 Aristech Chemical Corporation Process for making efficient anionic clay catalyst, catalysts made thereby, and method of making isophorone
GB8922359D0 (en) * 1989-10-04 1989-11-22 British Petroleum Co Plc Process for the preparation of catalysts
GB8922358D0 (en) * 1989-10-04 1989-11-22 British Petroleum Co Plc Process for the preparation of glycol ethers
US5079203A (en) * 1990-05-25 1992-01-07 Board Of Trustees Operating Michigan State University Polyoxometalate intercalated layered double hydroxides
DE4020838A1 (de) * 1990-06-29 1992-01-02 Henkel Kgaa Verfahren zur aldolisierung von verbindungen mit aktiven wasserstoffatomen
JPH04170173A (ja) * 1990-11-02 1992-06-17 Canon Inc 撮像装置
DK167145B1 (da) * 1990-09-11 1993-09-06 Topsoe Haldor As Fremgangsmaade til fremstilling af aromatiske forbindelser
US5194613A (en) * 1990-09-20 1993-03-16 Union Carbide Chemicals & Plastics Technology Corporation Catalytic processes for the preparation of bridged nitrogen-containing compounds
DE4034305A1 (de) * 1990-10-29 1992-04-30 Henkel Kgaa Hydrophobierte doppelschichthydroxid-verbindungen, verfahren zur herstellung und ihre verwendung als alkoxylierungskatalysatoren
US5237107A (en) * 1991-05-10 1993-08-17 Sumitomo Chemical Company, Limited Magnesium, aluminium complex compounds, process for preparing the same and process of aldol condensation dehydration products using the same
CA2068489A1 (en) * 1991-05-16 1992-11-17 Masaru Ishino Aldol condensation dehydration catalyst, a process for preparing the same and a process for preparing an aldol condensation dehydrate using the process
US5246899A (en) * 1991-08-16 1993-09-21 Amoco Corporation Simplified preparation of hydrotalcite-type clays
US5260495A (en) * 1991-08-23 1993-11-09 Union Carbide Chemicals & Plastics Technology Corporation Monoalkylene glycol production using highly selective monoalkylene glycol catalysts
JPH0575916A (ja) * 1991-09-18 1993-03-26 Hitachi Ltd ビデオカメラ
US5144089A (en) * 1991-10-21 1992-09-01 Uop 2-ethyl-2-hexenal by aldol condensation of butyraldehyde in a continuous process
US5367073A (en) * 1992-03-06 1994-11-22 The Regents Of The University Of California Asymmetric synthesis of β-amino alcohols from chiral or achiral enamines
US5364828A (en) * 1992-10-21 1994-11-15 Minerals Technologies Spheroidal aggregate of platy synthetic hydrotalcite
EP0640387A1 (en) * 1993-08-25 1995-03-01 Union Carbide Chemicals & Plastics Technology Corporation Preparation of isophorone using a magnesium/aluminum mixed oxide catalyst
FR2729137A1 (fr) * 1995-01-06 1996-07-12 Atochem Elf Sa Aldolisation selective de l'acetone en diacetonealcool par un catalyseur basique solide
US5583263A (en) * 1995-08-30 1996-12-10 Shell Oil Company Process of making ketones
US5637774A (en) * 1995-09-29 1997-06-10 Eastman Chemical Company Process for the production of vinyl carbonyls
FR2745566B1 (fr) * 1996-02-29 1998-04-24 Atochem Elf Sa Procede d'obtention d'isophorone
FR2745565B1 (fr) 1996-02-29 1998-04-03 Atochem Elf Sa Procede d'obtention de composes carbonyles beta hydroxy et/ou alpha-beta insatures
EP0870750A3 (en) * 1997-04-07 1999-07-14 Novartis AG Catalyst for reactions of the aldol type
FR2772024B1 (fr) * 1997-12-05 2000-01-21 Atochem Elf Sa Utilisation de composes de structure de type hydrotalcite pour la preparation de composes carbonyles-beta-hydroxy et/ou alpha-beta-insatures
CN1314826A (zh) 1998-06-30 2001-09-26 伊斯曼化学公司 用于生产二元醇—酯的碱性粘土催化剂
NL1009934C2 (nl) * 1998-08-24 2000-02-25 Akcros Chemicals V O F Anionische kleien, anionische kleien bevattende stabilisatoren, werkwijze voor het stabiliseren van samenstellingen van polymeren.
EP1029843A1 (en) * 1999-02-16 2000-08-23 Universiteit Utrecht Method for the condensation of an aldehyde and a ketone
EP1029844A1 (en) * 1999-02-16 2000-08-23 Universiteit Utrecht Method for the condensation of an aldehyde and a ketone
ES2159259B1 (es) * 1999-11-24 2002-04-16 Univ Valencia Politecnica Procedimiento y catalizadores para la obtencion de compuestos carbonilicos alfa-beta insaturados de interes en la industria de perfumes y aromas.
DE10055758A1 (de) * 2000-11-07 2002-05-16 Siemens Axiva Gmbh & Co Kg Verfahren zur Herstellung von Aldolen unter Verwendung eines mikrostrukturierten Reaktionssystems
JP2002263500A (ja) * 2001-03-14 2002-09-17 Kyowa Hakko Kogyo Co Ltd アルドール縮合反応用触媒
US6812186B2 (en) * 2002-03-27 2004-11-02 Council of Industrial Research Preparation of new layered double hydroxides exchanged with diisopropylamide for C-C bond forming reactions
US6486365B1 (en) * 2002-04-04 2002-11-26 General Electric Company Production and purification of phenol: hydroxyacetone removal by hydrotalcite
MX2007003775A (es) * 2007-03-29 2008-10-28 Mexicano Inst Petrol Procedimiento de preparacion de arcillas anionicas multimetalicas y producto resultante.
DE102009050345A1 (de) 2009-10-22 2011-06-01 Süd-Chemie AG Aldolkondensation in Gegenwart von Hydrotalciten
DE102010062587A1 (de) 2010-12-08 2012-06-14 Evonik Degussa Gmbh Verfahren zur Herstellung von Isophoron
DE102010062603A1 (de) 2010-12-08 2012-06-14 Evonik Degussa Gmbh Verfahren zur Herstellung von 3-Aminomethyl-3,5,5-trimethylcyclohexylamin
DE102010055399A1 (de) 2010-12-21 2012-06-21 Süd-Chemie AG Verwendung von seltenerdmetallhaltigen Mischoxidkatalysatoren in basisch heterogen katalysierten chemischen Reaktionen
DE102011075777A1 (de) 2011-05-13 2012-11-15 Evonik Degussa Gmbh Verfahren zur Herstellung von Isophoron in Gegenwart mindestens eines Entschäumers in der Abwasserkolonne im Aufarbeitungsteil
CN119549148B (zh) * 2024-11-19 2025-10-10 南京工业大学 一种Fe3O4@FeMgAl-LDH磁性催化剂及其制备方法与在催化糠醛与丙酮缩合反应中的应用
CN119746840B (zh) * 2024-12-18 2025-11-21 中国石油大学(华东) 一种催化丙酮定向缩聚生产均三甲苯和异佛尔酮催化剂的制备方法

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB559682A (en) * 1941-06-23 1944-03-01 Shell Dev Production of unsaturated ketones
US3316303A (en) * 1961-06-12 1967-04-25 Exxon Research Engineering Co Synthesis of higher ketones
US3796792A (en) * 1969-12-12 1974-03-12 Kyowa Chem Ind Co Ltd Composite metal hydroxides
BE789849A (fr) * 1971-10-13 1973-04-09 Basf Ag Procede de preparation de cetones alpha-ethyleniques
US4170609A (en) * 1973-08-20 1979-10-09 Turner William F Aldol condensation process
US4086188A (en) * 1976-02-12 1978-04-25 Union Carbide Corporation Catalyst for aldol condensations
US4165339A (en) * 1976-02-12 1979-08-21 Union Carbide Corporation Catalytic aldol condensations
DE2625541A1 (de) * 1976-06-05 1977-12-22 Basf Ag Verfahren zur herstellung einer zink und nickel oder kobalt enthaltenden kontaktmasse

Also Published As

Publication number Publication date
CA1203071A (en) 1986-04-15
JPH0260376B2 (enExample) 1990-12-17
EP0095783A3 (en) 1985-08-28
US4476324A (en) 1984-10-09
JPS58219139A (ja) 1983-12-20
EP0095783A2 (en) 1983-12-07
EP0095783B1 (en) 1987-06-10

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Legal Events

Date Code Title Description
8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee