DE2540069C2 - Transparentes Papier und Verfahren zu seiner Herstellung - Google Patents
Transparentes Papier und Verfahren zu seiner HerstellungInfo
- Publication number
- DE2540069C2 DE2540069C2 DE2540069A DE2540069A DE2540069C2 DE 2540069 C2 DE2540069 C2 DE 2540069C2 DE 2540069 A DE2540069 A DE 2540069A DE 2540069 A DE2540069 A DE 2540069A DE 2540069 C2 DE2540069 C2 DE 2540069C2
- Authority
- DE
- Germany
- Prior art keywords
- paper
- weight
- pva
- percent
- copolymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title description 30
- 238000004519 manufacturing process Methods 0.000 title description 20
- 230000008569 process Effects 0.000 title description 12
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 65
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 65
- 229920001577 copolymer Polymers 0.000 claims description 44
- 239000000835 fiber Substances 0.000 claims description 33
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 24
- 229920002959 polymer blend Polymers 0.000 claims description 23
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 21
- 238000003825 pressing Methods 0.000 claims description 4
- 239000000123 paper Substances 0.000 description 193
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 35
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 32
- 238000006116 polymerization reaction Methods 0.000 description 20
- 229920001131 Pulp (paper) Polymers 0.000 description 19
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 18
- 229920000578 graft copolymer Polymers 0.000 description 16
- 238000000227 grinding Methods 0.000 description 14
- 239000002655 kraft paper Substances 0.000 description 14
- 210000001724 microfibril Anatomy 0.000 description 14
- 239000000203 mixture Substances 0.000 description 14
- 239000000243 solution Substances 0.000 description 13
- 229920000642 polymer Polymers 0.000 description 11
- 239000011248 coating agent Substances 0.000 description 10
- 238000000576 coating method Methods 0.000 description 9
- 239000003292 glue Substances 0.000 description 9
- 239000011121 hardwood Substances 0.000 description 8
- 238000010438 heat treatment Methods 0.000 description 8
- 239000000976 ink Substances 0.000 description 8
- 238000009987 spinning Methods 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 7
- 230000018044 dehydration Effects 0.000 description 7
- 238000006297 dehydration reaction Methods 0.000 description 7
- JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 7
- 239000011122 softwood Substances 0.000 description 7
- 239000000454 talc Substances 0.000 description 7
- 229910052623 talc Inorganic materials 0.000 description 7
- 238000002166 wet spinning Methods 0.000 description 7
- 238000009736 wetting Methods 0.000 description 7
- 229920002544 Olefin fiber Polymers 0.000 description 6
- 239000003054 catalyst Substances 0.000 description 6
- 239000004767 olefin fiber Substances 0.000 description 6
- 230000000704 physical effect Effects 0.000 description 6
- 229920005989 resin Polymers 0.000 description 6
- 239000011347 resin Substances 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 239000006227 byproduct Substances 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 230000007423 decrease Effects 0.000 description 5
- 239000002657 fibrous material Substances 0.000 description 5
- 238000003801 milling Methods 0.000 description 5
- 150000003254 radicals Chemical group 0.000 description 5
- 229920002472 Starch Polymers 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- 229920002678 cellulose Polymers 0.000 description 4
- 239000001913 cellulose Substances 0.000 description 4
- 239000000470 constituent Substances 0.000 description 4
- 238000007645 offset printing Methods 0.000 description 4
- 229920002239 polyacrylonitrile Polymers 0.000 description 4
- 238000007639 printing Methods 0.000 description 4
- 239000002002 slurry Substances 0.000 description 4
- 239000008107 starch Substances 0.000 description 4
- 235000019698 starch Nutrition 0.000 description 4
- 239000000654 additive Substances 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 3
- 239000002216 antistatic agent Substances 0.000 description 3
- 239000007795 chemical reaction product Substances 0.000 description 3
- 238000007334 copolymerization reaction Methods 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 239000011086 glassine Substances 0.000 description 3
- 230000002209 hydrophobic effect Effects 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 238000010558 suspension polymerization method Methods 0.000 description 3
- 229920000742 Cotton Polymers 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000012298 atmosphere Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000012662 bulk polymerization Methods 0.000 description 2
- 206010061592 cardiac fibrillation Diseases 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 230000002600 fibrillogenic effect Effects 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 230000036571 hydration Effects 0.000 description 2
- 238000006703 hydration reaction Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000001254 oxidized starch Substances 0.000 description 2
- 235000013808 oxidized starch Nutrition 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- -1 polyethylene Polymers 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- 238000004513 sizing Methods 0.000 description 2
- 238000010557 suspension polymerization reaction Methods 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- YJLUBHOZZTYQIP-UHFFFAOYSA-N 2-[5-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]-1,3,4-oxadiazol-2-yl]-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethanone Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C1=NN=C(O1)CC(=O)N1CC2=C(CC1)NN=N2 YJLUBHOZZTYQIP-UHFFFAOYSA-N 0.000 description 1
- 102100039179 Ankyrin repeat domain-containing protein 46 Human genes 0.000 description 1
- 101710189046 Ankyrin repeat domain-containing protein 46 Proteins 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- 241000251730 Chondrichthyes Species 0.000 description 1
- 241000195493 Cryptophyta Species 0.000 description 1
- 240000006927 Foeniculum vulgare Species 0.000 description 1
- 235000004204 Foeniculum vulgare Nutrition 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- IIDJRNMFWXDHID-UHFFFAOYSA-N Risedronic acid Chemical compound OP(=O)(O)C(P(O)(O)=O)(O)CC1=CC=CN=C1 IIDJRNMFWXDHID-UHFFFAOYSA-N 0.000 description 1
- 241000519995 Stachys sylvatica Species 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 230000005587 bubbling Effects 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000000578 dry spinning Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 239000012456 homogeneous solution Substances 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000007591 painting process Methods 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000001226 reprecipitation Methods 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 235000015424 sodium Nutrition 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 210000001550 testis Anatomy 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H5/00—Special paper or cardboard not otherwise provided for
- D21H5/12—Special paper or cardboard not otherwise provided for characterised by the use of special fibrous materials
- D21H5/20—Special paper or cardboard not otherwise provided for characterised by the use of special fibrous materials of organic non-cellulosic fibres too short for spinning, with or without cellulose fibres
- D21H5/205—Special paper or cardboard not otherwise provided for characterised by the use of special fibrous materials of organic non-cellulosic fibres too short for spinning, with or without cellulose fibres acrylic fibres
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H13/00—Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
- D21H13/10—Organic non-cellulose fibres
- D21H13/12—Organic non-cellulose fibres from macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H13/18—Polymers of unsaturated acids or derivatives thereof, e.g. polyacrylonitriles
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/26—Agents rendering paper transparent or translucent
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paper (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP49103702A JPS597839B2 (ja) | 1974-09-09 | 1974-09-09 | 透明化紙 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE2540069A1 DE2540069A1 (de) | 1976-03-25 |
| DE2540069C2 true DE2540069C2 (de) | 1984-07-05 |
Family
ID=14361075
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2540069A Expired DE2540069C2 (de) | 1974-09-09 | 1975-09-09 | Transparentes Papier und Verfahren zu seiner Herstellung |
Country Status (9)
| Country | Link |
|---|---|
| JP (1) | JPS597839B2 (enrdf_load_stackoverflow) |
| BE (1) | BE833164A (enrdf_load_stackoverflow) |
| CA (1) | CA1057911A (enrdf_load_stackoverflow) |
| DE (1) | DE2540069C2 (enrdf_load_stackoverflow) |
| FR (1) | FR2283991A1 (enrdf_load_stackoverflow) |
| GB (1) | GB1522854A (enrdf_load_stackoverflow) |
| IT (1) | IT1042387B (enrdf_load_stackoverflow) |
| NL (1) | NL7510609A (enrdf_load_stackoverflow) |
| SE (1) | SE7509849L (enrdf_load_stackoverflow) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10002576A1 (de) * | 1999-09-21 | 2001-03-22 | Heinr Aug Schoeller Soehne Gmb | Verfahren zur Herstellung von Papier sowie entsprechendes Papier |
| DE102011087742A1 (de) * | 2011-12-05 | 2013-06-06 | Papierfabrik Schoellershammer Heinr. Aug. Schoeller Söhne GmbH & Co. KG | Transparente Wellpappe |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS597840B2 (ja) * | 1976-10-04 | 1984-02-21 | 三菱製紙株式会社 | 透明紙の製造方法 |
| DE3368092D1 (en) * | 1982-07-30 | 1987-01-15 | Mishima Paper Co Ltd | Conductive film for packaging |
| JP2005048323A (ja) * | 2003-07-29 | 2005-02-24 | Daio Paper Corp | 感熱透明化シート |
| CN110552234B (zh) * | 2018-05-30 | 2022-02-15 | 华南理工大学 | 一种超耐折、高雾度、高透明纸及其制备方法 |
| AT525436B1 (de) * | 2022-02-11 | 2023-04-15 | Mondi Ag | Transparentpapier |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3101294A (en) * | 1959-12-17 | 1963-08-20 | Du Pont | Process for forming a web of synthetic fibers |
| FR2108395A5 (enrdf_load_stackoverflow) * | 1970-09-25 | 1972-05-19 | Toray Industries | |
| JPS5117608B2 (enrdf_load_stackoverflow) * | 1973-07-26 | 1976-06-03 | ||
| JPS5040803A (enrdf_load_stackoverflow) * | 1973-08-10 | 1975-04-14 |
-
1974
- 1974-09-09 JP JP49103702A patent/JPS597839B2/ja not_active Expired
-
1975
- 1975-09-03 CA CA234,678A patent/CA1057911A/en not_active Expired
- 1975-09-04 SE SE7509849A patent/SE7509849L/xx unknown
- 1975-09-08 BE BE159820A patent/BE833164A/xx unknown
- 1975-09-08 FR FR7527478A patent/FR2283991A1/fr active Granted
- 1975-09-09 GB GB37151/75A patent/GB1522854A/en not_active Expired
- 1975-09-09 NL NL7510609A patent/NL7510609A/xx not_active Application Discontinuation
- 1975-09-09 IT IT27044/75A patent/IT1042387B/it active
- 1975-09-09 DE DE2540069A patent/DE2540069C2/de not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10002576A1 (de) * | 1999-09-21 | 2001-03-22 | Heinr Aug Schoeller Soehne Gmb | Verfahren zur Herstellung von Papier sowie entsprechendes Papier |
| DE102011087742A1 (de) * | 2011-12-05 | 2013-06-06 | Papierfabrik Schoellershammer Heinr. Aug. Schoeller Söhne GmbH & Co. KG | Transparente Wellpappe |
Also Published As
| Publication number | Publication date |
|---|---|
| IT1042387B (it) | 1980-01-30 |
| DE2540069A1 (de) | 1976-03-25 |
| FR2283991A1 (fr) | 1976-04-02 |
| BE833164A (fr) | 1975-12-31 |
| JPS597839B2 (ja) | 1984-02-21 |
| GB1522854A (en) | 1978-08-31 |
| CA1057911A (en) | 1979-07-10 |
| JPS5132803A (enrdf_load_stackoverflow) | 1976-03-19 |
| FR2283991B1 (enrdf_load_stackoverflow) | 1979-06-29 |
| NL7510609A (nl) | 1976-03-11 |
| AU8458475A (en) | 1977-03-10 |
| SE7509849L (sv) | 1976-03-10 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8110 | Request for examination paragraph 44 | ||
| 8128 | New person/name/address of the agent |
Representative=s name: ABITZ, W., DIPL.-ING.DR.-ING. MORF, D., DR., PAT.- |
|
| D2 | Grant after examination | ||
| 8364 | No opposition during term of opposition | ||
| 8339 | Ceased/non-payment of the annual fee |