DE2826686A1 - AUXILIARY CARRIERS FOR TRANSFER PRINTING - Google Patents
AUXILIARY CARRIERS FOR TRANSFER PRINTINGInfo
- Publication number
- DE2826686A1 DE2826686A1 DE19782826686 DE2826686A DE2826686A1 DE 2826686 A1 DE2826686 A1 DE 2826686A1 DE 19782826686 DE19782826686 DE 19782826686 DE 2826686 A DE2826686 A DE 2826686A DE 2826686 A1 DE2826686 A1 DE 2826686A1
- Authority
- DE
- Germany
- Prior art keywords
- printing
- auxiliary carrier
- dyes
- transfer printing
- reserve
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000010023 transfer printing Methods 0.000 title claims description 9
- 239000000969 carrier Substances 0.000 title description 3
- 239000000975 dye Substances 0.000 claims description 20
- 238000007639 printing Methods 0.000 claims description 19
- 229910052751 metal Inorganic materials 0.000 claims description 9
- 239000002184 metal Substances 0.000 claims description 9
- 150000001875 compounds Chemical class 0.000 claims description 8
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical class [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical class [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 4
- 229910052802 copper Inorganic materials 0.000 claims description 4
- 239000010949 copper Substances 0.000 claims description 4
- 150000002739 metals Chemical class 0.000 claims description 4
- 150000003839 salts Chemical class 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- 239000011701 zinc Chemical class 0.000 claims description 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical class [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical class [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical class [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 2
- 239000000370 acceptor Substances 0.000 claims description 2
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical class [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 2
- 229910052804 chromium Chemical class 0.000 claims description 2
- 239000011651 chromium Chemical class 0.000 claims description 2
- 229910017052 cobalt Inorganic materials 0.000 claims description 2
- 239000010941 cobalt Chemical class 0.000 claims description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical class [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 2
- 239000011777 magnesium Chemical class 0.000 claims description 2
- 229910052749 magnesium Inorganic materials 0.000 claims description 2
- 229910052759 nickel Inorganic materials 0.000 claims description 2
- 239000012209 synthetic fiber Substances 0.000 claims description 2
- 229920002994 synthetic fiber Polymers 0.000 claims description 2
- 229910052725 zinc Inorganic materials 0.000 claims description 2
- 230000000536 complexating effect Effects 0.000 claims 1
- 229910052500 inorganic mineral Inorganic materials 0.000 claims 1
- 239000011707 mineral Substances 0.000 claims 1
- 239000004744 fabric Substances 0.000 description 5
- 229920000728 polyester Polymers 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical class CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 230000008719 thickening Effects 0.000 description 3
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
- 239000004280 Sodium formate Substances 0.000 description 2
- 230000009918 complex formation Effects 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Chemical class OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000000661 sodium alginate Substances 0.000 description 2
- 235000010413 sodium alginate Nutrition 0.000 description 2
- 229940005550 sodium alginate Drugs 0.000 description 2
- HLBBKKJFGFRGMU-UHFFFAOYSA-M sodium formate Chemical compound [Na+].[O-]C=O HLBBKKJFGFRGMU-UHFFFAOYSA-M 0.000 description 2
- 235000019254 sodium formate Nutrition 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- MHXFWEJMQVIWDH-UHFFFAOYSA-N 1-amino-4-hydroxy-2-phenoxyanthracene-9,10-dione Chemical compound C1=C(O)C=2C(=O)C3=CC=CC=C3C(=O)C=2C(N)=C1OC1=CC=CC=C1 MHXFWEJMQVIWDH-UHFFFAOYSA-N 0.000 description 1
- FFRBMBIXVSCUFS-UHFFFAOYSA-N 2,4-dinitro-1-naphthol Chemical compound C1=CC=C2C(O)=C([N+]([O-])=O)C=C([N+]([O-])=O)C2=C1 FFRBMBIXVSCUFS-UHFFFAOYSA-N 0.000 description 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical class COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- 229920000298 Cellophane Polymers 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical class OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- -1 NiCl 2 1 Zn (NO 3 ) Chemical class 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Chemical class [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- 235000011054 acetic acid Nutrition 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 150000004696 coordination complex Chemical class 0.000 description 1
- 239000002274 desiccant Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 229910000000 metal hydroxide Inorganic materials 0.000 description 1
- 150000004692 metal hydroxides Chemical class 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 238000010020 roller printing Methods 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000011975 tartaric acid Chemical class 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/12—Reserving parts of the material before dyeing or printing ; Locally decreasing dye affinity by chemical means
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M3/00—Printing processes to produce particular kinds of printed work, e.g. patterns
- B41M3/12—Transfer pictures or the like, e.g. decalcomanias
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/003—Transfer printing
- D06P5/004—Transfer printing using subliming dyes
Description
BAYER AKTIENGESELLSCHAFT 5090 Leverkusen, BayerwerkBAYER AKTIENGESELLSCHAFT 5090 Leverkusen, Bayerwerk
Zentralbereich K-byCentral area K-by
Patente, Marken und Lizenzen * -■ fPatents, trademarks and licenses * - ■ f
Gegenstand der Erfindung sind Hilfsträger für den Wärmetransferdruck, welche dadurch gekennzeichnet sind, daß auf diesen zunächst mittels zur Metallkomplexbildung befähigten, sublimierbaren Farbstoffen ein Fond hergestellt wird, auf welchen anschließend eine Reservedruckpaste musterförmig aufgedruckt wird, welche komplexbildende Metalle abgebende Verbindungen enthält, sowie deren Verwendung zur Ausübung des trockenen Transferdrucks von textlien Flächengebilden aus synthetischem oder teilsynthetischem Fasermaterial.The invention relates to auxiliary carriers for heat transfer printing, which are characterized by the fact that they are initially capable of metal complex formation by means of sublimable dyes a base is produced, on which a reserve printing paste is then applied is printed in a pattern, which contains complex-forming metals releasing compounds, and their use for performing dry transfer printing of textile fabrics made of synthetic or semi-synthetic Fiber material.
Das neue Verfahren vereinigt in hervorragender Weise die bekannten Vorteile des trockenen Wärmetransferdrucks mit denen des Reservedrucks, indem es die Herstellung konturenscharfer Drucke mittels einfacher und preiswerter Druckformen ermöglicht.The new process combines the well-known advantages of dry heat transfer printing in an excellent way those of the reserve print by making it possible to produce prints with sharp contours using simple and inexpensive printing forms enables.
Le A 18 915Le A 18 915
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Der Aufdruck der Reservepaste wird in an sich bekannter Weise im Rotationsfilmdruck oder Rouleauxdruck vorgenommen. Das Aufbringen des Fonds kann durch Aufstreichen, Aufsprühen/ Aufräkeln oder Drucken erfolgen.The printing of the reserve paste is carried out in a manner known per se using rotary film printing or roller printing. The fund can be applied by brushing on, spraying on / ruffling or printing.
Vorteilhafterweise werden jedoch Fondfärbung und Aufbringen der Reservedruckpaste in einem Arbeitsgang ohne Zwischentrocknung, also naß-in-naß auf ein und derselben Maschine, durchgeführt.Advantageously, however, the base coloring and the application of the reserve printing paste are carried out in one operation without intermediate drying, i.e. wet-on-wet on one and the same machine.
Die zu verwendenden Druckpasten sind vorzugsweise wäßriger Natur und enthalten neben den erfindungsgemäßen Bestandteilen die üblichen Verdickungs- und Dispergiermittel.The printing pastes to be used are preferably aqueous in nature and contain, in addition to the components according to the invention the usual thickeners and dispersants.
Die Reservedruckpasten können darüber hinaus auch sublimierbare Farbstoffe, die nicht zur Komplexbildung befähigt sind, enthalten.The reserve printing pastes can also contain sublimable dyes that are not capable of complex formation included.
Ig Man erhält so Hilfsträger mit einer Buntreserve.Ig You get an auxiliary carrier with a colored reserve.
Geeignete Fondfarbstoffe sind Transferfarbstoffe auf der Basis von ortho-Hydroxyazoverbindungen oder o£"-Hydroxyantrachinonen. Suitable base dyes are transfer dyes based on ortho-hydroxyazo compounds or o £ "-hydroxyantraquinones.
Beispielhaft seien die in der DE-OS 2 115 174 (entspricht GB-PS 1 320 819) auf den Seiten 5-14 aufgeführten Verbindungstypen genannt.Examples are those in DE-OS 2 115 174 (corresponds to GB-PS 1 320 819) on pages 5-14 called.
Le A 18 915Le A 18 915
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-V--V-
Geeignete Reservefarbstoffe sind handelsübliche Transferfarbstoffe, die frei von komplexbildenden Gruppen sind.Suitable reserve dyes are commercially available transfer dyes, which are free from complex-forming groups.
Geeignete komplexbildende Metalle abgebende Verbindungen sind insbesondere Salze von Kupfer, Nickel, Kobalt, Aluminium, Magnesium, Zink und Chrom, wie z.B. NiCl2 1 Zn(NO3), MgCl2, Al2(SO4)3, FeSO4 und CoCl2.Suitable compounds releasing complex-forming metals are, in particular, salts of copper, nickel, cobalt, aluminum, magnesium, zinc and chromium, such as NiCl 2 1 Zn (NO 3 ), MgCl 2 , Al 2 (SO 4 ) 3 , FeSO 4 and CoCl 2 .
Bevorzugt sind die wasserlöslichen Komplexsalze des zweiwertigen Kupfers, insbesondere der Kupfertetraninkomplex. Bei Verwendung sauer hydrolysierender Metallsalze sind •jQ der Reservedruckpaste Säureakzeptoren zuzusetzen, wobei jedoch darauf zu achten ist, daß dabei keine wasserunlöslichen Metallhydroxide entstehen.The water-soluble complex salts of divalent copper, in particular the copper tetranine complex, are preferred. If acidic hydrolyzing metal salts are used, acid acceptors must be added to the reserve printing paste, whereby However, care must be taken that no water-insoluble metal hydroxides are formed.
Diese Forderung wird beispielsweise von den Alkalisalzen der Essigsäure, Ameisensäure, Weinsäure sowie von wäßrigem Ammoniak erfüllt, da die meisten der obengenannten Metalle unter Einwirkung dieser Verbindungen einen wasserlöslichen Komplex bilden.This requirement is for example of the alkali salts of acetic acid, formic acid, tartaric acid and of aqueous ammonia met, as most of the above metals under the action of these compounds form a water-soluble complex.
Als textile Flächengebilde kommen Gewirke und Gewebe sowie Teppiche aus aromatischen Polyestern, synthetischen PoIyamiden, Celluloseestern sowie Polyester/Baumwoll-Mischungen in Betracht. *As textile fabrics, knitted and woven fabrics as well as carpets made of aromatic polyesters, synthetic polyamides, Cellulose esters and polyester / cotton blends are possible. *
Geeignete Materialien zur Herstellung der Hilfsträger sind Metallfolien, Cellophan sowie vor allem Papier.Suitable materials for producing the auxiliary carriers are metal foils, cellophane and, above all, paper.
Le A 18 915Le A 18 915
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Der Umdruck von Hilfsträger auf das Substrat erfolgt bei 16O-24O°C, vorzugsweise 180-: während 15 bis 120 Sekunden.The transfer printing of the auxiliary carrier onto the substrate takes place at 160-24O ° C, preferably 180-: for 15 to 120 seconds.
16O-24O°C, vorzugsweise 18O-21O°C in üblicher Weise160-240 ° C., preferably 180-210 ° C. in the usual way
Das erfindungsgemäße Verfahren sei anhand der folgenden Beispiele näher erläutert.The method of the invention is based on the following Examples explained in more detail.
Le A 18 915Le A 18 915
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Eine Druckpaste bestehend ausA printing paste consisting of
50 g einer Farbstoff-Präparation aus 50 % 1-Amino-2-phenoxy-4-hydroxyanthrachinon, 10 % eines handelsüblichen nichtionen Dispergiermittels auf Polyäther-Basis, 10 % eines Eintrocknungsverhinderungsmittels (z.B. Äthylenglykol) und 30 % Wasser sowie50 g of a dye preparation made from 50% 1-amino-2-phenoxy-4-hydroxyanthraquinone, 10% of a commercially available non-ionic dispersant based on polyether, 10% of an anti-drying agent (e.g. ethylene glycol) and 30% water as well
950 g Natriumalginat (4 %ige wäßrige Lösung)950 g sodium alginate (4% aqueous solution)
wird im Rotationsfilmdruck gleichmäßig auf ein Transferpapier gedruckt. Auf das noch feuchte Papier wird anschließend auf der gleichen Maschine eine Reservedruckpaste bestehend ausis evenly printed on a transfer paper in rotary film printing printed. A reserve printing paste is then applied to the still damp paper on the same machine consisting of
50 g Cu-II-Acetat
100 g Wasser
50 g Ammoniak 25 %ig50 g Cu-II acetate
100 g of water
50 g ammonia 25%
400 g Verdickung (Kristallgummi)
200 g Na-Acetat
200 g Wasser400 g thickening (crystal rubber)
200 g Na acetate
200 g of water
1000 g
musterförmig aufgedruckt.1000 g
printed in pattern.
Nach dem Trocknen wird das Papier während 30 Sekunden bei 210°C in engen Kontakt mit einem Polyestergewebe gebracht.After drying, the paper is brought into close contact with a polyester fabric at 210 ° C. for 30 seconds.
Le A 18 915Le A 18 915
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Man erhält einen roten Umdruck mit einer konturenscharfen Weißreserve.A red transfer print with a white reserve with sharp contours is obtained.
Ersetzt man in der Reservedruckpaste einen Teil des Wassers durch 40 g einer Farbstoffpräparation enthaltend 50 % des Farbstoffs der FormelPart of the water in the reserve printing paste is replaced by 40 g of a dye preparation containing it 50% of the dye of the formula
so erhält man auf dem Polyestergewebe konturenscharfe gelbe Muster auf rotem Grund.in this way, sharply outlined yellow patterns on a red background are obtained on the polyester fabric.
Ähnliche Effekte erzielt man, wenn man anstelle der vorstehend beschriebenen Farbstoffe die in nachfolgenden Tabellen aufgeführten Verbindungen einsetzt:Similar effects are achieved if, instead of the dyes described above, the dyes below are used The compounds listed in the tables are used:
Le A 18 915Le A 18 915
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Tabelle 1 - Fondfarbstoffe -Table 1 - Fond dyes -
Formelformula
Nuancenuance
a) CH0-Ca) CH 0 -C
3 Ii 3 ii
C =CH-C C-CH.C = CH-C C-CH.
N C=O C NN C = O C N
gelbyellow
HOHO
0H0H
gelbyellow
c) CH-.-O-C-//c) CH -.- O-C - //
SWSW
-O-C-// V-N=N-O-C - // V-N = N
N-, rrN-, rr
JJJJ
I CH3 gelbI CH 3 yellow
0 NH,0 NH,
0 OH0 OH
rotRed
Le A 18 915Le A 18 915
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Tabelle 1 (Fortsetzung) Table 1 (continued)
Formel NuanceFormula nuance
0 NH,0 NH,
0 OH rot0 OH red
0 OH0 OH
)H 0 NHC3H5 blau) H 0 NHC 3 H 5 blue
blaublue
Le A 18Le A 18
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Tabelle 2 - Illuminierfarbstoffe - (für Buntreserve)Table 2 - Illuminating dyes - (for color reserve)
Formelformula
Nuancenuance
O NHO NH
C2H4OHC 2 H 4 OH
violettviolet
blau rotblue red
N
CHN
CH
CH-CH-
I 3 I 3
C— CH3 J=CH-CH=CC-CH 3 J = CH-CH = C
CNCN
CNCN
gelbyellow
0 NH,0 NH,
0 NH,0 NH,
blaugrünblue green
Le A 18 915Le A 18 915
909881/0159909881/0159
Ein Transferpapier wird mit einer Farbstoffpaste bestrichen, welche aus 50 g einer 40 flüssigen Färbst off präparat ion, die 40 % des Farbstoffs der FormelA transfer paper is coated with a dye paste, which from 50 g of a 40 liquid dye off preparation, the 40% of the dye of the formula
NO2 -N=N NO 2 - N = N
n HO η n HO η
und 60 % üblicher Zusätze enthält und 9 5Og einer 4 %igen Natriumalginat-Verdickung besteht.and contains 60% of the usual additives and 9 50 g of a 4% strength There is sodium alginate thickening.
Auf das getrocknete Papier wird dann eine Reservedruckpaste im Rouleaux- Druck musterförmig aufgedruckt. Die Paste hat folgende Zusammensetzung:A reserve printing paste is then printed in pattern form on the dried paper using Rouleaux printing. the Paste has the following composition:
40 g Al2(SO4J3 40 g Al 2 (SO 4 J 3
500 g Kristallgummi-Verdickung 160 g Natriumformiat 50 g 1 ,4-Di-methylainino-anthrachinon (als 50 %ige500 g crystal rubber thickening 160 g sodium formate 50 g 1,4-dimethylainino-anthraquinone (as 50%
Flüssigeinstellung) 250 ml WasserLiquid setting) 250 ml water
Beim Umdruck (30 Sekunden 200 C) des getrockneten Papiers auf ein Polyestergewebe erhält man ein gestochen scharfes blaues Muster auf goldgelbem Grund.When transferring (30 seconds 200 C) the dried paper A razor-sharp blue pattern on a golden yellow background is obtained on a polyester fabric.
Le A 18 915Le A 18 915
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Ähnliche Ergebnisse erhält man, wenn man das Aluminiumsalz in der Reservedruckpaste durch etwa die gleiche Menge NiCl2 oder CoCl2 und das Natriumformiat durch Natriumacetat ersetzt.Similar results are obtained if the aluminum salt in the reserve printing paste is replaced by approximately the same amount of NiCl 2 or CoCl 2 and the sodium formate by sodium acetate.
Le A 18 915Le A 18 915
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Claims (6)
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19782826686 DE2826686A1 (en) | 1978-06-19 | 1978-06-19 | AUXILIARY CARRIERS FOR TRANSFER PRINTING |
| GB7920322A GB2023502A (en) | 1978-06-19 | 1979-06-12 | Temporary supports for transfer printing |
| IT7923639A IT7923639A0 (en) | 1978-06-19 | 1979-06-15 | AUXILIARY SUPPORT SUBSTANCES FOR TRANSFER PRINTING. |
| FR7915596A FR2429107A1 (en) | 1978-06-19 | 1979-06-18 | AUXILIARY MEDIA FOR TRANSFER PRINTING |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19782826686 DE2826686A1 (en) | 1978-06-19 | 1978-06-19 | AUXILIARY CARRIERS FOR TRANSFER PRINTING |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2826686A1 true DE2826686A1 (en) | 1980-01-03 |
Family
ID=6042082
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19782826686 Pending DE2826686A1 (en) | 1978-06-19 | 1978-06-19 | AUXILIARY CARRIERS FOR TRANSFER PRINTING |
Country Status (4)
| Country | Link |
|---|---|
| DE (1) | DE2826686A1 (en) |
| FR (1) | FR2429107A1 (en) |
| GB (1) | GB2023502A (en) |
| IT (1) | IT7923639A0 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0023659A1 (en) * | 1979-07-25 | 1981-02-11 | Hoechst Aktiengesellschaft | Process for the production of resist-printing effects by the transfer printing process and appropriate temporary supports |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2193687B (en) * | 1986-07-11 | 1991-02-13 | Canon Kk | Image forming method and transfer recording medium therefor |
-
1978
- 1978-06-19 DE DE19782826686 patent/DE2826686A1/en active Pending
-
1979
- 1979-06-12 GB GB7920322A patent/GB2023502A/en not_active Withdrawn
- 1979-06-15 IT IT7923639A patent/IT7923639A0/en unknown
- 1979-06-18 FR FR7915596A patent/FR2429107A1/en not_active Withdrawn
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0023659A1 (en) * | 1979-07-25 | 1981-02-11 | Hoechst Aktiengesellschaft | Process for the production of resist-printing effects by the transfer printing process and appropriate temporary supports |
Also Published As
| Publication number | Publication date |
|---|---|
| IT7923639A0 (en) | 1979-06-15 |
| FR2429107A1 (en) | 1980-01-18 |
| GB2023502A (en) | 1980-01-03 |
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