DE268891C - - Google Patents
Info
- Publication number
- DE268891C DE268891C DENDAT268891D DE268891DA DE268891C DE 268891 C DE268891 C DE 268891C DE NDAT268891 D DENDAT268891 D DE NDAT268891D DE 268891D A DE268891D A DE 268891DA DE 268891 C DE268891 C DE 268891C
- Authority
- DE
- Germany
- Prior art keywords
- dyes
- sulfur
- sulfhydrates
- sulfuric acid
- particular alkali
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000975 dye Substances 0.000 claims description 6
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 4
- -1 Sodium sulfur Chemical compound 0.000 claims description 3
- 239000003513 alkali Substances 0.000 claims description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 2
- 239000011593 sulfur Substances 0.000 claims description 2
- 229910052717 sulfur Inorganic materials 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims 1
- 230000004048 modification Effects 0.000 claims 1
- 238000006011 modification reaction Methods 0.000 claims 1
- UJOBWOGCFQCDNV-UHFFFAOYSA-N Carbazole Natural products C1=CC=C2C3=CC=CC=C3NC2=C1 UJOBWOGCFQCDNV-UHFFFAOYSA-N 0.000 description 2
- GRVFOGOEDUUMBP-UHFFFAOYSA-N Sodium sulfide Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 description 2
- HOQAPVYOGBLGOC-UHFFFAOYSA-N 1-ethyl-9H-carbazole Chemical compound C12=CC=CC=C2NC2=C1C=CC=C2CC HOQAPVYOGBLGOC-UHFFFAOYSA-N 0.000 description 1
- JSTCPNFNKICNNO-UHFFFAOYSA-N 4-nitrosophenol Chemical compound OC1=CC=C(N=O)C=C1 JSTCPNFNKICNNO-UHFFFAOYSA-N 0.000 description 1
- RSAZYXZUJROYKR-UHFFFAOYSA-N Indophenol Chemical compound C1=CC(O)=CC=C1N=C1C=CC(=O)C=C1 RSAZYXZUJROYKR-UHFFFAOYSA-N 0.000 description 1
- ZOCLAPYLSUCOGI-UHFFFAOYSA-M Potassium hydrosulfide Chemical compound [SH-].[K+] ZOCLAPYLSUCOGI-UHFFFAOYSA-M 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B49/00—Sulfur dyes
- C09B49/10—Sulfur dyes from diphenylamines, indamines, or indophenols, e.g. p-aminophenols or leucoindophenols
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Indole Compounds (AREA)
Description
KAISERLICHESIMPERIAL
PATENTAMT.PATENT OFFICE.
PATENTSCHRIFTPATENT LETTERING
- JVl 268891 -KLASSE lld. GRUPPE - JVl 268891 - CLASS lld. GROUP
FARBWERKE vorm. MEISTER LUCIUS & BRÜNING in HÖCHST a. M.FARBWERKE vorm. MASTER LUCIUS & BRÜNING in HÖCHST a. M.
Verfahren zur Herstellung in Schwefelnatrium löslicher Farbstoffe.Process for the preparation of dyes soluble in sodium sulphide.
Zusatz zum Patent 264044.Addendum to patent 264044.
Patentiert im Deutschen Reiche vom 14. Januar 1912 ab. Längste Dauer: 13.Januar 1927.Patented in the German Empire on January 14, 1912. Longest duration: January 13, 1927.
In dem Patent 264044, Kl. 22 d, wurde gezeigt, daß man die Farbstoffe der Patentschriften 222640, 224590 und 224591, Kl. 22 d, insbesondere aus den Indophenolen, welche sich von Alkyl- oder Arylcarbazolen ableiten, mittels Schwefelsäure in Farbstoffe, welche sich in Schwefelnatrium leicht färben lassen, umwandeln kann.In the patent 264044, cl. 22 d, it was shown that the dyes of the patents 222640, 224590 and 224591, class 22 d, in particular from the indophenols, which are derived from alkyl or aryl carbazoles, by means of sulfuric acid in dyes, which can be easily colored in sodium sulphide, can be transformed.
Es wurde nun weiter gefunden, daß man auch durch Behandlung mittels Schwefelalkalien, insbesondere Alkalisulfhydrate, eine Umwandlung erzielt.It has now been found that treatment with alkaline sulfur, in particular alkali sulfhydrates, achieved a conversion.
40 Teile Farbstoff, erhalten durch Verschwefeln des Indophenols aus einem Alkylcarbazol, z. B. Äthylcarbazol und Nitrosophenol, werden in Form einer Paste mit Teilen Kaliumsulfhydrat, gelöst in 600 Teilen Wasser, längere Zeit gekocht; das Reaktionsprodukt wird dann mit Säure gefällt.40 parts of dye, obtained by sulphurizing the indophenol from an alkyl carbazole, z. B. ethyl carbazole and nitrosophenol are in the form of a paste with parts of potassium sulfhydrate dissolved in 600 parts Water, boiled for a long time; the reaction product is then precipitated with acid.
Claims (1)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE268891C true DE268891C (en) |
Family
ID=525813
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DENDAT268891D Active DE268891C (en) |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE268891C (en) |
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0
- DE DENDAT268891D patent/DE268891C/de active Active
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