DE308089C - - Google Patents
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- Publication number
- DE308089C DE308089C DENDAT308089D DE308089DA DE308089C DE 308089 C DE308089 C DE 308089C DE NDAT308089 D DENDAT308089 D DE NDAT308089D DE 308089D A DE308089D A DE 308089DA DE 308089 C DE308089 C DE 308089C
- Authority
- DE
- Germany
- Prior art keywords
- fiber
- pelt
- product
- cellulose solution
- cellulose
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
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Classifications
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
- D04H1/64—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives the bonding agent being applied in wet state, e.g. chemical agents in dispersions or solutions
- D04H1/645—Impregnation followed by a solidification process
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
- D04H1/587—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives characterised by the bonding agents used
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
- D04H1/64—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives the bonding agent being applied in wet state, e.g. chemical agents in dispersions or solutions
- D04H1/655—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives the bonding agent being applied in wet state, e.g. chemical agents in dispersions or solutions characterised by the apparatus for applying bonding agents
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/70—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres
- D04H1/74—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres the fibres being orientated, e.g. in parallel (anisotropic fleeces)
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0086—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/02—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with cellulose derivatives
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H23/00—Processes or apparatus for adding material to the pulp or to the paper
- D21H23/02—Processes or apparatus for adding material to the pulp or to the paper characterised by the manner in which substances are added
- D21H23/22—Addition to the formed paper
- D21H23/70—Multistep processes; Apparatus for adding one or several substances in portions or in various ways to the paper, not covered by another single group of this main group
- D21H23/72—Plural serial stages only
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H5/00—Special paper or cardboard not otherwise provided for
- D21H5/0005—Processes or apparatus specially adapted for applying liquids or other fluent materials to finished paper or board, e.g. impregnating, coating
- D21H5/005—Processes or apparatus specially adapted for applying liquids or other fluent materials to finished paper or board, e.g. impregnating, coating involving several different techniques of application
- D21H5/0052—Plural serial stages
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dispersion Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
Description
KAISERLICHESIMPERIAL
PATENTAMT.PATENT OFFICE.
PATENTSCHRIFTPATENT LETTERING
- JVl 308089 .-KLASSE 8 h. GRUPPE - JVl 308089 .- CLASS 8 h. GROUP
Es ist ein Verfahren zur Herstellung von künstlichem Leder durch Imprägnierung von Geweben mit filzähnlichen Oberflächen bekannt, wobei dieses Gewebe mit einer Zelluloselösung imprägniert und der m'li Zellulose imprägnierte Stoff dann durch Verdampfen der überschüssigen Feuchtigkeit getrocknet und ausgespült wird. Bei diesem Verfahren geht man von einem Gewebe aus, das denrA method for producing artificial leather by impregnating fabrics with felt-like surfaces is known, this fabric being impregnated with a cellulose solution and the m'li cellulose-impregnated fabric then being dried and rinsed out by evaporating the excess moisture. This method is based on a tissue that denr
ίο Kunstleder seinen Charakter aufdrückt, indem dieses leicht dem1 Faden des Gewebes nach zerreißbar ist. Die Zelluloselösung ist ferner nur auf physikalischem Wege getrocknet "bzw. ; fixiert, so daß die Widerstandsfähigkeit des Endproduktes eine geringe ist. Wohl hat man vorgeschlagen, das fertige Endprodukt durch Walzen hindurchgehen zu lassen, aber nur zum Zwecke, glatte, schmiegsame und glänzende Stoffe zu erhalten, eine äußere Ver^ edlung, die die innere Beschaffenheit nicht verbessert. . Das Kunstlederprodukt muß, weil man von einem Gewebe ausgeht, verhältnismäßig teuer sein. Auch hat man vorgeschlagen, zur Herstellung von Tüchern,ίο Imitation leather expresses its character by being easy to tear along the 1 thread of the fabric. The cellulose solution is further dried only by physical means "or;. Fixed so that the resistance of the final product is a small well one has proposed to pass the finished product by rolling, but only for the purpose of smooth, pliable and shiny fabrics to obtain an external refinement that does not improve the internal quality. The artificial leather product must be relatively expensive, because it is based on a fabric.
»5' Platten, Riemen aus beliebig langen Pflanzen-, Tier- oder Mineralfasern, diese in Form eines Flors auf eine Klebmittelschicht zu legen, hierauf zu pressen und so oft wieder mit einer Klebmittelschicht und darauf mit einer Florschicht zu belegen, bis die erforderliche Stärke erreicht ist. Der dünne Kardeflor bedingt nicht allein eine Unterstützung (Lauftuch), weil er keinen inneren Halt hat, sondern für ein Erzeugnis sind mehrere.. auf ein Klebmittel, aufgelegte Schichten nötwendig. Das Erzeugnis besteht somit aus : Schichten, hat nur eine relative Stärke, istinicht: homogen und bedingt für seine Herstellung leine um-, ständliche Vorrichtung. . ;: .. -"*.»5 'panels, belts made of plant, animal or mineral fibers of any length, to lay them in the form of a pile on a layer of adhesive, to press them and to cover them with a layer of adhesive and then a layer of pile until the required thickness is reached. The thin cardel pile does not only require a support (running sheet), because it has no inner hold, but several layers are necessary for a product. The product thus consists of : Layers, has only a relative strength, is not: homogeneous and, conditionally, not a cumbersome, cumbersome device for its production. . ; : .. - "*.
Im Gegensatz zu diegee^bekannten \ erfahren steht das Verfahren gemäß vorliegen-' der Erfindung, wonach, ein nach- allen Richtungen gleich starkes, "unzerreißbares homogenes Erzeugnis entsteht. Das Verfahren gemäß der Erfindung zur Herstellung eines Er- 4^ Zeugnisses geschlossener Struktur, wie z. B. Kunstleder, Filz- und Japanpapiernachahmung, beruht darauf, daß ein kardierter yerfilzter , -'" Faserpelz einer Appreturmaschine zugeführt wird, welche unter Druck dem Faserpelz eine Zelluloselösung, z. B. eine Viskose- oder Kupferoxydammoniak - Zelluloselösung, einwalzt und nachher durch eine Zellulosehärtungsflüssigkeit, ,z. B. ein Lauge- oder Säurebad, führt. Es entsteht so ein außerordentlich festes Produkt von geschlossener Struktur. Der' kardierte Faserpelz kann aus ; ungebleichtem, aus nur leicht gebleichtem oder aus vollständig gebleichtem und wasserfest nachbehandeltem, einheitlich oder. verschieden Go gefärbtem Fasermaterial, wie z. B. Baumwolle, Ramie, Bast, Wolle, Seide oder Kunst- .", seideabfällen, hergestellt sein.In contrast to known diegee ^ \ out the method is according to vorliegen- 'the invention, according to which a demand all directions equally strong, "unbreakable homogeneous product is formed. The method of the invention for the manufacture of a parent 4 ^ certificate closed structure, such as, for example, artificial leather, felt and Japanese paper imitation, is based on the fact that a carded felted fiber pelt is fed to a finishing machine which, under pressure, converts the fiber pelt into a cellulose solution, e.g. B. a viscose or copper oxide ammonia - cellulose solution, rolled in and then through a cellulose hardening liquid, e.g. B. a lye or acid bath leads. The result is an extremely solid product with a closed structure. The carded fiber pelt can be made from; unbleached, from only slightly bleached or from completely bleached and waterproof post-treated, uniform or. different Go colored fiber material, such as B. cotton, ramie, raffia, wool, silk or artificial. ", Silk waste, be made.
Man bedient sich zur beispielsweisen Aüs-For example, one uses
übung des Verfahrens der in der Zeichnung . beispielsweise dargestellten Appreturmaschine. Auf einer einfachen oder einer Doppelkrempel (auf der Zeichnung nicht angegeben) • 5 wird das Ausgangsmaterial in üblicher Weise zu einem durchaus gleichmäßigen Faserpelz kardiert. Direkt hinter der Krempel oder Karde ist ein Fließquerlegetisch (auch Kreuzpelzoder Blamireapparat genannt): angebracht, welcher die in der Längsrichtung liegenden, vom Peigneur der Karde abgegebenen Fasern kreuz und quer legt, um den so erzeugten, gut ausgeglichenen Faserpelz in Wickelform A einer Appreturmaschine C zuzuführen, die zwei unter Hebelvorrichtung/,/ und Belastungsgewichten K gelagerte Preßwalzen B, B1 aufweist, von welchen die eine gerauht oder geriffelt, die andere mit Gummiüberzug versehen ist. Die untere Walze Bx dieser Appreturmaschine C taucht in einen Trog D, der mit Zelluloselösung gefüllt ist. Diese Zelluloselösung dient als Bindemasse des zwischen den Preß walzen B, B1 mittels Zuführtisch E hindurchgeführten Faserpelzes. Die untere in den Trog D eintauchende Walze B1 führt dem Faserpelz die Zelluloselösung zu, genau wie in der Appretur einem Gewebe der Appret oder die Schlichte zugeführt wird. Die obere Walze B preßt die Masse in die Filzschicht; der Überschuß läuft in den Trog D zurück. Bei Anwendung einer der vorerwähnten Zelluloselösungen haften, unter der Einwirkung des Druckes der Preßwalzen B, B1, welche das Bindemittel auftragen, die verfilzten Fasern schon'so gut zusammen, .daß das Erzeugnis ohne weiteres mit großer Geschwindigkeit vorteilhaft in gespanntem Zustand durch' einen Trog F hindurchgeführt werden kann, welcher eine Härtungsflüssigkeit für die gelöste Zellulose enthält. Das durch die Walzen G, G1 freist gebene durchlaufende Erzeugnis kann dann sofort auf einer Welle Ii aufgewickelt oder in einen Behälter gefaltet werden, wo es aust.45 gewaschen und weiterbehandelt wird, um nachher unter Zug. getrocknet und zuletzt gaufriert zu werden. Das fertige Erzeugnis ist infolge der kombinierten Wirkung des Fließquerlegetisches, der Zelluloselösung, der Preßwalzen und der Härtungsflüssigkeit fast unzerreißbar und ist weich und geschmeidig", besonders wenn man von einem aus -unge,-bleichten oder nur leicht gebleichten Fasern bestehenden Faserpelz ausgeht. So hergestelltes Kunstleder ist von geschlossener. Struktur und kann noch durch Nachbehandlung wasserdicht gemacht werden, oder man kann der Zellulosemasse wasserabstoßende Mittel beimischen. Will man mit derselben Einrichtung neben Kunstleder auch Filz- und Pelznachahmungen herstellen, so geht man zur Kardierung des Easerpelzes von langstapeligem Fasermaterial aus, und richtet die Appreturmaschine so ein, daß die eine der ,Preßwalzen B, B1 nur stellen- oder streifenweise gerauht oder geriffelt und dann wieder stellenweise glatt ist. Da wo die gerauhte oder., geriffelte Walzenoberfläche mit dem Bindemittel auf die Faserschicht einwirkt, wird das Fasermaterial inniger zusammengeklebt, hingegen findet an den Stellen, wo die glatte, Oberfläche der Preßwalzen einwirkt, also weniger Bindemasse aufgetragen wird, ein geringeres Zusammenkleben statt, so daß nach dem Trocknen an den weniger verklebten Stellen die Fasern durch Aufkrätzen an der Oberfläche wieder ^freigelegt und über die verklebten Streifen. oder Stellen hinweggebürstet werden können, wodurch man einen schönen, langfaserigen Filz und auch" Pelznachahmungen erhält. Würde aber so viel Zelluloselösung aufgetragen, daß noch ein wesentlicher Überschuß durch die Preßwalzen B, B1 abgequetscht wird, dann wäre das Erzeugnis zu stark verklebt, 'und man würde auch durch Aufkratzen keinen Filz mehr erhalten. Will man ein Erzeugnis herstellen, welches dem Japanpapier ähnlich sieht, so muß man dem zu Faserpelz zu bearbeitenden ungebleichten Fasermaterial einen; geeigneten Prozentsatz gebleichter Baumwolle zusetzen. Für ganz harte Nachahmungen geht man durchaus von gebleichten Fasern aus. Je nach dem Verhältnis des gebleichten zum ungebleichten Fasermaterial erhält man ein mehr oder weniger zähes pergamentartiges Japanpapier. Dieses Ergebnis läßt sich dadurch erklären, daß bei Anwendung eines ungebleichten Fasermaterials infolge der sehr geringen Netzbarkeit der Faseroberfläche die Zelluloselösung trotz des großen Druckes der Preßwalzen B, B1 nicht' in die Zellen der Fasern eindringt, sondern die Fasern nur umhüllt und ohne wesentliche Durchtränkung , bindet. Bei Anwendung gebleichten Fasermaterials hingegen, welches infolge der vorherigen Bleiche keine fett- und wachsartigen Stoffe mehr enthält, sich deshalb auch leicht netzen läßt, dringt die Zelluloselösung bis in die Zellen der Fasern ein und verbindet dieselben zu einem steifen, pergamentartigen Erzeugnis. Erzeugnisse, welche den knisternden Papiercharakter nicht haben, erhält man aber auch, trotzdem man von gebleichten Fasern ausgeht, wenn man dieses Faser- ; material zuvor nach, einem bekannten Ver- : fahren wasserfest macht, um hierdurch ein Eindringen der Appreturmasse in die Faser-• zellen zu verhüten. Zum Schluß werden die : getrockneten und evtl. gebleichten Leder- und ; Filznachahmungen zweckmäßigerweise noch, durch ein kaltes Schwefelsäurebad von 50 bis,exercise the procedure shown in the drawing. for example, the finishing machine shown. On a single or double card (not shown in the drawing) • 5, the starting material is carded in the usual way to form a thoroughly even fiber pelt. Directly behind the card or card there is a flow cross-laying table (also called cross-pelt or blamire-machine), which criss-crosses the fibers, which are laid in the longitudinal direction and which are dispensed by the card pucker, around the well-balanced fiber pelt produced in this way in winding form A of a finishing machine C. feed, which has two press rolls B, B 1 mounted under lever device /, / and load weights K , one of which is roughened or corrugated, the other is provided with a rubber coating. The lower roller B x of this finishing machine C is immersed in a trough D which is filled with cellulose solution. This cellulose solution serves as a binding material for the fiber pelt passed through between the press rolls B, B 1 by means of a feed table E. The lower roller B 1 , which is immersed in the trough D , feeds the cellulose solution to the fiber fur, exactly as the finish or the size is fed to a fabric in the finish. The upper roller B presses the mass into the felt layer; the excess runs back into trough D. When using one of the cellulose solutions mentioned above, under the action of the pressure of the press rollers B, B 1 , which apply the binding agent, the matted fibers adhere so well together that the product easily passes through at high speed, advantageously in a tensioned state Trough F can be passed, which contains a hardening liquid for the dissolved cellulose. The continuous product released by the rollers G, G 1 can then immediately be wound up on a shaft Ii or folded into a container, where it is washed and treated further, and then under tension. to be dried and finally embossed. The finished product is almost unbreakable due to the combined effect of the flow cross-bed table, the cellulose solution, the press rollers and the hardening liquid and is soft and pliable ", especially if one starts with a fiber fleece consisting of -ung, -bleached or only slightly bleached fibers Artificial leather has a closed structure and can be made waterproof by subsequent treatment, or water-repellent agents can be added to the cellulose mass. and sets up the finishing machine in such a way that one of the press rolls B, B 1 is only roughened or grooved in places or stripes and then smooth again in places the fiber material closer together but where the smooth surface of the press rolls acts, i.e. less binding compound is applied, there is less sticking together, so that after drying, the fibers are exposed again by scratching on the surface and over them at the less glued places the glued strips. or areas can be brushed away, resulting in a nice, long-fiber felt and also "imitations of fur. If so much cellulose solution were applied that a substantial excess is squeezed off by the press rollers B, B 1 , then the product would be too strongly glued," If you want to make a product that looks similar to Japanese paper, you have to add a suitable percentage of bleached cotton to the unbleached fiber material to be processed into fiber fur Depending on the ratio of the bleached to the unbleached fiber material, a more or less tough parchment-like Japanese paper is obtained B, B 1 does not 'penetrate into the cells of the fibers, but only envelops the fibers and binds them without substantial saturation. When using bleached fiber material, however, which as a result of the previous bleaching no longer contains any fatty or waxy substances and can therefore be easily wetted, the cellulose solution penetrates into the cells of the fibers and binds them together to form a stiff, parchment-like product. Products that do not have the crackling paper character can also be obtained, despite the fact that bleached fibers are used as the starting point if one uses this fiber; makes the material water-resistant beforehand according to a well-known process, in order to prevent the finishing compound from penetrating the • fiber cells. Finally, the: dried and possibly bleached leather and; Felt imitations are expediently still, with a cold sulfuric acid bath of 50 to
600Be und nach dem Auswaschen und Abpressen noch in feuchtem Zustand durch ein Natron- oder Kalilaugebad " hindurchgeführt. Durch diese Behandlung werden sie .ziemlich wasserfest und durchscheinend.60 0 After washing and pressing, passed through a soda or potassium hydroxide bath while still moist. This treatment makes them quite waterproof and translucent.
Claims (3)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH101536X | 1915-09-23 |
Publications (1)
Publication Number | Publication Date |
---|---|
DE308089C true DE308089C (en) |
Family
ID=32235069
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DENDAT308089D Active DE308089C (en) | 1915-09-23 |
Country Status (3)
Country | Link |
---|---|
DE (1) | DE308089C (en) |
FR (1) | FR482898A (en) |
GB (1) | GB101536A (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE742219C (en) * | 1937-12-23 | 1943-11-24 | Freudenberg Carl Fa | Process for the refinement of artificial leather-like surfaces |
DE747686C (en) * | 1941-04-06 | 1944-10-09 | Julius Fischer Fa | Device for drawing and gluing a sliver to produce a leather-like plastic |
DE767479C (en) * | 1935-03-15 | 1952-09-08 | Joshua Harold Goldman | Process for the production of fibrous sheets |
DE897090C (en) * | 1938-07-13 | 1953-11-19 | Freudenberg Carl Kg | Process for the production of molded articles of leather-like texture from fibers and binders |
-
0
- DE DENDAT308089D patent/DE308089C/de active Active
-
1916
- 1916-08-24 GB GB12024/16A patent/GB101536A/en not_active Expired
- 1916-09-16 FR FR482898A patent/FR482898A/en not_active Expired
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE767479C (en) * | 1935-03-15 | 1952-09-08 | Joshua Harold Goldman | Process for the production of fibrous sheets |
DE742219C (en) * | 1937-12-23 | 1943-11-24 | Freudenberg Carl Fa | Process for the refinement of artificial leather-like surfaces |
DE897090C (en) * | 1938-07-13 | 1953-11-19 | Freudenberg Carl Kg | Process for the production of molded articles of leather-like texture from fibers and binders |
DE747686C (en) * | 1941-04-06 | 1944-10-09 | Julius Fischer Fa | Device for drawing and gluing a sliver to produce a leather-like plastic |
Also Published As
Publication number | Publication date |
---|---|
GB101536A (en) | 1917-03-08 |
FR482898A (en) | 1917-05-02 |
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