DE2033744B2 - USE OF A NICKEL ALLOY FOR THE PRODUCTION OF HARD WEAR RESISTANT AND CORROSION RESISTANT COATING LAYERS ON METALLIC OBJECTS - Google Patents

USE OF A NICKEL ALLOY FOR THE PRODUCTION OF HARD WEAR RESISTANT AND CORROSION RESISTANT COATING LAYERS ON METALLIC OBJECTS

Info

Publication number
DE2033744B2
DE2033744B2 DE19702033744 DE2033744A DE2033744B2 DE 2033744 B2 DE2033744 B2 DE 2033744B2 DE 19702033744 DE19702033744 DE 19702033744 DE 2033744 A DE2033744 A DE 2033744A DE 2033744 B2 DE2033744 B2 DE 2033744B2
Authority
DE
Germany
Prior art keywords
until
nickel alloy
nickel
coating layers
alloy
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
DE19702033744
Other languages
German (de)
Other versions
DE2033744A1 (en
Inventor
Ewald; Salzmann Helmut; 4630 Bochum Lehmann
Original Assignee
Deutsche Edelstahlwerke Ag, 4150 Krefeld
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Deutsche Edelstahlwerke Ag, 4150 Krefeld filed Critical Deutsche Edelstahlwerke Ag, 4150 Krefeld
Priority to DE19702033744 priority Critical patent/DE2033744B2/en
Priority to GB1297758D priority patent/GB1297758A/en
Publication of DE2033744B2 publication Critical patent/DE2033744B2/en
Publication of DE2033744A1 publication Critical patent/DE2033744A1/de
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C19/00Alloys based on nickel or cobalt
    • C22C19/03Alloys based on nickel or cobalt based on nickel
    • C22C19/05Alloys based on nickel or cobalt based on nickel with chromium
    • C22C19/051Alloys based on nickel or cobalt based on nickel with chromium and Mo or W
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/24Selection of soldering or welding materials proper
    • B23K35/30Selection of soldering or welding materials proper with the principal constituent melting at less than 1550 degrees C
    • B23K35/3033Ni as the principal constituent
    • B23K35/304Ni as the principal constituent with Cr as the next major constituent
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/04Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
    • C23C4/06Metallic material
    • C23C4/067Metallic material containing free particles of non-metal elements, e.g. carbon, silicon, boron, phosphorus or arsenic

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Coating By Spraying Or Casting (AREA)

Description

1 21 2

Die Erfindung bezieht sich auf die Verwendung einer gehalts ausgezeichnete Fließeigenschaften beim Auf-Nickellegierung zur Herstellung harter, verschleiß- spritzen oder -schweißen. Bor setzt außerdem den fester und korrosionsbeständiger, aufgespritzter oder Schmelzpunkt der Legierung herab, was hinsichtlich aufgeschweißter Überzugsschichten auf metallischen einer Erniedrigung der Aufspritz- bzw. Aufschweiß-Gegenständen. 5 temperatur wünschenswert ist. Durch den ZusatzThe invention relates to the use of a content-excellent flow properties in the on-nickel alloy for the production of hard, wear spraying or welding. Bor also sets the solid and corrosion-resistant, sprayed-on or melting point of the alloy, what with regard to welded-on coating layers on metallic a lowering of the spray-on or weld-on objects. 5 temperature is desirable. By adding

Für die Erzeugung von harten, verschleißfesten von Bor werden weiterhin gebildete Oxyde auf-For the production of hard, wear-resistant boron, oxides continue to be formed.

Überzugsschichten sind Metallegierungen als Pulver geschlossen und die Bildung von Borsilikaten ermög-Coating layers are metal alloys closed as a powder and the formation of borosilicates enables

oder Schweißstäbe bekannt, die durch Aufspritzen licht, welche an die Oberfläche der Überzugsschichtenor welding rods known, which light by spraying, which on the surface of the coating layers

bzw. Aufschweißen auf die Oberfläche metallischer auf steigen, dadurch den weiteren Zutritt von Sauerstoffor welding onto the surface in a more metallic way, thereby further admitting oxygen

Gegenstände aufgebracht werden. Durch Zusatz von iq verhindern und eine glatte Oberfläche der Überzugs-Objects are applied. Prevent by adding iq and ensure a smooth surface of the coating

Metallkarbiden zu solchen metallischen Auftrags- schicht bilden.Form metal carbides to form such a metallic coating.

legierungen kann die Härte der Überzugsschichten in Durch das Verhältnis Chrom/Molybdän/SiliziumAlloys can reduce the hardness of the coating layers in terms of the ratio of chromium / molybdenum / silicon

bekannter Weise verbessert werden. Allerdings ist die wird die Korrosionsbeständigkeit, insbesondere gegen-are known to be improved. However, it is the corrosion resistance, especially against

Verschleißfestigkeit derartiger Überzugsschichten nicht über Kunststoffen mit molekularer Umwandlung beiWear resistance of such coating layers does not contribute to plastics with molecular conversion

besonders hoch. Die Bindelegierung wird nämlich 15 Temperaturen von über 3000C wesentlich verbessert,especially high. The binding alloy is in fact significantly improved at temperatures of over 300 0 C,

mit der Zeit ausgewaschen, und die in sie eingelagerten Die Härte einer Überzugsschicht aus der vorge-washed out over time, and the stored in them The hardness of a coating layer from the previous

Metallkarbidkörner werden an der Oberfläche der schlagenen Nickellegierung liegt bei 67 R0 und er-Metal carbide grains are on the surface of the beaten nickel alloy is 67 R 0 and he

Überzugsschicht freigelegt. Dadurch rufen sie einmal reicht damit den Wert bekannter Auftragswerkstoffe,Coating layer exposed. As a result, they call once so that the value of known contract materials is sufficient,

einen starken Verschleiß an den Teilen hervor, die die Metallkarbideinlagerungen aufweisen. Dabei istsevere wear and tear on the parts with the metal carbide inclusions. It is

mit der Überzugsschicht in Berührung kommen, und ao die erfindungsgemäß zu verwendende Nickellegierungcome into contact with the coating layer, and ao the nickel alloy to be used according to the invention

werden zum anderen, wenn sie nicht mehr genügend jedoch verschleißfester, weil die in ihr gebildetenon the other hand, if they are no longer sufficiently more wear-resistant, because those formed in them

Halt in der Bindelegierung finden, aus der Überzugs- Karbide und Boride eutektisch in homogener Ver-Find hold in the binding alloy, from which the coating carbides and borides are eutectically homogeneous

schicht herausgebrochen. teilung in einer y-Mischkristallgrundmasse vorliegen.layer broken out. division in a y mixed crystal matrix.

Andere bekannte metallische Spritzpulver haben Korrosionsbeständigkeit und Härte des erfindungs-Other known metallic spray powders have corrosion resistance and hardness of the invention

zum Teil eine bessere Verschleißfestigkeit, dabei dann 25 gemäßen Spritzpulvers sind bis zu Betriebstemperaturenpartly a better wear resistance, then according to spray powder are up to operating temperatures

aber eine geringere Härte und keine ausreichende von etwa 6000C vorhanden. . .·but a lower hardness and insufficient hardness of about 600 ° C. is available. . . ·

Korrosionsbeständigkeit. Auf Grund der vorgenannten Eigenschaften eignetCorrosion resistance. Due to the aforementioned properties, it is suitable

Aufgabe der vorliegenden Erfindung ist es, einen sich die vorgeschlagene Nickellegierung für die Hermetallischen Werkstoff vorzuschlagen, welcher sich stellung von Überzugsschichten auf metallischen als Pulver gut auf die Oberflächen metallischer 30 Gegenständen, die in korrodierender Atmosphäre Gegenstände aufspritzen und als Schweißstab gut hart und verschleißfest sein müssen, z. B. Plungern aufschweißen läßt, d. h. fließfähig ist, und eine harte, und Kolbenstangen, bei der Verarbeitung von Kunstverschleißfeste und sehr korrosionsbeständige Schicht stoffen bei höherer Temperatur. Auf Grund des bildet. hohen Verschleißwiderstands gegenüber abrasivemThe object of the present invention is to propose the proposed nickel alloy for the hermetallic material, which position of coating layers on metallic as a powder good on the surfaces of metallic objects that are in a corrosive atmosphere Spray on objects and have to be hard and wear-resistant as a welding rod, e.g. B. Plunging can be welded on, d. H. Is flowable, and a hard, and piston rods, in the processing of art wear-resistant and very corrosion-resistant coatings at higher temperatures. Due to the forms. high wear resistance to abrasive

Zur Lösung dieser Aufgabe wird erfindungsgemäß 35 Angriff eignet sich die erfindungsgemäß zu verwendendeAccording to the invention, the attack to be used according to the invention is suitable for solving this problem

für den vorgenannten Zweck eine Nickellegierung Legierung auch für Zwecke der Steinzeugindustrie,for the aforementioned purpose a nickel alloy alloy also for purposes of the stoneware industry,

vorgeschlagen, die aus Die erfindungsgemäß zu verwendendende Nickellegierung kann in Form von Pulver oder Stäben zumproposed that the nickel alloy to be used according to the invention can be made in the form of powder or sticks

1,5 bis 3 °/o Kohlenstoff, Einsatz kommen und durch Flamm- oder Plasma-1.5 to 3% carbon, are used and by flame or plasma

2 bis 5 % Silizium, 40 spritzen oder Piasmarc-Schweißen aufgetragen werden.2 to 5% silicon, 40 spray or Piasmarc welding can be applied.

0 bis 1 % Mangan, Durch eine an sich bekannte thermische Nach-10 bis 30% Chrom, behandlung bei 1050 bis 1070° C kann die aus der0 to 1% manganese, by a known thermal after-10 up to 30% chromium, treatment at 1050 to 1070 ° C can result from the

5 bis 20 % Molybdän, erfindungsgemäß zu verwendenden Nickellegierung5 to 20% molybdenum, nickel alloy to be used according to the invention

3 bis 10 % Kobalt, aufgespritzte Überzugsschicht in der Oberfläche des 3 bis 15 % Wolfram, 45 überzogenen Gegenstands durch Diffusion fest ver-3 to 10% cobalt, sprayed coating layer in the surface of the 3 to 15% tungsten, 45 coated object firmly bonded by diffusion

1 bis 5 % Vanadium, ankert werden.
1,5 bis 5% Bor,
1 to 5% vanadium.
1.5 to 5% boron,

Rest Nickel D+ " ·· 1, ■Remainder nickel D+ "·· 1, ■

Claims (1)

Patentansprüche:Patent claims: besteht. 5oconsists. 5 o Aus diesem Bereich wird bevorzugt eine Nickel- 1. Verwendung einer Nickellegierung, bestehendFrom this range, a nickel alloy is preferred. 1. Use of a nickel alloy legierung mit ausalloy with off 5555 6060 zur Verwendung für den vorgenannten Zweck vor- 65 in Form von Pulver oder Stäben zur Herstellung geschlagen. harter, verschleißfester und korrosionsbeständiger, Die erfindungsgemäß zu verwendende Nickel- aufgespritzter oder aufgeschweißter Überzugslegierung hat auf Grund des hohen Bor- und Silizium- schichten auf metallischen Gegenständen. for use for the aforementioned purpose, in the form of powder or sticks for manufacture beaten. harder, more wear-resistant and more corrosion-resistant. The nickel-sprayed or welded-on coating alloy to be used according to the invention has, due to the high boron and silicon layers on metallic objects. 2,02.0 bisuntil 2,5%2.5% Kohlenstoff,Carbon, 3,73.7 bisuntil 4,0%4.0% ' Silizium,'Silicon, 00 bisuntil 0,15%0.15% Mangan,Manganese, 1616 bisuntil 18%18% Chrom,Chrome, 1414th bisuntil 15%15% Molybdän,Molybdenum, 6,56.5 bisuntil 7%7% Kobalt,Cobalt, 55 bisuntil 7%7% Wolfram,Tungsten, 1,81.8 bisuntil 2,2%2.2% Vanadium,Vanadium, 3,53.5 bisuntil 4%4% Bor,Boron, Restrest Nickelnickel
1,1, 5 bis5 to 3%3% Kohlenstoff,Carbon, Chrom,Chrome, 22 bisuntil 5%5% Silizium,Silicon, Molybdän,Molybdenum, 00 bisuntil 1 % Mangan,1% manganese, Kobalt,Cobalt, 1010 bisuntil 30%30% Wolfram,Tungsten, 55 bisuntil 20%20% Vanadium,Vanadium, 33 bisuntil 10%10% Bor,Boron, 33 bisuntil 15%15% Nickel,Nickel, 11 bisuntil 5%5% 1,1, 5 bis5 to 5%5% Rest:Rest:
3 43 4 2. Verwendung einer Nickellegierung der Zu- 14 bis 15% Molybdän,2. Use of a nickel alloy containing 14 to 15% molybdenum, sammensetzung nach Anspruch 1, bestehend aus 6,5 bis 7 % Kobalt,Composition according to claim 1, consisting of 6.5 to 7% cobalt, 5 bis 7% Wolfram,5 to 7% tungsten, 2,0 bis 2,5% Kohlenstoff, 1.8 bis 2,2% Vanadium,2.0 to 2.5% carbon, 1.8 to 2.2% vanadium, 3,7 bis 4,0% Silizium, 5 3,5 bis 4% Bor,3.7 to 4.0% silicon, 5 3.5 to 4% boron, 0 bis 0,15% Mangan, Rest Nickel,0 to 0.15% manganese, balance nickel, 16 bis 18 % Chrom, für den im Anspruch 1 genannten Zweck.16 to 18% chromium, for the purpose mentioned in claim 1.
DE19702033744 1970-07-08 1970-07-08 USE OF A NICKEL ALLOY FOR THE PRODUCTION OF HARD WEAR RESISTANT AND CORROSION RESISTANT COATING LAYERS ON METALLIC OBJECTS Pending DE2033744B2 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
DE19702033744 DE2033744B2 (en) 1970-07-08 1970-07-08 USE OF A NICKEL ALLOY FOR THE PRODUCTION OF HARD WEAR RESISTANT AND CORROSION RESISTANT COATING LAYERS ON METALLIC OBJECTS
GB1297758D GB1297758A (en) 1970-07-08 1971-06-15

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19702033744 DE2033744B2 (en) 1970-07-08 1970-07-08 USE OF A NICKEL ALLOY FOR THE PRODUCTION OF HARD WEAR RESISTANT AND CORROSION RESISTANT COATING LAYERS ON METALLIC OBJECTS

Publications (2)

Publication Number Publication Date
DE2033744B2 true DE2033744B2 (en) 1971-12-30
DE2033744A1 DE2033744A1 (en) 1971-12-30

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GB (1) GB1297758A (en)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2366126A1 (en) * 1976-09-30 1978-04-28 Eutectic Corp FERROUS METAL SUPPORT COATED WITH AN ALLOY, WITH RESPECTIVE THERMAL CONDUCTIVITIES EXCEEDING A GIVEN MINIMUM, ESPECIALLY FOR HEAT EXCHANGES
FR2456143A1 (en) * 1979-05-09 1980-12-05 Special Metals Corp ALLOY FOR HARD COATING BASED ON NICKEL, COBALT AND CHROME
EP0039450A1 (en) * 1980-05-02 1981-11-11 FUKUDA METAL FOIL & POWDER CO., LTD Hard facing nickel-base alloy
DE102016008745A1 (en) 2016-07-18 2018-01-18 Wieland-Werke Ag Copper-nickel-tin alloy, process for their preparation and their use
DE102016008753A1 (en) 2016-07-18 2018-01-18 Wieland-Werke Ag Copper-nickel-tin alloy, process for their preparation and their use
DE102016008758A1 (en) 2016-07-18 2018-01-18 Wieland-Werke Ag Copper-nickel-tin alloy, process for their preparation and their use
DE102016008757A1 (en) 2016-07-18 2018-01-18 Wieland-Werke Ag Copper-nickel-tin alloy, process for their preparation and their use
DE102016008754A1 (en) 2016-07-18 2018-01-18 Wieland-Werke Ag Copper-nickel-tin alloy, process for their preparation and their use

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0051461A1 (en) * 1980-10-30 1982-05-12 Allied Corporation Homogeneous ductile brazing foils
CN112846566B (en) * 2020-12-31 2022-03-29 钢铁研究总院 Solid solution strengthening type heat-resistant alloy C-HRA-2 argon arc welding wire
CN112846565B (en) * 2020-12-31 2022-03-29 钢铁研究总院 Solid welding wire for pure solid solution strengthening type heat-resistant alloy C-HRA-2 submerged arc welding

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2366126A1 (en) * 1976-09-30 1978-04-28 Eutectic Corp FERROUS METAL SUPPORT COATED WITH AN ALLOY, WITH RESPECTIVE THERMAL CONDUCTIVITIES EXCEEDING A GIVEN MINIMUM, ESPECIALLY FOR HEAT EXCHANGES
FR2456143A1 (en) * 1979-05-09 1980-12-05 Special Metals Corp ALLOY FOR HARD COATING BASED ON NICKEL, COBALT AND CHROME
EP0039450A1 (en) * 1980-05-02 1981-11-11 FUKUDA METAL FOIL & POWDER CO., LTD Hard facing nickel-base alloy
DE102016008745A1 (en) 2016-07-18 2018-01-18 Wieland-Werke Ag Copper-nickel-tin alloy, process for their preparation and their use
DE102016008753A1 (en) 2016-07-18 2018-01-18 Wieland-Werke Ag Copper-nickel-tin alloy, process for their preparation and their use
DE102016008758A1 (en) 2016-07-18 2018-01-18 Wieland-Werke Ag Copper-nickel-tin alloy, process for their preparation and their use
DE102016008757A1 (en) 2016-07-18 2018-01-18 Wieland-Werke Ag Copper-nickel-tin alloy, process for their preparation and their use
DE102016008754A1 (en) 2016-07-18 2018-01-18 Wieland-Werke Ag Copper-nickel-tin alloy, process for their preparation and their use
WO2018014994A1 (en) 2016-07-18 2018-01-25 Wieland-Werke Ag Copper-nickel-tin alloy, method for the production and use thereof
WO2018014990A1 (en) 2016-07-18 2018-01-25 Wieland-Werke Ag Copper-nickel-tin-alloy, method for the production and use thereof
WO2018014992A1 (en) 2016-07-18 2018-01-25 Wieland-Werke Ag Copper-nickel-tin alloy, method for the production and use thereof
WO2018014993A1 (en) 2016-07-18 2018-01-25 Wieland-Werke Ag Copper-nickel-tin alloy, method for the production and use thereof
WO2018014991A1 (en) 2016-07-18 2018-01-25 Wieland-Werke Ag Copper-nickel-tin alloy, method for the production and use thereof

Also Published As

Publication number Publication date
DE2033744A1 (en) 1971-12-30
GB1297758A (en) 1972-11-29

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Date Code Title Description
E77 Valid patent as to the heymanns-index 1977