DE2163190A1 - Process for making metal strips from metal powder - Google Patents
Process for making metal strips from metal powderInfo
- Publication number
- DE2163190A1 DE2163190A1 DE19712163190 DE2163190A DE2163190A1 DE 2163190 A1 DE2163190 A1 DE 2163190A1 DE 19712163190 DE19712163190 DE 19712163190 DE 2163190 A DE2163190 A DE 2163190A DE 2163190 A1 DE2163190 A1 DE 2163190A1
- Authority
- DE
- Germany
- Prior art keywords
- metal
- foil
- molten
- film
- cooled
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/12—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the method of spraying
- C23C4/14—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the method of spraying for coating elongate material
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/12—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the method of spraying
- C23C4/137—Spraying in vacuum or in an inert atmosphere
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S29/00—Metal working
- Y10S29/039—Spraying with other step
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/49636—Process for making bearing or component thereof
- Y10T29/49705—Coating or casting
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/4981—Utilizing transitory attached element or associated separate material
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/4998—Combined manufacture including applying or shaping of fluent material
- Y10T29/49982—Coating
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/4998—Combined manufacture including applying or shaping of fluent material
- Y10T29/49988—Metal casting
- Y10T29/49991—Combined with rolling
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Continuous Casting (AREA)
- Coating By Spraying Or Casting (AREA)
Description
zur Eingabe vom 3. Ι>βΖΘΙΐΛ>βΓ 1971 VA// Name d. Anm. HOMOGENEOUS METALS, INC<for entering the 3rd Ι> βΖΘΙΐΛ> βΓ 1971 VA // Name of d. Note: HOMOGENEOUS METALS, INC <
Verfahren zum Herstellen von Metallstreifen aus Metallpulver Process for making metal strips from metal powder
Die Erfindung bezieht sich auf Verfahren zum Herstellen von Metallstreifen aus Metallpulver und insbesondere auf ein Verfahren zum Herstellen von Superlegierungsstreifen aus Metallpulver, obwohl das Verfahren auch auf andere Legierungen Anwendung finden kanno The invention relates to methods of making metal strips from metal powder and, more particularly, to a method of making superalloy strips from metal powder, although the method can apply to other alloys and the like
Gewöhnlich werden die als Superlegierungen bekannten Metalle, das heißt Legierungen aus Eisen, Nickel oder Kobalt, welche ihre nützelichen mechanischen Eigenschaften bei erhöhten Temperaturen beibehalten, in Barren gegossen, welche dann zu Tafeln geschmiedet oder ausgewalzt, zerschnitten und konditioniert werden, hierauf zu Bändern oder Platten ausgewalzt, wieder konditioniert und schließlich zu Streifen ausgewalzt und zerschnitten werden. Während des Prozesses sind mehrere Hitzebehandlungen erforderlich, sowie eine abschließende Hitzebehandlung, je nach den Anforderungen des Kunden«, Alle diese Behandlungen kosten Zeit und Geld. Viel wichtiger ist aber die Tatsache, daß dieses große Ausmaß der Heißbearbeitung den Borgehalt der Superlegierung durch Oxydation zu erschöpfen trachtet. Bor ist wesentlich für den Bruchbelastungswiderstand bei erhöhter Temperatur. Usually the metals known as superalloys, i.e. alloys of iron, nickel or cobalt, are their Maintaining useful mechanical properties at elevated temperatures, pouring them into bars, which are then made into sheets forged or rolled out, cut up and conditioned, then rolled out into strips or plates, conditioned again and finally rolled out and cut into strips. During the process there are several heat treatments required, as well as a final heat treatment, depending on the customer's requirements. ”All of these treatments cost Time and money. Much more important, however, is the fact that this large amount of hot working reduces the boron content of the superalloy seeks to exhaust itself by oxidation. Boron is essential for breaking load resistance at elevated temperatures.
Bleche und Streifen aus Nickel, Aluminium und Eisen sind direkt aus Metallpulver ausgewalzt worden, indem das Pulver durch ein Walzwerk zugeführt wurde, dessen Walzen in einer waagerechten Ebene angeordnet waren. Wenn Streifen auf diese Weise ausgewalzt werden, ist es notwendig, daß die Anfangsfestigkeit des Streifens ausreichend ist, um eine spätere Verarbeitung zu ermöglichen. Dies bedeutet, daß das Pulver eine spezielle FormSheets and strips of nickel, aluminum and iron have been rolled out directly from metal powder by passing the powder through a Rolling mill was fed, the rollers of which were arranged in a horizontal plane. When strips are rolled out this way it is necessary that the initial strength of the strip is sufficient to allow later processing. This means that the powder has a special shape
209829/0933209829/0933
aufweisen muß, welche zu einer hohen Anfangsfestigkeit beitragen kann. Superlegierungspulver von hoher Reinheit werden im allgemeinen durch ein Trockenverfahren hergestellt, das ein kugelförmiges Pulver ergibt, welches eine schlechte Zusammendrückbarkeit in kaltem Zustand aufweist und dem daher die zur Erzielung d?r Anfangsfestigkeit notwendige spezielle Form mangelt»must have, which can contribute to a high initial strength. High purity superalloy powders are used in the generally produced by a dry process which gives a spherical powder which has poor compressibility when cold and therefore lacks the special shape necessary to achieve initial strength »
Die Aufgabe der Erfindung besteht in der Ausbildung eines Verfahrens zum Herstellen von Metallstreifen aus Metallpulver, welches die Herstellung des Streifens aus Pulver ohne Rücksicht auf dessen Form ermöglicht» Gemäß diesem Verfahren wird das Metallpulver durch eine Plasmaspritzpistole oder eine ähnliche Metallisierungspistole auf eine Unterlage aus Aluminium, Kupfer oder einen Streifen oder eine Folie aus Eisen aufgebracht, wobei die Folie sich in innigem Kontakt mit einem Kühlelement zu dem Zeitpunkt befindet, in dem die heißen Metallteilchen auf die Unterlage aufgespritzt werden» Der Metallspritzvorgang wird in einer inerten Atmosphäre ausgeführt, zum Beispiel in einer mit einem inerten Gas gespülten Kammero Die gespritzte Folie wird vorzugsweise auf eine vorher bestimmte Verdünnung kalt gewalzt und dann wieder gespritzt, wenn eine größere Dicke gewünscht wird. Die Menge des aufgebrachten Spritzmetalls und das Ausmaß des Kaltwalzens sind von der besonderen Legierung und der gewünschten Dicke abhängig» Jedes nachfolgende Bespritzen oder Metallisieren nach dem Walzen wird die Spannung des Streifens entlasten. Da die ganze Hitzebehandlung in einer inerten Atmosphäre ausgeführt wird, ist die Oxydation eliminierte Die Unterlage kann von dem fertigen Streifen vorzugsweise durch Ätzen entfernt werden, indem beispielsweise Hydroxyd für eine Aluminiumfolie und Salpetersäure für Kupfer oder Eisen verwendet wird»The object of the invention is to develop a method for manufacturing metal strips from metal powder, which enables the strip to be manufactured from powder regardless of its shape. Copper or a strip or foil made of iron, the foil being in intimate contact with a cooling element at the time the hot metal particles are sprayed onto the substrate Chamber flushed with an inert gas o The sprayed film is preferably cold-rolled to a predetermined dilution and then sprayed again if a greater thickness is desired. The amount of spray metal applied and the extent of cold rolling will depend on the particular alloy and thickness desired. Any subsequent spraying or plating after rolling will relieve the tension on the strip. Since the entire heat treatment is carried out in an inert atmosphere, the oxidation is eliminated. The base can be removed from the finished strip, preferably by etching, using, for example, hydroxide for an aluminum foil and nitric acid for copper or iron »
Die Erfindung betrifft daher ein Verfahren zum Herstellen von Metallstreifen aus Metallpulver, bei welchem das Pulver als geschmolzenes Metall auf eine gekühlte, bewegte Metallfolie aufgespritzt wird, worauf die Folie und das aufgespritzte MetallThe invention therefore relates to a method for producing metal strips from metal powder, in which the powder is molten Metal is sprayed onto a cooled, moving metal foil, whereupon the foil and the sprayed-on metal
209829/0933209829/0933
durch Druckeinwirkung verfestigt werden.solidified by the action of pressure.
In der vorstehenden allgemeinen Beschreibung sind bestimmte Aufgaben, Merkmale und Vorteile der Erfindung angegeben. Weitere Aufgaben, Merkmale und Vorteile ergeben sich aus der nachstehenden Beschreibung unter Bezugnahme auf die Zeichnung,■in welcher zeigt:In the above general description, certain tasks are Features and advantages of the invention indicated. Further objects, features and advantages emerge from the following Description with reference to the drawing, ■ in which shows:
Fig. 1 schematisch einen Längsschnitt durch eine Vorrichtung zur Ausführung des Verfahrens gemäß der Erfindung und1 schematically shows a longitudinal section through an apparatus for carrying out the method according to the invention and
Fig. 2 einen Längsschnitt eines Streifens, der gemäß der Erfindung aus Metallpulver hergestellt ist.Figure 2 is a longitudinal section of a strip made according to the invention is made of metal powder.
In Fig. 1 ist ein Blech oder eine Folie 10 dargestellt, die von einer Rolle 11 durch eine Dichtung 12 in das Innere einer Kammer 13 eingeführt wird, in welcher dieselbe über eine wassergekühlte Walze 14 hinweggeht«, Die Folie 10 wird mit geschmolzener Superlegierung 15 durch eine Plasmaspritzpistole 16 bespritzt, der die pulverförmige Superlegierung aus einem Trichter 17 zugeführt wird. Die geschmolzene Superlegierung 15 erstarrt auf der Folie 10, um eine Schicht der Superlegierungzu bilden, welche zwischen Druckwalzen 18 hindurchgeführt wird, um den neu gebildeten Superlegierungsstreifen 15 kalt zu k walzen«.In Fig. 1, a sheet or a film 10 is shown, which is from a roll 11 through a seal 12 in the interior of a chamber 13 is introduced, in which the same passes over a water-cooled roller 14. The foil 10 is made with molten superalloy 15 sprayed by a plasma spray gun 16, which is supplied with the powdery superalloy from a funnel 17 will. The molten superalloy 15 solidifies on the foil 10 to form a layer of the superalloy which is between Pressure rollers 18 are passed through to the newly formed superalloy strip 15 to be rolled cold «.
Wenn eine größere Dicke des Streifens 15 gewünscht wird, als bei einem Durchgang vor der Plasmaspritzpistole 16 aufgebracht werden kann, wird der Überzugsvorgang einfach sooft wiederholt wie notwendig ist. Durch das Aufspritzen der geschmolzenen Superlegierung auf den Streifen 15 wird die vorher gebildete Schicht von Spannung entlastet, ohne daß die Gefahr der Oxydation besteht. If a greater thickness of the strip 15 is desired than would be applied in one pass in front of the plasma spray gun 16 the coating process is simply repeated as often as necessary. By spraying the molten superalloy the previously formed layer on the strip 15 is relieved of tension without the risk of oxidation.
Wenn die Unterlage 10 entfernt werden soll, wird der zusammengesetzte Streifen durch eine entsprechende Ätzlösung hindurchge- When the base 10 is to be removed, the assembled strip is passed through an appropriate etching solution.
20932 9/093320932 9/0933
führt, um die Unterlage von dem Superlegierungsstreifen 15 nach dem Kaltwalzen wegzulösen.leads to peel the backing away from the superalloy strip 15 after cold rolling.
Die Erfindung ist nicht auf die dargestellte und beschriebene beispielsweise Ausführungsform beschränkt, die verschiedene Abänderungen erfahren kann, ohne den Rahmen der Erfindung zu verlassen. The invention is not limited to the illustrated and described exemplary embodiment, which has various modifications can experience without departing from the scope of the invention.
2 0 9 3 2 9 / 0 9 3 32 0 9 3 2 9/0 9 3 3
Claims (1)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10195470A | 1970-12-28 | 1970-12-28 |
Publications (1)
Publication Number | Publication Date |
---|---|
DE2163190A1 true DE2163190A1 (en) | 1972-07-13 |
Family
ID=22287361
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE19712163190 Pending DE2163190A1 (en) | 1970-12-28 | 1971-12-20 | Process for making metal strips from metal powder |
Country Status (7)
Country | Link |
---|---|
US (1) | US3742585A (en) |
BE (1) | BE776976A (en) |
CA (1) | CA944632A (en) |
DE (1) | DE2163190A1 (en) |
FR (1) | FR2120899A5 (en) |
GB (1) | GB1357770A (en) |
IT (1) | IT945535B (en) |
Families Citing this family (39)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE790453A (en) * | 1971-10-26 | 1973-02-15 | Brooks Reginald G | MANUFACTURE OF METAL ARTICLES |
US3909921A (en) * | 1971-10-26 | 1975-10-07 | Osprey Metals Ltd | Method and apparatus for making shaped articles from sprayed molten metal or metal alloy |
US3833983A (en) * | 1972-06-21 | 1974-09-10 | Alcan Res & Dev | Method of making aluminium bearing alloy strip |
GB1431895A (en) * | 1972-06-30 | 1976-04-14 | Alcan Res & Dev | Production of aluminium alloy products |
US4076640A (en) * | 1975-02-24 | 1978-02-28 | Xerox Corporation | Preparation of spheroidized particles |
US4066117A (en) * | 1975-10-28 | 1978-01-03 | The International Nickel Company, Inc. | Spray casting of gas atomized molten metal to produce high density ingots |
US4254164A (en) * | 1979-07-06 | 1981-03-03 | Nassau Recycle Corporation | Method of depositing copper on copper |
US4323419A (en) * | 1980-05-08 | 1982-04-06 | Atlantic Richfield Company | Method for ribbon solar cell fabrication |
US4418124A (en) * | 1980-10-06 | 1983-11-29 | General Electric Company | Plasma spray-cast components |
US4481237A (en) * | 1981-12-14 | 1984-11-06 | United Technologies Corporation | Method of applying ceramic coatings on a metallic substrate |
SE437682B (en) * | 1982-10-13 | 1985-03-11 | Inventing Ab | SET AND APPLICATION TO APPLY A NUTS-RESISTANT COATING ON A THIN METALLIC, BAND-SHAPED BEARING MATERIAL |
US4592781A (en) * | 1983-01-24 | 1986-06-03 | Gte Products Corporation | Method for making ultrafine metal powder |
US4625400A (en) * | 1983-07-06 | 1986-12-02 | Olin Corporation | Method of making a strip for an electrical contact terminal |
US4723589A (en) * | 1986-05-19 | 1988-02-09 | Westinghouse Electric Corp. | Method for making vacuum interrupter contacts by spray deposition |
DE68908057T2 (en) * | 1988-09-14 | 1993-11-18 | Hitachi Chemical Co Ltd | Process for producing a metallic strip coated with flame-sprayed ceramic. |
US4966224A (en) * | 1988-09-20 | 1990-10-30 | Olin Corporation | Substrate orientation in a gas-atomizing spray-depositing apparatus |
US4945973A (en) * | 1988-11-14 | 1990-08-07 | Olin Corporation | Thermal conductivity of substrate material correlated with atomizing gas-produced steady state temperature |
US4926927A (en) * | 1988-09-20 | 1990-05-22 | Olin Corporation | Vertical substrate orientation for gas-atomizing spray-deposition apparatus |
WO1990003236A1 (en) * | 1988-09-20 | 1990-04-05 | Olin Corporation | Substrate for use in spray-deposited strip production |
US4938278A (en) * | 1988-09-20 | 1990-07-03 | Olin Corporation | Substrate for use in spray-deposited strip |
US4917170A (en) * | 1988-09-20 | 1990-04-17 | Olin Corporation | Non-preheated low thermal conductivity substrate for use in spray-deposited strip production |
US4977950A (en) * | 1989-03-13 | 1990-12-18 | Olin Corporation | Ejection nozzle for imposing high angular momentum on molten metal stream for producing particle spray |
US4907639A (en) * | 1989-03-13 | 1990-03-13 | Olin Corporation | Asymmetrical gas-atomizing device and method for reducing deposite bottom surface porosity |
US4925103A (en) * | 1989-03-13 | 1990-05-15 | Olin Corporation | Magnetic field-generating nozzle for atomizing a molten metal stream into a particle spray |
US4901784A (en) * | 1989-03-29 | 1990-02-20 | Olin Corporation | Gas atomizer for spray casting |
US5240061A (en) * | 1990-12-28 | 1993-08-31 | Osprey Metals Limited | Substrate for spray cast strip |
US5476725A (en) * | 1991-03-18 | 1995-12-19 | Aluminum Company Of America | Clad metallurgical products and methods of manufacture |
JPH05135787A (en) * | 1991-03-28 | 1993-06-01 | Ngk Insulators Ltd | Manufacture of solid electrolyte film and manufacture of solid electrolyte fuel cell |
US5881645A (en) * | 1992-09-10 | 1999-03-16 | Lenney; John Richard | Method of thermally spraying a lithographic substrate with a particulate material |
JPH0841621A (en) * | 1994-05-25 | 1996-02-13 | Aisin Seiki Co Ltd | Production of friction plate and production of ring-shaped friction plate |
AU3230195A (en) * | 1994-08-18 | 1996-03-14 | Horsell Graphic Industries Limited | Improvements in and relating to the manufacture of printing plates |
KR19980703106A (en) * | 1995-03-17 | 1998-10-15 | 악커만 요아힘, 쿤켈 디트마르 | Thermal deposition method and related apparatus for depositing thin ceramic layer |
US5942289A (en) * | 1997-03-26 | 1999-08-24 | Amorphous Technologies International | Hardfacing a surface utilizing a method and apparatus having a chill block |
US8828155B2 (en) | 2002-12-20 | 2014-09-09 | Crucible Intellectual Property, Llc | Bulk solidifying amorphous alloys with improved mechanical properties |
US7896982B2 (en) * | 2002-12-20 | 2011-03-01 | Crucible Intellectual Property, Llc | Bulk solidifying amorphous alloys with improved mechanical properties |
WO2004059019A1 (en) * | 2002-12-20 | 2004-07-15 | Liquidmetal Technologies, Inc. | Pt-BASE BULK SOLIDIFYING AMORPHOUS ALLOYS |
US7147446B2 (en) * | 2003-01-02 | 2006-12-12 | Weyerhaeuser Company | Crosslinking agent application method and system |
WO2014078535A1 (en) * | 2012-11-15 | 2014-05-22 | David Payne | Methods for applying aluminum coating layers to a core of copper wire |
US11371108B2 (en) | 2019-02-14 | 2022-06-28 | Glassimetal Technology, Inc. | Tough iron-based glasses with high glass forming ability and high thermal stability |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3310870A (en) * | 1967-03-28 | Process for producing nickel-coated steel | ||
US2129702A (en) * | 1934-05-05 | 1938-09-13 | Joseph M Merie | Process for making metal products |
US2289311A (en) * | 1940-03-06 | 1942-07-07 | Sk Wellman Co | Composite blank and method of shaping |
US2490543A (en) * | 1945-06-27 | 1949-12-06 | Gen Motors Corp | Method of making composite stock |
US2639490A (en) * | 1948-08-12 | 1953-05-26 | Joseph B Brennan | Formation of metal strip under controlled pressures |
US2864137A (en) * | 1952-10-25 | 1958-12-16 | Helen E Brennan | Apparatus and method for producing metal strip |
US3025182A (en) * | 1957-03-05 | 1962-03-13 | Kanthal Ab | Formation of corrosion-resistant metallic coatings by so-called flame-spraying techniques |
US3221392A (en) * | 1960-09-28 | 1965-12-07 | Federal Mogul Bower Bearings | Method of making bearings |
US3378392A (en) * | 1963-07-24 | 1968-04-16 | Metco Inc | High temperature flame spray powder and process |
US3652317A (en) * | 1970-05-01 | 1972-03-28 | Getters Spa | Method of producing substrate having a particulate metallic coating |
-
1970
- 1970-12-28 US US00101954A patent/US3742585A/en not_active Expired - Lifetime
-
1971
- 1971-12-15 CA CA130,222A patent/CA944632A/en not_active Expired
- 1971-12-18 IT IT54851/71A patent/IT945535B/en active
- 1971-12-20 BE BE776976A patent/BE776976A/en unknown
- 1971-12-20 DE DE19712163190 patent/DE2163190A1/en active Pending
- 1971-12-21 GB GB5922271A patent/GB1357770A/en not_active Expired
- 1971-12-27 FR FR7146741A patent/FR2120899A5/fr not_active Expired
Also Published As
Publication number | Publication date |
---|---|
IT945535B (en) | 1973-05-10 |
CA944632A (en) | 1974-04-02 |
BE776976A (en) | 1972-04-17 |
US3742585A (en) | 1973-07-03 |
GB1357770A (en) | 1974-06-26 |
FR2120899A5 (en) | 1972-08-18 |
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