DE281146C - - Google Patents
Info
- Publication number
- DE281146C DE281146C DENDAT281146D DE281146DC DE281146C DE 281146 C DE281146 C DE 281146C DE NDAT281146 D DENDAT281146 D DE NDAT281146D DE 281146D C DE281146D C DE 281146DC DE 281146 C DE281146 C DE 281146C
- Authority
- DE
- Germany
- Prior art keywords
- hydrocarbons
- water
- mixture
- alkalis
- sodium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 229930195733 hydrocarbon Natural products 0.000 claims description 11
- 150000002430 hydrocarbons Chemical class 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 5
- 239000004215 Carbon black (E152) Substances 0.000 claims description 4
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 4
- 229940099259 vaseline Drugs 0.000 claims description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
- 159000000011 group IA salts Chemical class 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims description 2
- 125000003158 alcohol group Chemical group 0.000 claims 1
- -1 e.g. B. vaseline oil Chemical class 0.000 claims 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000000344 soap Substances 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 229940072033 potash Drugs 0.000 description 1
- 235000015320 potassium carbonate Nutrition 0.000 description 1
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- PFUVRDFDKPNGAV-UHFFFAOYSA-N sodium peroxide Chemical compound [Na+].[Na+].[O-][O-] PFUVRDFDKPNGAV-UHFFFAOYSA-N 0.000 description 1
- ZBNMBCAMIKHDAA-UHFFFAOYSA-N sodium superoxide Chemical compound [Na+].O=O ZBNMBCAMIKHDAA-UHFFFAOYSA-N 0.000 description 1
- 229910000144 sodium(I) superoxide Inorganic materials 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
- C10G27/04—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen
- C10G27/12—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen with oxygen-generating compounds, e.g. per-compounds, chromic acid, chromates
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Description
KAISERLICHESIMPERIAL
PATENTAMT.PATENT OFFICE.
PATENTSCHRIFTPATENT LETTERING
- JVe 281146 KLASSE 23 e, GRUPPE- JVe 281146 CLASS 23 e, GROUP
BERNHARD BENEDIX in HAMBURG.BERNHARD BENEDIX in HAMBURG.
Zur Herstellung von Seifen aus Kohlenwasserstoffen hat man bereits .vorgeschlagen, die Kohlenwasserstoffe dadurch zu oxydieren, daß man sie im Gemenge von Alkalien mit einem Luft- oder Sauerstoffstrom unter Anwendung höherer !. Temperaturen behandelt.For the production of soaps from hydrocarbons, one has already proposed the use of hydrocarbons to be oxidized by being mixed with alkalis with a stream of air or oxygen using higher ! Treated temperatures.
Die zu dem beabsichtigten Zweck verwendbaren Kohlenwasserstoffe zersetzen sich aber bei Anwendung höherer Temperaturen, so daßHowever, the hydrocarbons which can be used for the intended purpose decompose when using higher temperatures, so that
ίο sich bei einem Versuch, auf dem vorgeschlagenen Wege zu Seifen zu kommen; ein vollkommener Mißerfolg ergibt. Wollte man sodann bei dem vorgeschlagenen Verfahren auch noch Druck · anwenden, wie dies angeregt worden ist, dann würde man außerdem bei dem Versuch, die · Kohlenwasserstoffe zu oxydieren, den Betrieb aufs äußerste gefährden.ίο in an attempt on the proposed Ways to get soaps; a total failure results. If you wanted to then with that then apply pressure as suggested by the proposed method one would also stop operating in an attempt to oxidize the hydrocarbons endanger to the utmost.
Demgegenüber wird gemäß der Erfindung in der Weise vorgegangen, daß man die Kohlen-Wasserstoffe, beispielsweise Vaselinöl, mit durch' Alkalien oder alkalische Salze verdünntem-Natrium- oder Wasserstoffsuperoxyd bei Gegenwart von Wasser innig mischt. Durch diese Verfahrensweise wird eine stärkere Einwirkung des Sauerstoffes auf die einzelnen Kohlenwasserstoffmoleküle erreicht, so daß diese durch den frei werdenden Sauerstoff zu Säuren oxydiert werden, die mit den zugesetzten bzw. aus dem Natriumsuperoxyd entstehenden Alkalien und dem überschüssigen Kohlenwasserstoff in eine in Wasser leicht verteilbare, wie eine Seife verwendbare Masse übergehen.In contrast, the procedure according to the invention is that the hydrocarbons, for example vaseline oil, with sodium diluted by alkalis or alkaline salts or hydrogen peroxide mixes intimately in the presence of water. This procedure increases the impact of the Oxygen reaches the individual hydrocarbon molecules, so that these through the released oxygen is oxidized to acids, which with the added or from the alkalis and the excess hydrocarbon in the sodium peroxide a mass that is easily dispersible in water and can be used like a soap pass over.
Während bei den bekannten Verfahren die Ausbeute eine schlechte ist, werden nach dem vorliegenden Verfahren 60 Prozent brauchbare Masse, bestehend aus einer Mischung unzersetzter und umgewandelter Kohlenwasserstoffe, erhalten. While the yield is poor in the known processes, after present process 60 percent usable mass, consisting of a mixture of undecomposed and converted hydrocarbons.
Die innige Berührung und damit die Reaktion der in Mischung gebrachten Stoffe kann durch den Zusatz von Alkohol befördert werden.The intimate contact and thus the reaction of the mixed substances can be promoted by the addition of alcohol.
Zur Oxydation von 1Z4I Vaselinöl werden zunächst etwa 50 g Kristallsoda, 20 g Pottäsche und 20 g Natriumsuperoxyd .gemischt. Die Mischung erfolgt unter Zusatz von Wasser, und zwar wird so viel Wasser hinzugefügt, bis eine dicke Paste entsteht. Hierauf werden dieser Mischung ev. noch etwa 5 g Alkohol hinzugefügt. Das Gemenge wird alsdann mit dem zu oxydierenden Kohlenwasserstoff gemischt. Nach einigem Rühren verdickt sich die Mischung, so daß ev. noch etwas Wasser hinzugesetzt werden muß. Es ist zweckmäßig, nicht bei höheren, d. h. 600C übersteigenden Temperaturen zu arbeiten.To oxidize 1 Z 4 l of vaseline oil, first about 50 g of crystal soda, 20 g of potash and 20 g of sodium superoxide are mixed. Mixing is done with the addition of water, adding enough water to form a thick paste. About 5 g of alcohol are then added to this mixture. The mixture is then mixed with the hydrocarbon to be oxidized. After some stirring, the mixture thickens, so that a little more water may have to be added. It is appropriate, not at higher working ie 60 0 C for rising temperatures.
Das fertige Produkt stellt sich als eine weiche, in Wasser leicht verteilbare Paste von großem Reinigungswert dar. "The finished product turns out to be a soft paste of large size that is easily spreadable in water Cleaning value. "
Claims (2)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE281146C true DE281146C (en) |
Family
ID=33102707
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DENDAT281146D Active DE281146C (en) |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE281146C (en) |
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0
- DE DENDAT281146D patent/DE281146C/de active Active
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