DE214715C - - Google Patents
Info
- Publication number
- DE214715C DE214715C DE1908214715D DE214715DA DE214715C DE 214715 C DE214715 C DE 214715C DE 1908214715 D DE1908214715 D DE 1908214715D DE 214715D A DE214715D A DE 214715DA DE 214715 C DE214715 C DE 214715C
- Authority
- DE
- Germany
- Prior art keywords
- etching
- thioindigo
- glucose
- soda
- carbohydrates
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000005530 etching Methods 0.000 claims description 5
- WQZGKKKJIJFFOK-GASJEMHNSA-N D-Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims description 4
- 229940097275 Indigo Drugs 0.000 claims description 4
- 235000000177 Indigofera tinctoria Nutrition 0.000 claims description 4
- JOUDBUYBGJYFFP-FOCLMDBBSA-N Thioindigo Chemical compound S\1C2=CC=CC=C2C(=O)C/1=C1/C(=O)C2=CC=CC=C2S1 JOUDBUYBGJYFFP-FOCLMDBBSA-N 0.000 claims description 4
- 150000001720 carbohydrates Chemical class 0.000 claims description 4
- 235000014633 carbohydrates Nutrition 0.000 claims description 4
- 239000008103 glucose Substances 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- 239000003513 alkali Substances 0.000 claims description 3
- 239000000975 dye Substances 0.000 claims description 3
- 240000007871 Indigofera tinctoria Species 0.000 claims 1
- 239000003518 caustics Substances 0.000 claims 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N Carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 3
- 241001062009 Indigofera Species 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- GUBGYTABKSRVRQ-YOLKTULGSA-N Maltose Natural products O([C@@H]1[C@H](O)[C@@H](O)[C@H](O)O[C@H]1CO)[C@@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 GUBGYTABKSRVRQ-YOLKTULGSA-N 0.000 description 2
- XOLBLPGZBRYERU-UHFFFAOYSA-N Tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 2
- 229920000591 gum Polymers 0.000 description 2
- 239000003638 reducing agent Substances 0.000 description 2
- 229910001887 tin oxide Inorganic materials 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- -1 B. maltose Chemical class 0.000 description 1
- FYGDTMLNYKFZSV-MRCIVHHJSA-N Dextrin Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)OC1O[C@@H]1[C@@H](CO)OC(O[C@@H]2[C@H](O[C@H](O)[C@H](O)[C@H]2O)CO)[C@H](O)[C@H]1O FYGDTMLNYKFZSV-MRCIVHHJSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000008121 dextrose Substances 0.000 description 1
- GRWZHXKQBITJKP-UHFFFAOYSA-L dithionite(2-) Chemical class [O-]S(=O)S([O-])=O GRWZHXKQBITJKP-UHFFFAOYSA-L 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N tin hydride Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 239000000984 vat dye Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/15—Locally discharging the dyes
- D06P5/155—Locally discharging the dyes with reductants
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Coloring (AREA)
Description
KAISERLICHESIMPERIAL
PATENTAMT.PATENT OFFICE.
PATENTSCHRIFTPATENT LETTERING
KLASSE Sn. GRUPPECLASS Sn. GROUP
Verfahren zum Ätzen von Thioindigo- und Indigofarbstoffen.Process for etching thioindigo and indigo dyes.
Patentiert im Deutschen Reiche vom 27. März 1908 ab.Patented in the German Empire on March 27, 1908.
Im Patent 213474 ist ein Verfahren zum
Ätzen von Thioindigo- und Indigofarbstoffen unter Verwendung einer Ätzfarbe aus Zinnoxydul
und Alkali beschrieben.
Es wurde nun gefunden, daß man in diesem Verfahren als Reduktionsmittel statt Zinnoxydul
auch. Traubenzucker oder ähnliche Kohlehydrate in Gegenwart von Alkali verwenden
kann. Diese Mittel sind bisher nur zu dem entgegengesetzten Zweck, nämlich
zum Fixieren von Küpenfarbstoffen beim Färben oder Drucken, benutzt worden.Patent 213474 describes a method for etching thioindigo and indigo dyes using an etching color made from tin oxide and alkali.
It has now been found that the reducing agent used in this process is instead of tin oxide. Can use glucose or similar carbohydrates in the presence of alkali. These agents have hitherto only been used for the opposite purpose, namely to fix vat dyes during dyeing or printing.
Gegenüber den bisher zum Ätzen von Indigo und Thioindigo benutzten Reduktionsmitteln, den Hydrosulfiten (vgl. Patentschrift 194878 und Lehnes Färberzeitung, 1907, S. 33) sowie gegenüber anderen alkalischen Ätzmitteln und auch dem in dem vorerwähnten Patent benutzten Zinnoxydulalkali haben die Kohlehydrate den Vorteil eines besonders billigen Preises.Compared to the reducing agents previously used to etch indigo and thioindigo, the hydrosulfites (see patent 194878 and Lehnes Färberzeitung, 1907, p. 33) as well as other alkaline etchants and also the tin oxydulalkali used in the aforementioned patent Carbohydrates have the advantage of a particularly cheap price.
Auch das vorliegende Verfahren eignet sich sowohl für Weiß- wie auch für Buntätzen.The present method is also suitable for both white and colored etching.
Beispiel 650 g Gummiverdickung 1:1,Example 650 g rubber thickening 1: 1,
100 g Wasser,
200 g Natronlauge 40 ■
50 g Traubenzucker100 g water,
200 g caustic soda 40 ■
50 g of glucose
Be., kalt zusammen gegeben.Be., Given together cold.
1000 g1000 g
900 g Soda-Gummiverdickung, 50 g Traubenzucker,
50 g Wasser Soda-Gummiverdickung:
ι Teil Britishgum,
ι Teil Sodalösung 20 Prozent.900 g soda gum thickening, 50 g dextrose,
50 g water soda gum thickening:
ι part of Britishgum,
ι Part soda solution 20 percent.
iooo g.iooo g.
An Stelle von Traubenzucker können andere, ähnlich wirkende Kohlehydrate, z. B. Maltose, verwendet werden.Instead of glucose, other, similarly acting carbohydrates, e.g. B. maltose, be used.
Im übrigen arbeitet man wie bei dem Verfahren des Patentes 213474.The rest of the procedure is the same as for the method of patent 213474.
Claims (1)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT47414D AT47414B (en) | 1908-03-26 | 1909-03-08 | Process for etching thioindigo and indigo dyes. |
Publications (1)
Publication Number | Publication Date |
---|---|
DE214715C true DE214715C (en) |
Family
ID=476277
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE1908214715D Expired - Lifetime DE214715C (en) | 1908-03-26 | 1908-03-26 |
Country Status (1)
Country | Link |
---|---|
DE (1) | DE214715C (en) |
-
1908
- 1908-03-26 DE DE1908214715D patent/DE214715C/de not_active Expired - Lifetime
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