DE2163190A1 - Process for making metal strips from metal powder - Google Patents

Process for making metal strips from metal powder

Info

Publication number
DE2163190A1
DE2163190A1 DE19712163190 DE2163190A DE2163190A1 DE 2163190 A1 DE2163190 A1 DE 2163190A1 DE 19712163190 DE19712163190 DE 19712163190 DE 2163190 A DE2163190 A DE 2163190A DE 2163190 A1 DE2163190 A1 DE 2163190A1
Authority
DE
Germany
Prior art keywords
metal
foil
molten
film
cooled
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
DE19712163190
Other languages
German (de)
Inventor
Joseph M. Remsen N.Y. Wentzell (V.StA.). P
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Homogeneous Metals Inc
Original Assignee
Homogeneous Metals Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Homogeneous Metals Inc filed Critical Homogeneous Metals Inc
Publication of DE2163190A1 publication Critical patent/DE2163190A1/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/12Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the method of spraying
    • C23C4/14Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the method of spraying for coating elongate material
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/12Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the method of spraying
    • C23C4/137Spraying in vacuum or in an inert atmosphere
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S29/00Metal working
    • Y10S29/039Spraying with other step
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T29/00Metal working
    • Y10T29/49Method of mechanical manufacture
    • Y10T29/49636Process for making bearing or component thereof
    • Y10T29/49705Coating or casting
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T29/00Metal working
    • Y10T29/49Method of mechanical manufacture
    • Y10T29/4981Utilizing transitory attached element or associated separate material
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T29/00Metal working
    • Y10T29/49Method of mechanical manufacture
    • Y10T29/4998Combined manufacture including applying or shaping of fluent material
    • Y10T29/49982Coating
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T29/00Metal working
    • Y10T29/49Method of mechanical manufacture
    • Y10T29/4998Combined manufacture including applying or shaping of fluent material
    • Y10T29/49988Metal casting
    • Y10T29/49991Combined with rolling

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Continuous Casting (AREA)
  • Coating By Spraying Or Casting (AREA)

Description

Dr.-lng. E. BERKENFELD · Dipl.-Ing. H. BERKENFELD, Patentanwälte, KölnDr.-lng. E. BERKENFELD · Dipl.-Ing. H. BERKENFELD, patent attorneys, Cologne Anlage AktenzeichenAttachment file number

zur Eingabe vom 3. Ι>βΖΘΙΐΛ>βΓ 1971 VA// Name d. Anm. HOMOGENEOUS METALS, INC<for entering the 3rd Ι> βΖΘΙΐΛ> βΓ 1971 VA // Name of d. Note: HOMOGENEOUS METALS, INC <

Verfahren zum Herstellen von Metallstreifen aus Metallpulver Process for making metal strips from metal powder

Die Erfindung bezieht sich auf Verfahren zum Herstellen von Metallstreifen aus Metallpulver und insbesondere auf ein Verfahren zum Herstellen von Superlegierungsstreifen aus Metallpulver, obwohl das Verfahren auch auf andere Legierungen Anwendung finden kanno The invention relates to methods of making metal strips from metal powder and, more particularly, to a method of making superalloy strips from metal powder, although the method can apply to other alloys and the like

Gewöhnlich werden die als Superlegierungen bekannten Metalle, das heißt Legierungen aus Eisen, Nickel oder Kobalt, welche ihre nützelichen mechanischen Eigenschaften bei erhöhten Temperaturen beibehalten, in Barren gegossen, welche dann zu Tafeln geschmiedet oder ausgewalzt, zerschnitten und konditioniert werden, hierauf zu Bändern oder Platten ausgewalzt, wieder konditioniert und schließlich zu Streifen ausgewalzt und zerschnitten werden. Während des Prozesses sind mehrere Hitzebehandlungen erforderlich, sowie eine abschließende Hitzebehandlung, je nach den Anforderungen des Kunden«, Alle diese Behandlungen kosten Zeit und Geld. Viel wichtiger ist aber die Tatsache, daß dieses große Ausmaß der Heißbearbeitung den Borgehalt der Superlegierung durch Oxydation zu erschöpfen trachtet. Bor ist wesentlich für den Bruchbelastungswiderstand bei erhöhter Temperatur. Usually the metals known as superalloys, i.e. alloys of iron, nickel or cobalt, are their Maintaining useful mechanical properties at elevated temperatures, pouring them into bars, which are then made into sheets forged or rolled out, cut up and conditioned, then rolled out into strips or plates, conditioned again and finally rolled out and cut into strips. During the process there are several heat treatments required, as well as a final heat treatment, depending on the customer's requirements. ”All of these treatments cost Time and money. Much more important, however, is the fact that this large amount of hot working reduces the boron content of the superalloy seeks to exhaust itself by oxidation. Boron is essential for breaking load resistance at elevated temperatures.

Bleche und Streifen aus Nickel, Aluminium und Eisen sind direkt aus Metallpulver ausgewalzt worden, indem das Pulver durch ein Walzwerk zugeführt wurde, dessen Walzen in einer waagerechten Ebene angeordnet waren. Wenn Streifen auf diese Weise ausgewalzt werden, ist es notwendig, daß die Anfangsfestigkeit des Streifens ausreichend ist, um eine spätere Verarbeitung zu ermöglichen. Dies bedeutet, daß das Pulver eine spezielle FormSheets and strips of nickel, aluminum and iron have been rolled out directly from metal powder by passing the powder through a Rolling mill was fed, the rollers of which were arranged in a horizontal plane. When strips are rolled out this way it is necessary that the initial strength of the strip is sufficient to allow later processing. This means that the powder has a special shape

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aufweisen muß, welche zu einer hohen Anfangsfestigkeit beitragen kann. Superlegierungspulver von hoher Reinheit werden im allgemeinen durch ein Trockenverfahren hergestellt, das ein kugelförmiges Pulver ergibt, welches eine schlechte Zusammendrückbarkeit in kaltem Zustand aufweist und dem daher die zur Erzielung d?r Anfangsfestigkeit notwendige spezielle Form mangelt»must have, which can contribute to a high initial strength. High purity superalloy powders are used in the generally produced by a dry process which gives a spherical powder which has poor compressibility when cold and therefore lacks the special shape necessary to achieve initial strength »

Die Aufgabe der Erfindung besteht in der Ausbildung eines Verfahrens zum Herstellen von Metallstreifen aus Metallpulver, welches die Herstellung des Streifens aus Pulver ohne Rücksicht auf dessen Form ermöglicht» Gemäß diesem Verfahren wird das Metallpulver durch eine Plasmaspritzpistole oder eine ähnliche Metallisierungspistole auf eine Unterlage aus Aluminium, Kupfer oder einen Streifen oder eine Folie aus Eisen aufgebracht, wobei die Folie sich in innigem Kontakt mit einem Kühlelement zu dem Zeitpunkt befindet, in dem die heißen Metallteilchen auf die Unterlage aufgespritzt werden» Der Metallspritzvorgang wird in einer inerten Atmosphäre ausgeführt, zum Beispiel in einer mit einem inerten Gas gespülten Kammero Die gespritzte Folie wird vorzugsweise auf eine vorher bestimmte Verdünnung kalt gewalzt und dann wieder gespritzt, wenn eine größere Dicke gewünscht wird. Die Menge des aufgebrachten Spritzmetalls und das Ausmaß des Kaltwalzens sind von der besonderen Legierung und der gewünschten Dicke abhängig» Jedes nachfolgende Bespritzen oder Metallisieren nach dem Walzen wird die Spannung des Streifens entlasten. Da die ganze Hitzebehandlung in einer inerten Atmosphäre ausgeführt wird, ist die Oxydation eliminierte Die Unterlage kann von dem fertigen Streifen vorzugsweise durch Ätzen entfernt werden, indem beispielsweise Hydroxyd für eine Aluminiumfolie und Salpetersäure für Kupfer oder Eisen verwendet wird»The object of the invention is to develop a method for manufacturing metal strips from metal powder, which enables the strip to be manufactured from powder regardless of its shape. Copper or a strip or foil made of iron, the foil being in intimate contact with a cooling element at the time the hot metal particles are sprayed onto the substrate Chamber flushed with an inert gas o The sprayed film is preferably cold-rolled to a predetermined dilution and then sprayed again if a greater thickness is desired. The amount of spray metal applied and the extent of cold rolling will depend on the particular alloy and thickness desired. Any subsequent spraying or plating after rolling will relieve the tension on the strip. Since the entire heat treatment is carried out in an inert atmosphere, the oxidation is eliminated. The base can be removed from the finished strip, preferably by etching, using, for example, hydroxide for an aluminum foil and nitric acid for copper or iron »

Die Erfindung betrifft daher ein Verfahren zum Herstellen von Metallstreifen aus Metallpulver, bei welchem das Pulver als geschmolzenes Metall auf eine gekühlte, bewegte Metallfolie aufgespritzt wird, worauf die Folie und das aufgespritzte MetallThe invention therefore relates to a method for producing metal strips from metal powder, in which the powder is molten Metal is sprayed onto a cooled, moving metal foil, whereupon the foil and the sprayed-on metal

209829/0933209829/0933

durch Druckeinwirkung verfestigt werden.solidified by the action of pressure.

In der vorstehenden allgemeinen Beschreibung sind bestimmte Aufgaben, Merkmale und Vorteile der Erfindung angegeben. Weitere Aufgaben, Merkmale und Vorteile ergeben sich aus der nachstehenden Beschreibung unter Bezugnahme auf die Zeichnung,■in welcher zeigt:In the above general description, certain tasks are Features and advantages of the invention indicated. Further objects, features and advantages emerge from the following Description with reference to the drawing, ■ in which shows:

Fig. 1 schematisch einen Längsschnitt durch eine Vorrichtung zur Ausführung des Verfahrens gemäß der Erfindung und1 schematically shows a longitudinal section through an apparatus for carrying out the method according to the invention and

Fig. 2 einen Längsschnitt eines Streifens, der gemäß der Erfindung aus Metallpulver hergestellt ist.Figure 2 is a longitudinal section of a strip made according to the invention is made of metal powder.

In Fig. 1 ist ein Blech oder eine Folie 10 dargestellt, die von einer Rolle 11 durch eine Dichtung 12 in das Innere einer Kammer 13 eingeführt wird, in welcher dieselbe über eine wassergekühlte Walze 14 hinweggeht«, Die Folie 10 wird mit geschmolzener Superlegierung 15 durch eine Plasmaspritzpistole 16 bespritzt, der die pulverförmige Superlegierung aus einem Trichter 17 zugeführt wird. Die geschmolzene Superlegierung 15 erstarrt auf der Folie 10, um eine Schicht der Superlegierungzu bilden, welche zwischen Druckwalzen 18 hindurchgeführt wird, um den neu gebildeten Superlegierungsstreifen 15 kalt zu k walzen«.In Fig. 1, a sheet or a film 10 is shown, which is from a roll 11 through a seal 12 in the interior of a chamber 13 is introduced, in which the same passes over a water-cooled roller 14. The foil 10 is made with molten superalloy 15 sprayed by a plasma spray gun 16, which is supplied with the powdery superalloy from a funnel 17 will. The molten superalloy 15 solidifies on the foil 10 to form a layer of the superalloy which is between Pressure rollers 18 are passed through to the newly formed superalloy strip 15 to be rolled cold «.

Wenn eine größere Dicke des Streifens 15 gewünscht wird, als bei einem Durchgang vor der Plasmaspritzpistole 16 aufgebracht werden kann, wird der Überzugsvorgang einfach sooft wiederholt wie notwendig ist. Durch das Aufspritzen der geschmolzenen Superlegierung auf den Streifen 15 wird die vorher gebildete Schicht von Spannung entlastet, ohne daß die Gefahr der Oxydation besteht. If a greater thickness of the strip 15 is desired than would be applied in one pass in front of the plasma spray gun 16 the coating process is simply repeated as often as necessary. By spraying the molten superalloy the previously formed layer on the strip 15 is relieved of tension without the risk of oxidation.

Wenn die Unterlage 10 entfernt werden soll, wird der zusammengesetzte Streifen durch eine entsprechende Ätzlösung hindurchge- When the base 10 is to be removed, the assembled strip is passed through an appropriate etching solution.

20932 9/093320932 9/0933

führt, um die Unterlage von dem Superlegierungsstreifen 15 nach dem Kaltwalzen wegzulösen.leads to peel the backing away from the superalloy strip 15 after cold rolling.

Die Erfindung ist nicht auf die dargestellte und beschriebene beispielsweise Ausführungsform beschränkt, die verschiedene Abänderungen erfahren kann, ohne den Rahmen der Erfindung zu verlassen. The invention is not limited to the illustrated and described exemplary embodiment, which has various modifications can experience without departing from the scope of the invention.

Patentansprüche ;Claims;

2 0 9 3 2 9 / 0 9 3 32 0 9 3 2 9/0 9 3 3

Claims (1)

Dr.-lng. E. BERKENFELD · Dipl.-Ing. H. BERKENFELD, Patentanwälte, KölnDr.-lng. E. BERKENFELD · Dipl.-Ing. H. BERKENFELD, patent attorneys, Cologne Anlage AktenzeichenAttachment file number zur Eingabe vom 3. Dezember 1971 VA// Named.Anm. HOMOGENEOUS METALS, INC on the submission of December 3, 1971 VA // Named.Anm. HOMOGENEOUS METALS, INC PATENTANSPR Ü C H E PATENT CLAIMS 1. Verfahren zum Herstellen von Metallstreifen aus Metallpulver, gekennzeichnet durch die folgenden Schritte:1. A method for producing metal strips from metal powder, characterized by the following steps: a) die Umwandlung eines Metallpulvers in ein geschmolzenes Spritzmetall,a) the transformation of a metal powder into a molten spray metal, b) die Aufbringung des geschmolzenen Spritzmetalls auf eine bewegte Metallfolie in einer im wesentlichen gleichmäßigen Schicht,b) the application of the molten spray metal to a moving metal foil in an essentially uniform layer, c) die Abkühlung der Metallfolie und des auf dieselbe aufgebrachten geschmolzenen Spritzmetalls, um dasselbe zum Erstarren zu bringen, undc) the cooling of the metal foil and that applied to it molten spray metal to solidify it, and d) die Verfestigung der Folie und des aufgespritzten Metalls durch Einwirkung von Druck auf dieselben.d) the solidification of the film and the sprayed-on metal by the action of pressure on the same. 2o Verfahren nach Anspruch 1, dadurch gekennzeichnet, daß die Folie gleichzeitig mit der Aufbringung des geschmolzenen Spritzmetalls auf dieselbe gekühlt wird.2o method according to claim 1, characterized in that the foil is cooled simultaneously with the application of the molten spray metal to the same. 3. Verfahren nach Anspruch 1, dadurch gekennzeichnet, daß die Folie mit dem Spritzmetall überzogen und in einer inerten Atmosphäre gekühlt wird.3. The method according to claim 1, characterized in that the film is coated with the spray metal and in an inert Atmosphere is cooled. 4. Verfahren nach Anspruch 1, dadurch gekennzeichnet, daß die Folie aus einem Metall besteht, das aus der Gruppe ausgewählt wird, welche Aluminium, Nickel, Kupfer und Eisen enthält,,4. The method according to claim 1, characterized in that the foil consists of a metal selected from the group which contains aluminum, nickel, copper and iron, 5„ Verfahren nach Anspruch 1, dadurch gekennzeichnet, daß das Metall durch Walzen unter Druck verfestigt wird.5 "The method according to claim 1, characterized in that the metal is solidified by rolling under pressure. 6. Verfahren nach Anspruch 1, dadurch gekennzeichnet, daß das Metallpulver durch eine Plasmaspritzpistole hindurchgeht, um ein geschmolzenes Spritzmetall zu bilden,6. The method according to claim 1, characterized in that the metal powder passes through a plasma spray gun to form a molten spray metal, 7. Verfahren nach Anspruch 1, dadurch gekennzeichnet, daß die Folie nach der Verfestigung des Metalls durch Ätzen entfernt wird.7. The method according to claim 1, characterized in that the film is removed by etching after solidification of the metal will. 8. Verfahren nach Anspruch 1, dadurch gekennzeichnet, daß die Folie in einer inerten Atmosphäre über eine wassergekühlte Walze hinweggeht und daß das geschmolzene Metall auf die Folie aufgespritzt wird, während sich dieselbe auf der wassergekühlten Walze befindete8. The method according to claim 1, characterized in that the film in an inert atmosphere via a water-cooled Roll goes away and that the molten metal is splashed onto the foil, while the same is on the water-cooled Roller
DE19712163190 1970-12-28 1971-12-20 Process for making metal strips from metal powder Pending DE2163190A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US10195470A 1970-12-28 1970-12-28

Publications (1)

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DE2163190A1 true DE2163190A1 (en) 1972-07-13

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DE19712163190 Pending DE2163190A1 (en) 1970-12-28 1971-12-20 Process for making metal strips from metal powder

Country Status (7)

Country Link
US (1) US3742585A (en)
BE (1) BE776976A (en)
CA (1) CA944632A (en)
DE (1) DE2163190A1 (en)
FR (1) FR2120899A5 (en)
GB (1) GB1357770A (en)
IT (1) IT945535B (en)

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US2864137A (en) * 1952-10-25 1958-12-16 Helen E Brennan Apparatus and method for producing metal strip
US3025182A (en) * 1957-03-05 1962-03-13 Kanthal Ab Formation of corrosion-resistant metallic coatings by so-called flame-spraying techniques
US3221392A (en) * 1960-09-28 1965-12-07 Federal Mogul Bower Bearings Method of making bearings
US3378392A (en) * 1963-07-24 1968-04-16 Metco Inc High temperature flame spray powder and process
US3652317A (en) * 1970-05-01 1972-03-28 Getters Spa Method of producing substrate having a particulate metallic coating

Also Published As

Publication number Publication date
IT945535B (en) 1973-05-10
CA944632A (en) 1974-04-02
BE776976A (en) 1972-04-17
US3742585A (en) 1973-07-03
GB1357770A (en) 1974-06-26
FR2120899A5 (en) 1972-08-18

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