DE2605420A1 - Washing and rinsing composition for softening textiles - nonionic surfactant, softening agent and polyglycol difatty acid ester - Google Patents

Washing and rinsing composition for softening textiles - nonionic surfactant, softening agent and polyglycol difatty acid ester

Info

Publication number
DE2605420A1
DE2605420A1 DE19762605420 DE2605420A DE2605420A1 DE 2605420 A1 DE2605420 A1 DE 2605420A1 DE 19762605420 DE19762605420 DE 19762605420 DE 2605420 A DE2605420 A DE 2605420A DE 2605420 A1 DE2605420 A1 DE 2605420A1
Authority
DE
Germany
Prior art keywords
softening
weight
integer
washing
polyglycol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
DE19762605420
Other languages
German (de)
Inventor
Rudolf Dr Bimczok
Geb Boelcke Ursula Meschkat
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EXQUISIT KOSMETIK GmbH
Original Assignee
EXQUISIT KOSMETIK GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by EXQUISIT KOSMETIK GmbH filed Critical EXQUISIT KOSMETIK GmbH
Priority to DE19762605420 priority Critical patent/DE2605420A1/en
Priority to SE7604127A priority patent/SE424647B/en
Priority to IT22435/76A priority patent/IT1059193B/en
Priority to NO761523A priority patent/NO146436C/en
Priority to DK218976A priority patent/DK144798C/en
Priority to FI761456A priority patent/FI62681C/en
Priority to PT65249A priority patent/PT65249B/en
Priority to ES449540A priority patent/ES449540A1/en
Publication of DE2605420A1 publication Critical patent/DE2605420A1/en
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/835—Mixtures of non-ionic with cationic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/722—Ethers of polyoxyalkylene glycols having mixed oxyalkylene groups; Polyalkoxylated fatty alcohols or polyalkoxylated alkylaryl alcohols with mixed oxyalkylele groups
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/74—Carboxylates or sulfonates esters of polyoxyalkylene glycols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/001—Softening compositions
    • C11D3/0015—Softening compositions liquid

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

A liq. compsn. used for end-washing clothes, etc. in washing machines, comprises 7-40% of a nonionic surfactant 3-15% diester of a polyglycol with an 8-20C fatty acid, 1-7.5% of quate. ammonium textile agent, opt. with other additives together with water. The compsn. are particu. used for softening rinses. They have both a remarkable washing action and softening effect.

Description

Flüssiges Feinwaschmittel Liquid mild detergent

Gegenstand des Hauptpatentes Nr. (Patentanmeldung P 25 29 444.4) ist ein flüssiges Feinwaschmittel mit weichmachender Wirkung, das dadurch gekennzeichnet ist, daß es etwa 7 bis 40 Gew.-% eines C1o-C2o-Alkylpolyglykoläthers und/oder C6-C20-Alkylphenolpolyglykoläthers, etwa 3 bis LCIPY . tLLeEfi und 15 Gew.-% eines C8-C20-Fettsäurepolyglykoletwa4 bis 7,5 Gew.-% eines Di-C10-C22-alkyldimethyl- bzw. äthylammoniumhalogenids sowie gegebenenfalls weitere in Waschmitteln übliche Bestandteile auf wäßriger Basis enthält.The subject of the main patent no. (Patent application P 25 29 444.4) is a liquid mild detergent with a softening effect, which is characterized in that it contains about 7 to 40% by weight of a C1o-C2o-alkyl polyglycol ether and / or C6-C20 alkyl phenol polyglycol ether, about 3 to LCIPY. tLLeEfi and 15% by weight of a C8-C20 fatty acid polyglycol, about 4 to 7.5% by weight of a di-C10-C22-alkyldimethyl or ethylammonium halide and, if appropriate, other aqueous-based constituents that are common in detergents.

Ein solchermaßen zusammengesetztes Waschmittel weist neben einer guten Waschwirkung noch eine ausgezeichnete faserpflegende Wirkung auf und verleiht den damit behandelten Textilien einen weichen Griff.A detergent composed in this way shows, in addition to a good one Washing effect still has an excellent fiber care effect and gives the textiles treated with it have a soft feel.

Es wurde nun gefunden, daß man ein flüssiges Feinwaschmittel mit besonders guter Waschwirkung und einer ausgezeichneten weichmachenden Wirkung auf das damit gewaschene Gewebe dann erhält, wenn man den C10-C20-Alkylpolyglykoläther und/oder C6-C20-Alkylphenolpolyglykoläther nach dem Hauptpatent ganz oder teilweise durch ein Polyoxiäthylenpolyoxipropylen-Blockpolymerisat ersetzt.It has now been found that you can use a liquid mild detergent with special good detergency and an excellent softening effect on it Washed fabric is obtained when using the C10-C20 alkyl polyglycol ether and / or C6-C20-alkylphenol polyglycol ether according to the main patent in whole or in part replaced a polyoxyethylene polyoxy propylene block polymer.

Diese Produkte weisen die allgemeinen Struktureinheiten I) HO - (C2H4°) - (C3H6°)y - (C2H4°) H oder II) HO - (C3H6O)n - (C2H4O)m - (C3H6O)nH auf, wobei y eine ganze Zahl von 1o bis 40, vorzugsweise 26 bis 30, und x + z eine ganze Zahl von 1o bis 60, vorzugsweise 30 bis 40, bedeuten, während m für eine ganze Zahl von 1o bis So, vorzugsweise 30 bis 40, und n für eine ganze Zahl von 1o bis 40, vorzugsweise 20 bis 30, steht.These products have the general structural units I) HO - (C2H4 °) - (C3H6 °) y - (C2H4 °) H or II) HO - (C3H6O) n - (C2H4O) m - (C3H6O) nH on, where y is an integer from 10 to 40, preferably 26 to 30, and x + z is an integer Number from 10 to 60, preferably 30 to 40, mean, while m is an integer from 10 to 50, preferably 30 to 40, and n for an integer from 10 to 40, preferably 20 to 30.

Die Herstellung und Eigenschaften dieser Verbindungen sind in der Monographie von Rurt Lindner, Tenside-Textilhilfsmittel-Waschrohstoffe, S. 1052-1057 (Wissenschaftliche Verlagsgesellschaft mbH Stuttgart, 1964) ausführlich beschrieben.The preparation and properties of these compounds are in the Monograph by Rurt Lindner, Tenside-Textilhilfsmittel-Waschrohstoffe, pp. 1052-1057 (Wissenschaftliche Verlagsgesellschaft mbH Stuttgart, 1964) described in detail.

Das Molgewicht der erfindungsgemäß zum Einsatz gelangenden Polyoxiäthylenpolyoxipropylen-Copolymerisate liegt vorzugsweise zwischen etwa looo und etwa 15 ooo; geeignete Handelsprodukte sind beispielsweise unter dem Namen PluronicR (siehe McCutcheons, Detergents and Emulsifiers, 1974 Ed., S. 137-138) beschrieben.The molecular weight of the polyoxyethylene-polyoxypropylene copolymers used according to the invention is preferably between about 1,000 and about 15,000; suitable commercial products are for example under the name PluronicR (see McCutcheons, Detergents and Emulsifiers, 1974 Ed., Pp. 137-138).

Im übrigen gelten sämtliche Ausführungsformen des Hauptpatents auch für das Zusatzpatent.In addition, all embodiments of the main patent also apply for the additional patent.

Anwendungsbeispiel PolyoxiäthylenpolyoxipRopylen-Blockpoly- 25,0 Gew.-% merisat (z.B. Pluronic L 62 der BASF-Wyandotte Co.) Polyäthylenglykol-6oo-distearat 6,5 Gew.-% Distearyldimethylammoniumchlorid 2,5 Gew.-% Lauryldimethylaminoxid 1,5 Gew.-% Konservierungsmittel (40%-ige 0,3 Gew.-% CH20-Lösung) Parfum 0,7 Gew.-% Farbstofflösung (0,1%-ig) 0,5 Gew.-% Wasser 63,0 Gew.-%Application example polyoxyethylene polyoxyethylene block poly- 25.0% by weight merisate (e.g. Pluronic L 62 from BASF-Wyandotte Co.) polyethylene glycol 600 distearate 6.5% by weight distearyldimethylammonium chloride 2.5% by weight lauryldimethylamine oxide 1.5 % By weight preservative (40% 0.3% by weight CH20 solution) perfume 0.7% by weight dye solution (0.1%) 0.5% by weight water 63.0% by weight

Claims (3)

Patentansprüche Ol Flüssiges Waschmittel mit weichmachender Wirkung nach Patent Nr. (Patentanmeldung P 25 29 444.4), enthaltend etwa 7 bis 40 Gew.-% eines C1o-C2o-Alkylpolyglykoläthers und/oder C6-C20-Alkylphenolpolyglykoläthers, etwa 3 bis 15 Gew.-% eines C8-C20-Fettsäurepolyglykoldiesters und etwa 1 bis 7,5 Gew.-% eines Di-C1O-C22-alkyldimethyl- bzw. -äthylammoniumhalogenids sowie gegebenenfalls noch weitere in Waschmitteln übliche Bestandteile auf wäßriger Basis, dadurch gekennzeichnet, daß der C10-C20-Alkylpolyglykoläther und/oder der C6 -C2o-Alkylphenolpolyglykoläther ganz oder teilweise durch ein Polyoxiäthylenpolyoxipropylen-Blockpolymerisat ersetzt ist. Claims Oil Liquid detergent with a softening effect according to patent no. (patent application P 25 29 444.4), containing about 7 to 40% by weight a C1o-C2o-alkyl polyglycol ether and / or C6-C20-alkylphenol polyglycol ether, about 3 to 15% by weight of a C8-C20 fatty acid polyglycol diester; and about 1 to 7.5 % By weight of a di-C1O-C22-alkyldimethyl- or -äthylammoniumhalogenids and optionally still further aqueous-based constituents customary in detergents, characterized in that that the C10-C20-alkyl polyglycol ether and / or the C6 -C20 -alkylphenol polyglycol ether completely or partially replaced by a polyoxyethylene polyoxy propylene block polymer is. 2. Flüssiges Feinwaschmittel nach Anspruch 1, dadurch gekennzeichnet, daß das Polyoxiäthylenpolyoxipropylen-Blockpolymerisat aus Struktureinheiten der allgemeinen Formel HO - (C2H4O)x - (C3H6O)y - (C2H4O)zH, wobei y eine ganze Zahl von 1o bis 40, vorzugsweise 26 bis 30, und x + z eine ganze Zahl von lo bis 60, vorzugsweise 30 bis 40, bedeuten, besteht.2. Liquid mild detergent according to claim 1, characterized in that that the Polyoxiäthylenpolyoxipropylen block polymer from structural units of the general formula HO - (C2H4O) x - (C3H6O) y - (C2H4O) zH, where y is an integer from 10 to 40, preferably 26 to 30, and x + z is an integer from lo to 60, preferably 30 to 40, consists. 3. Flüssiges Feinwaschmittel nach Anspruch 1, dadurch gekennzeichnet, daß das Polyoxiäthylenpolyoxipropylen-Blockpolymerisat aus Struktureinheiten der allgemeinen Formel HO - (C3H6O)n - (C2H4O)m - (C3H6O)nH, wobei m für eine ganze Zahl von 10 bis 50, vorzugsweise 30 bis 40, und n für eie ganze Zahl von lo bis 40, vorzugsweise 20 bis 30,besteht. 3. Liquid mild detergent according to claim 1, characterized in that the polyoxyethylene polyoxy propylene block polymer of structural units of the general formula HO - (C3H6O) n - (C2H4O) m - (C3H6O) nH, where m is an integer from 10 to 50, preferably 30 to 40, and n for an integer from lo to 40, preferably 20 to 30.
DE19762605420 1975-07-02 1976-02-12 Washing and rinsing composition for softening textiles - nonionic surfactant, softening agent and polyglycol difatty acid ester Withdrawn DE2605420A1 (en)

Priority Applications (8)

Application Number Priority Date Filing Date Title
DE19762605420 DE2605420A1 (en) 1976-02-12 1976-02-12 Washing and rinsing composition for softening textiles - nonionic surfactant, softening agent and polyglycol difatty acid ester
SE7604127A SE424647B (en) 1975-07-02 1976-04-08 LIQUID FINE WASHES WITH SOFTY EFFECT
IT22435/76A IT1059193B (en) 1975-07-02 1976-04-16 LIQUID DETERGENTS FOR FINE WASHING
NO761523A NO146436C (en) 1975-07-02 1976-05-04 LIQUID FINE DETERGENT
DK218976A DK144798C (en) 1975-07-02 1976-05-18 LIQUID FINISHING LIQUID
FI761456A FI62681C (en) 1975-07-02 1976-05-24 FLAT-BASED FLOWER BODY MACHINERY WITH TEXTILMJUKGOERANDE VERKAN
PT65249A PT65249B (en) 1975-07-02 1976-06-21 Process of preparation of liquid fine washing agent
ES449540A ES449540A1 (en) 1975-07-02 1976-07-02 Procedure for the preparation of a fine, liquid washing agent. (Machine-translation by Google Translate, not legally binding)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19762605420 DE2605420A1 (en) 1976-02-12 1976-02-12 Washing and rinsing composition for softening textiles - nonionic surfactant, softening agent and polyglycol difatty acid ester

Publications (1)

Publication Number Publication Date
DE2605420A1 true DE2605420A1 (en) 1977-09-01

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Family Applications (1)

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DE19762605420 Withdrawn DE2605420A1 (en) 1975-07-02 1976-02-12 Washing and rinsing composition for softening textiles - nonionic surfactant, softening agent and polyglycol difatty acid ester

Country Status (1)

Country Link
DE (1) DE2605420A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2424316A1 (en) * 1978-04-24 1979-11-23 Henkel Kgaa LIQUID WASHING PRODUCT WITH SOFTENING EFFECT FOR DELICATE ITEMS
EP0368383A2 (en) * 1988-11-09 1990-05-16 Unilever N.V. Fabric conditioner

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2424316A1 (en) * 1978-04-24 1979-11-23 Henkel Kgaa LIQUID WASHING PRODUCT WITH SOFTENING EFFECT FOR DELICATE ITEMS
EP0368383A2 (en) * 1988-11-09 1990-05-16 Unilever N.V. Fabric conditioner
EP0368383A3 (en) * 1988-11-09 1991-07-03 Unilever N.V. Fabric conditioner

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