DE3226702A1 - Process for the utilisation of coalmining dirt with feed of waste products from flue gas purification - Google Patents

Process for the utilisation of coalmining dirt with feed of waste products from flue gas purification

Info

Publication number
DE3226702A1
DE3226702A1 DE19823226702 DE3226702A DE3226702A1 DE 3226702 A1 DE3226702 A1 DE 3226702A1 DE 19823226702 DE19823226702 DE 19823226702 DE 3226702 A DE3226702 A DE 3226702A DE 3226702 A1 DE3226702 A1 DE 3226702A1
Authority
DE
Germany
Prior art keywords
flue gas
dirt
alkaline earth
waste products
coalmining
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
DE19823226702
Other languages
German (de)
Inventor
Heribert Dipl.-Ing. 4390 Gladbeck Dewert
Heinrich Ing.(grad.) 4600 Dortmund Gresch
Heinz Dipl.-Ing. 4390 Gladbeck Hölter
Heinrich Dipl.-Ing. 4390 Gladbeck Igelbüscher
Rolf Dr.-Ing. 4630 Bochum Köhling
Heinz-Walter Prof. Dr.-Ing. 4220 Dinslaken Wild
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE19823209266 external-priority patent/DE3209266A1/en
Application filed by Individual filed Critical Individual
Priority to DE19823226702 priority Critical patent/DE3226702A1/en
Priority to DE19823229520 priority patent/DE3229520A1/en
Publication of DE3226702A1 publication Critical patent/DE3226702A1/en
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B20/00—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
    • C04B20/02—Treatment
    • C04B20/04—Heat treatment
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00—Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/02—Agglomerated materials, e.g. artificial aggregates
    • C04B18/023—Fired or melted materials
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00—Clay-wares
    • C04B33/02—Preparing or treating the raw materials individually or as batches
    • C04B33/13—Compounding ingredients
    • C04B33/132—Waste materials; Refuse; Residues
    • C04B33/1328—Waste materials; Refuse; Residues without additional clay
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00—Technologies relating to the processing of minerals
    • Y02P40/60—Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes

Abstract

The main application P 3209266.0 relates to a process in which washed dirt and/or milling dirt, by admixture of refuse and waste, is utilised as fuel and availability improver against caking in the thermal, ceramic formation area. In a further development of this process, it is proposed according to the invention to add alkaline earth metal compounds to the ceramic formation process. The alkaline earth metal compounds are composed of residual products of flue gas desulphurisation plants. This addition is used for the ceramic formation process for particle sizes below 10 mm.

Description

Beschreibung und Erläuterung zur ZusatzpatentanmeldungDescription and explanation of the additional patent application

"Verfahren zur Verwendung von Bergen aus dem Kohlebergbau unter Zuführung von Abfallprodukten aus der Rauchgasreinigung" Zusatz zu P 32 09 266.0 In der Eauptanmeldung wird ein Verfahren beschrieben, das Keramisieren von Bergbaubergen so herzustellen, daß es mit hoher Verfügbarkeit unter Verwendung von Abfallstoffen, vorzugsweise Hausmüll als Zusatzbrennstoff und Lockerungsmittel, und Chemisorptionsmitteln als Beimischung für die Schadstoffbindung Anwendung findet, wobei vorzugsweise das Gesamtverfahren in mehreren Körnungsstufen aufgebaut ist."Method of using piles from coal mining under feed of waste products from flue gas cleaning "Addition to P 32 09 266.0 in the main application a process is described to produce the ceramization of mining mountains in such a way that that it is highly available using waste materials, preferably Household waste as additional fuel and loosening agent, and chemisorbents as Admixture for binding pollutants is used, preferably the overall process is built up in several grain sizes.

Der weitere erfindungsgemäße Gedanke liegt im folgenden begründet: Das Abfallprodukt der Kohleförderung sind Brech-und/oder Waschberge.The further idea according to the invention is based on the following: That Waste products from coal mining are piles of crushing and / or washing mountains.

Das Abfallprodukt bei der Verwendung von Kohle in Kraftwerken ist für rauchgasentschwefelte Kraftwerke 1. Filterasche und 2. gibt es Abfallprodukte aus eingesetzten Erdalkaliverbindungen, wie Kalkstein usw. und den bei der Schwefelbildung daraus entstehenden Naßgips -ungebrannt Es ist bekannt, Baustoffe durch Zusatzstoffe wie Erdalkaliverbindungen zu verbessern.The waste product from using coal in power plants is for flue gas desulphurized power plants 1. fly ash and 2. there are waste products from the alkaline earth compounds used, such as limestone, etc. and those involved in the formation of sulfur The resulting wet gypsum - unburned It is known to add additives to building materials how to improve alkaline earth compounds.

Hierdurch wird insbesondere das hydraulische Abbindeverhalten gefördert.This particularly promotes the hydraulic setting behavior.

Erfindungsgeinäß wird daher vorgeschlagen, entsprechend der Hauptanmeldung dem Keramisierungsprozeß die nassen, ungebrannten Erdalkaliverbindungen vorzugsweise im Endprodukt der Rauchgasentschwefelungstechnologie wie Gips, den Wasch- und/oder Brechbergen zuzuführen, wobei hier zwangsläufig erfindungsgemäß durch die überschüssige Wärme z.B. Beta Halbhydrat entsteht, das sich zwangsläufig mit dem Eeramisierungsprozeß bildet und einen wunschgerechten Baustoff -entsprechend der Beimischung - darstellt.According to the invention, it is therefore proposed in accordance with the main application the ceramization process the wet, unfired alkaline earth compounds preferably in the end product of flue gas desulfurization technology such as gypsum, the To supply washing and / or crushing mountains, inevitably according to the invention here due to the excess heat e.g. beta hemihydrate is created, which inevitably develops with the Eeramisierungsprocess and forms a desired building material - accordingly the admixture - represents.

Durch verschiedene Verfahrensschritte können natürlich auch Eristallstrukturen des Gipses im Naß- und oder Trockenzustand - je nach dem Verfahrensprozeß zur Rauchgasentschwefelung - der keramisierten Masse zugesetzt werden, so daß nicht nur Beta-Halbhydratkristalle, sondern auch alle anderen Eristallformen bis einschließlich dem Alpha-Halbhydrat zur Verwendung kommen können.Of course, crystalline structures can also be created through various process steps of gypsum in the wet and or dry state - depending on the process for flue gas desulphurisation - are added to the ceramized mass, so that not only beta hemihydrate crystals, but also all other crystalline forms up to and including the alpha hemihydrate can be used.

Weiterhin - je nach dem Verwendungszweck - wird erfindungsgemäß vorgeschlagen, diesem genannten erfindungsgemäßen Keramisierungsprozeß Filterasche aus dem Entstaubungsprozeß hinter Kohlekraftwerken oder Müllverbrennungsanlagen zuzuführen, so daß Baustoffe mit den Eigenschaften des Klinkers oder mit ähnlichen gewollten Eigenschaften herstellbar sind.Furthermore - depending on the intended use - it is proposed according to the invention, this ceramization process according to the invention mentioned filter ash from the dedusting process Behind To supply coal-fired power plants or waste incineration plants, so that building materials with the Properties of the clinker or with similar desired properties can be produced are.

Claims (1)

Zusatz-Patentansprüche: ======================= Anspruch I Verfahren zur Verwendung von Bergen aus dem Eohlebergbau und Abfallstoffen aus der Rauchgasreinigung, vorzugsweise hinter Kohlekraftwerken, dadurch gekennzeichnet, daß dem Keramisierungsprozeß gemäß der Hauptanmeldung P 32 O9 266.0 vorzugsweise Erdalkaliverbindungen zugesetzt werden.Additional patent claims: ======================= Claim I method for the use of mountains from coal mining and waste materials from flue gas cleaning, preferably behind coal-fired power stations, characterized in that the ceramization process According to the main application P 32 O9 266.0, alkaline earth compounds are preferably added will. Anspruch II Verfahren nach Anspruch I dadurch gekennzeichnet, daß die Erdalkaliverbindungen vorzugsweise aus Rückstandsprodukten der Rauchgasentschwefelungsanlagen bestehen.Claim II, method according to claim I, characterized in that the alkaline earth compounds preferably from residue products of the flue gas desulphurisation systems exist. Anspruch III Verfahren nach Anspruch I bis II dadurch gekennzeichnet, daß dieser Zusatz vorzugsweise für den Keramisierungsprozeß für Korngrößen kleiner 10 mm eingesetzt wird.Claim III Method according to Claims I to II, characterized in that that this additive is preferably used for the ceramization process for grain sizes smaller 10 mm is used.
DE19823226702 1982-03-13 1982-07-16 Process for the utilisation of coalmining dirt with feed of waste products from flue gas purification Ceased DE3226702A1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
DE19823226702 DE3226702A1 (en) 1982-03-13 1982-07-16 Process for the utilisation of coalmining dirt with feed of waste products from flue gas purification
DE19823229520 DE3229520A1 (en) 1982-07-16 1982-08-07 Process for using wastes from coal mining with addition of chemisorbents which serve for waste gas desulphurisation and are fed under control to the ceramisation process for binding further pollutants and at the same time for improving the overall process

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19823209266 DE3209266A1 (en) 1982-03-13 1982-03-13 Process for utilising spoil from coal mining
DE19823226702 DE3226702A1 (en) 1982-03-13 1982-07-16 Process for the utilisation of coalmining dirt with feed of waste products from flue gas purification

Publications (1)

Publication Number Publication Date
DE3226702A1 true DE3226702A1 (en) 1984-02-09

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
DE19823226702 Ceased DE3226702A1 (en) 1982-03-13 1982-07-16 Process for the utilisation of coalmining dirt with feed of waste products from flue gas purification

Country Status (1)

Country Link
DE (1) DE3226702A1 (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3604825A1 (en) * 1986-02-15 1987-08-20 Hoelter Heinz Process for disposing of crude gypsum in flotation tailings in underground mining
DE3612931A1 (en) * 1986-04-17 1987-10-22 Hoelter Heinz Mining mortar from waste dirt of coal extraction
DE3730248A1 (en) * 1987-09-09 1989-03-30 Hoelter Heinz Mining gypsum
DE3743818A1 (en) * 1987-12-23 1989-07-06 Hoelter Heinz Conversion of waste materials from dry or pseudo-dry desulphurisation plants based on lime into building materials for underground mining
DE3802429A1 (en) * 1987-10-31 1989-08-31 Hoelter Heinz Reprocessing and conversion of contaminated problem waste materials into products for the production of load-bearing building materials for underground mining

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0039798A1 (en) * 1980-05-14 1981-11-18 BABCOCK-BSH AKTIENGESELLSCHAFT vormals Büttner-Schilde-Haas AG Method of firing and sintering waste washings
DE3020007A1 (en) * 1980-05-24 1981-12-03 Herbert Keller GmbH & Co, 4600 Dortmund Moulding plant for mfg. sintered pellets from fly:ash - where dryer and sintering furnace for pellets are heated by exhaust gas from power station boiler providing fly:ash
DD153361A1 (en) * 1980-10-01 1982-01-06 Jochen Auerbach METHOD FOR THE PRODUCTION OF LIGHT SUPPLEMENTS AND FOR THE IMPROPER EVALUATION OF ABPRODUCTS
EP0045297A1 (en) * 1980-07-17 1982-02-03 Wienerberger Baustoffindustrie Aktiengesellschaft Process for the preparation of a concrete filler
DE3114555A1 (en) * 1981-04-10 1982-10-28 Gebr. Knauf Westdeutsche Gipswerke, 8715 Iphofen Hydraulically setting multi-component mixture
DE3113714A1 (en) * 1981-03-14 1982-11-25 Hölter, Heinz, Dipl.-Ing., 4390 Gladbeck Dam-building materials for underground mining

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0039798A1 (en) * 1980-05-14 1981-11-18 BABCOCK-BSH AKTIENGESELLSCHAFT vormals Büttner-Schilde-Haas AG Method of firing and sintering waste washings
DE3018411A1 (en) * 1980-05-14 1981-11-19 Babcock-BSH AG vormals Büttner-Schilde-Haas AG, 4150 Krefeld METHOD FOR BURNING AND CERAMIZING WASHING MOUNTAINS
DE3020007A1 (en) * 1980-05-24 1981-12-03 Herbert Keller GmbH & Co, 4600 Dortmund Moulding plant for mfg. sintered pellets from fly:ash - where dryer and sintering furnace for pellets are heated by exhaust gas from power station boiler providing fly:ash
EP0045297A1 (en) * 1980-07-17 1982-02-03 Wienerberger Baustoffindustrie Aktiengesellschaft Process for the preparation of a concrete filler
DD153361A1 (en) * 1980-10-01 1982-01-06 Jochen Auerbach METHOD FOR THE PRODUCTION OF LIGHT SUPPLEMENTS AND FOR THE IMPROPER EVALUATION OF ABPRODUCTS
DE3113714A1 (en) * 1981-03-14 1982-11-25 Hölter, Heinz, Dipl.-Ing., 4390 Gladbeck Dam-building materials for underground mining
DE3114555A1 (en) * 1981-04-10 1982-10-28 Gebr. Knauf Westdeutsche Gipswerke, 8715 Iphofen Hydraulically setting multi-component mixture

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3604825A1 (en) * 1986-02-15 1987-08-20 Hoelter Heinz Process for disposing of crude gypsum in flotation tailings in underground mining
DE3612931A1 (en) * 1986-04-17 1987-10-22 Hoelter Heinz Mining mortar from waste dirt of coal extraction
DE3730248A1 (en) * 1987-09-09 1989-03-30 Hoelter Heinz Mining gypsum
DE3802429A1 (en) * 1987-10-31 1989-08-31 Hoelter Heinz Reprocessing and conversion of contaminated problem waste materials into products for the production of load-bearing building materials for underground mining
DE3743818A1 (en) * 1987-12-23 1989-07-06 Hoelter Heinz Conversion of waste materials from dry or pseudo-dry desulphurisation plants based on lime into building materials for underground mining

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