DE19753222A1 - Selbstvernetzende Polyurethan-Polyacrylat-Hybriddispersionen - Google Patents

Selbstvernetzende Polyurethan-Polyacrylat-Hybriddispersionen

Info

Publication number
DE19753222A1
DE19753222A1 DE19753222A DE19753222A DE19753222A1 DE 19753222 A1 DE19753222 A1 DE 19753222A1 DE 19753222 A DE19753222 A DE 19753222A DE 19753222 A DE19753222 A DE 19753222A DE 19753222 A1 DE19753222 A1 DE 19753222A1
Authority
DE
Germany
Prior art keywords
polyurethane
dispersion
polyols
weight
hybrid dispersion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
DE19753222A
Other languages
German (de)
English (en)
Inventor
Christoph Dr Irle
Harald Dr Blum
Wolfgang Kremer
Rolf Roschu
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer AG
Original Assignee
Bayer AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer AG filed Critical Bayer AG
Priority to DE19753222A priority Critical patent/DE19753222A1/de
Priority to AT98121884T priority patent/ATE223446T1/de
Priority to EP98121884A priority patent/EP0919579B1/de
Priority to DE59805396T priority patent/DE59805396D1/de
Priority to US09/199,676 priority patent/US6063861A/en
Priority to JP35217898A priority patent/JP4204121B2/ja
Priority to CA002254603A priority patent/CA2254603C/en
Publication of DE19753222A1 publication Critical patent/DE19753222A1/de
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
    • C08F283/006—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polymers provided for in C08G18/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/0804—Manufacture of polymers containing ionic or ionogenic groups
    • C08G18/0819—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups
    • C08G18/0823—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups containing carboxylate salt groups or groups forming them
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C08G18/12—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/44—Polycarbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4854—Polyethers containing oxyalkylene groups having four carbon atoms in the alkylene group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/75—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
    • C08G18/758—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing two or more cycloaliphatic rings
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
    • Y10T428/31591—Next to cellulosic

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Paints Or Removers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Graft Or Block Polymers (AREA)
DE19753222A 1997-12-01 1997-12-01 Selbstvernetzende Polyurethan-Polyacrylat-Hybriddispersionen Withdrawn DE19753222A1 (de)

Priority Applications (7)

Application Number Priority Date Filing Date Title
DE19753222A DE19753222A1 (de) 1997-12-01 1997-12-01 Selbstvernetzende Polyurethan-Polyacrylat-Hybriddispersionen
AT98121884T ATE223446T1 (de) 1997-12-01 1998-11-18 Lagerstabile, selbstvernetzende hybriddispersionen
EP98121884A EP0919579B1 (de) 1997-12-01 1998-11-18 Lagerstabile, selbstvernetzende Hybriddispersionen
DE59805396T DE59805396D1 (de) 1997-12-01 1998-11-18 Lagerstabile, selbstvernetzende Hybriddispersionen
US09/199,676 US6063861A (en) 1997-12-01 1998-11-25 Self crosslinkable polyurethane-polyacrylate hybrid dispersions
JP35217898A JP4204121B2 (ja) 1997-12-01 1998-11-27 自己架橋性ポリウレタンポリアクリレートハイブリッド分散液
CA002254603A CA2254603C (en) 1997-12-01 1998-11-27 Self crosslinkable polyurethane-polyacrylate hybrid dispersions

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19753222A DE19753222A1 (de) 1997-12-01 1997-12-01 Selbstvernetzende Polyurethan-Polyacrylat-Hybriddispersionen

Publications (1)

Publication Number Publication Date
DE19753222A1 true DE19753222A1 (de) 1999-06-02

Family

ID=7850378

Family Applications (2)

Application Number Title Priority Date Filing Date
DE19753222A Withdrawn DE19753222A1 (de) 1997-12-01 1997-12-01 Selbstvernetzende Polyurethan-Polyacrylat-Hybriddispersionen
DE59805396T Expired - Lifetime DE59805396D1 (de) 1997-12-01 1998-11-18 Lagerstabile, selbstvernetzende Hybriddispersionen

Family Applications After (1)

Application Number Title Priority Date Filing Date
DE59805396T Expired - Lifetime DE59805396D1 (de) 1997-12-01 1998-11-18 Lagerstabile, selbstvernetzende Hybriddispersionen

Country Status (6)

Country Link
US (1) US6063861A (enExample)
EP (1) EP0919579B1 (enExample)
JP (1) JP4204121B2 (enExample)
AT (1) ATE223446T1 (enExample)
CA (1) CA2254603C (enExample)
DE (2) DE19753222A1 (enExample)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6602972B1 (en) 1999-11-06 2003-08-05 Basf Coatings Ag Self crosslinking polyurethanes and graft copolymers and based on polyurethane, for producing coating materials, adhesives and sealing masses
US6737477B1 (en) 1999-11-06 2004-05-18 Basf Coatings Ac Polyurethanes and graft copolymers based on polyurethane and their use in the production of coating materials, adhesives and sealing masses
DE19953203A1 (de) * 1999-11-05 2007-12-06 Basf Coatings Ag Verfahren zur Herstellung farb- und/oder effektgebender Mehrschichtlackierungen unter Verwendung selbstvernetzender Pfropfmischpolymerisate von Polyurethanen sowie neue selbstvernetzende Polyurethane und ihre Propfmischpolymerisate

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DE19964153B4 (de) * 1999-03-10 2006-06-01 Wacker Chemie Ag Verwendung von Fällungsmittel-Konzentrat zur Herstellung von schnell trocknenden Putzmassen
DE19948004B4 (de) 1999-10-06 2006-05-11 Basf Coatings Ag Polyurethane und Pfropfmischpolymerisate auf Polyurethanbasis sowie ihre Verwendung zur Herstellung von Beschichtungsstoffen, Klebstoffen und Dichtungsmassen
DE60000928T2 (de) * 2000-06-23 2003-08-14 National Starch And Chemical Investment Holding Corp., Wilmington Polymerdispersion enthaltend PU-Partikel und durch Emulsionspolymerisation olefinisch ungesättigter Monomerer erhaltenes Co- oder Terpolymer
JP5100948B2 (ja) * 2000-06-29 2012-12-19 Ｋｈネオケム株式会社 樹脂組成物
WO2002036524A1 (en) * 2000-11-01 2002-05-10 Valspar Sourcing, Inc. Abrasion resistant coating for stacks of fiber cement siding
US6639016B2 (en) 2000-12-31 2003-10-28 Basf Corporation Method of making a graft polymer
DE10115592A1 (de) 2001-03-29 2002-10-10 Basf Coatings Ag Von flüchtigen organischen Verbindungen freie oder im wesentlichen freie, wäßrige Dispersionen, Verfahren zu ihrer Herstellung und ihre Verwendung
DE10115602A1 (de) 2001-03-29 2002-10-24 Basf Coatings Ag Mit Polyurethanen modifizierte Copolymerisate, Verfahren zu ihrer Herstellung und ihre Verwendung
CA2495953C (en) † 2002-09-18 2011-11-22 Valspar Sourcing, Inc. Self-crosslinkable waterborne coating composition
AU2004255334A1 (en) * 2003-07-14 2005-01-20 Cytec Surface Specialties, S.A. Waterbone self-crosslinkable polyurethane dispersions and polyurethane: acrylic hybrid dispersions
ES2615030T3 (es) * 2003-12-17 2017-06-05 Dsm Ip Assets B.V. Composiciones de revestimiento acuosas de uretano-vinilo resistentes a las manchas
US20050238883A1 (en) * 2004-04-27 2005-10-27 Peeler Calvin T Urethane acrylate composite structure
US20060052524A1 (en) * 2004-09-07 2006-03-09 Peters David D Urethane acrylate composition
US20060051590A1 (en) * 2004-09-07 2006-03-09 Peters David D Urethane acrylate composition
US20050239991A1 (en) * 2004-04-27 2005-10-27 Basf Corporation. Method of producing a urethane acrylate
US20050238884A1 (en) * 2004-04-27 2005-10-27 Peters David D Urethane acrylate composition structure
US20050239955A1 (en) * 2004-04-27 2005-10-27 Basf Corporation. Urethane acrylate composition structure
US20060051593A1 (en) * 2004-04-27 2006-03-09 Peeler Calvin T Urethane acrylate composite structure
US7476705B2 (en) * 2005-02-07 2009-01-13 Lubrizol Advanced Materials, Inc. Aqueous dispersions of polyurethane compositions
US8901244B2 (en) * 2005-02-07 2014-12-02 Lubrizol Advanced Materials, Inc. Aqueous dispersions of polyurethane/acrylic hybrid compositions
EP2210908A1 (en) 2006-07-31 2010-07-28 Lubrizol Advanced Materials, Inc. Aqueous dispersions of polyurethane compositions with ketone-hydrazide
KR100774957B1 (ko) 2006-12-28 2007-11-09 (주)디피아이 홀딩스 금속 코팅용 수분산 우레탄 아크릭 하이브리드 도료 및이를 이용한 도막 형성방법
FR2921162B1 (fr) * 2007-09-14 2010-03-12 Essilor Int Article d'optique comportant un revetement temporaire bicouche
US9234068B2 (en) * 2007-10-02 2016-01-12 The Hong Kong University of Science and Technologhy Method for preparing aqueous polyacrylate modified polyurethane dispersions
EP2473541A1 (en) 2009-03-30 2012-07-11 Dow Global Technologies LLC Hybrid dispersions and methods for producing the same
WO2014194048A1 (en) 2013-05-30 2014-12-04 Laticrete International, Inc. Premixed hybrid grout
US11198153B2 (en) 2016-03-18 2021-12-14 Ppg Industries Ohio, Inc. Multi-layer coatings and methods of preparing the same
US10577518B2 (en) 2017-06-29 2020-03-03 Ppg Industries Ohio, Inc. Aqueous dispersions, coating compositions formed with aqueous dispersions, and multi-layer coatings
US10865326B2 (en) 2017-09-20 2020-12-15 Ppg Industries Ohio, Inc. Coating compositions, elastic barrier coatings formed therefrom, and methods of applying such coatings
US11958775B2 (en) 2018-06-29 2024-04-16 Laticrete International, Inc. Dispersion-based ready-to-use (RTU) technology with performance of a reactive resin
US11059993B2 (en) 2018-09-07 2021-07-13 Ppg Industries Ohio, Inc. Coating composition exhibiting specific gloss properties for extreme washable coatings
US11111409B2 (en) 2019-01-03 2021-09-07 Ppg Industries Ohio, Inc. Coating composition comprising self-crosslinkable core-shell particles and imparting improved stain resistance
US10829664B2 (en) 2019-03-15 2020-11-10 Ppg Industries Ohio, Inc. Coating compositions containing polythioethers and elastic barrier coatings formed therefrom
US10836924B2 (en) 2019-03-15 2020-11-17 Ppg Industries Ohio, Inc. Coating compositions and elastic barrier coatings formed therefrom
CN110982418B (zh) * 2019-12-24 2022-05-13 Ppg涂料(天津)有限公司 具有颜色稳定性的水性色漆涂料组合物

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BE757936A (fr) * 1969-10-23 1971-04-01 Bayer Ag Procede de preparation de polymeres anioniques modifies en emulsion
IT1153000B (it) * 1982-07-01 1987-01-14 Resem Spa Dispersioni acquose di poliuretani da oligouretani aventi gruppi terminali insaturi
NL8401785A (nl) * 1984-06-04 1986-01-02 Polyvinyl Chemie Holland Werkwijze voor de bereiding van een waterige dispersie van urethan-acrylaat entcopolymeren, alsmede aldus verkregen stabiele waterige dispersie.
US4644030A (en) * 1985-02-01 1987-02-17 Witco Corporation Aqueous polyurethane - polyolefin compositions
GB8721538D0 (en) * 1987-09-14 1987-10-21 Polyvinyl Chemie Holland Bv Aqueous dispersions
GB8904102D0 (en) * 1988-03-09 1989-04-05 Ici Resins Bv Polyurethane coating compositions
US5371133A (en) * 1990-09-12 1994-12-06 National Starch And Chemical Investment Holding Corporation Process for preparing urethane/acrylic-or-vinyl latexes
DE4122265A1 (de) * 1991-07-05 1993-01-07 Hoechst Ag Polyurethan-dispersionen
DE4122266A1 (de) * 1991-07-05 1993-01-07 Hoechst Ag Polyurethan-dispersionen
DE4137613A1 (de) * 1991-11-15 1993-05-19 Herberts Gmbh Bindemittelzusammensetzung, diese enthaltende ueberzugsmittel und deren verwendung
DE4336206A1 (de) * 1993-10-23 1995-04-27 Hoechst Ag Wäßrige selbstvernetzende Polyurethan-Vinyl-Hybrid-Dispersionen
DE4406547A1 (de) * 1994-02-28 1995-08-31 Herberts Gmbh Wäßrige Polyurethanharzdispersion, deren Herstellung und hierzu geeignete Polyurethanmakromere, und ihre Verwendung in wäßrigen Überzugsmitteln
US5536784A (en) * 1994-10-06 1996-07-16 Air Products And Chemicals, Inc. Water borne crosslinkable compositions

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19953203A1 (de) * 1999-11-05 2007-12-06 Basf Coatings Ag Verfahren zur Herstellung farb- und/oder effektgebender Mehrschichtlackierungen unter Verwendung selbstvernetzender Pfropfmischpolymerisate von Polyurethanen sowie neue selbstvernetzende Polyurethane und ihre Propfmischpolymerisate
US7855266B2 (en) 1999-11-05 2010-12-21 Basf Coatings Ag Method for multilayer coatings with self-crosslinking graft polyurethane copolymers, self-crosslinking polyurethanes and graft copolymers thereof
US6602972B1 (en) 1999-11-06 2003-08-05 Basf Coatings Ag Self crosslinking polyurethanes and graft copolymers and based on polyurethane, for producing coating materials, adhesives and sealing masses
US6737477B1 (en) 1999-11-06 2004-05-18 Basf Coatings Ac Polyurethanes and graft copolymers based on polyurethane and their use in the production of coating materials, adhesives and sealing masses

Also Published As

Publication number Publication date
US6063861A (en) 2000-05-16
EP0919579B1 (de) 2002-09-04
JP4204121B2 (ja) 2009-01-07
ATE223446T1 (de) 2002-09-15
EP0919579A1 (de) 1999-06-02
DE59805396D1 (de) 2002-10-10
JPH11256033A (ja) 1999-09-21
CA2254603C (en) 2008-09-23
CA2254603A1 (en) 1999-06-01

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Legal Events

Date Code Title Description
8139 Disposal/non-payment of the annual fee