DE3242725A1 - Verfahren zur umwandlung eines kohlenstoffhaltigen materials in niedere paraffin-kohlenwasserstoffe und monozyklische aromatische kohlenwasserstoffe - Google Patents
Verfahren zur umwandlung eines kohlenstoffhaltigen materials in niedere paraffin-kohlenwasserstoffe und monozyklische aromatische kohlenwasserstoffeInfo
- Publication number
- DE3242725A1 DE3242725A1 DE19823242725 DE3242725A DE3242725A1 DE 3242725 A1 DE3242725 A1 DE 3242725A1 DE 19823242725 DE19823242725 DE 19823242725 DE 3242725 A DE3242725 A DE 3242725A DE 3242725 A1 DE3242725 A1 DE 3242725A1
- Authority
- DE
- Germany
- Prior art keywords
- stage
- fraction
- hydrocarbons
- hydrogen
- temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000000034 method Methods 0.000 title claims description 24
- 239000000463 material Substances 0.000 title claims description 5
- 239000012188 paraffin wax Substances 0.000 title claims description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 title 2
- 229930195733 hydrocarbon Natural products 0.000 claims description 34
- 150000002430 hydrocarbons Chemical class 0.000 claims description 33
- 239000007789 gas Substances 0.000 claims description 32
- 239000001257 hydrogen Substances 0.000 claims description 28
- 229910052739 hydrogen Inorganic materials 0.000 claims description 28
- 239000003245 coal Substances 0.000 claims description 27
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 26
- 239000007787 solid Substances 0.000 claims description 24
- 239000003575 carbonaceous material Substances 0.000 claims description 10
- 239000003054 catalyst Substances 0.000 claims description 10
- 238000005984 hydrogenation reaction Methods 0.000 claims description 10
- 238000002309 gasification Methods 0.000 claims description 8
- 239000004215 Carbon black (E152) Substances 0.000 claims description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 6
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 6
- 229910052799 carbon Inorganic materials 0.000 claims description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 4
- 229910052750 molybdenum Inorganic materials 0.000 claims description 4
- -1 monocyclic aromatic hydrocarbons Chemical class 0.000 claims description 4
- 229910052759 nickel Inorganic materials 0.000 claims description 4
- 239000001301 oxygen Substances 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- 238000005194 fractionation Methods 0.000 claims description 3
- 229910052742 iron Inorganic materials 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 229910052721 tungsten Inorganic materials 0.000 claims description 3
- 229910052720 vanadium Inorganic materials 0.000 claims description 3
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 2
- 239000003638 chemical reducing agent Substances 0.000 claims description 2
- 229910017052 cobalt Inorganic materials 0.000 claims description 2
- 239000010941 cobalt Substances 0.000 claims description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 2
- 239000011733 molybdenum Substances 0.000 claims description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 2
- 239000010937 tungsten Substances 0.000 claims description 2
- 125000003118 aryl group Chemical group 0.000 claims 1
- 125000002950 monocyclic group Chemical group 0.000 claims 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 15
- 239000003921 oil Substances 0.000 description 15
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 14
- 238000002474 experimental method Methods 0.000 description 11
- 239000007788 liquid Substances 0.000 description 11
- 238000006243 chemical reaction Methods 0.000 description 9
- 239000000047 product Substances 0.000 description 8
- 239000002956 ash Substances 0.000 description 7
- 239000003502 gasoline Substances 0.000 description 7
- 238000010438 heat treatment Methods 0.000 description 7
- 239000000725 suspension Substances 0.000 description 7
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 6
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 229910002091 carbon monoxide Inorganic materials 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 5
- 238000004821 distillation Methods 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 4
- 238000009835 boiling Methods 0.000 description 3
- 229910002092 carbon dioxide Inorganic materials 0.000 description 3
- 239000001569 carbon dioxide Substances 0.000 description 3
- 230000004087 circulation Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000005360 mashing Methods 0.000 description 3
- 238000000197 pyrolysis Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000004517 catalytic hydrocracking Methods 0.000 description 2
- 238000009903 catalytic hydrogenation reaction Methods 0.000 description 2
- 239000003610 charcoal Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000001722 flash pyrolysis Methods 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 239000000295 fuel oil Substances 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- 150000003738 xylenes Chemical class 0.000 description 2
- 240000005561 Musa balbisiana Species 0.000 description 1
- 235000018290 Musa x paradisiaca Nutrition 0.000 description 1
- HHUIAYDQMNHELC-UHFFFAOYSA-N [O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O HHUIAYDQMNHELC-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical group 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000010883 coal ash Substances 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 238000004939 coking Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 230000001351 cycling effect Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000000921 elemental analysis Methods 0.000 description 1
- 210000000540 fraction c Anatomy 0.000 description 1
- 238000001033 granulometry Methods 0.000 description 1
- 230000000887 hydrating effect Effects 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 238000007327 hydrogenolysis reaction Methods 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 239000003077 lignite Substances 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- MOWMLACGTDMJRV-UHFFFAOYSA-N nickel tungsten Chemical compound [Ni].[W] MOWMLACGTDMJRV-UHFFFAOYSA-N 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 239000003415 peat Substances 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 239000010913 used oil Substances 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
- C10G1/006—Combinations of processes provided in groups C10G1/02 - C10G1/08
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
- C10G1/08—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal with moving catalysts
- C10G1/083—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal with moving catalysts in the presence of a solvent
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR8122018A FR2516931A1 (fr) | 1981-11-23 | 1981-11-23 | Procede de conversion d'une matiere carbonee en hydrocarbures paraffiniques inferieurs et hydrocarbures aromatiques monocycliques |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE3242725A1 true DE3242725A1 (de) | 1983-06-01 |
Family
ID=9264329
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19823242725 Withdrawn DE3242725A1 (de) | 1981-11-23 | 1982-11-19 | Verfahren zur umwandlung eines kohlenstoffhaltigen materials in niedere paraffin-kohlenwasserstoffe und monozyklische aromatische kohlenwasserstoffe |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US4519895A (enExample) |
| JP (1) | JPS58132080A (enExample) |
| DE (1) | DE3242725A1 (enExample) |
| FR (1) | FR2516931A1 (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3438330A1 (de) * | 1983-11-05 | 1985-05-15 | GfK Gesellschaft für Kohleverflüssigung mbH, 6600 Saarbrücken | Verfahren zum verfluessigen von kohle |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1265760A (en) * | 1985-07-29 | 1990-02-13 | Reginald D. Richardson | Process utilizing pyrolyzation and gasification for the synergistic co-processing of a combined feedstock of coal and heavy oil to produce a synthetic crude oil |
| US5096569A (en) * | 1990-02-27 | 1992-03-17 | Exxon Research And Engineering Company | Catalytic hydropyrolysis of carbonaceous material with char recycle |
| CN110437874B (zh) * | 2019-08-07 | 2020-10-02 | 北京中科诚毅科技发展有限公司 | 一种加氢混合物配制工艺 |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3644192A (en) * | 1970-08-28 | 1972-02-22 | Sik U Li | Upflow three-phase fluidized bed coal liquefaction reactor system |
| US3855070A (en) * | 1971-07-30 | 1974-12-17 | A Squires | Hydropyrolysis of hydrocarbonaceous fuel at short reaction times |
| US3960700A (en) * | 1975-01-13 | 1976-06-01 | Cities Service Company | Coal hydrogenation to produce liquids |
| US4013543A (en) * | 1975-10-20 | 1977-03-22 | Cities Service Company | Upgrading solid fuel-derived tars produced by low pressure hydropyrolysis |
| US4229185A (en) * | 1975-11-10 | 1980-10-21 | Occidental Petroleum Corporation | Process for the gasification of carbonaceous materials |
| US4166786A (en) * | 1976-06-25 | 1979-09-04 | Occidental Petroleum Corporation | Pyrolysis and hydrogenation process |
| US4162959A (en) * | 1976-06-25 | 1979-07-31 | Occidental Petroleum Corporation | Production of hydrogenated hydrocarbons |
| US4085030A (en) * | 1976-06-25 | 1978-04-18 | Occidental Petroleum Corporation | Pyrolysis of carbonaceous materials with solvent quench recovery |
| US4141794A (en) * | 1976-06-25 | 1979-02-27 | Occidental Petroleum Corporation | Grid-wall pyrolysis reactor |
| US4123347A (en) * | 1976-12-22 | 1978-10-31 | Exxon Research & Engineering Co. | Coal liquefaction process |
| US4190518A (en) * | 1977-12-29 | 1980-02-26 | Gulf Research And Development Company | Solvent refined coal process |
| US4219402A (en) * | 1978-05-30 | 1980-08-26 | Exxon Research & Engineering Co. | Integration of stripping of fines slurry in a coking and gasification process |
| US4226698A (en) * | 1978-08-04 | 1980-10-07 | Schroeder Wilburn C | Ash removal and synthesis gas generation from heavy oils produced by coal hydrogenation |
| US4225414A (en) * | 1979-02-26 | 1980-09-30 | The United States Of America As Represented By The United States Department Of Energy | Process for hydrocracking carbonaceous material to provide fuels or chemical feed stock |
| GB2057493B (en) * | 1979-09-04 | 1983-07-20 | Mobil Oil Corp | Coal liquefaction process with reduced hydrogen consumption |
| US4272501A (en) * | 1980-03-03 | 1981-06-09 | International Coal Refining Company | Carbon fibers from SRC pitch |
| US4313816A (en) * | 1980-08-25 | 1982-02-02 | Exxon Research & Engineering Co. | Staged temperature coal conversion process |
| US4328088A (en) * | 1980-09-09 | 1982-05-04 | The Pittsburg & Midway Coal Mining Co. | Controlled short residence time coal liquefaction process |
| US4379744A (en) * | 1980-10-06 | 1983-04-12 | Chevron Research Company | Coal liquefaction process |
-
1981
- 1981-11-23 FR FR8122018A patent/FR2516931A1/fr active Granted
-
1982
- 1982-11-19 DE DE19823242725 patent/DE3242725A1/de not_active Withdrawn
- 1982-11-23 US US06/444,016 patent/US4519895A/en not_active Expired - Fee Related
- 1982-11-24 JP JP57206822A patent/JPS58132080A/ja active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3438330A1 (de) * | 1983-11-05 | 1985-05-15 | GfK Gesellschaft für Kohleverflüssigung mbH, 6600 Saarbrücken | Verfahren zum verfluessigen von kohle |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2516931A1 (fr) | 1983-05-27 |
| JPS58132080A (ja) | 1983-08-06 |
| FR2516931B1 (enExample) | 1984-01-13 |
| US4519895A (en) | 1985-05-28 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8139 | Disposal/non-payment of the annual fee |