DE2602603A1 - DETERGENT FORMULATION - Google Patents

Description

CLBA-GEIGY AG, CH-4002 Base!

CSBA-GEIGY

Case 1-9767 / MA 1603 / + GERMANY

Detergent formulation

The present invention is a soap or synthetic detergent formulation which is characterized in that it is an anion-active and / or non-ionic surfactant and 0.5% to 15 Weight .-? O of a sulfited or sulfated, natural or synthetic oil.

609832/0939

Any soap or synthetic detergent formulation can be used as the soap or synthetic detergent formulation in question, which is suitable for washing textile articles. Appropriate formulations are, for example, in Handbook "Domestic and Industrial Chemical Specialties" by L. Chalmers, the chapter under "Synthetic Detergents" being particularly relevant is.

The synthetic detergent formulation contains a non-ionic surfactant or preferably an anion-active one Surfactant. The non-ionic surfactant chimney fall into one of the following subgroups:

a) polyglycol monoethers with long-chain fatty alcohols, for example the condensation product of 5 to 20 moles of ethylene oxide with a C-, g-C-jo fatty alcohol, e.g. B. cetyl-. alcohol;

b) polyglycol monoesters with long-chain fatty acids, for example the condensation products of 5 to 20 moles of ethylene

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oxide with a fatty acid with 12 Ms 18 carbon atoms, z. B. stearic acid;

c) Polyglycol monoethers with alkyl phenols, for example the reaction product of 5 to 20 moles of ethylene oxide with a Cg_ ₁₂ alkyl phenol, e.g. B. nonylphenol;

d) Ν, Ν-polyethoxylated long-chain fatty amines, for example the reaction product of 5 to 50 moles of ethylene oxide with a C ₁₂ -C, o-fatty amine, e.g. B. coconut amine and tallow amine; as

e) Ν, Ν-polyethoxylated long-chain fatty acid amides, for example the reaction product of 5 to 50 moles of ethylene oxide with hydrogenated tallow amide.

The alkali metal or ammonium salts of fatty acids or fatty sulfates are particularly used as anion-active surfactants or sulfonates, particularly those having 8 to 22 carbon atoms, are preferred. For example, alkali metal stearates are suitable, Alkali metal alkyl sulfates, e.g. sodium dodecyl sulfate, Alkali metal alkyl sulfonates,. z. B. potassium dodecyl sulfonate, alkali metal alkaryl sulfonates, e.g. sodium dodecylbenzenesulfonate, Fatty acid sarcosinates, sulfonated alkyl esters of long-chain fatty acids and alkyl sulfosuccinates, their Alkyl parts each preferably contain 8 to 22 carbon atoms.

The surfactant content in the synthetic detergent formulation is expediently up to 40% by weight, preferably

10 to 30 % by weight, based on the total weight of the formulation.

To further, usually in synthetic washing

603832 ^3/0939

^ - 2S02603

Ingredients contained in agent formulations include builders, bleaches, soil-dispersing agents, optical brighteners, enzymes and weak perfumes.

One or more water-soluble alkali metal salts are suitable as building materials, so-called "builders", z. B. carbonates, borates, phosphates, polyphosphates, bicarbonates and silicates. Examples of such salts are sodium carbonate, Sodium tetraborate, sodium pyrophosphate, potassium polyphosphate, Sodium bicarbonate and sodium silicate, water-soluble, chelating agents are also suitable as building materials Alkali metal or ammonium salts, ζ. B, sodium, potassium and ammonium ethylenediamine tetraacetate, Preferred bleaching agents include alkali metal percarbonates and persulfates, and especially alkali metal perborates. As a dirt-dispersing agent Carboxymethyl cellulose is particularly suitable as a brightener, for example the following types Consideration: triazinyl-diaminostilbenedisulfonic acids, aminocoumarins, pyrazolines, imidazolones, benzidinesulfon-bisoxazoles, Distyrylbiphenyls, dibenzimidazoles and benzoxazoles and their derivatives. Appropriate enzymes are those which predominantly contain a protease produced by a spore-forming Bacillus subtilis bacterium. As a perfume those based on citrus fruits, cologne or spruce needle oil are particularly suitable.

The sulfited or sulfated natural oil content of the detergent formulations according to the invention is preferably based on sperm oil or fish oil. Synthetic OeI

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preferably has a paraffinic hydrocarbon base.

Sperm oil, which mainly consists of the higher fatty acid esters of monovalent long-chain alcohols, is particularly suitable as a natural oil. It differs from other marine and vegetable oils in that it is a wax that is liquid at room temperature.

The following analysis is typical for the fatty acid and fatty alcohol components of a sperm oil (Physeter macrocephalus):

Saturated

Saturated

Monounsaturated Saturated

Monounsaturated Saturated

Monounsaturated Saturated

Monounsaturated doubly unsaturated monounsaturated doubly unsaturated

The investigations on top oil result in a mixture of about 74% wax esters with 26% triglycerides (of which about 30% are fully saturated) and a clear tendency towards that the fully saturated wax esters are preferably derived from the acids

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fat
acids fat
alcohols 0.4% - 2.0% - 0.7% - 5.4% 3.6% 4.7% 1.2% 9.5% 27.0% 18.3% 7.2% 4.5% 6.0% 37.2% 48.2% 1.5% - 12.8% 2.5% 3.0% 4.3%

and form lower molecular weights with alcohols than with those of higher molecular weight. Cetyl myristate and laurate would therefore represent the main components of whale rat rather than cetyl palmitate.

Commercially available sperm oil is usually a mixture of head and lard oils, consisting essentially of esters of C, Q-Cpp fatty acids with monohydric C, Q-Cpp alcohols. The above figures apply, for example, to such a mixture. The main differences between head and Bacon oils are the following:

Head of bacon

Fatty acids ^C 10 - 6 - 3.5 - Saturated ^C 12 609832/0939 16.0 1.0 ^C 14 14.0 5.0 ^C 16 8.0 6.5 ^C 18 2.0 - ^C 12 4.0 - Unsaturated ^C 14 14.0 4.0 ^C 16 15.0 26.5 ^C 18 17.0 37.0 ^C 20 6.5 19.0 C ₂₂ - 1.0 Alcohols ^C 16 50 10 Saturated ^C 18 10 5

Unsaturated

10 10 25th 65 5 10

Suitable fish oils are e.g. herring oil, cod oil, cod liver oil, shark oil, sardine oil, mackerel oil and Bxinfish oil. The composition of these fish oils is Although they differ, they are generally composed as a percentage of triglycerides of the following acids: where herring oil is given as an example:

Saturated Acids - Generally directs Acids amount herring «14 2-8 of triglycerides of the following 3.5 - 8.0 «16 Acids 10-19 Saturated 12.0 «18 - 0.1 - 5 «14 1.0 Unsaturated Generally «16 herring ^C 14 0.1 - 2 «18 0.5 ^C 16 4 - 16 6.5 ^C 18 16-38 21.0 ^C 20 Cod liver oil 15-30 28.0 C ₂₂ general .10 - 27 23.0 is similar, however, in - Acids from: 6th 6.5 - 11 1

8098? 2? 0939

Unsaturated acids amount %

^C 14 O - 0.5 ^C 16 10-20 ^C 18 25 - 31 ^C 20 25-31.5 ^C 22 10-20

The natural or synthetic oils can be Sulphating or sulphiting by methods known per se. For example, the oils can be treated with a Sulfur, especially alkali metal salt of an oxy acid sulphite with an alkali metal salt of sulphurous acid, for example sodium bisulphite or sodium metabisulphite.

Chlorinated paraffin sulfonic acids of C - ^ - C ^ Q paraffin hydrocarbons represent a preferred group of sulfated synthetic oils.

These sulfonic acids can be according to DT-OS 2 118 363 by sulfoxidation of up to 25 percent by weight of branched saturated paraffin hydrocarbons containing saturated Cj ^ -C ^ Q paraffin hydrocarbons with sulfur dioxide and oxygen, air or other oxygen-containing gases, until the sulfonic acid content 4 to 34 percent by weight based on the reaction mixture is, with, optionally after partial separation of the unreacted paraffinic hydrocarbons, the following Chlorination of the oxygenation mixture with chlorine in Represent the presence of light at 20 to 60 ° C.

The sulfoxidation of the C ^ -C ^ Q paraffin hydrocarbons

609832/0939

substances are produced in a known manner by reacting the paraffin hydrocarbons with sulfur dioxide and oxygen or oxygen-containing gases in the presence of photoactive radiation and / or catalysts; Sulphoxidation in the presence of nitric acid, nitrates, nitrites or nitrogen oxides, as for example in German patent specification 1 257 136 and British Patent 1,171,048 is particularly preferred.

In the manufacturing process for the surface active As a lubricant, it is essential that the sulfoxidation proceeds only to the extent that the sulfoxidation product does not turn dark entry. Darkening of the reaction mixture is generally avoided if up to a sulfonic acid content from 4 to 40, preferably 12 to 34 percent by weight on the weight of the mixture, is sulfoxidized. If the sulfoxidation does not occur in time before a If the reaction product is darkened, the result is paraffin sulfonic acids or paraffin + sulfonic acid paraffin mixtures, which can no longer be chlorinated by light chlorination.

The chlorination of the sulfoxydation mixture can follow directly on sulfoxidation «The chlorination is carried out under the conditions customary for light chlorination, d, h. at temperatures of 20 to 60 °, preferably 30 to 50 C, carried out, irradiating as long as chlorine gas is introduced into the sulfoxidation mixture until the desired chlorine content of 16 to 28%, preferably 18 to 25% »

_ 9 _ 609832/0939

is reached.

In many cases it proves to be advantageous to add some of the unreacted paraffinic hydrocarbon before the chlorination to separate. The separation is preferably carried out by adding water and / or lower alcohols such as methanol or ethanol to the reaction mixture. This addition causes a separation of the sulfo-oxidation mixture into a phase containing the unreacted paraffinic hydrocarbons contains, and a phase which contains the paraffin sulfonic acids. The one containing the sulfonic acids Phase is separated off, optionally subjected to a distillation to remove water and alcohol, and then chlorinated as described above.

The sulfonic acids produced in this way consist of one Fully synthetic product, which contains straight-chain paraffin and chlorinated paraffin sulfonates with a high proportion of neutral oil contains. A typical sulfonic acid has the following composition: 10% paraffin, 65% chlorinated paraffin (about 45% chlorine containing), 20% sodium salt of sulfonated paraffin / Chlorinated paraffins and 5% water.

Specific examples of sulfated or sulfited, natural or synthetic oils that can be used in the detergent compositions of the invention include commercial products:
Naturally

A) sulfited sperm oil

B) sulfited stabilized fish oil

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C) sulfited fish oil

D) sulfated fish oil with ampholyte emulsifier

E) sulfated fish oil

F) mixed sulfited oils

G) Mixture of sulfited fish oil and lecithin

As natural oils, (F), (D) and (G) are preferred. Synthetic

H) sulfated methyl oleate

I) sulfated ethoxylated trioleate with a linear Alkylaryl derivative

K) mixture of sulfonated chlorinated paraffin oil, sulfonated Paraffin and paraffin oil

L) Mixture of straight-chain paraffin / chloroparaffin sulfonate and neutral oil

As synthetic oils (L) and (I) are preferred,

The present invention also relates to a method for washing and softening textile articles, which is characterized in that the article in an aqueous soap or according to the invention defined above Treated bath containing detergent formulation.

Preferably, the concentration of the soap or Waschmittelforaulierung is in the range of 0.5 to 20 g / l, particularly preferably in the range of 2 to 10 g / l · Gesaiitbad the desired treatment temperature is zwectenassig in the range of 55 ^e to 98 ° C.

liach a modification of the invention Procedure you can use the Wasehmittelgrandstof f

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• / U2602803

and the oil softener separately from the textile article in FIG Give washing liquor.

All textile fabrics, for example ceHulosehaTugt Tissue,. Polyamide and acrylic fiber fabrics can be used in the methods according to the invention can be used.

Textile articles washed by the process of the invention show up clearly after rinsing and drying softer feel, although the softener is applied during the main wash stage. In addition to this softening effect In the main wash, textile articles washed according to the method according to the invention have further desirable ones Properties such as easy treatment, improved crease resistance as well as easy ironing. Compared to the more common treatments, the plasticizers being are to be added intentionally during the last rinse, the inventive combined ¥ ash and softening process obviously more convenient.

In the following examples, the parts and percentages listed are, unless otherwise stated, Parts and percentages by weight.

Examples 1 to 5

The following sulphated or sulphited natural oils are incorporated into washing liquors in such a way that they result in 0.375 % by weight of active ingredient based on the weight of the dry washing powder:

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Aktivbe
component Ions
Type Solid
salary A. anion active 80% G anion active 37% F. anion-active 60% multiple.loaded 100% E. anion-active 63% Guar ammonium
product cation-active 79%

As a control, a wash liquor contains only one anion-active detergent with the following composition:

20% dodecylbenzenesulfonate 35% sodium tripolyphosphate 20% sodium perborate

10% sodium silicate 2% carboxymethyl cellulose

13% sodium sulfate

Cotton, nylon, polyacrylonitrile and wool yarns are each separated in the relevant washing liquor washed under the following conditions:

Washing time:

Water temperature:

Detergent concentration:

Liquor ratio:

Number of washes:

Flushing:

15 minutes 6O ⁰ C.

5 g / l 20: 1

5
running cold water

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The amount of active ingredient added is like

follows:

Aktivbe
component Weight of the product based on
the weight of the detergent A. 0.469% G 1.014% F. 0.625% D. 0.375% . E. 0.595% Quaternary ammonium
product 0.475%

At the end of the fifth wash cycle, the softness of the washed fabrics is reduced to five Persons using the "pairwise comparison" method (International Dyer, August 19, 1966, p. 266, Statistical Methods in the Finishing Industries in the processing industry]). In addition, the degree of of washed fabrics compared to a control washed in detergent alone.

- 14 -

609832/0939

cn ο co oo co ro ■ "%, ο co co

■ RESULTS - SOFTENING , COTTON

Active
component Quaternary
Ammonium-
uroduct A. 11 1 G 11 1 F. 1 0 D. 3 Ξ 3 laundry detergent
alone 1 Lines
total _ Lines
"minus
-Columns-.. Quartares
Ammonium-
product mi β 111 3 3 11 6th 5 -32 A. XIl I 1111 6th 1 0 111 10 111 0 1111 6th 16 1 G 11111 10 1111 6th Hill 10 111 1 1111 6th 41 39 P. 11111 10 11 1 11 1 1111 6th 11111 1 1111 3 32 20th D. 11, 1 11 · 1 1 0 1 0 3 11 6th 111 0 6th -24 E. 11111 10 111 311 0 2 12th 111 1 13th 1 21 8th laundry detergent
ft "11. A.IM 37 15th Ii 30th 1111 22nd .10 -19 Columns-
suinme

NYLON

α to,

to tj ro -ν ι ο co

Aktivbe
component Quarters =
ammonium
product A ' G F. D. E. Washing center
alone .Line-
total Lines
minus
columns Quartares
ammonium
product 111 3 11 1 1 0 VJl "35 A. 11 1 ^^ Π. 1 11 1 1111 6 111 3 1111 6 18th 8th G Hill 10 St. 3 ^^ St. 3 Hill 10 Hill 6 St. 3 35 32 F. Hill 10 111 3 11 1 ^^ 111 3 111 3 Hill 10 30th 24 D. St. 3 1 0 H 1 1111 6 11 1 11 -12 E ■ Hill 10 Π 1 1 0 11 1 1 0 ^^ 1 0 12th -12 Washing belts
alone 1111 6 1 0 H 1 111 3 1111 6 16 - 4th Columns-
total 40 10 3 6th 23 24 20th

Polyacrylonitrile such as OrIon

Aktiybe-
component Quaternary
ammonium
product O A. 6th G 1 O F. 3 D. Ll 1 E. 1 O Washing with
tel alone 3 Lines
total Lines
minus
Ρρλΐtpn Quaternary
Ammonium-
product 6th 1111 11 1 6th L. O 11111 10 111 10 10 -16 A. 1 10 ■ 5 111 ' 11111 10 11 1 Hill 3 24 8th G 1111 3 111 • ι 1 O 1111 1 111 3 11 1 111 6th 29 26th F. Hill 6th 11 e ^^ - ^ 3 1 O 1111 O 21 8th D. 111 1 1111 11 1 11 O 1111 6th 1 3 10 -16 E. 1111 26th 11 1 111 13th 1111 6th 11 1 111 19th 6th Detergents
.alone 11 16
ι 3 1 26th 13th 25th 9 · -16 Columns-·
total

σ? ο co

WOOL

Aktivbe
component Quartars s
ammonium
product A. G F. D. E. laundry detergent
alone Lines
total I.
■ Lines Uraternary
Ammonium-
product Hill 10 1111 6 111 3 1 0 Hill IC St. 3 32 24 A. ^^ 11 1 1 0 11 1 2 -40 G 1 '0 Hill 10. 11 1 11 1 111 3 1111 6 21 8th F. 11 1 111 ■ 3 111 3 ^^ 1 0 St. 3 111 3 13th 0 D. 1111 6 1111 6 111 3 1111 6 ^^ 1111 6 Hill 10 37 36 E. 1 Ό Hill 10 11 1 11 1 1 0 ^^ 111 3 15th - 8th laundry detergent 11 1 111 3 1 0 11 1 11 1 6th -20 Columns- ·
total 8th 42 13th 13th 1 23 26th

SEQUENCE OF SOFTENING EFFECTIVENESS

Aktivbe
component COTTON Soft bat
Degree NYLON tfeijiheits-
Degree Polyacrylic
nitrile VfeKÜieits-
grari WOOL Wetöibaits- A. 4th Rjnk-
be 3 Ftirk-
te 2 = te 7th G 1 1 8th • 1 8th 1 -40 3 F. 39 2 32 2 26th 2 = 8th 4th D. 20th 6th 24 5 = 8th 5 = O 1 E. -24 3 -12 5 = -16 4th 36 5 Quaternary
Ammonium-
product 8th 7th -12 7th 6th 5 = -8th 2 Detergents]
alone ■ 32 5 -35 4th -16 5 = 24 6th -12 - 4th -16 -20

.Active component Order of plasticizer
effect as an average
of all fibers G
F.
A '
D.
E "
Detergent alone
Guartarees
Ammonium product 1
2
3
4 =
4 =
6th
7th

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Assessment of the degree of whiteness

With the exception of the active ingredients G and F, the fatty liquor incorporated in the washing baths has the effect of a slight reduction in the degree of whiteness of the washed tree fabric. In the case of nylon, polyacrylonitrile and wool, there is no adverse effect on the degree of whiteness. Examples 6-11

Cotton, nylon, polyacrylonitrile or wool yarns are washed in washing liquors, the 5% i 10 #> or 15 wt .-% G or F, based on detergent, which is the same as the detergent used in Examples 1 to 5 is included. As a control, corresponding samples are washed in detergent alone, without any plasticizer content. The washing conditions are as follows:

Washing time: 15 minutes

Washing temperature: 60 C

Liquor ratio: 40: 1

Detergent concentration: 5 g / l

Rinse: flowing cold

water

Number of consecutive washes: 5

After completing the five washes, the patterns will be according to the method of "pairwise comparison" (International Dyer, ibid.) For softness.

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CD O CO CO

Results; COTTON

Active
component G 11 1 G 3 G 6th F. 11 1 F. 3 F. 1 0 tfaschmitbel
alone 1 ZeDen-
total Lines
minus
'Columns 596 G 1 0 111 1111 .3 111 1 11 3 14th -4 1090 G 111 3 ^ 1 111 11 1 11 1 1 0 111 1 8th -12 1590 G 11 1 11 6th 3 11 6th 1 0 11 10 4th -24 5% F 11111 10 1111 3 111 3 1 0 1111 11111 3 28 16 10% F 111 3 111 . 6th 111 10 11111 10 6th 11 1 111 3 10 -8th 1596 F. 18th 1111 1 111.11 3 1 0 1111 1 1 111 45 44 laundry detergent 11 20th 111 28 12th 11 18th 21 9 -12 'Columns-
total 0

NYLON

co co co

Active
stan & part G 0 G 6th G 11 1 F. 3 F. 6th F. 3 laundry detergent
alone 3 Evidence
sunme Lines minus
columns 5% G ^ " 3 1111 111 0 1111 111 0 111 22nd 16 10% G 1 1 10 1 6th 3 1 6th 0 -48 15% G 111 0 11111 6th 1 0 1111 111 3 3 1111 6th 28 16 5% F 11 1 mi 10 11 1 1 111 111 3 1111 6th 19th 8th 10% F 1 1 inn • 6 lllll 10 11 1 1 111 1111 6th 21 8th 15% F 11 6th Nile 10 1 0 11 0 11 0 0 1111 25th 16 laundry detergent
alone · 11 Lllll 48 12th 1 11 1 13th 1 . 9 27 11 -16 columns
total 0

cn ο rsi cn ο

Polyacrylonitrile such as Orion

CD O to ca ro

O CO

CD

Active
component G 3 G 11 1 G L. O F. 1 O F. "Z F. "2 laundry detergent
alone 2 2sü.-
total Lines
minus
columns 5% G , 6 Ll 1 1 O 111 1 111 10 111 C. 10 -8th 1090 G 111 6th 111 3 11 Hill ■ z 11 16 O 15% G 1111 1 1111 6th Ulli 10 3 111 6th 1 12th -16 5% F 1111 1 111 3 11111 10 11 1 111 1111 1 111 1 34 32 ' 10% F 11 1 11 1 1 O 3 11 16 -4 15% F 11 18th 111 3 1111 6th 11 1 111 10 ■ 2
J 11 8th 6th -20 laundry detergent
,alone 11 16 28 2 Hill 20th 111 26th 24 16 Columns-
total 0

8th" ro

CD

co co u>

WOOL G 111 0 G . 1 G β F. 6th F. 10 F. 6th Washing agent
alone 3 , Evidence
sunme Lines
minus
.Columns Aktivbe
component 1 0 111 1 1111 1 1111 3 Hill 1 1111 0 111 3 34 30th 5% G 1 • st 11 111 β mLiJL 3 1 ,, 3 111 10 11 - 4th 10% G 0 11 1 JLaLi kl * iJL 1 111 0 6th 23 13th 15% G i 1 11 1 11 1 3 11 1 1 1111 1 9 -15 5% P. 11 4th 111 IS 1 111 β 3 11 11 6th 9 -12 10% F Uli 11 JLm «bL (wu . 0 111 3 0 1111 22nd 12th 15% F 11 10 1 24 111 21 1 10 29 5 -24 laundry detergent
alone • 0 Columns"

Order of plasticizer effectiveness

co co ^

^w previous year ₁

Ca) (O ->. O CO to co

Active
component COTTON Soft
neatly
Degree NYLON Soft
neatly
Degree Polyacrylic
nitrile Soft
neatly
Degree WOOL Soft
neatly
Motorcycle 5% F punk
te 2 punk
te 4 = punk
te 1 punk
te 6th 10% F 16 4th 8th 4 = 32 4th -15 5 15% F -8th 1 8th 1 = -4 7th -12 3 5% G 44 3 16 -20 5 · 12th 1 . 10% G -4 5 = 16 7th -8th 3 30th 4th 15% G -12 7th -48 1 = O 6th -4 2 laundry detergent
alone -24 5 = 16 6th -16 2 13th 7th -12 -16 16 -24

fr

ro σ> ο rs) cd ο

Active ingredients il Order of plasticizers
effect as an average
of all fibers 5% G 1 15% F 2 5% F 3 15% G 4th 10% F 5 10% G 6th laundry detergent
alone 7th

Examples 12 Ms 14

The following are sulfated synthetic oils so incorporated into washing liquors that they contain 1.68% active ingredient based on the weight of the dry washing powder result:

Active ingredient Ion type Solids content I.
H anion-active
anion active 71%
79%

For the purpose of a direct comparison of this synthetic oil with a natural oil, a further 1.68% (G) containing wash liquor set.

As a control, a wash liquor is used which only contains the anion-active detergent and its composition is given in Examples 1 to 5 contains.

Strands of cotton, nylon, polyacrylonitrile and wool yarn are included in the relevant washing liquors washed under the following conditions:

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609832/0939

Washing time: 15 minutes

Temperature: 6O ⁰ G

Liquor ratio: 40: 1

Detergent concentration: 5 g / l

Number of washes: 5

Rinse: "running cold water

The amount of active ingredient added is as follows:

G $ 5.0 based on the weight of the

Detergent

I 2 ₉ h% based on the weight of the

Detergent

H $ 2.1 based on the weight of the

Detergent

The washed swatches are dried and conditioned for 24 hours before the softness assessment takes place after pairwise comparisons by a committee of five people.

The results are summarized in the following tables

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Results; COTTON

Aktivbe
component G 11111 10 I. 11 O H 1 0 O Ropes with
lus columns G. 1111 6th 111 3 13th -16 I. 16 1 ^^ ^ " 7th 12th H 1 3 20th 4th

NYLON

Active
component G IO I. 0 H 1 C. 0 Ropes with
QXis columns G. 6th 11111 IC 20th -16 I. inn 16 ^^ O ^^ 6th 20th H 1111 O IC 26th -4

Polyacrylonitrile

Aktivbe
component • G 11 1 I. 111 3 H 111 3 6th file with
ius SOaLten G 11 1 1111 6th 7th 4th I. 2 1 0 , / - ^ 1 4th H 3 9 14th -8th

- 28 -

609832/0939

WOOL

Active stock
part G 1 O I. IO H 6th 16 Lines mi
nus columns G O 11111 ~ - ~ 1111 O O 16 I. 6th 1 6th -16 H 1111 16 ^^ 6th 22nd O

Order of plasticizer effectiveness

Active
Standing part COTTON Soft
neatly
Degree NYLON Soft
neatly
Degree Polyacrylic
nitrile Soft
neatly
Degree WOOL Soft
neatly
Degree I. punk
te 1 Renk
te 1 punk
te η _ punk
te 3 H 12th 2 20th 2 4th 3 -16 2 G 4th 3 - 4th 3 -8th 1 = O 1 -16 -16 4th 16

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609832/0939

3ο

Examples 15-17

The following are sulfated synthetic oils so incorporated into washing liquors that they contain 1.68% active ingredient based on the weight of the dry washing powder result:

Active ingredient Ion type Solids content K
L. anion active
anion active 65%
89%

For the purpose of a direct comparison of this synthetic oil with a natural oil, a further, 1.68% G based on the weight of the detergent-containing wash liquor.

A wash liquor is used as a control, which is only the anion-active detergent, its composition is given in Examplefei 1 to 5, contains.

Cotton, nylon, polyacrylonitrile and wool yarns are used in the relevant washing liquors under the following Washed conditions:

Washing time: 15 minutes Temperature: 60 ° C Liquor ratio: 40: 1 Detergent concentrate
tion: 5 g / l. Number of washes: 5 Flushing: running cold water

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The amount of active ingredient added is as follows:

G 5.0% based on the weight of the

Detergent

K 2.6% based on the weight of the

Detergent

L 2.9% based on the weight of the

Detergent

The samples are dried, conditioned for 24 hours and then according to the "method of pairwise comparisons" judged for softness.

The results are given in the following tables.

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Results; COTTON

Active ingredient G IO K O L. 10 ZeDen-
sunme Zsüßtimixis
Columns. G O 1 11111 1 10 O K 11111 10 6th 11 11 5 L. 1 1111 6th 11 6th -5 Column total 27 O

NYLON

Active component G 11 G 1 1 ■ K 6th L. L. 1 3 Zeüai-
total columns G 111 Hill 3 1111 111 1 O 9 VJl K 4th ID 1 1 -15 L. • Hill 16 3 13th 10 Column total 23 0 Polyacrylonitrile Active component O K X) O total Cells nflnus
columns G IO 11111 O 10 0 K 10 X 0 -20 L. Hill 20th O 20th 20th Column total 30th 0

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609832/0939

GREAT

Order of plasticizer effectiveness

Assets
part G 3 κ- 3 L. 11 1 Zsflai-
surome Zeflm mims
columns G 6th LIl 11 1 4th VJl K 111 9 6th 4th -5 L. 1111 LlIl 9 2 12th 10 Column total 20th 0

Aktivbe
component COTTON Soft
neatly
Degree NYLON Soft
neatly
Degree Polyacrylic
nitrile • Soft
neatly
Degree WOOL - Soft
neatly
Degree G Eürk- 2 punk
te 2 punk
te 2 punk
te 2 = K O 1 9 3 O 3 -5 2 = L. VJl Previous year -15 1 -20 1 -5 1 v! n IO 20th 10

- 33 §09832 / 0939

Claims (1)

Patent claims: 14 soap or synthetic ash formulation, characterized in that it is an anion-active and / or non-ionic tanside and 0.556 to 15% by weight of a sulfited one or contains sulfated, natural or synthetic oils. 2. Formulation according to claim 1, characterized in that the surfactant is an alkali metal or ammonium salt Fatty acid or a fatty sulfate or sulfonate. 3 Formulation according to Claim 2, characterized in that that the surfactant is an alkali metal stearate, an alkali metal alkyl sulfate, an alkali metal alkyl sulfonate, an alkali metal alkaryl sulfonate, a fatty acid sarcosinate, a sulfonated alkyl ester a long chain fatty acid or an alkyl sulfosuccinate. 4. Formulation according to one of claims 1 to 3, characterized in that the surfactant content in the synthetic detergent is 10% to 30 % by weight based on the total weight of the formulation. 5. Formulation according to one of claims 1 to 4, characterized in that the formulation additionally has one Builder, bleach, soil-dispersing agent, optical brightener, enzyme, or weak perfume contains. 6. Formulation according to one of claims 1 to 5, characterized in that the sulfited or sulfated natural oil based on sperm oil or fish oil. 7. Formulation according to claim 6, characterized in that that the sperm oil is a mixture of head and bacon oils, . - 34 -§09832 / 0933 "which essentially consists of esters of C - ,, γ-with monohydric C-jQ-Cpp alcohols _Des then _# 8. Formulation according to claim 6, characterized in that the fish oil is henna oil, cod, cod liver or HaHLschträn or sardine, mackerel or tuna oil, 9. Formulation according to claim 8, characterized in that the fish oil is made from triglycerides of a mixture of saturated and unsaturated 0-, If ^ ^is Cpp-carboxylic acids is composed. 10. Formulation according to one of claims 1 to 5 »thereby characterized in that the sulfited or sulfated synthetic oil is based on a paraffin hydrocarbon. 11. Formulation according to claim 10, characterized in that the sulfated synthetic oil is a chloroparaffin sulfonic acid from C ^ -C ^ Q paraffinic hydrocarbons. 12. Formulation according to claim 11, characterized in that the chlorinated paraffin sulfonic acid is a straight-chain paraffin and chlorinated paraffin f insulf onate with a high content of neutral oil. 13. Formulation according to claim 12, characterized in that the chloroparaffin sulfonic acid is a 10 $ έ paraffin, 655ε chlorinated paraffin, 2056 of the sodium salt of sulfonated! Paraffin / Chlorparaf fin and 3% water containing product is. 14. A method for washing and softening a textile article, characterized in that the article is treated in an aqueous, a soap or detergent formulation according to 'claim 1 containing bath. - 35 - 009832/0939 Process according to Claim 14, characterized in that the concentration of the soap or detergent formulation is in the range from 0.5 to 20 g / l total bath. 16. The method according to claim 14, characterized in that the concentration of the soap or detergent formulation is in the range from 2 to 10 g / l total bath. 17 «A method according to any one of claims 14 to 16, characterized in that the treatment temperature is in the range of 55 ° to 98 ⁰ C. 18. The method according to any one of claims 14 to 17, characterized in that the textile article is a cellulose-containing Article or a polyamide or polyacrylonitrile article. - 36 -. 609832/093 $