DE2326998A1 - CONTACT ADHESIVES BASED ON POLYURETHANES AND BUTADIENE ACRYLNITRILE RUBBER - Google Patents

CONTACT ADHESIVES BASED ON POLYURETHANES AND BUTADIENE ACRYLNITRILE RUBBER

Info

Publication number
DE2326998A1
DE2326998A1 DE19732326998 DE2326998A DE2326998A1 DE 2326998 A1 DE2326998 A1 DE 2326998A1 DE 19732326998 DE19732326998 DE 19732326998 DE 2326998 A DE2326998 A DE 2326998A DE 2326998 A1 DE2326998 A1 DE 2326998A1
Authority
DE
Germany
Prior art keywords
solvent
resin
mixtures
adhesives according
polyurethane
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
DE19732326998
Other languages
German (de)
Other versions
DE2326998C3 (en
DE2326998B2 (en
Inventor
Wolfgang Dipl-Chem Dr Hesse
Erich Dipl-Chem Schunck
Heinrich Sender
Joachim Weil
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Reichhold Albert Chemie AG
Original Assignee
Reichhold Albert Chemie AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Reichhold Albert Chemie AG filed Critical Reichhold Albert Chemie AG
Priority to DE2326998A priority Critical patent/DE2326998C3/en
Priority to AT429074A priority patent/AT332957B/en
Priority to GB2339174A priority patent/GB1477486A/en
Priority to FR7418048A priority patent/FR2230703B1/fr
Priority to IT23176/74A priority patent/IT1012815B/en
Publication of DE2326998A1 publication Critical patent/DE2326998A1/en
Publication of DE2326998B2 publication Critical patent/DE2326998B2/en
Application granted granted Critical
Publication of DE2326998C3 publication Critical patent/DE2326998C3/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/12—Bonding of a preformed macromolecular material to the same or other solid material such as metal, glass, leather, e.g. using adhesives
    • C08J5/124—Bonding of a preformed macromolecular material to the same or other solid material such as metal, glass, leather, e.g. using adhesives using adhesives based on a macromolecular component
    • C08J5/125—Adhesives in organic diluents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B7/00—Mixing; Kneading
    • B29B7/30—Mixing; Kneading continuous, with mechanical mixing or kneading devices
    • B29B7/58—Component parts, details or accessories; Auxiliary operations
    • B29B7/72—Measuring, controlling or regulating
    • B29B7/726—Measuring properties of mixture, e.g. temperature or density
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J109/00—Adhesives based on homopolymers or copolymers of conjugated diene hydrocarbons
    • C09J109/02—Copolymers with acrylonitrile
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08J2327/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
    • C08L2666/14—Macromolecular compounds according to C08L59/00 - C08L87/00; Derivatives thereof
    • C08L2666/16—Addition or condensation polymers of aldehydes or ketones according to C08L59/00 - C08L61/00; Derivatives thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Description

Tabelle 1Table 1 Trennfestigkeit (kp/cm)Separation strength (kp / cm)

Ablüftungszeit Ablüftungstemperatur Alter der Verklebung PrüftemperaturFlash-off time Exhaust temperature Age of the bond test temperature

■20.*'■ 20. * '

■■ "; 3h 6h
2O°C ■ ■■ "; 3 h 6 h
20 ° C ■

TageDays

209C 20° C 20°C 2O°C 5O°C20 9 C 20 ° C 20 ° C 20 ° C 50 ° C

Polyurethan, nit Novolak +)Polyurethane, nit novolak +)

1) +25 % Harz A1) + 25 % resin A

2) + 50 % Harz .Λ2) + 50% resin .Λ

3) + 25 Z Harz E3) + 25 Z resin E.

4) + 50 % Harz E4) + 50% resin E.

5-,5-, 33 55 ,9, 9 11 ,8.,8th. —- .8".8th" 2.32.3 6,6, 11 55 ,3, 3 44th ,9, 9 11 3,23.2 6,6, 55 66th ,5, 5 33 ,3, 3 -- ,5, 5 2.72.7 7,7, 11 77th ,0, 0 77th ,0, 0 66th 3.53.5

Polyurethan mit modifiziertem Epoxydharz +.+).Polyurethane with modified epoxy resin +. +).

5) + 25 % Harz G5) + 25% resin G

6) + 50 Z Harz C6) + 50 Z resin C

7,17.1

7,07.0

6,5 . 6,8 -6.5. 6.8 -

3.0 4,33.0 4.3

Polyurethan mit halogenhaltigen Polymeren bzw» i1ischpolyr,erisaten +)Polyurethane with halogen-containing polymers or » i1ischpolyr, erisaten +)

7) + 25 % Clilörkautschuk7) + 25% Clilör rubber

0) + 50 % Chlorkautschuk0) + 50 % chlorinated rubber

9) -f 25 %}chlor£ertes9) -f 25%} chlorine ertes

10) +50 %)Polypropylen10) + 50%) polypropylene

11) + 25 Z)?1ischpolyniGrisat11) + 25 Z)? 1ischpolyniGrisat

12) -J- 50 % Won PVC und12) -J- 50% won PVC and

PolyvinylacetetPolyvinyl acetate

6,56.5 4, G4, G 7,77.7 7.,87th, 8th 6,26.2 6,16.1 7,87.8 7,97.9 r,,nr ,, n 6,16.1

5,85.8

7,4 7,6 7,5 7,57.4 7.6 7.5 7.5

2,5 3.3 2,6 3,7 2,72.5 3.3 2.6 3.7 2.7

3,93.9

Vergleichsbeispielc au. 1 bis 12 PolyurethanComparative example c au. 1 to 12 polyurethane

ohne Harz bzw. Zusatz -without resin or additive -

+ .5.0 % Harz Verf?l.Beispiel I + 50 Z Harz Vergl. Beispiel 2 -+ .5.0 % resin availability Example I + 50 Z resin comp. Example 2 -

+) Verklebung von Weich-PVC mit 40 Z Weichmacher, 2 mm stark ++) Verklebung von PVC-Fußbodenbelag mit 10 % Weichmacher Keine Verklebung möglich, Klebefilm völlig-trocken+) Bonding of soft PVC with 40 Z plasticizer, 2 mm thick ++) Bonding of PVC flooring with 10% plasticizer No gluing possible, the adhesive film is completely dry

409 8 5 0/TO 0 5409 8 5 0 / TO 0 5

Tabelle 2Table 2

AXAX

Scherfestigkeit (kp/cra )Shear strength (kp / cra)

Verklebung von l/eich-PVC mit ko £> Weichmacher, 2 mm starkBonding l / calibration PVC with ko £> plasticizer, 2 mm thick

Ablüftungszeit AbliiftungGtenperatur Alter der Verklebung PrüftemperaturFlash-off time Flash-off temperature Age of the bond Test temperature

20' 20°C20 '20 ° C

20'20 '

20'
20°C
Tage20 '
20 ° C
Days

1h 1 h

20°C Tage20 ° C days

20v 20 BC

50^50 ^

50" 20l 50 "20 l

10« 90°C Tage10 «90 ° C days

50u 20l 50 u 20 l

12) + 50 c/o Mischpolymerisat v. PVC und Polyvinylacetat 12) + 50 c / o mixed polymer v. PVC and polyvinyl acetate

2,4 0,7 2.4 0.7

1,11.1

Beispielexample %% PolyurethanPolyurethane 2,2, 22 ο,ο, 66th 88th 11 ,1,1 99 '0M' 0 M 11 ,8,8th 99 '2T-I' 2 TI 1,1, 99 *0 + 50* 0 + 50 eA e A Harz BResin B 4,4, 00 ο,ο, 66th 88th 11 ,3, 3 88th '%'% 11 ,3, 3 99 >\> \ 2,2, 33 10) + 5010) + 50 chlorierteschlorinated

1,1 8,9„ 1,51.1 8.9 "1.5

VergleichsbeiGpieleCOMPARATIVE EXAMPLES

ohne Harz + 50 /·> Harz Vergl.Beisp.1 + 50 ?J Harz Vergl.Beicp.2without resin + 50 / ·> Harz compare example 1 + 50? J Harz compare example 2

8,88.8

K = HaterialrißK = crack in the material

- = keine Verklebung möglich, Klebefila völlig trocken.- = no gluing possible, glue layer completely dry.

40 9850/100540 9850/1005

Tabelle 3Table 3 Trennfestigkeit (kp/cn)Separation strength (kp / cn)

nach Verstärkung mit 5 % bezogen auf das Lösungsmittelklebegeaisch einerafter reinforcement with 5% based on the solvent adhesive layer one

20 /jjgen Lösung von Triphenylaethan -h^h% , V- -triisocyanat in Methylenchlorid ■ 20% solution of triphenylaethane -h ^ h % , V- -triisocyanate in methylene chloride

Verklebung von FVC-Fußbodenbelag mit 10 CJ> UeichraaeherBonding of FVC flooring with 10 C J> Ueichraaeher

Ablüftungszeit ' .20· 1h 3h 6h Flash-off time '.20 · 1 h 3 h 6 h

Ablüftungetemperatur 20 C .....'■ Ventilation temperature 20 C ..... '■

Alter der Verklebung : : — 7 Tage > — :— TopfzeitAge of application:: - 7 days> -: - pot life

Beispiel Polyurethan Example polyurethane

13) + 50 Ϊ* Harz B 7,1 11*) + 50 % chlor.Polyprop. 8,713) + 50 Ϊ * Resin B 7.1 1 1 *) + 50 % chlorine, polyprop. 8.7

15) + 50 c/j LIisclip.PVC + PVAC* 7,015) + 50 c / j LIisclip.PVC + PVAC * 7.0

ohne Harz 3,5without resin 3.5

- = keine Verklebung möglich, Klebefilm völlig trocken.- = no gluing possible, adhesive film completely dry.

χ ■ Polyvinylacetatχ ■ Polyvinyl acetate

77th »2 » 2 77th ,3, 3 77th ,0, 0 ca.approx. 33 TageDays 88th ,0, 0 77th • °• ° ΛΛ ,0, 0 ca.approx. 33 TageDays 66th ,3, 3 66th ,0, 0 66th ,2, 2 ca.approx. 33 TageDays __ —- ca.approx. 33 TageDays

409850/1005409850/1005

TabelleTabel Trennfestigkeit (kp/cm)Separation strength (kp / cm)

Verklebung von PVC-Fußbodenbelag mit 10 /ί U-ichmacherGluing PVC flooring with 10 / ί U-ichmacher

Ablüftungszext
Ablüftungstemperatur
Alter der Verklebung
P rü ft emperaturVentilation period
Exhaust temperature
Age of the bond
Check temperature 10 mn.
20°C10 mn.
20 ° C 1 Std.
20°C1 H.
20 ° C 3 Std.
900C3 hours.
90 0 C 10 mm.
90°C10 mm.
90 ° C 10 mm
90°C10 mm
90 ° C Beispiel
16) + Harz B
17) + chlor.Polypropylen
18) + Mischpolymerisat von PVCexample
16) + resin B
17) + chlorinated polypropylene
18) + mixed polymer of PVC 20°C20 ° C 200C20 0 C 20°C -20 ° C - 20°C20 ° C 50°C50 ° C 2,6
1,62.6
1.6 2.8
1,82.8
1.8 2,12.1 2,7
2,62.7
2.6 0,60.6

mit Polyvinylacetat
ohne Harzwith polyvinyl acetate
without resin

1,91.9

1,91.9

2,22.2

0,50.5

0,3 0,10.3 0.1

- keine Verklebung möglich, Klebefilm völlig trocken.- No gluing possible, the adhesive film is completely dry.

409850/1005409850/1005

Claims (2)

PatentansprücheClaims 1. Verwendung von Lösungsmittelklebstoffen auf Basis von Polyurethanoder ITitrilkautschuk-Klebstoffen zum Kleben von Polyvinylchlorid mit sich selbst oder mit anderen Materialien, dadurch gekennzeichnet, daß sie a) Novolake aus 1. Aldehyden, vorzugsweise Formaldehyd, und 2. Bisphenolen, Alkylphenolen mit mindestens 3 C-Atomen im Alkylrest, Arylphenolen, Gemischen davon .oder Gemischen aus einem oder mehreren dieser Phenole mit bis zu 50 MoIZ Phenol und/ oder Alkylphenolen mit bis zu 2 C-Atomen als Alkylrest, oder1. Use of solvent-based adhesives based on polyurethane or ITitrile rubber adhesives for bonding polyvinyl chloride with itself or with other materials, characterized that they a) novolaks from 1. aldehydes, preferably formaldehyde, and 2. bisphenols, alkylphenols with at least 3 carbon atoms in the alkyl radical, arylphenols, mixtures thereof. or mixtures of one or more of these phenols with up to 50 MoIZ phenol and / or alkylphenols with up to 2 carbon atoms as an alkyl radical, or b) Epoxydharze, die durch Umsetzung mit Alkoholaten mehrwertiger Metalle modifiziert sind oder c) halogenierte .Kohlenwasserstoff-Kunststoffe oder Copolymerisationsharze von Vinylchlorid oder Mischungen von diesen Komponenten enthalten.b) Epoxy resins which are polyhydric by reaction with alcoholates Metals are modified or c) halogenated hydrocarbon plastics or copolymerization resins of vinyl chloride or mixtures of these components. 2. Verwendung von Lösungsmittelklebstoffen nach Anspruch 1, dadurch gekennzeichnet, daß das Polyurethanelastomer ein auf der Basis von mit Isocyanaten vorvernetzter hydroxylgruppenhaltig«, höher— molekularer Polyester ist.2. Use of solvent adhesives according to claim 1, characterized characterized in that the polyurethane elastomer is based on of hydroxyl groups pre-crosslinked with isocyanates «, higher— molecular polyester. 3. Verwendung von Lösungsmittelklebstoffen nach den Ansprüchen 1 bis 3, dadurch gekennzeichnet, daß sie ein Epoxydharz auf der Basis Diphenylolpropan enthalten, das durch Umsetzung mit einem Aluminiuraalkoholat modifiziertist.3. Use of solvent adhesives according to claims 1 to 3, characterized in that they have an epoxy resin on the Base contain diphenylolpropane, which is obtained by reacting with a Aluminum alcoholate is modified. 4. Verwendung von Lösungsmittelklebstoffen nach den Ansprüchen 1 bis 4, dadurch gekennzeichnet, daß sie chloriarten Naturkautschuk und/oder chloriertes Polypropylen enthalten.4. Use of solvent adhesives according to Claims 1 to 4, characterized in that they are chlorinated natural rubber and / or chlorinated polypropylene. 5. Verwendung von Lösungsmittelklebstoffen nach den Ansprüchen 1 bis 5, dadurch gekennzeichnet, daß sie Mischpolymerisate aus Vinylchlorid und Vinylacetat in einem bevorzugten Gewichtsverhältnis von J: (ijf 5-0,3) en thai ten.5. Use of solvent adhesives according to Claims 1 to 5, characterized in that they contain copolymers of vinyl chloride and vinyl acetate in a preferred weight ratio of J: (ijf 5-0.3) en thai. -10--10- 4098507 100 64098507 100 6 -IQ--IQ- 6. Verwendung von Lösunigsiaittelklebstof fen nach den Ansprüchen ! bis 3, dadurch gekennzeichnet, daß sie einen Gehalt von IO — 70 Gew.-% bezogen atif eiraea Elastomeren-Gehalt an Harz und/ oder halogenierten Elastomeren aufweisen.6. Use of Lösunigsiaittelklebstof fen according to the claims ! to 3, characterized in that they have a content of IO - 70% by weight based on atif eiraea elastomer content of resin and / or halogenated elastomers. 16. Mai 1973
Dr.E/CbMay 16, 1973
Dr.E / Cb 4G9850/10054G9850 / 1005
DE2326998A 1973-05-26 1973-05-26 Use of polyurethane-based contact adhesives to bond polyvinyl chloride to itself or to other materials Expired DE2326998C3 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
DE2326998A DE2326998C3 (en) 1973-05-26 1973-05-26 Use of polyurethane-based contact adhesives to bond polyvinyl chloride to itself or to other materials
AT429074A AT332957B (en) 1973-05-26 1974-05-24 CONTACT ADHESIVES BASED ON POLYURETHANES AND BUTADIENE ACRYLNITRILE RUBBER
GB2339174A GB1477486A (en) 1973-05-26 1974-05-24 Method of bonding polyvinyl chloride to a substrate
FR7418048A FR2230703B1 (en) 1973-05-26 1974-05-24
IT23176/74A IT1012815B (en) 1973-05-26 1974-05-24 CONTACT ADHESIVES BASED ON LIURETHANE PO AND ACRYLONITRILE BUTADIENE RUBBER

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE2326998A DE2326998C3 (en) 1973-05-26 1973-05-26 Use of polyurethane-based contact adhesives to bond polyvinyl chloride to itself or to other materials

Publications (3)

Publication Number Publication Date
DE2326998A1 true DE2326998A1 (en) 1974-12-12
DE2326998B2 DE2326998B2 (en) 1977-10-13
DE2326998C3 DE2326998C3 (en) 1978-06-15

Family

ID=5882276

Family Applications (1)

Application Number Title Priority Date Filing Date
DE2326998A Expired DE2326998C3 (en) 1973-05-26 1973-05-26 Use of polyurethane-based contact adhesives to bond polyvinyl chloride to itself or to other materials

Country Status (5)

Country Link
AT (1) AT332957B (en)
DE (1) DE2326998C3 (en)
FR (1) FR2230703B1 (en)
GB (1) GB1477486A (en)
IT (1) IT1012815B (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0710967B2 (en) * 1985-02-04 1995-02-08 日立化成工業株式会社 Adhesive for printed wiring board
FR2617494B1 (en) * 1987-06-30 1989-12-29 Landry Plastiques Sa COMPOSITION FOR BONDING A TEXTILE COATING ON PLASTIC MATERIALS
DE3815520A1 (en) * 1988-05-06 1989-11-16 Bayer Ag ADHESIVE BLEND
US5474827A (en) * 1994-03-23 1995-12-12 Minnesota Mining And Manufacturing Company Retroreflective article and method of making the same
US20050101725A1 (en) * 2003-11-12 2005-05-12 Lord Corporation Low-formaldehyde thermoplastic seal adhesive

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB741599A (en) * 1952-06-11 1955-12-07 Semtex Ltd Adhesive bonding of surfaces
FR1170168A (en) * 1955-09-06 1959-01-12 Dunlop Sa Adhesive compositions, their preparation and applications
US3558546A (en) * 1964-12-04 1971-01-26 Goodrich Co B F Adhesive cement

Also Published As

Publication number Publication date
DE2326998C3 (en) 1978-06-15
GB1477486A (en) 1977-06-22
FR2230703B1 (en) 1978-01-20
IT1012815B (en) 1977-03-10
DE2326998B2 (en) 1977-10-13
AT332957B (en) 1976-10-25
FR2230703A1 (en) 1974-12-20
ATA429074A (en) 1976-02-15

Similar Documents

Publication Publication Date Title
DE69727592T2 (en) PRIMER COMPOSITION AND LIABILITY OF ORGANIC POLYMER SUBSTRATES
US3970717A (en) Saturated hydroxy polyester urethanes and styrene copolymers
DE2113631A1 (en) Modified polyurethane adhesives for bonding rubber materials
DE2326998A1 (en) CONTACT ADHESIVES BASED ON POLYURETHANES AND BUTADIENE ACRYLNITRILE RUBBER
EP0362472A3 (en) Polyblend of thermoplastic polyurethane elastomer and process for its preparation
DE3590249C2 (en) Polyurethane glue
EP0543794A1 (en) Molding compositions
DE1256822B (en) Bonding of plasticized plastics made of polyvinyl chloride or its copolymers
DE2407408A1 (en) ADHESIVE COMPOUND TO CONNECT POLYESTERS WITH RUBBER
DE68920914T2 (en) Flake adhesive composition.
DE2502691A1 (en) PROCESS FOR THE PRODUCTION OF AN ADHESIVE BASED ON A THERMOPLASTIC ELASTOMER BLOCK MIXED POLYMERIZATE
EP0359926B1 (en) Cross-linkable compositions, process for their preparation, their use as moulding compositions and for the production of moulded parts
US2683103A (en) Curing organic substituted polymers with oximes
DE1930336B2 (en) Use of polyurethanes for the production of adhesives with high green strength
EP0129016B1 (en) Composite materials and composite construction elements containing epdm
DE2316034A1 (en) COATING AGENT FOR THE PRODUCTION OF THE BASE LAYER OF A TWO-LAYER ADHESIVE FOR COMPOSITE MATERIALS FROM AN ELASTOMER AND A POLYESTER
CH615936A5 (en)
DE1132331B (en) Process for the production of pliable, elastic, hardenable synthetic resins
DE1812565C3 (en) Bonding of materials with polyisocyanate-containing adhesives based on natural or synthetic rubber
DE1794334A1 (en) NEW COMPOSITIONS CONTAINING CHLORINATED POLYBUTEN-L
DE2333150A1 (en) Toluene diisocyanate wastes - used in adhesives, binders and moulding compsns
DE69028584T2 (en) Vinyl chloride resin-based composition and seals made from it
JPS6340230B2 (en)
DE2123182A1 (en) Method of gluing plastic veneers to wood
SU664980A1 (en) Adhesive

Legal Events

Date Code Title Description
C3 Grant after two publication steps (3rd publication)