DE317402C - - Google Patents
Info
- Publication number
- DE317402C DE317402C DENDAT317402D DE317402DA DE317402C DE 317402 C DE317402 C DE 317402C DE NDAT317402 D DENDAT317402 D DE NDAT317402D DE 317402D A DE317402D A DE 317402DA DE 317402 C DE317402 C DE 317402C
- Authority
- DE
- Germany
- Prior art keywords
- humus
- peat
- ordinary
- detergents
- solutions
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000003864 humus Substances 0.000 claims description 10
- 239000003415 peat Substances 0.000 claims description 8
- 239000003599 detergent Substances 0.000 claims description 5
- 239000000243 solution Substances 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 4
- 150000007513 acids Chemical class 0.000 claims description 3
- 238000004140 cleaning Methods 0.000 claims description 3
- 239000012459 cleaning agent Substances 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 239000007864 aqueous solution Substances 0.000 claims description 2
- 238000005406 washing Methods 0.000 claims description 2
- 239000003610 charcoal Substances 0.000 claims 1
- 235000013861 fat-free Nutrition 0.000 claims 1
- 239000000126 substance Substances 0.000 description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
- BVKZGUZCCUSVTD-UHFFFAOYSA-N Carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 5
- 239000003245 coal Substances 0.000 description 5
- NTHWMYGWWRZVTN-UHFFFAOYSA-N Sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 4
- 230000002378 acidificating Effects 0.000 description 4
- 239000003513 alkali Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 235000019353 potassium silicate Nutrition 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 239000011780 sodium chloride Substances 0.000 description 4
- 239000002253 acid Substances 0.000 description 3
- 239000003518 caustics Substances 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 210000003491 Skin Anatomy 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical class OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 239000004021 humic acid Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate dianion Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- -1 alkalis Substances 0.000 description 1
- 159000000009 barium salts Chemical class 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000002864 coal component Substances 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 231100001010 corrosive Toxicity 0.000 description 1
- 231100000078 corrosive Toxicity 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000001264 neutralization Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000001590 oxidative Effects 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000005201 scrubbing Methods 0.000 description 1
- 230000028327 secretion Effects 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- KEAYESYHFKHZAL-UHFFFAOYSA-N sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/40—Products in which the composition is not well defined
- C11D7/44—Vegetable products
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Description
Es wurde gefunden, daß die löslichen Bestandteile des Torfes und der Humuskohle, die bekanntlich in der Hauptsache kolloidlösliche Humusstoffe darstellen, Wasch- und Reinigungsmittel bilden, welche geeignet sind, Seife zu ersetzen. Das ist um so überraschender, da man bisher gewohnt war, die genannten Stoffe als Schmutzstoffe zu betrachten. It has been found that the soluble components of peat and humus coal, which are known to represent mainly colloid-soluble humus substances, detergents and Form detergents that are suitable to replace soap. That is all the more surprising because up to now one was used to regard the substances mentioned as pollutants.
ίο Zur Verwendung als Reinigungsmittel sind sowohl unveränderter Torf und' Humuskohle in passender Zerkleinerung, besonders aber die aus diesen Stoffen in bekannter Weise mittels wäßriger Lösungen alkalisch oder sauer reagierender Verbindungen, wie Ätz- oder kohlensaurer Alkalien, Säuren oder alkalisch oder sauer, reagierender Salze gewonnenen kolloiden Lösungen oder deren Eindampfrückstände geeignet. Für die Reinigungs wirkung ist besonders wichtig der kolloidale Zustand der in ihnen enthaltenen Humusstoffe. Sie werden entweder für sich, zweckmäßiger in Mischung mit anderen fettlosen Reinigungsmitteln, wie Ätz- oder kohlensauren Alkalien, Wasserglasίο Are for use as a cleaning agent both unchanged peat and humus coal in suitable comminution, but especially the from these substances in a known manner by means of aqueous solutions alkaline or acidic reacting Compounds such as caustic or carbonic acidic alkalis, acids or alkaline or acidic, reacting salts obtained colloidal Solutions or their evaporation residues are suitable. For the cleaning effect is special important is the colloidal state of the humus substances they contain. They are either on their own, more expedient in mixture with other grease-free cleaning agents, such as caustic or carbonic acid alkalis, water glass
u. dgl. benutzt. Sie sind nicht nur zur Körperreinigung und zum Scheuern, sondern auch zum Reinigen von Wäsche zu gebrauchen. and the like used. They're not just for body cleansing and scrubbing, but Can also be used to clean laundry.
Man mischt beispielsweise Soda oder ein Gemenge von Soda und Wasserglas mit ι bis 5 Prozent der Erzeugnisse, die durch Eindampfen und Trocknen der kolloiden Lösungen gewonnen sind, welche man beim Ausziehen von Torf oder Humuskohle erhält. Kohlensaure Alkalien oder Wasserglas sind nämlich . die bequemsten Träger für die neue wasche wirksame Substanz. An deren Stelle können aber gegebenenfalls auch mit alkalisch reagierenden Stoffen versetzte Neutralsalze treten, auch kann man Ätzalkalien sowie unlösliche Füllmittel, Riechstoffe, Schaumstoffe, organische Lösungsmittel, Oxydations- und Reduktionsstoffe zusetzen.For example, you mix soda or a mixture of soda and water glass with ι bis 5 percent of the products produced by evaporation and drying of the colloidal solutions obtained by extracting peat or humus coal. Carbonic acid Alkali or water glass are namely. the most comfortable carriers for the new wash effective substance. In their place, however, can optionally also with alkaline reactants Neutral salts mixed with substances occur, caustic alkalis and insoluble ones can also be used Fillers, fragrances, foams, organic solvents, oxidizing and reducing substances to add.
Die Waschwirkung der neuen Waschmittel beruht einerseits auf der adsorbierenden Natur der kolloidal löslichen Torf- oder Humus-, kohlenbestandteile, andererseits auf dem zersetzenden Einfluß, welchen diese auf die den Schmutz bindenden Sekrete ausüben. Die in den löslichen Torf- und Humuskohlebestandteilen enthaltenen huminsäuren Alkalien spalten sich mit viel Wasser und ergeben dann freies Alkali in milder Form, das der Wäsche nicht schadet und die Haut angenehm beeinflußt, während die Humussäure den Schmutz an sich zieht und ihn aus den Hautporen und von der Wäsche frei macht, so daß er nachher leicht abgespült werden kann.The washing effect of the new detergents is based on the one hand on their adsorbing nature the colloidally soluble peat or humus, carbon components, on the other hand on the decomposing Influence which these exert on the secretions that bind the dirt. In the break down humic acids alkalis contained in the soluble peat and humus coal components with a lot of water and then produce free alkali in a mild form, which the laundry does not harms and has a pleasant effect on the skin, while the humic acid attracts the dirt and removes it from the skin pores and frees from the laundry so that it can be easily rinsed off afterwards.
Die zu verwendenden Lösungen oder Suspensionen werden in bekannter Weise durch Auslaugen der Ausgangsstoffe mit Wasser, Alkalien, Säuren, oder alkalisch oder sauer reagierenden Salzen bei gewöhnlicher oder erhöhter Temperatur und gewöhnlichem oder verstärktem Druck gewonnen. Besonders geeignet sind Lösungen ätzender und kohlensaurer Alkalien, saurer Salze und von Wasserglas. Vorhergehende feine Mahlung des Torfes oder der, Humuskohle,. trocken- oder naß, ist angebracht. Der entstehende Auszug wird gegebenenfalls neutralisiert und dann entweder durch Filtrieren oder durch Absetzen-The solutions or suspensions to be used are carried out in a known manner Leaching of the starting materials with water, alkalis, acids, or alkaline or acidic reacting salts at ordinary or elevated temperature and ordinary or gained increased pressure. Corrosive and carbonic acid solutions are particularly suitable Alkalis, acid salts and water glass. Previous fine grinding of the Peat or humus coal. dry or wet is appropriate. The resulting excerpt is neutralized if necessary and then either by filtering or by settling
lassen und Abgießen der klaren. ..Flüssigkeit abgetrennt. Der filtrierte oder. abgegossene' Auszug wird ,.in:■. eingedicktem Zustande öder nach völligem Trocknen ;mit; den erwähnten Zusatzstoffen vermischt. ' * :let and pour off the clear. .. liquid separated. The filtered or. poured 'extract becomes, .in: ■. thickened condition or after complete drying ; with; mixed with the additives mentioned. '*:
Das Trocknen darf übrigens nicht bei höherer Temperatur erfolgen, damit der Kolloidzustand nicht leidet.Incidentally, drying must not take place at a higher temperature, so that the colloid state does not suffer.
Da humussaures Kalium oder Natrium amSince humic potassium or sodium am
ίο leichtesten dissoziieren, ist es empfehlenswert, -wenn nach Art der Gewinnungsreaktion diese Alkaliverbindungen nicht unmittelbar entstehen, die Suspension oder das Filtrat mit Alkalisalzen, insbesondere Alkalikarbonat, umzusetzen. ίο easily dissociate, it is recommended - if, according to the type of recovery reaction, these alkali compounds do not arise directly, to react the suspension or the filtrate with alkali salts, in particular alkali carbonate.
Die Wirkung der als Waschmittel Verwendung findenden Torf- oder Humuskohlenerzeugnisse wird durch die Anwesenheit von schwefelsauren Salzen etwas beeinträchtigt.The effect of the peat or humus coal products used as detergents is somewhat affected by the presence of sulfuric acid salts.
Es ist deshalb zweckmäßig, zur Streckung oder auch bei den Aufschlußoperatiönen keine schwefelsauren Verbindungen zu benutzen. Sind solche doch vorhanden, so empfiehlt es sich, sie in üblicher Weise mit Stoffen, wie Bariumsalzen, auszufällen.'It is therefore advisable not to use any for stretching or during the breakdown operations to use sulfuric acid compounds. If there are, it recommends to precipitate them in the usual way with substances such as barium salts. '
Claims (1)
Publications (1)
Publication Number | Publication Date |
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DE317402C true DE317402C (en) |
Family
ID=570059
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DENDAT317402D Active DE317402C (en) |
Country Status (1)
Country | Link |
---|---|
DE (1) | DE317402C (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20090094801A1 (en) * | 2007-10-11 | 2009-04-16 | Aaw Products, Inc. | Magnetic work clothes |
US20090314813A1 (en) * | 2008-06-24 | 2009-12-24 | Aaw Products, Inc. | Magnetic tool holster |
EP2942385A1 (en) * | 2014-05-07 | 2015-11-11 | Hayat Kimya Sanayi Anonim Sirketi | Use of oxidized humic acid and its salts in cleaning compositions |
-
0
- DE DENDAT317402D patent/DE317402C/de active Active
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20090094801A1 (en) * | 2007-10-11 | 2009-04-16 | Aaw Products, Inc. | Magnetic work clothes |
US20090314813A1 (en) * | 2008-06-24 | 2009-12-24 | Aaw Products, Inc. | Magnetic tool holster |
EP2942385A1 (en) * | 2014-05-07 | 2015-11-11 | Hayat Kimya Sanayi Anonim Sirketi | Use of oxidized humic acid and its salts in cleaning compositions |
WO2015171090A1 (en) * | 2014-05-07 | 2015-11-12 | Hayat Kimya Sanayi Anonim Sirketi | Use of oxidized humic acid its salts and derivatives in cleaning compositions |
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