DE249238C - - Google Patents
Info
- Publication number
- DE249238C DE249238C DENDAT249238D DE249238DA DE249238C DE 249238 C DE249238 C DE 249238C DE NDAT249238 D DENDAT249238 D DE NDAT249238D DE 249238D A DE249238D A DE 249238DA DE 249238 C DE249238 C DE 249238C
- Authority
- DE
- Germany
- Prior art keywords
- anthraquinone
- alkali
- derivatives
- reducing agent
- addition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000007859 condensation product Substances 0.000 claims description 4
- 239000000835 fiber Substances 0.000 claims description 3
- 239000003638 reducing agent Substances 0.000 claims description 3
- BYSUDJAFZYUOGY-UHFFFAOYSA-N 10H-acridin-9-one;anthracene-9,10-dione Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3NC2=C1.C1=CC=C2C(=O)C3=CC=CC=C3C(=O)C2=C1 BYSUDJAFZYUOGY-UHFFFAOYSA-N 0.000 claims description 2
- 150000004056 anthraquinones Chemical class 0.000 claims description 2
- 239000003513 alkali Substances 0.000 claims 3
- FZEYVTFCMJSGMP-UHFFFAOYSA-N Acridone Chemical class C1=CC=C2C(=O)C3=CC=CC=C3NC2=C1 FZEYVTFCMJSGMP-UHFFFAOYSA-N 0.000 claims 1
- 238000000034 method Methods 0.000 claims 1
- 239000000047 product Substances 0.000 claims 1
- YRHRIQCWCFGUEQ-UHFFFAOYSA-N thioxanthen-9-one Chemical class C1=CC=C2C(=O)C3=CC=CC=C3SC2=C1 YRHRIQCWCFGUEQ-UHFFFAOYSA-N 0.000 claims 1
- 239000000984 vat dye Substances 0.000 claims 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- RZVHIXYEVGDQDX-UHFFFAOYSA-N Anthraquinone Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3C(=O)C2=C1 RZVHIXYEVGDQDX-UHFFFAOYSA-N 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- 240000000358 Viola adunca Species 0.000 description 2
- 235000005811 Viola adunca Nutrition 0.000 description 2
- 235000013487 Viola odorata Nutrition 0.000 description 2
- 235000002254 Viola papilionacea Nutrition 0.000 description 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 2
- GRWZHXKQBITJKP-UHFFFAOYSA-L dithionite(2-) Chemical compound [O-]S(=O)S([O-])=O GRWZHXKQBITJKP-UHFFFAOYSA-L 0.000 description 2
- 125000005462 imide group Chemical group 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Natural products C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 1
- 239000010446 mirabilite Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 235000002639 sodium chloride Nutrition 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- RSIJVJUOQBWMIM-UHFFFAOYSA-L sodium sulfate decahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].[O-]S([O-])(=O)=O RSIJVJUOQBWMIM-UHFFFAOYSA-L 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 125000004434 sulfur atoms Chemical group 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B5/00—Dyes with an anthracene nucleus condensed with one or more heterocyclic rings with or without carbocyclic rings
- C09B5/24—Dyes with an anthracene nucleus condensed with one or more heterocyclic rings with or without carbocyclic rings the heterocyclic rings being only condensed with an anthraquinone nucleus in 1-2 or 2-3 position
- C09B5/34—Anthraquinone acridones or thioxanthrones
- C09B5/342—Anthraquinone thioxanthrones
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B5/00—Dyes with an anthracene nucleus condensed with one or more heterocyclic rings with or without carbocyclic rings
- C09B5/24—Dyes with an anthracene nucleus condensed with one or more heterocyclic rings with or without carbocyclic rings the heterocyclic rings being only condensed with an anthraquinone nucleus in 1-2 or 2-3 position
- C09B5/34—Anthraquinone acridones or thioxanthrones
- C09B5/347—Anthraquinone acridones
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/22—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using vat dyestuffs including indigo
- D06P1/24—Anthraquinone dyes or anthracene nucleus containing vat dyes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Coloring (AREA)
Description
KAISERLICHESIMPERIAL
PATENTAMT.PATENT OFFICE.
PATENTSCHRIFTPATENT LETTERING
- JV* 249238 -KLASSE Sm. GRUPPE - GROUP CLASS Sm - JV * 249,238th
der Anthrachinonreihe.the anthraquinone series.
Patentiert im Deutschen Reiche vom 20. April 1909 ab. Patented in the German Empire on April 20, 1909 .
COCO
X K y X X K y X χχ
)i? bzw. R ζ >ι XC0' Ο C/ ) i? or R ζ > ι X C0 ' Ο C /
Ji.Ji.
bzw.respectively.
worin X eine Imidgruppe, eine substituierte . Imidgruppe oder ein Schwefelatom und R einen einfachen oder substituierten (ausgenommen durch die Sulfogruppe 5 O3 H) Benzol- oder Naphtalinrest bedeutet (vgl. z. B. die Patente 216480 und 234977), mit alkalischen Reduktionsmitteln Küpen bilden, mittels welcher auf der pflanzlichen Faser Färbungen von hervorragenden Eigenschaften erzeugt werden können.wherein X is an imide group, a substituted one. Imide group or a sulfur atom and R is a simple or substituted (except for the sulfo group 5 O 3 H) benzene or naphthalene radical (see, for example, patents 216480 and 234977), with alkaline reducing agents form vats, by means of which on the vegetable Fiber dyeings of excellent properties can be produced.
Das in dem Patent 221853 beschriebene Anthrachinonmonoakridon sowie dessen im Anthrachinonrest substituierte Derivate sollen hier ausgenommen werden.The anthraquinone monoacridone described in the patent 221853 and its im Derivatives substituted by anthraquinone radicals should be excluded here.
Das Kondensationsprodukt aus der Anthrachinon-i · 5-bis-thiosalicylsäure liefert beispielsweise auf Baumwolle rote Nuancen, dasjenigeThe condensation product from the anthraquinone-i · 5-bis-thiosalicylic acid gives, for example on cotton red nuances, that one
/\ X CO/ \ X CO 4040
4545
X COX CO 5555
aus der Anthrachinon -1 · 5 - bis-anthranilsäure violette bis blauviolette Töne von großer Echtheit. from the anthraquinone -1 · 5 - bis-anthranilic acid violet to blue-violet tones of great authenticity.
In das 40 bis 60 ° warme Färbebad von 1000 1 Wasser gibt man 0,5 kg des im Patent 234977 beschriebenen Kondensationsproduktes aus Anthrachinon-i · 5-bis-thiosalicylsäure, welches zweckmäßig zuvor in üblicher Weise in feine Verteilung gebracht wird, fügt 5 1 Natronlauge 300 Be. und 10 bis 15 1 Hydrosulfitlösung (1 kg Hydrosulfit cone. B. A. S. F. in Pulver in 5 1 Wasser) hinzu und rührt gut um. Nach V2 bis 3/4 stündigem Hantieren der Baumwolle in dieser Flotte bei 40 bis 60 ° wird gut gespült und in üblicher Weise0.5 kg of the condensation product of anthraquinone-i.5-bis-thiosalicylic acid described in patent 234977, which is expediently finely divided beforehand in the customary manner, is added to the 40 to 60 ° warm dyebath of 1000 liters of water Caustic soda 30 0 Be. and 10 to 15 1 hydrosulfite solution (1 kg hydrosulfite cone. BASF in powder in 5 1 water) and stir well. After 2 to 3 V / for 4 hours, handling of cotton in this liquor at 40 to 60 ° is rinsed well and in a conventional manner
fertig gemacht. Das Bad zieht nicht vollkommen aus; durch Zusatz von 25 bis 50 kg Kochsalz oder Glaubersalz wird es besser erschöpft. Man erhält auf diese Weise reine rote Nuancen.ready. The bathroom doesn't take off completely; by adding 25 to 50 kg Table salt or Glauber's salt will deplete it better. In this way you get pure red nuances.
Ersetzt man in Beispiel I das dort verwendete Kondensationsprodukt aus Anthrachinon-ι . 5-bis-thiosalicylsäure durch dasjenige aus der Anthrachinon-i · 5-bis-anthranilsäure, so erhält man blauviolette Nuancen von großer Echtheit. \If the condensation product of anthraquinone-ι used there is replaced in Example I . 5-bis-thiosalicylic acid by that of the anthraquinone-i · 5-bis-anthranilic acid, see above blue-violet nuances of great authenticity are obtained. \
Ganz analog verhalten sich die übrigen, den angegebenen Formeln entsprechenden Akridone und Thioxanthone. Sie können auch in geeigneter Weise durch Drucken und Klotzen auf der Faser fixiert werden.The other acridons, which correspond to the formulas given, behave in a completely analogous manner and thioxanthones. They can also be fixed on the fiber in a suitable manner by printing and padding.
Claims (1)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE249238C true DE249238C (en) |
Family
ID=507878
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DENDAT249238D Active DE249238C (en) |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE249238C (en) |
-
0
- DE DENDAT249238D patent/DE249238C/de active Active
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