DE231448C - - Google Patents
Info
- Publication number
- DE231448C DE231448C DENDAT231448D DE231448DA DE231448C DE 231448 C DE231448 C DE 231448C DE NDAT231448 D DENDAT231448 D DE NDAT231448D DE 231448D A DE231448D A DE 231448DA DE 231448 C DE231448 C DE 231448C
- Authority
- DE
- Germany
- Prior art keywords
- stain
- coloring
- dyes
- dye
- azo dyes
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000987 azo dye Substances 0.000 claims description 3
- 238000004040 coloring Methods 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 238000000034 method Methods 0.000 claims description 2
- 241000947840 Alteromonadales Species 0.000 claims 1
- 239000000975 dye Substances 0.000 description 6
- 150000003672 ureas Chemical class 0.000 description 3
- JWAZRIHNYRIHIV-UHFFFAOYSA-N 2-Naphthol Chemical compound C1=CC=CC2=CC(O)=CC=C21 JWAZRIHNYRIHIV-UHFFFAOYSA-N 0.000 description 2
- QELUYTUMUWHWMC-UHFFFAOYSA-N Edaravone Chemical compound O=C1CC(C)=NN1C1=CC=CC=C1 QELUYTUMUWHWMC-UHFFFAOYSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Natural products OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- GHMLBKRAJCXXBS-UHFFFAOYSA-N Resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 2
- 210000002268 Wool Anatomy 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- 150000002989 phenols Chemical class 0.000 description 2
- 238000007747 plating Methods 0.000 description 2
- KJCVRFUGPWSIIH-UHFFFAOYSA-N 1-Naphthol Chemical compound C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 description 1
- -1 B. resorcinol Chemical class 0.000 description 1
- 150000001555 benzenes Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005755 formation reaction Methods 0.000 description 1
- 150000002790 naphthalenes Chemical class 0.000 description 1
- IOVCWXUNBOPUCH-UHFFFAOYSA-M nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 description 1
- YGYAWVDWMABLBF-UHFFFAOYSA-N phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 description 1
- 238000004382 potting Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B35/00—Disazo and polyazo dyes of the type A<-D->B prepared by diazotising and coupling
- C09B35/02—Disazo dyes
- C09B35/039—Disazo dyes characterised by the tetrazo component
- C09B35/26—Disazo dyes characterised by the tetrazo component the tetrazo component being a derivative of a diaryl urea
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
Description
Es hat sich gezeigt, daß das Harnstoffderivat folgender Konstitution:It has been shown that the urea derivative has the following constitution:
,NH-, NH-
CO-CO-
-Ν H2 -OH ^SO3H /SO3H -OH NH0 -Ν H 2 -OH ^ SO 3 H / SO 3 H -OH NH 0
das man beispielsweise durch Einwirkung von Phosgen auf 1 · 4-Aminophenol-2-nitro-6-sulfosäure und darauffolgende Reduktion erhalten kann, sich zur Herstellung wertvoller beizenfärbender Azofarbstoffe verwenden läßt. Die auf diese Weise erhältlichen Farbstoffe sind durch hervorragende Walk- und Lichtechtheit ausgezeichnet.for example, by the action of phosgene on 1x4-aminophenol-2-nitro-6-sulfonic acid and subsequent reduction can be obtained for the production of valuable stain-coloring Can use azo dyes. The dyes obtainable in this way are characterized by excellent mill and lightfastness excellent.
43,5 Gewichtsteile des oben genannten Harnstoffderivats werden durch Einwirkung von Nitrit in die Tetrazoverbindung übergeführt, die man daraufhin in sodaalkalischer Lösung mit 29 Teilen β - Naphtol kombiniert. Nach beendeter Farbstoff bildung wärmt man auf und salzt den Färbstoff aus. Er färbt Wolle in saurem Bade bräunlichrot; durch Nachchromieren werden die Färbungen schwarzviolett. Sie besitzen dann eine große WaIk- und Pottingechtheit sowie hervorragende Lichtechtheit. 43.5 parts by weight of the above-mentioned urea derivative are by the action of Nitrite converted into the tetrazo compound, which is then placed in a soda-alkaline solution combined with 29 parts of β-naphtol. After dye formation is complete, the product is warmed up and salt out the dye. He dyes wool brownish-red in an acid bath; by re-chrome plating the colorations become black-violet. You will then have a great and potting fastness as well as excellent light fastness.
Ersetzt man in vorigem Beispiel das ß-Naphtol durch die äquivalente Menge Phenylmethylpyrazolon, so erhält man einen Farbstoff, der Wolle in saurem Bade orange färbt. Durch Nachchromieren werden die Färbungen rot. Sie erhalten dabei eine hervorragende Echtheit.If in the previous example the ß-naphtol is replaced by the equivalent amount of phenylmethylpyrazolone, in this way a dye is obtained which dyes wool orange in an acid bath. By After chrome plating, the colors turn red. You get excellent authenticity.
An Stelle des Phenylmethylpyrazolons können unter Erzielung eines ähnlichen Effekts dessen nichtsulfurierte Derivate, wie z. B. Halogenphenylmethylpyrazolone usw., verwendet werden. Ebenso kann man das Naphtol durch andere Phenole der Naphtalin- oder Benzolreihe, wie z. B. Resorcin, Dioxynaphtalin usw., ersetzen. .Instead of the Phenylmethylpyrazolons can with achieving a similar effect of unsulfurized derivatives, such as. Halophenylmethylpyrazolones, etc., can be used. The naphthol can also be replaced by other phenols of the naphthalene or benzene series, such as B. resorcinol, dioxynaphthalene, etc. replace. .
Ρλ τ ε ν τ - A ν s ρ r υ c η :Ρλ τ ε ν τ - A ν s ρ r υ c η:
Verfahren zur Herstellung beizenfärbender Azofarbstoffe, darin bestehend, daß man das Harnstoffderivat der folgenden Konstitution :Process for the preparation of stain-coloring azo dyes, consisting in that the urea derivative of the following constitution:
/NH2 / NH 2
/NH/ NH
CO-CO- SNH- S NH-
-OH-OH
~xS03H~ x S0 3 H
-OH-OH
6060
mit Phenolen der Benzol- und Naphtalinreihe oder mit Phenylmethylpyrazolon bzw. dessen nichtsulfurierten Derivaten kombiniert. with phenols of the benzene and naphthalene series or with phenylmethylpyrazolone or its unsulfurized derivatives combined.
BERLIN. GEDRUCKT IN DER REICHSDRUCKEREI.BERLIN. PRINTED IN THE REICHSDRUCKEREI.
Claims (1)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE231448C true DE231448C (en) |
Family
ID=491560
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DENDAT231448D Active DE231448C (en) |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE231448C (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE933287C (en) * | 1952-09-18 | 1955-09-22 | Sandoz Ag | Process for the preparation of metallizable disazo dyes |
| DE1025629B (en) * | 1955-12-23 | 1958-03-06 | Marcel Eugene Rouaux | Rotary furnace for the reduction of metal ores |
-
0
- DE DENDAT231448D patent/DE231448C/de active Active
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE933287C (en) * | 1952-09-18 | 1955-09-22 | Sandoz Ag | Process for the preparation of metallizable disazo dyes |
| DE1025629B (en) * | 1955-12-23 | 1958-03-06 | Marcel Eugene Rouaux | Rotary furnace for the reduction of metal ores |
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