DE2122264A1 - - Google Patents

Description

fiauleionen

Priorities: 5-5.1970 and 26.4.1971 - Great Britain

The invention relates to improved emulsions of dyes and textile finishes in halogenated hydrocarbons « solvents and the use of such emulsions in the dyeing and finishing of tertiary fabrics.

It is known to produce dyes and finishes with the aid of organic solvents, such as halogenated hydrocarbons, to be applied to textile materials. tuck

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Application methods have been used as an alternative to the traditional

developed process carried out with aqueous media, namely from Reasons of economy, keeping water bodies clean or avoiding wastewater problems. However that is Number of dyes or finishes used in such solutions agents are sufficiently soluble, and it is therefore usually necessary to use the dye or the finish in To use the form of a dispersion or emulsion in the solvent. A known method for making such dispersions or emulsions, consists in that one an aqueous solution or dispersion with the aid of a suitable Produces emulsifier in organic solvent.

It has now been found that a combination of ethyl hydroxy ethyl cellulose with an anionic surfactant makes a particularly good emulsifier for this purpose.

Therefore, a stabilized emulsion of an aqueous solution or an aqueous dispersion according to the invention it is proposed a dye or textile finish in a halogenate hydrocarbon solvent which iat _{characterized%} that the emulsion as emulsifiers Äthylhydroxyäthyl »b © llulos © \ m & at least one anionic oberflächenaktive® Hittal contains.

With the expression "It & jl-Jsydroxyafc ^ l-zellwlose" is a mixed cellulose ether g @ m © Iir & _% d @ r is produced by, © is ¥ ®rfahren, bsi the dl® following three l © aktion®a

(1.) Alkali cellulose image, whereby the cellulose is gecp3.GlI © a wijcds
Zeil -OH + WaOH ^ sä Zeil - QIg *

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(2.) Reaction of cellulose with ethylene oxide in the presence of an alkali: ~ _NaCH
Zeil - OH + CH ^ CH ₂ £ Zeil -

(3 ·) Ethylation of cellulose and hydroxyethyl cellulose: (a) Zeil - OCH ₂ CH ₂ OH + NaOH +

Zeil - O CHoCHoOCoHc + NaCl + H ₂ C

(b) Zeil - OH + NaOH + C ₂ H ₅ Cl- ^ ZeIl -

NaCl + H ₂ O

Atnyl-hydroxyethyl-cellulose can accordingly be defined as cellulose in which most of the hydroxyl groups are converted into ethyl ether groups or ethoxyethyl ether groups. Ethyl-hydroxyethyl cellulose is commercially available in different grades depending on the molecular weight. These varieties can are characterized by their solution viscosities, which range from 10 cp to 230 cp, measured on a 5% (weight) Solution of ethyl hydroxyethyl cellulose in a toluene / ethanol mixture with a weight ratio of 80:20. Every type of ethyl-hydroxyethyl-cellulose is for use in the Emulsions according to the invention are suitable, but are types with a solution viscosity as defined above of 20 to 35 cp is preferred.

Anionic surfactant gowns that are suitable for use Suitable in the emulsions according to the invention are e.g. Castor oil, which is commonly used with the Collective names "Turkish red oil" are referred to, salts of sulfated ffethyl oleate, salts of dodecylbenzene sulfonic acid, Salts of oleic and linoleic acids, salts of tall oil, salts of Sulphated mixtures of oleyl and cetyl alcohols and Salts of oleyl p-anisidide sulfonic acid and oleyl sarcoside,.

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in particular the sodium salts thereof. It can either a single anionic surfactant or a mixture of two or more such agents can be used.

Halogenated hydrocarbon solvents which can be used in the emulsions according to the invention are e.g. Trichlorethylene, perehloroethylene, 1,1,1-trichloroethane, Carbon tetrachloride, chloroform, monochlorobenzene and 1,2,4-trichlorobenzene.

Dyes which can be incorporated into the emulsions of the present invention are, for example, the dyes of those well known Classes, wi® e.g. acidic, basic, direct, reactive or disperse dyes, as they are commonly used for dyeing textile materials made of polyamide, Put cotton, wool, silk, acetate, polyester, viscose or acrylic fibers or threads together.

Textile finishes which can be incorporated into the emulsions according to the invention are, for example, fluorescent optical ones. Brighteners, such as the sodium salts of Bls-triazinylaminostilbene-disulfonic acids, waterproofing agents, such as stearamido-methylpyridinium chloride and N-methylolstearamide, anti-crease resins, such as dimethyloldihydroacy-ethylene urea, antistatic and repellent agents, such as, for example Condensates of ethylene oxide with polyamides, crystallizable polyesters containing polyoxyalkylene groups, such as polyoxyalkylene terephthalate / polyalkylene terephthalate block copolymers and copolymers of polymerizable acids, such as acrylic acid, with other polymerizable vinyl monomers, emollients, such as long-chain quaternary ammonium salts, such as, for example _, sizing agents , hardening agents or fire retardants such as ζ »Β« antimony oxide or mixtures of boric acid and borax.

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The emulsions according to the invention can thereby be produced be that one is a mixture of a halogenated hydrocarbon solvent and an aqueous solution or dispersion a dye or a textile finish in the presence of ethyl hydroxyethyl cellulose and at least one anionic surfactants subjected to appropriate mechanical agitation. · ■ · - -

The emulsifiers used, ie the ethyl-hydroxyethyl cellulose and the anionic coat or the anionic agents, can initially be present either in the halogenated hydrocarbon solvent or in the aqueous solution or dispersion of the dye or the finish or in both. In view of the solubility properties of ethyl-hydroxyethyl cellulose, especially with regard to the preferred variety of 20 to 35 cp, it will usually be expedient that this component is initially dissolved in the halogenated hydrocarbon solvent. The anionic agent or agents may initially be dissolved in either the solvent phase or the aqueous phase, but according to a well-known technique of emulsification using such agents, this agent can optionally be prepared in situ by reaction between an appropriate one organic acidic precursor, such as dodecylbenzenesulfonic acid, which is dissolved in the halogenated hydrocarbon solvent phase, and an alkali such as sodium hydroxide, which is dissolved in the aqueous phase.

The relative proportions of the halogenated hydrocarbon solvent and the aqueous phase which are in the Emulsions according to the invention are processed, can vary widely, and awar according to the species and catfish,

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in which the emulsions are applied to the fabric, and according to the type and solubility of the used "dye" or finishes. In general, however, the amount of water in the range from 0.3 to 20 0 ** .-%, based on the total weight of the emulsion.

The emulsions according to the invention are of particular value for the application of dyes or finishes Textile materials. In general, the emulsions on the textile materials by padding, exhausting or other customary impregnation processes and then Evaporation of the halogenated hydrocarbon solvent are applied, and if necessary, a heating treatment can follow to the dye or the To fix the finish on the textile material «The halogenated hydrocarbon solvent, which during Evaporated in this process can of course be recovered for reuse.

Textile materials to which the emulsions according to the invention can be applied are, for example, yarns and knitted, woven or non-woven fabric.

If one emulsions according to the invention instead of the conventional aqueous solutions or dispersions of dyes or T © © xtilappr®tur n used then _s esfaält to a number of il Vort © @ a _s B i © © s absatewoises Pr @ ss © B, the exhaustion

quicker w ^ lamfos, nat "bsi !! © tew ^ fatasm is the Bemstsmag Tb® @ s © £ O ¥@2?Ιΐ2.//ΐogle ia dos ³ B i © tele2psi © i? * 6 © a E © ai © & mg

al © UaSSgQg ¹ S, w © dua? eii ülo Eosj'öoa for the heating sis, ^ 7Qs? 2? iSiis © s? ii3 w®rd @ a and wödiarch also the organisclia

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Economically recovered liquid for reuse which avoids the difficulties encountered in treating aqueous effluents. Young Number of finishing treatments as well as dry cleaning treatments of textile materials are used in non-aqueous Media carried out, and in appropriate cases they can with the application of a treatment agent to the textile material be combined"

The excellent stability of the emulsions according to the invention is of particular advantage for such application processes. These emulsions show no noticeable separation of the organic and aqueous phases over a period of time of several days. In contrast, show emulsions with a similar composition, but only the Äthylhydroatyäthyl-cellulose contain as a stabilizer (i.e. that the anionic surfactant or the anionic surfactants are omitted) a considerable amount Separation after just one day. Worse results will also be obtained if you get one anionic agent used alone (i.e. omitting the ethyl hydroxyethyl cellulose). It is possible to have one to achieve a moderate degree of stability of the emulsions by that the concentration of the anionic compound is increased. But this often has a detrimental effect on the Subsequent use of the emulsion if certain types of fruit are used.

The invention will now be elucidated by means of the following examples explained. All parts and percentages are expressed by weight unless otherwise indicated.

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example 1

0.70 parts of the dye which is the disodium salt of 2- £ 2 · -acetylamino-4 · - (4 "-chloro-6" -eamino-1 ", 3", 5 "-triazine-2" -ylamino) phenylazo-naphthalene-4,8-disulfonic acid and 0.22 parts of caustic soda are dissolved in 13t3 parts of water, and 1.5 parts Turkish Eot Oil are then added and it is stirred until a solution has been obtained. 1.5 parts of ethyl hydroxyethyl cellulose with a viscosity of 20 to 35 cp (measured at 25 ° C on a 5% (weight) solution in 80:20 toluene / lthanol) are perchloroäthyXen in 132 parts dissolved. The solution is stirred vigorously while the dye solution is slowly added over the course of 5 minutes. Rapid stirring is continued for an additional 5 minutes, followed by 2 minutes is stirred slowly to allow the trapped air to escape. The resulting emulsion is excellent Stability.

A sample of cellulosic textile material is placed in the emulsion padded, dried and kept at 200 ° 0 for 1 min. The textile material is colored evenly in a yellow color.

If the above procedure is repeated but with the Turkish red oil is omitted and the amount of ethylhydroxyethyl cellulose is increased from 1.5 to 2.25 parts, the resulting emulsion is found to be a has considerably poorer stability. A separation of the aqueous phase can already be determined after 18 to 20 hours, whereas the emulsion, which contains both ethyl hydroxyethyl cellulose as well as Turkish Eot Oil, shows no separation for at least 10 days.

If the above procedure is repeated, where

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However, the ethyl-hydroxyethyl-cellulose is omitted and the amount of Turkish red oil increased from 1.5 parts to 3 parts a good emulsion is initially obtained, but this already shows a separation after 3 days the aqueous phase.

Example 2

The procedure of Example 1 is repeated, with the difference that instead of the dye Π described there, 1 part of the dye is used, which is the trisodium salt of copper phthalocyanine-3- (sulfonic acid), -3- | N - (ß-6 ^l ~ chloro-4- ^? -methoxy-1 ', 3'»5'-triazine-2 · -ylamino) ethyl] sulfonamides.

Cellulose textile materials made with this stable emulsion are evenly colored in a turquoise shade.

Example 3

The procedure of Example 1 is repeated, except that 0.75 part of a dye is used instead of the dye indicated therein, which is the tetrasodium salt of 1- {2 ·, 5'-diinethyl-V- [4 - "- (4 ^f "-chloro-6 '" -amino * "·, y ·', 5 '" -triazine-2 ¹ ·' -ylamino ^ -sulfoiiaphth - ^^ azoj -naphthalene-2,5,7-trisulfonic acid .

Cellulosic textile material, is.a with the stable obtained Emulsion is treated is colored evenly in an orange-brown color.

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Example 4

The procedure of Example 1 is repeated, with the difference that the perchlorethylene by an equal weight 1,1,1-trichloroethane is replaced. It'll be back Obtained emulsion with excellent stability.

Example 5

The procedure of Example 1 is repeated, with the difference that the perehloroethylene is replaced by an equal weight of trlehloroethylene. Eb becomes an emulsion with a preferred stability

Example 6

1.4 parts of the dye of Example 1 and 0.45 parts of caustic soda are dissolved in 26.6 parts of water. 1.5 parts Ethyl hydroxyethyl cellulose with a viscosity of 20 to 35 cp, measured as in Example 1, are in 132 parts Perchlorethylene dissolved, and 1.0 part tall oil is added, then see the addition of 0.5 part triethanolamine closes® Bi © solution is stirred gently while di © FaÄstofflognisg is closed drop by drop as quickly as possible «. The © seteell ©! ÜJir © ® will continue for a further 5 min.

Baaa witu- ? aia langgam g @ rüfert ₉ um an Entd®s · IsQ £ t evl g © instead of © a _o Until yasiiltierende © ia © foraugiiehs stability namä kaaa sum

wi® @s in B © lspi @ l 1 besetoi®fe © a 1st.

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- 11 -

Example 7

0.05 part of a dye which is the ^{pentanatrium salt of 1- (2 l} -methyl-3 '- [4 "-chloro-6 ^ll -silfoanilino-1 ⁿ ₁ 3 ¹ ·, 5" -triazine-2 "-ylamincQ -5 · -sulf ophenylj -3-carboxy - ^ - p '''- eulfo ~ 4«' »- (chlrosulfoanilino-i"' ¹ ^ ¹ '", 5 ' ^! " -triazine-2 "" -ylamino) -phenylazq) -5-pyrazolone acts, and 1.1 parts of urea are dissolved in 1.9 parts of water * 0.145 parts of a 45% aqueous solution of the sodium salt of sulfated methyl oleate and 0.26 part of sodium dodecylbenzenesulfonate are then added to Dissolution stirred in. This solution is added to a solution of 0.025 part of ethyl-hydroxyethyl cellulose with a viscosity of 20 to 35 cp »measured as in Example 1, in 25 parts of perchlorethylene. This is followed by mixing to make a coarse emulsion. This emulsion is gradually diluted with a further 164 parts of perchlorethylene, a stable product being obtained.

Cellulosic textile material is batch dyed to a yellow color by immersing it in a dye bath containing consists of the emulsion described above, which is continuously stirred and gradually heated to the boiling point and then held at the boiling point for 30 minutes.

Example 8

0.036 part of the dye which is in the Color Index as CI. Acid Yellow 72 is called in 0.6 parts of water dissolved, and 0.145 parts of a 45% aqueous solution of the sodium salt of sulfated methyl oleate are added. The dye solution thus obtained is vigorously Stir to a solution of 0.025 parts of ethyl hydroxyäthy1 cellulose a viscosity of 20 to 35 cp in 15 parts of perchlorethylene admitted. The one made in this way

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Emulsion is added with stirring to 14-9 parts of perchlorethylene at 3G ⁰ C, whereby a stable product is obtained »

The resulting emulsion is used for the batchwise dyeing of Hylontextilmaterialien in a yellow color by the textile material is immersed in the held at 85 ⁰ C emulsion. A clear solution is formed at this temperature.

Example 9

The procedure of Example 8 is repeated with instead of the dye described therein 0.016 parts of the dye may be used, which is listed in Color Index as C.I. Acid Red 266 is called. Similar results are obtained.

Example 10

The procedure of Example 8 is repeated, with 0.015 parts of the dye instead of the dye described there * - IV - (Phenyla * o) phenyla * oil -H-ethyl-K - (»~ sulf above» yl) aniline be used. Similar results are obtained.

example

0.02 part of the dye contained in Color Index ala CI. Acid Blue 6? are dissolved in 0.6 parts of water, and 0.0 ^ 5 parts of dodecylbene sol sulfonic acid are added. A solution of 0.025 part of ethyl hydroaryethyl jellulose with a viscosity of 2 to 35 cp in 15 parts of perchlorethylene is added to the solution obtained under good flow. The Kauleion obtained in this manner © is added with stirring to the other parts 14-5 Perchlorethylene at 30 ⁰ C

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BATH ORIGINAL

added «The dye liquid obtained is used for a paragraph» wise coloring of nylon textile materials like the following Procedure used;

Perchlorethylene is circulated through the nylon textile material at 40 ⁰ O for 10 minutes. The dye liquid is then circulated in an amount sufficient, 1.25 to 1.5 <* ev .-% dye (based on the textile material taken and the textile material treated in this way at 40 * 0 for 15 minutes, whereupon the temperature during a period of time of 40 min at 85 ° C is raised and then 15 nia at this value -contents wirdv The material is dried at 70 to 80 ⁰ C ';;

Example 12

"The * procedure of Example 11 is repeated" where instead of the dye specified there «0.016 parts of the Dyes from Example 10 can be used * There will be i Y similar results as in Example 11 were obtained.

Example 15 #

The process of Example 11 is repeated, but instead of the dye described there, 0.037 parts of the in Color Index with C.I. Acid Yellow 135 can be used. Similar results are obtained.

Beispi el

The process of Example 11 is repeated, but instead of the dye described there, 0 ^ 01? Parts of the dye referred to in Color Index with CI Acid Blue 40 can be used. Eu will get similar results.

^209812/1770 BADORlG ₁ NAt

Λ5 Λ.

The procedure of Example 11 is repeated with Jedech instead of the dye described there 0.036 parts of the in Color Index with C.I. Acid Yellow 72 designated dye can be used. Similar results are obtained.

Example 16

1 part Turkish red oil is used in 30 parts of an 18% solution a fluorescent brightener (exn anionic stilbene derivative dissolved in aqueous diethylene glycol. This solution becomes a solution of 5 parts of ethyl hydroxyethyl cellulose (Viscosity 20 to 35 cp) added in 70 parts of perchlorethylene, the latter being stirred with a homogenizer. Bach's addition is finished stirring for another minute continued; The solution obtained is viscous but -gie ££ 8fil <g and has excellent stability. It is suitable for the 'optical' brightening of cellulose or polyamide fibers; For this purpose it can be diluted with additional perchlorethylene without breaking the emulsion.

In "'a" typical treatment, the diluted emulsion is padded onto a cellulose fabric so that 0.05 to 0.5% by weight of the fluorescent brightener is applied to the fabric. The solvent 'is removed by the fabric passed through a steam chamber and 5 minutes is dried at 60 ⁰ C.

The treated fabric is much lighter in appearance than the untreated fabric.

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BAD ORiGiNAL

Example 17

1 part Turkish Rotol is made in $ 0 parts of a 50% aqueous Solution τοπ dimethylol-dihydroxyethylene ~ dissolved urea The solution is made up of a further solution of 1.5 parts of ethylhydroxyethyl cellulose (Viscosity 20 to 55 cp) in 70 parts Perchioroethylene is given, while the latter is done with a homogenizer stirring is continued. When the addition is complete, stirring is continued for 1 min. The eoulsion obtained, which is viscous but pourable is, has a favorable ^ stability. She is suitable Sum application exactly with a latent acid catalyst on cellulosic and polyester / cellulosic fabrics, with a kaitter-resistant and permanent finish is obtained. For The emulsion can do this with additional ferric chloroethylene can be diluted without breaking the emulsion.

In a typical treatment, a latent acid catalyst such as SB monochloroacetic acid or stearamidomethylpyridine chloride is added to the dilute perchloroethylene emulsifier and the resulting composition is applied to a 100% cellulose or polyester and cellulose fabric so that

4 to 8% by weight of the Maethylol ^ ihydroaqrathylen'-harnetoiis

to be deposited on the fabric, Bas solvent is then removed by passing the fabric through a steam chamber is passed through »The textile fabric is then

5 minutes dried and heated for 3 minutes to a temperature of 155-160 ⁰ C at 60 ⁰ C.

The treated fabric is much better wet and trocieie wrinkle resistance than the untreated Textile fabric.

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BATH ORIGINAL

Example 18

0.4 parts of sodium hydroxide are in 50 parts of a (GA) aqueous dispersion of a polyalkylene terephthalate / Polyoxyethylene terephthalate block mixed polymer dissolved. 2 parts ethyl hydroxyethyl cellulose (viscosity 20 to 35 cp) are dissolved in 45 parts of Perchloroäthyleu, in front of you the addition of 2.6 files oleic acid follows. The watery Dispersion is added to the oil phase over a period of 10 minutes using a high speed stirrer will. After the addition is complete, the rapid charging is still 3 ain continued, followed by slow stirring for 2 minutes. The resulting emulsion is excellent Stability and is suitable for producing permanent antistatic and dirt-repellent effects Polyester *, polyester / cellulose and polyester / full textiles » For this purpose it can be used with additional Perchloric ~ Ethylene can be diluted without breaking the emulsion.

The dilute emulsion is applied to the polyester fabric, such that 1 to 3 percent "- are deposited on the fabric% Folyäthylenterephthalat / Pölyoxyäthylenterephthalat-Blockmischpolyaer * The fabric is dried by heating at 60 ⁰ C for 20 Bin. The treated fabric has improved barrier deposition, stain removal and mold repelling properties than the untreated fabric.

Example 19

0.2 parts of an azo dye obtained by coupling 4-aainobenzene-sulfonamide with U-methyl ~ 5? - fi ~ cyanoethylaniline. represents, and 0.1 part of the polyurea Eat flocculant, the mixed according to the rule below 2,4- and 2,6-Tolylenedi.isocyanaten and one made from soya oil long-chain secondary amine has been obtained,

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are ground in 3 parts of Perchloroäthylön 40 et long with a ball mill. The dispersion obtained is cooked in a solution of 1 part of ethyl hydroxyethyl eelluloae (viscosity 20 to 55 Cp ₁ geuesaen at 25 ⁰ C with a 5% (weight) solution in 80:20 oteluene / ethanol) in 115 Share perchlorethylene sug ents. A mixture of 5 te :? Lea water and 1 part Turkish HotSl are slowly added while stirring to produce an emulsion * which is then further diluted with 690 parts of perchlorethylene.

Sin Polyestertextilaaterial is intermittently dyed a yellow color in 'by being immersed in a dye bath consisting of the above emulsion and which is continuously stirred and heated min at 120 ° C for 10 and 30 maintained at 120 ^e C min.

The polyurea deflocculant used in this example will be prepared by the following process: 3.7 parts of a commercial 40% solution of polymerize mixed 2 »4- and 2,6-Tolylßnaiisocya.-aaten with 5 * 7% Isocyanate groups and less than Ο.59έ free tolylene diisocyanate in butyl acetate with 52% acetone. It will solution langaa "su a stirred solution of 53.5 parts of a langkett.ig" n _t (available from H & S el under de "trademark Anaeen 2S) from soybean oil hei'gestellten secondary amines iii divider 116 * acetone of 50 to 55 * C suggest. The acetone WI3? D a & mi removed by distillation up to a temperature of 100 ⁰ C under veraindertem Ditick.

BAD ORIGIMAT 209812/1770

Example 20

0.5 parts of the in Color Index as CI. The dye designated Baoic Red 18 is dissolved in 5 parts of boiling water and 5 parts of Turkish. Hot oil are added. The dye solution obtained in this way is mixed with a solution of 1 part of ethyl hydroxyethyl cellulose (20 to 35 cp) with thorough stirring. in 115 parts of perchlorethylene, and that on this The emulsion thus obtained is nit 687 parts with stirring Perchlorethylene diluted.

The resulting emulsion is used au a absatsiielsen staining of Polyacrylnitr-iitextilmaterialien in a red color by the textile material 30 vird immersed min at 105 ⁰ C in a closed container under continuous stirring in the emulsion.

BATH ORIGINAL

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Claims (1)

Claims 1. Stable emulsion of an aqueous solution or an aqueous dispersion of a dye or a textile finish in a halogenated hydrocarbon solvent characterized that the emulsion as emulsifiers ethyl-hydroxy- * contains ethyl cellulose and at least one anionic surfactant. 2. Emulsion according to Claim 1, characterized in that: Xthyl-hydro: ryäthyl ~ * ellulo8e eil "LSaungeviekaeität according to the above definition rom 20 to 35" p besitxt. 3 «emulsion according to claim 2, characterized in that the anionic surfactants a salt of sulfonated Kastorol is. 4. Emulsion according to claim 2 _f gekenncelehnet that the anionic surface act ire smock consists of de »Triathanolaainalz of tall oil. 5 " Sauls lon according to claim 2 _v characterized in that the ani-oni-Bche Oberflachen & ktivo gown is the fatriuosa.l £ of sulfated methyl oleate. 6. Emulsion according to claim 2, characterized in that the anionic surfactants sodium dodecylbene sulfonate. 7. Eaulaion according to claim 2, characterized in that the HatriuKoleate is anionic surfactants. 8. Emulsion according to one of claims 1 to 7, characterized in that the fcalogejaterte HydrocarbonSmxngeclttel Is perchlorethylene. 209812/1770 BAD 9 »Emulsion naeli one of claims 1 to? _t characterized _f that the halogenated β hydrocarbon solvent consists of triehloroethylene. 10. Eoulsicn according to one of claims 1 to 7% gekennseichnet characterized in that the halogenated carbon atomic solvent consists of 1,1,1-trichloroethane. 11 emulsion according to one of claims 1 to 10, characterized in that that the reading dye is an acidic, a basic, a direct, a reactive or a disperse dye iet. ^Λ 2 » Eulßion according to one of claims 1 to 10, characterized in that the textile & finishing of a fluorescent optical brightener, a waterproof smock, a crease-resistant resin, an antistatic agent, one. Discharge repellant aiitfcel, a softening agent, a desizing agent, a fire-retardant agent or a flame-retardant agent. '! J- Softilsioa nsch cijaeia der Ajisprücha 1 "to 12, characterized by the fact that the amount of water present is 0.3 to 20 % by weight, based on the dish of the entire emulsion. Use of the emulsions according to one of the preceding claims, for dyeing or finishing textile materials FATPNTANA ^ LTi BATH ORIGINAL 209812/1770