DE3364259D1 - Process for preparing nonionic surfactants by an oxyalkylation with calcium and/or strontium catalysts - Google Patents

Process for preparing nonionic surfactants by an oxyalkylation with calcium and/or strontium catalysts

Info

Publication number
DE3364259D1
DE3364259D1 DE8383103891T DE3364259T DE3364259D1 DE 3364259 D1 DE3364259 D1 DE 3364259D1 DE 8383103891 T DE8383103891 T DE 8383103891T DE 3364259 T DE3364259 T DE 3364259T DE 3364259 D1 DE3364259 D1 DE 3364259D1
Authority
DE
Germany
Prior art keywords
oxyalkylation
calcium
nonionic surfactants
preparing nonionic
strontium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DE8383103891T
Other languages
German (de)
English (en)
Inventor
James Herndon Mccain
Louis Foster Theiling
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Union Carbide Corp
Original Assignee
Union Carbide Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Union Carbide Corp filed Critical Union Carbide Corp
Application granted granted Critical
Publication of DE3364259D1 publication Critical patent/DE3364259D1/de
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C08G65/2645—Metals or compounds thereof, e.g. salts
    • C08G65/2651—Alkaline earth metals or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0211—Oxygen-containing compounds with a metal-oxygen link
    • B01J31/0212—Alkoxylates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0211—Oxygen-containing compounds with a metal-oxygen link
    • B01J31/0214—Aryloxylates, e.g. phenolates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/02—Preparation of ethers from oxiranes
    • C07C41/03—Preparation of ethers from oxiranes by reaction of oxirane rings with hydroxy groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/40—Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
    • B01J2231/48—Ring-opening reactions

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Polyethers (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
  • Detergent Compositions (AREA)
DE8383103891T 1982-04-21 1983-04-20 Process for preparing nonionic surfactants by an oxyalkylation with calcium and/or strontium catalysts Expired DE3364259D1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US06/370,204 US4453022A (en) 1982-04-21 1982-04-21 Process for preparing nonionic surfactants-oxyalkylation with calcium and/or strontium catalysts

Publications (1)

Publication Number Publication Date
DE3364259D1 true DE3364259D1 (en) 1986-07-31

Family

ID=23458676

Family Applications (1)

Application Number Title Priority Date Filing Date
DE8383103891T Expired DE3364259D1 (en) 1982-04-21 1983-04-20 Process for preparing nonionic surfactants by an oxyalkylation with calcium and/or strontium catalysts

Country Status (5)

Country Link
US (1) US4453022A (enrdf_load_stackoverflow)
EP (1) EP0092256B1 (enrdf_load_stackoverflow)
JP (1) JPS58189128A (enrdf_load_stackoverflow)
CA (1) CA1195697A (enrdf_load_stackoverflow)
DE (1) DE3364259D1 (enrdf_load_stackoverflow)

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US4453023A (en) * 1982-12-30 1984-06-05 Union Carbide Corporation Process for preparing nonionic surfactants-oxyalkylation with promoted barium catalysts
WO1985000365A1 (en) * 1983-07-05 1985-01-31 Union Carbide Corporation Alkoxylation using calcium catalysts and products therefrom
DE3413563A1 (de) 1984-04-11 1985-10-24 Merck Patent Gmbh, 6100 Darmstadt Medizinische oelbaeder
US4721816A (en) * 1985-12-23 1988-01-26 Shell Oil Company Preparation of nonionic surfactants
US4731486A (en) * 1986-11-18 1988-03-15 Union Carbide Corporation Hydroformylation using low volatile phosphine ligands
DE3706047A1 (de) * 1987-02-25 1988-09-08 Henkel Kgaa Erdalkalimetallsalze vicinal hydroxy, alkoxy-substituierter c(pfeil abwaerts)1(pfeil abwaerts)(pfeil abwaerts)6(pfeil abwaerts)-c(pfeil abwaerts)2(pfeil abwaerts)(pfeil abwaerts)2(pfeil abwaerts)-fettsaeuren, verfahren zu ihrer herstellung und ihre verwendung als alkoxylierungskatalysatoren
JP2693760B2 (ja) * 1987-02-27 1997-12-24 花王株式会社 分散剤の製造法
TR23339A (tr) * 1987-06-15 1989-12-14 Henkel Kgaa Alkoksillendirme icin katalizoer,olarak eter karbonik asitlerinin toprak alkalisi tozlarinin kullanilmasi
US5104575A (en) * 1987-09-30 1992-04-14 Union Carbide Chemicals & Plastics Technology Corporation Alkoxylation using heterogeneous calcium catalysts and products therefrom
US4902658A (en) * 1987-09-30 1990-02-20 Union Carbide Corporation Alkoxylation using heterogeneous calcium catalysts and products therefrom
DE3812168A1 (de) * 1988-04-12 1989-10-26 Henkel Kgaa Verwendung von erdalkalisalzen von polycarbonsaeuremonoestern als katalysatoren fuer die alkoxylierung
DE3814849A1 (de) * 1988-05-02 1989-11-16 Henkel Kgaa Verwendung von estern der titan- und/oder zirkonsaeure als katalysatoren fuer die ethoxylierung bzw. propoxylierung
DE3817415A1 (de) * 1988-05-21 1989-11-30 Henkel Kgaa Verdickte waessrige tensidloesungen
US5068456A (en) * 1988-06-13 1991-11-26 Texaco Chemical Company Preparation of nonionic surfactants by oxyalkylation with a phenolic activated magnesium catalyst
EP0347064A1 (en) * 1988-06-13 1989-12-20 Texaco Development Corporation Preparation of nonionic surfactants by oxyalkylation with a magnesium catalyst
US5059710A (en) * 1988-08-05 1991-10-22 Union Carbide Chemicals And Plastics Technology Corporation Ionic phosphites and their use in homogeneous transition metal catalyzed processes
US5113022A (en) * 1988-08-05 1992-05-12 Union Carbide Chemicals & Plastics Technology Corporation Ionic phosphites used in homogeneous transition metal catalyzed processes
US5114900A (en) * 1988-09-30 1992-05-19 Union Carbide Chemicals & Plastics Technology Corporation Alkoxylation using modified calcium-containing bimetallic or polymetallic catalysts
US5112788A (en) * 1988-09-30 1992-05-12 Union Carbide Chemicals & Plastics Technology Corporation Alkoxylation using modified group iia metal-containing bimetallic or polymetallic catalysts
US5118650A (en) * 1988-09-30 1992-06-02 Union Carbide Chemicals & Plastics Technology Corporation Alkoxylation using modified group iiib metal-containing bimetallic or polymetallic catalysts
US5120697A (en) * 1988-09-30 1992-06-09 Union Carbide Chemicals & Plastics Technology Corporation Alkoxylation using modified calcium-containing catalysts
US5112789A (en) * 1988-09-30 1992-05-12 Union Carbide Chemicals & Plastics Technology Corporation Alkoxylation catalysis
US4946984A (en) * 1988-09-30 1990-08-07 Union Carbide Chemicals And Plastics Company Inc. Alkoxylation using a calcium sulfate catalyst
US5114619A (en) * 1989-07-14 1992-05-19 The Dow Chemical Company Production of polyether polyols with reduced unsaturation
DE3916365A1 (de) * 1989-05-19 1990-11-22 Basf Ag Kraftstoffzusammensetzungen mit einem gehalt an alkoxylierungsprodukten
DE4005338A1 (de) * 1990-02-20 1991-08-22 Henkel Kgaa Verwendung von strontium- und/oder bariumacetylacetonaten als katalysatoren fuer die ethoxylierung bzw. propoxylierung von verbindungen mit aktiven h-atomen
DE4010606A1 (de) * 1990-04-02 1991-10-10 Henkel Kgaa Verwendung von hydrophobierten hydrotalciten als katalysatoren fuer die ethoxylierung bzw. propoxylierung
US5210325A (en) * 1990-04-23 1993-05-11 Shell Oil Company Alkoxylation process catalyzed by supported rare earth elements
US5208199A (en) * 1990-04-23 1993-05-04 Shell Oil Company Catalyst of rare earth and phosphorus-containing xerogels for alkoxylation process
US5102849A (en) * 1990-04-23 1992-04-07 Shell Oil Company Supported rare earth and phosphorus catalyst
US5118870A (en) * 1990-04-23 1992-06-02 Shell Oil Company Alkoxylation process catalyzed by rare earth and phosphorus-containing xerogels
US5191104A (en) * 1990-09-20 1993-03-02 Union Carbide Chemicals & Plastics Technology Corporation Alkoxylation of carboxylated compounds
US5104987A (en) * 1990-09-20 1992-04-14 Union Carbide Chemicals & Plastics Technology Corporation Alkoxylation of active hydrogen-containing compounds
DE4034305A1 (de) * 1990-10-29 1992-04-30 Henkel Kgaa Hydrophobierte doppelschichthydroxid-verbindungen, verfahren zur herstellung und ihre verwendung als alkoxylierungskatalysatoren
US5158612A (en) * 1991-10-25 1992-10-27 Henkel Corporation Foaming agent composition and process
KR950007045B1 (ko) * 1992-04-14 1995-06-30 주식회사태평양 폴리에톡실레이티드 비타민 e를 함유한 피부화장료
US6020296A (en) * 1993-08-04 2000-02-01 Colgate Palmolive Company All purpose liquid cleaning composition comprising anionic, amine oxide and EO-BO nonionic surfactant
EP0738183A4 (en) * 1993-12-13 1997-08-06 Henkel Corp FOAMING AGENT COMPOSITION AND RELATED METHODS
US5374705A (en) * 1993-12-27 1994-12-20 The Dow Chemical Company Process for the preparation of polyether polyols with a reduced unsaturation content
JP3174479B2 (ja) * 1995-03-28 2001-06-11 ライオン株式会社 活性水素を有する化合物のアルキレンオキサイド付加物の製造方法
DE19546946A1 (de) * 1995-12-15 1997-06-19 Hoechst Ag Precursor für Alkoxylierungskatalysatoren
US5858956A (en) * 1997-12-03 1999-01-12 Colgate-Palmolive Company All purpose liquid cleaning compositions comprising anionic, EO nonionic and EO-BO nonionic surfactants
US5866527A (en) * 1997-08-01 1999-02-02 Colgate Palmolive Company All purpose liquid cleaning compositions comprising anionic EO nonionic and EO-BO nonionic surfactants
US6111146A (en) * 1997-09-03 2000-08-29 Rayborn; Randy L. Alkyl cyclohexanol alkoxylates and method for making same
EP1120457B1 (en) * 1998-09-29 2013-07-03 Sanyo Chemical Industries, Ltd. Surfactant, process for producing the same, and detergent composition
US6593500B2 (en) 2001-01-19 2003-07-15 Rhodia, Inc. Process for alkoxylation with a boron-containing catalyst
CN101374599B (zh) * 2004-08-26 2013-01-09 亨斯迈石油化学有限责任公司 碱土基烷氧基化催化剂
DE102005008181A1 (de) * 2005-02-23 2006-08-24 Clariant Produkte (Deutschland) Gmbh Verfahren zur Herstellung von reinem alpha-Phenoxy-omega-hydroxy-Polyalkylenglykolen
US20080167501A1 (en) 2007-01-08 2008-07-10 Bayer Materialscience Llc. High productivity alkoxylation processes
DE102007027372A1 (de) 2007-06-11 2008-12-18 Cognis Oleochemicals Gmbh Verfahren zur Hydrierung von Glycerin
DE102007027371A1 (de) 2007-06-11 2008-12-18 Cognis Oleochemicals Gmbh Verfahren zur Herstellung einer Verbindung aufweisend mindestens eine Ester-Gruppe
US9650305B2 (en) * 2007-12-28 2017-05-16 United States Gypsum Company Hard water foaming agents and methods for gypsum board production
US7439405B1 (en) * 2008-01-14 2008-10-21 Lyondell Chemical Technology, L.P. Purification of propylene glycol monoalkyl ether
JP5001184B2 (ja) * 2008-01-29 2012-08-15 三洋化成工業株式会社 ポリオキシアルキレンエーテル組成物の製造法
WO2022129374A1 (en) 2020-12-18 2022-06-23 Unilever Ip Holdings B.V. Detergent composition
EP4015497A1 (en) 2020-12-18 2022-06-22 Clariant International Ltd Alkoxylates prepared by calcium catalyst

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US3100750A (en) * 1958-11-26 1963-08-13 Union Carbide Corp Process for polymerization of vicinal epoxides
US3328306A (en) * 1965-10-04 1967-06-27 Lubrizol Corp Foam inhibiting composition and foam inhibited phosphating process
US4210764A (en) * 1979-05-04 1980-07-01 Conoco, Inc. Barium oxide/cresylic acid catalyzed ethoxylation
US4223164A (en) * 1979-07-02 1980-09-16 Conoco, Inc. Ethoxylation with strontium bases
DE3071057D1 (en) * 1979-09-27 1985-10-10 Union Carbide Corp Process for reaction of epoxides with organic compounds having an active hydrogen
EP0034648A3 (en) * 1980-02-04 1981-10-21 Conoco Phillips Company A method for the alkoxylation of alkanols in the presence of strontium-containing catalysts and promoters
US4376868A (en) * 1980-02-14 1983-03-15 Conoco Inc. Alkoxylation of cresylic acids
US4302613A (en) * 1980-08-22 1981-11-24 Conoco Inc. Inorganic catalyst for alkoxylation of alcohols
JPS5745112A (en) * 1980-08-29 1982-03-13 Continental Oil Co Alkoxylation of organic compound

Also Published As

Publication number Publication date
US4453022A (en) 1984-06-05
EP0092256A1 (en) 1983-10-26
EP0092256B1 (en) 1986-06-25
CA1195697A (en) 1985-10-22
JPS58189128A (ja) 1983-11-04
JPH0339049B2 (enrdf_load_stackoverflow) 1991-06-12

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Legal Events

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8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee