DE19548586A1 - Insecticidal coating for controlling creeping insects - Google Patents
Insecticidal coating for controlling creeping insectsInfo
- Publication number
- DE19548586A1 DE19548586A1 DE1995148586 DE19548586A DE19548586A1 DE 19548586 A1 DE19548586 A1 DE 19548586A1 DE 1995148586 DE1995148586 DE 1995148586 DE 19548586 A DE19548586 A DE 19548586A DE 19548586 A1 DE19548586 A1 DE 19548586A1
- Authority
- DE
- Germany
- Prior art keywords
- paint
- insecticidal
- paints
- paint according
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D129/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Coating compositions based on hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Coating compositions based on derivatives of such polymers
- C09D129/02—Homopolymers or copolymers of unsaturated alcohols
- C09D129/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/24—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing ingredients to enhance the sticking of the active ingredients
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D131/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Coating compositions based on derivatives of such polymers
- C09D131/02—Homopolymers or copolymers of esters of monocarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/20—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for coatings strippable as coherent films, e.g. temporary coatings strippable as coherent films
Abstract
Description
Die Erfindung betrifft ein Verfahren zur Schädlingsbekämpfung mit film- oder haut- oder folienbil denden Anstrichen, die den insektiziden Wirkstoff enthalten, wobei sich nach der Anwendung der film- oder haut- oder folienbildende Anstrich rückstandsfrei wieder entfernen läßt.The invention relates to a method for pest control with film or skin or film bil the paints containing the insecticidal active ingredient, which after application of the film or skin or film-forming paint can be removed without residue.
Schädlingsbekämpfungsmaßnahmen gegen Insekten haben häufig den Nachteil, daß die Wirkstoffe auf den zu behandelnden Gütern oder Gegenständen zurückbleiben. Dadurch kann eine gesund heitliche Beeinträchtigung von Menschen und/oder Haus- und/oder Nutztieren stattfinden. Bevor zugt werden deshalb Schädlingsbekämpfungsmethoden angewendet, bei denen möglichst keine z. B. insektiziden Rückstände nach der Behandlung zurückbleiben. In der DE 32 25 515 C1 ist ein Verfahren beschrieben, bei dem ein Begasungsmittel in einen Behandlungsraum eingeleitet wird. Der Raum wird nach der Behandlung gelüftet und das Bekämpfungsgas entweicht vollständig, es bleibt also kein Rückstand. Diese Methode hat allerdings den Nachteil, daß keinerlei vorbeugender Schutzeffekt durch die Behandlung gegeben ist. In dem Buch von K. H. Büchel, Pflanzenschutz und Schädlingsbekämpfung, Verlag Georg Thieme, Stuttgart, S. 198 ff (1977) ist aufgeführt, daß Insektizide mit Formulierungshilfen versehen werden können. Die angegebenen Trägerstoffe haben aber den Nachteil, daß sie sich nach der Behandlung nicht mehr vollständig entfernen lassen, da z. B. bei einer Imprägnierung die Wirkstoffe in die zu behandelnden Güter eindringen oder die ein gesetzten Stäube sich nur schwer oder zeitaufwendig wieder entfernen bzw. aufsaugen oder an derweitig aufnehmen lassen.Pest control measures against insects often have the disadvantage that the active ingredients remain on the goods or objects to be treated. This can make you healthy uniform impairment of humans and / or domestic and / or farm animals take place. Before pest control methods are therefore applied in which, if possible, none e.g. B. Insecticidal residues remain after treatment. DE 32 25 515 C1 is a Process described in which a fumigant is introduced into a treatment room. The room is ventilated after the treatment and the control gas escapes completely so there is no residue. However, this method has the disadvantage that it is not preventive Protection effect is given by the treatment. In the book by K. H. Büchel, Plant Protection and pest control, Verlag Georg Thieme, Stuttgart, pp. 198 ff (1977) states that Insecticides can be provided with formulation aids. Have the specified carriers but the disadvantage that they cannot be completely removed after the treatment, because e.g. B. in the case of impregnation, the active ingredients penetrate into the goods to be treated or the one dust is difficult or time-consuming to remove or vacuum up again have it recorded.
Im Buch von G. H. Schmidt, Pestizide und Umweltschutz, Viehweg Verlag, Braunschweig, S. 71ff (1986) ist aufgeführt, daß eine Begiftung von Insekten auch mittels Insektizidfilmen erfolgen kann. Hierbei werden Insektizide in einem Lösungsmittel gelöst und das Lösungsmittel aufgestri chen. Zurück bleibt ein feiner Insektizidfilm. Vor allem kriechende Insekten krabbeln über diesen Film und kommen so in Kontakt mit dem Insektizid und sterben ab. Der Nachteil dieses Insekti zidfilms ist jedoch, daß er sich von der Oberfläche nur noch schwer entfernen läßt und durch das aufzubringende Lösungsmittel kann es passieren, daß der insektizide Wirkstoff in die Materialien, auf die der Film aufgebracht wird, eindringt und so haften bleibt. Auch dies ist wegen der Rück stände aus Umweltschutzgründen und gesundheitlichen Gesichtspunkten unerwünscht.In the book by G. H. Schmidt, Pesticides and Environmental Protection, Viehweg Verlag, Braunschweig, p. 71ff (1986) states that insects are also poisoned by means of insecticide films can. Here, insecticides are dissolved in a solvent and the solvent is spread on chen. What remains is a fine film of insecticide. In particular, crawling insects crawl over them Film and so come into contact with the insecticide and die. The disadvantage of this insect zidfilms is, however, that it is difficult to remove from the surface and through the Solvents to be applied may cause the insecticidal active ingredient to penetrate into the materials, to which the film is applied, penetrates and thus remains attached. This is also because of the back stands for environmental reasons and health considerations undesirable.
Im Prospekt der Fa. Ketol AG, Produktmerkblatt K081 10/92 ist ein insektizider Lack beschrie ben, der z. B. gegen Schaben auf Fußbodenleisten etc. aufgebracht wird. Die Schaben krabbeln über die mit dem insektiziden Lack behandelten Flächen und werden so begiftet. Der Lack läßt sich allerdings nicht mehr leicht entfernen und kann nur noch abgeschliffen oder mit aggressiven Lösungsmitteln entfernt werden. Auch dies ist zeitaufwendig bzw. nicht völlig rückstandsfrei.An insecticidal paint is described in the brochure from Ketol AG, product data sheet K081 10/92 ben, the z. B. is applied against scraping on baseboards etc. The cockroaches crawl over the areas treated with the insecticidal paint and are poisoned in this way. The paint leaves however, it is no longer easy to remove and can only be sanded or with aggressive Solvents are removed. This is also time-consuming or not completely free of residues.
Aufgabe der Erfindung ist es deshalb, ein Verfahren vorzuschlagen, bei dem insektizide Wirkstoffe auf einen Untergrund aufgebracht werden und sich die insektiziden Wirkstoffe nach einer Wirk phase wieder rückstandsfrei entfernen lassen. Die Aufgabe der Erfindung ist dadurch gelöst, daß ein film- oder haut- oder folienbildender Anstrich mit einem Insektizid versehen wird und auf den Untergrund (z. B. Fußbodenleiste) aufgebracht wird oder der film- oder haut- oder folienbildende Anstrich auf die Fußbodenleiste aufgebracht wird und anschließend ein Insektizid aufgetragen wird. Der film- oder haut- oder folienbildende Anstrich ist so beschaffen, daß er sich leicht vom Untergrund wieder vollständig abziehen läßt und somit nicht nur der film- oder haut- oder folien bildende Anstrich, sondern auch das Insektizid wieder entfernt werden können, ohne daß Rück stände zurückbleiben. In bevorzugter Ausgestaltung der Erfindung handelt es sich um farblose, transparente oder pigmentierte abziehbare Lacke bzw. Klarlacke, insbesondere um geruchlose dieser Art. Die Geruchlosigkeit ist wichtig, damit die Lacke nicht repellent auf Insekten wirken. Es ist jedoch möglich, Köderstoffe und/oder Attraktantien und/oder Pheromone und/oder sonstige Lockstoffe in die Lacke einzumischen oder nach dem Trocknen und/oder dem Aufbringen der Lacke diese auf den Film oder die Haut oder die Folie aufzusprühen oder sonstwie aufzutragen. Die abziehbaren Lacke eignen sich besonders gegen die Einwanderung oder Ausbreitung oder Vermehrung von Schaben, Silberfischchen, Ameisen, Teppichkäfern, Brotkäfern und anderen krie chenden Insektenarten. Sie können entlang von Boden und Wandfugen bzw. Scheuer-, Staub- und Wandleisten aufgetragen werden. Auch die Anwendung auf Sockeln von Küchenmöbeln, Boilern, Backöfen, Herden, Spülmaschinen, Waschmaschinen, Kühlschränken oder Truhen, in Hohlräumen zwischen diesen Elektrogeräten und dem Fußboden, in Hohlräumen von eingebauten Badewannen und Waschbecken, auf Oberflächen von Elektroleitungen oder sonstigen Leitungen in Mauer durchbrüchen, Ritzen, Schächten, Fugen, Aufzügen und Manschetten oder Abdeckungen von sani tären Installationen, in Klimaanlagen etc. ist möglich. Sie lassen sich auch auf empfindliche Ober flächen, z. B. bemalte oder lackierte Materialien und auch auf poröse Werkstoffe und Materialien auftragen. Die Lacke lassen sich mit Pinseln, Düsen oder sonstigen Sprüh- oder Spritzgeräten so wie aus Spraydosen oder sonstigen Druckbehältern aufbringen bzw. anwenden. In bevorzugter Ausgestaltung der Erfindung müssen die Oberflächen nicht trocken und weder staub- noch fettfrei sein. In bevorzugter Ausgestaltung der Erfindung sind die Lacke weder korrosiv noch vergilbend.The object of the invention is therefore to propose a method in which insecticidal active ingredients are applied to a substrate and the insecticidal active ingredients after one Have the phase removed again without leaving any residue. The object of the invention is achieved in that a film or skin or film-forming paint is provided with an insecticide and on the Substrate (e.g. skirting board) is applied or the film or skin or film-forming Paint is applied to the baseboard and then an insecticide is applied becomes. The film or skin or film-forming paint is such that it easily differs from Allow the surface to be completely peeled off and not just the film or skin or foils forming coat of paint, but also the insecticide can be removed again without having to return remain behind. In a preferred embodiment of the invention, it is colorless, transparent or pigmented peelable varnishes or clear varnishes, especially odorless of this kind. Odorlessness is important so that the paints do not have a repellent effect on insects. It however, bait and / or attractants and / or pheromones and / or others is possible Mix attractants into the paints or after drying and / or applying the Spray them on the film or the skin or the foil or apply them in any other way. The peelable paints are particularly suitable against immigration or spreading or Multiplication of cockroaches, silverfish, ants, carpet beetles, bread beetles and other krie insect species. You can along floor and wall joints or abrasion, dust and Wall moldings can be applied. Also used on the bases of kitchen furniture, boilers, Ovens, stoves, dishwashers, washing machines, refrigerators or chests, in cavities between these electrical devices and the floor, in cavities of built-in bathtubs and sinks, on surfaces of electrical lines or other lines in walls breakthroughs, gaps, shafts, joints, elevators and sleeves or covers from sani tary installations, in air conditioning systems etc. is possible. They can also be used on sensitive waiters surfaces, e.g. B. painted or lacquered materials and also on porous materials Instruct. The paints can be so with brushes, nozzles or other spray or spray equipment as from spray cans or other pressure vessels. In preferred Embodiment of the invention, the surfaces do not have to be dry and neither dust nor grease-free be. In a preferred embodiment of the invention, the paints are neither corrosive nor yellowing.
In die Lacke oder auf die Lacke lassen sich alle gängigen Insektizide einmischen oder aufbringen.
Es sind dies
Phosphorsäureester wie Azinphos-ethyl, Azinphos-methyl,
a-1(4-Chlorphenyl)-4-(O-ethyl,
S-propyl)phosphoryloxy-pyrazol, Chlorpyriphos, Coumaphos, Demeton, Demeton-S-methyl, Diazi
non, Dichlorvos, Dimethoate, Ethoate. Bthoprophos, Etrimphos, Fenitrothion, Fenthion, Hep
tenophos, Parathion, Parathionmethyl, Phosalone, Phoxim, Pirimiphos-ethyl, Pirimiphos-methyl,
Profenophos Prothiophos, Sulfprophos, Triazophos und Trichlorphon;
Carbamate wie Aldicarb, Bendiocarb, a-2-(1-Methylpropyl)-phenylmethylcarbamat, Butocar
boxim, Butoxycarboxim, Carbaryl, Carbofuran, Carbosulfan, Cloethocarb, Isoprocarb, Methomyl,
Oxamyl, Pirimicarb, Promecarb, Propoxur, Difenacoum und Thiodicarb,
Organosiliciumverbindungen, vorzugsweise Dimethyl(phenyl)silyl-methyl-3-phenoybenzylether
wie Dimethyl-(4-ethoxyphenyl)-silylmethyl-3-phenoxybenzylether oder (Dimethylphenyl)-silyl
methyl-2-phenoxy-6-pyridylmethylether wie z. B. Dimethyl-(9-ethoxy-phenyl)-silylmethyl-2-phen
oxy-6-pyridylmethylether oder [(Phenyl)-3-(3-phenoxyphenyl)-propyl](dimethyl)-silane wie z. B.
(4-Ethoxyphenyl)-[3-(4-fluoro-3-phenoxyphenylpropyl]dimethyl-silan, Silafluofin;
Pyrethroide wie Allethrin, Alphamethrin, Bioresmethrin, Byfenthrin, Cycloprothrin, Cyfluthrin,
Decamethrin, Cyhalothrin, Cypermethrin, Deltamethrin, Alpha-cyano-3-phenyl-2-methylbenzyl-
2,2-dimethyl-3-(2-chlor-2-trifluor-methylvinyl)cyclopropancarboxylat-, Fenpropathrin, Fenfluthrin,
Fenvalerate, Flucythrinate, Flumethrin, Fluvalinate, Permethrin, Resmethrin und Tralomethrin,
Naturpyrethrumextrakt;
Nitroimine und Nitromethylene wie 1-[(6-Chlor-3-pyridinyl)-methyl]-4,5-dihydro-N-nitro-1H-imidazol-2-a-min
(Imidacloprid), N-[(6-Chlor-3-pyridyl)methyl]-N²-cyano-N¹-methylacetamide
(NI-25), Abmectin, AC 303,630, Acephate, Acrinathrin, Alanycarb, Aldoxycarb, Aldrin, Ammo
niumbifluoride, Amitraz, Azamethiphos, Bacillus thuringiensis, Phosmet, Phosphamidon, Phosphi
ne, Prallethrin, Propaphos, Propetamphos, Prothoate, Pyraclophos, Pyrethrins, Pyridaben, Py
ridafenthion, Pyriproxyfen, Quinalphos, RH7988, Rotenone, Sodium fluonde Sodium hexaflu
orosilicate, Sulfotep, Sulfuryl fluoride, Tar Oils, Teflubenzuron, Tefluthrin, Temephos, Terbuphos,
Tetrachlorvinphos, Tetramethrin, O-2-tert.-Butyl-pyflinidrin-5-yl-o-isopropylphosphorothiate,
Thiocyclam, Thiofanox, Thiometon, Tralomethrin, Triflumuron, Trimethacarb, Vamidothion, Ver
ticillium Lacanii, XMC, Xylylcarb, Benfuracarb, Bensultap, Bifenthrin, Bioallethrin, MERbioal
lethrin (S)-cyclopentenyl isomer, Bromophos, Bromophosethyl, Buprofezin, Cadusaphos, Calcium
Polysulfide, Carbophenothion, Cartap, Chinomethionat, Chlordane, Chlorfenvinphos, Chlorfluazu
ron, Chlormephos, Chloropicrin, Chlorpyriphos, Cyanophos, Beta-Cyfluthrin, Alphacypermethrin,
Cyophenothrin, Cyromazine, Dazomet, DDT, Demeton-S-methylsulphon, Diafenthiuron, Diali
phos, Dicrotophos, Diflubenzuron, Dinoseb, Dioxabenzophos, Diaxacarb, Disulfoton, DNOC,
Empenthrin, Endosulfan, EPN, Esfenvalerate, Ethiofencarb, Ethion, Etofenprox, Fenobucarb,
Fenoxycarb, Fensulfothion, Fipronil, Flucycloxuron, Flufenprox, Flufenoxuron, Fonophos, Forme
tanate, Formothion, Phosmethilan, Furathiocarb, Heptachlor, Hexaflumuron, Hydramethylnon,
Hydrogen Cyanide, Hydroprene, IPSP, Isazophos, Isofenphos, Isoprothiolane, Isoxathion, Iodfen
phos, Kadethrin, Lindane, Malathion, Mecarbam, Mephosfolan, Mercurouschloride, Metam, Me
tarthizium anisopliae, Methacriphos, Methamidophos, Methidathion, Methiocarb, Methoprene,
Methoxychlor, Methyl isothiocyanate, Metholcarb, Mevinphos, Monocrotophos, Naled, Neodi
prion sertifer NPV, Nicotine, Omethoate, Oxydemetonmethyl, Pentachlorophenol, Petroleum oils,
Phenothrin, Phenthoate, Phorate,
Benzoylharnstoffe wie Chlorfluazuron, Diflubenzuron, Flufenoxuron, Flucycloxuron, Hexaflu
muron, Penfluron, Teflubenzuron, andere Entwicklungsinhibitoren wie beispielsweise Benzoe
säure-[2-benzoyl-1-(1,1-dimethylethyl)]-hydrazid, 2,6-Dimethoxy-N-[5-]4-(pentatluorethoxy) phe
nyl-[2,3,4-thiadiazol-2-yl]-benzamid, N-Cyclo-propyl-1,3,5-triazin-2,4-triamin, 2-(4-Phenoxyphe
nyl)-ethyl-ethylcarbamat, 1-(Decycloxy)-4-[(6-methoxy-4-hexinyl)-oxy]benzene, (2-Propinyl)-4-
methoxy-benzoat, Fenoxycarb, Pyriproxyfen, Triarathene, Thiapronil, Hexythiazox, Clofentezine,
4-Chloro-5-(6-chloro-3-pyridylmethoxy)-2-(3,4-dichlorophenyl)-pyrida-zin3(2H)-one, Buprofezin,
Hydroprene, Kinoprene, Methoprene, Cycloprate, Gusathin, Padan, Paraxon, Tribunil, Isomere
und Triprene sowie Sulfamid und Propuxur.All common insecticides can be mixed or applied into the paints or on the paints. They are
Phosphoric acid esters such as azinphos-ethyl, azinphos-methyl, a-1 (4-chlorophenyl) -4- (O-ethyl, S-propyl) phosphoryloxy-pyrazole, Chlorpyriphos, Coumaphos, Demeton, Demeton-S-methyl, Diazi non, dichlorvos , Dimethoate, Ethoate. Bthoprophos, Etrimphos, Fenitrothion, Fenthion, Hep tenophos, Parathion, Parathionmethyl, Phosalone, Phoxim, Pirimiphos-ethyl, Pirimiphos-methyl, Profenophos Prothiophos, Sulfprophos, Triazophos and Trichlorphone;
Carbamates such as aldicarb, bendiocarb, a-2- (1-methylpropyl) phenylmethyl carbamate, butocar boxim, butoxycarboxim, carbaryl, carbofuran, carbosulfan, cloethocarb, isoprocarb, methomyl, oxamyl, pirimicarb, promecarb, propoxur, difenacoum and difenacoum
Organosilicon compounds, preferably dimethyl (phenyl) silyl-methyl-3-phenoybenzyl ether such as dimethyl- (4-ethoxyphenyl) -silylmethyl-3-phenoxybenzyl ether or (dimethylphenyl) -silyl methyl-2-phenoxy-6-pyridylmethyl ether such as e.g. B. dimethyl- (9-ethoxy-phenyl) -silylmethyl-2-phenoxy-6-pyridylmethyl ether or [(phenyl) -3- (3-phenoxyphenyl) propyl] (dimethyl) -silanes such as, for. B. (4-ethoxyphenyl) - [3- (4-fluoro-3-phenoxyphenylpropyl] dimethyl silane, silafluofin;
Pyrethroids such as allethrin, alphamethrin, bioresmethrin, byfenthrin, cycloprothrin, cyfluthrin, decamethrin, cyhalothrin, cypermethrin, deltamethrin, alpha-cyano-3-phenyl-2-methylbenzyl-2,2-dimethyl-3- (2-chloro-2-trifluoromethyl) -methylvinyl) cyclopropanecarboxylate, fenpropathrin, fenfluthrin, fenvalerate, flucythrinate, flumethrin, fluvalinate, permethrin, resmethrin and tralomethrin, natural pyrethrum extract;
Nitroimines and nitromethylenes such as 1 - [(6-chloro-3-pyridinyl) methyl] -4,5-dihydro-N-nitro-1H-imidazol-2-a-min (imidacloprid), N - [(6-chloro -3-pyridyl) methyl] -N²-cyano-N¹-methylacetamide (NI-25), Abmectin, AC 303,630, Acephate, Acrinathrin, Alanycarb, Aldoxycarb, Aldrin, Ammonium bifluoride, Amitraz, Azamethiphos, Bacillus thuringiensis, Phosmet, Phosphamid Phosphi ne, Prallethrin, Propaphos, Propetamphos, Prothoate, Pyraclophos, Pyrethrins, Pyridaben, Py ridafenthion, Pyriproxyfen, Quinalphos, RH7988, Rotenone, Sodium fluonde Sodium hexaflu orosilicate, Sulfotep, Sulfuryl fluoride, Tar Oils, Tefuplenzuron, Tefuplenzuron, Tefuplenzuron, Tefuplenzuron Tetrachlorvinphos, tetramethrin, O-2-tert.-butyl-pyflinidrin-5-yl-o-isopropylphosphorothiate, thiocyclam, thiofanox, thiometone, tralomethrin, triflumuron, trimethacarb, vamidothion, ver ticillium carbi, xanifuryl, xaniifloyl, carbamyl, xaniifloyl, carbamyl, xaniylyl , Bioallethrin, MERbioal lethrin (S) -cyclopentenyl isomer, bromophos, bromophosethyl, buprofezin, Cadusaphos, Calcium Polysulfide, Carbophenothion, Cartap, Chinomethionat, Chlordane, Chlorfenvinphos, Chlorfluazu ron, Chlormephos, Chloropicrin, Chlorpyriphos, Cyanophos, Beta-Cyfluthrin, Alphacypermethrin, Cyophenothrin, Cyromazine-Methyls, Dazomethonon, Dazomethonon, Dazometonos , Dicrotophos, Diflubenzuron, Dinoseb, Dioxabenzophos, Diaxacarb, Disulfoton, DNOC, Empenthrin, Endosulfan, EPN, Esfenvalerate, Ethiofencarb, Ethion, Etofenprox, Fenobucarb, Fenoxycarb, Fensulfothion, Fipronil, Floxproxionon, Flucyclproxiononon Phosmethilan, Furathiocarb, Heptachlor, Hexaflumuron, Hydramethylnon, Hydrogen Cyanide, Hydroprene, IPSP, Isazophos, Isofenphos, Isoprothiolane, Isoxathion, Iodfen phos, Kadethrin, Lindane, Malathion, Mecarbam, Mephosfolan, Methamosophane, Methamosophane, Methamosophane, Methamosphosethane, Methamosphosethane, Mercamouschloride, Mercamous chloros Methidathione, Methiocarb, Methoprene, Methoxychlor, Methyl isothiocyanate, Metholcarb, Mevinphos, Monocrotop hos, Naled, Neodi prion sertifer NPV, Nicotine, Omethoate, Oxydemetonmethyl, Pentachlorophenol, Petroleum oils, Phenothrin, Phenthoate, Phorate,
Benzoyl ureas such as chlorfluazuron, diflubenzuron, flufenoxuron, flucycloxuron, hexafluuron, penfluron, teflubenzuron, other development inhibitors such as benzoic acid- [2-benzoyl-1- (1,1-dimethylethyl)] hydrazide, 2,6-dimethoxy-N- [5-] 4- (pentatluoroethoxy) phenyl- [2,3,4-thiadiazol-2-yl] benzamide, N-cyclopropyl-1,3,5-triazine-2,4-triamine, 2- (4-phenoxyphenyl) ethyl ethyl carbamate, 1- (decycloxy) -4 - [(6-methoxy-4-hexynyl) -oxy] benzene, (2-propynyl) -4-methoxy benzoate, fenoxycarb, pyriproxyfen, Triarathenes, thiapronil, hexythiazox, clofentezine, 4-chloro-5- (6-chloro-3-pyridylmethoxy) -2- (3,4-dichlorophenyl) -pyrida-zin3 (2H) -one, buprofezin, hydroprene, kinoprene, methoprene , Cycloprate, Gusathin, Padan, Paraxon, Tribunil, Isomers and Triprene as well as Sulfamide and Propuxur.
Bevorzugt konnen diese Insektizide mikroverkapselt sein oder auch in ihrer Wirkung durch Synergisten wie z. B. - jedoch nicht limitierend - Methylendioxyphenyl-Derivate, Propargylalkohol Derivate, Ether, nicht insektizide Phosphorsaureester bzw. Thiophosphorsaureester, substituierte Azol-Derivate, Pinonester, Dimethylformamid, Capryldiethylamid, Isopropylester von ungesättig ten C₁₂-Carbonsäuren bis C₁₈-Carbonsäuren, Diarylamin, langkettige cyclische Imide und Synepi rin verstärkt sein.These insecticides can preferably be microencapsulated or else in their action Synergists such as B. - but not limiting - methylenedioxyphenyl derivatives, propargyl alcohol Derivatives, ethers, non-insecticidal phosphoric acid esters or thiophosphoric acid esters, substituted Azole derivatives, pinone esters, dimethylformamide, caprylic diethylamide, isopropyl esters of unsaturated ten C₁₂-carboxylic acids to C₁₈-carboxylic acids, diarylamine, long-chain cyclic imides and Synepi be reinforced.
Die Abziehlacke können als wasserbasierende Lacke ausgebildet sein. Soweit sie nach dem trock nen wasserlöslich bleiben, lassen sie sich nach der Einwirkung leicht mit Wasser wieder entfernen. Sie sind jedoch auch als wasserbeständige Abziehlacke, insbesondere auf Alkohol basierend, for mulierbar. Sie haben den Vorteil, daß sie wesentlich schneller trocknen als die wasserbasierenden Abziehlacke. Besonders vorteilhaft ist in bevorzugter Ausgestaltung der Erfindung die Dehn- oder Reißfestigkeit der Lacke, damit sie beim Abziehen nicht einreißen und Teilstücke bilden, die auf dem Untergrund zurückbleiben. Die Reißfestigkeit der Lacke ist beeinflußbar durch die Schicht dicke der aufgetragenen Lacke. Die aufgetragene Menge der Lacke ist besonders vorteilhaft bei 0,3-0,5 kg/m². Als besonders geeignet haben sich auf einwertigen Alkoholen, wie Butanol, basie rende, bevorzugt wasserbeständige Abziehlacke (z. B. Isoflex 70 oder Isoflex 75) erwiesen, die organische Polymerverbindungen enthalten, wie Polyvinylbutyrate und Hilfsstoffe, wie trennwirk same Hilfsstoffe, sowie ggf. Pigmente. In diese Abziehlacke, die vor dem Auftragen als Flüssigkei ten vorliegen, läßt sich vor dem Auftragen wenigstens ein Insektizid oder lassen sich Insektizidmi schungen bzw. mehrere Insektizide einmischen. Es ist jedoch auch möglich, zunächst die Ab ziehlacke als Flüssigkeit aufzutragen und nach dem Auftragen und/oder nach dem Abtrocknen und/oder nach der Film bzw. Haut bzw. Folienbildung die Insektizide oder die Insektizidmi schungen und/oder die Synergisten hierauf aufzutragen, z. B. durch Streichen, Sprühen etc.The stripping lacquers can be designed as water-based lacquers. As far as after the dry remain water-soluble, they can easily be removed with water after exposure. However, they are also available as water-resistant peelable varnishes, especially based on alcohol mulbar. They have the advantage that they dry much faster than the water-based ones Peeling varnishes. In a preferred embodiment of the invention, the stretching or Tear resistance of the paints, so that they do not tear when peeled off and form sections that open remain on the ground. The tear strength of the paints can be influenced by the layer thickness of the applied varnish. The amount of varnish applied is particularly advantageous for 0.3-0.5 kg / m². Based on monohydric alcohols, such as butanol, have been found to be particularly suitable proven, preferably water-resistant peelable varnishes (e.g. Isoflex 70 or Isoflex 75), which contain organic polymer compounds, such as polyvinyl butyrates and auxiliaries, such as release agents same auxiliaries, and possibly pigments. In these peelable varnishes, which are applied as liquids before application ten are present, at least one insecticide or insecticide mixture can be applied before application mixtures or mix in several insecticides. However, it is also possible to start with the Ab Apply varnish as a liquid and after application and / or after drying and / or after the film or skin or film formation, the insecticides or the insecticide and / or to apply the synergists thereon, e.g. B. by painting, spraying, etc.
Weitere vorteilhafte Ausgestaltungen der Erfindung ergeben sich aus den nachfolgend aufgeführ ten Ansprüchen bzw. Unteransprüchen.Further advantageous refinements of the invention result from the following th claims or subclaims.
Claims (18)
Carbamate wie Aldicarb, Bendiocarb, a-2-(1-Methylpropyl)-phenylmethylcarbamat, Butocarboxim, Butoxy carboxim, Carbaryl, Carbofuran, Carbosulfan, Cloethocarb, Isoprocarb, Methomyl, Oxamyl, Pirimicarb, Promecarb, Propoxur, Difenacoum und Thiodicarb;
Organosiliciumverbindungen, vorzugsweise Dimethyl(phenyl)silyl-methyl-3-phenoybenzylether wie Dime thyl-(4-ethoxyphenyl)-silylmethyl-3-phenoxybenzylether oder (Dimethylphenyl)-silyl-methyl-2-phenoxy-6-pyridylmethylether wie z. B. Dimethyl-(9-ethoxy-phenyl)-silylmethyl-2-phenoxy-6-pyridylmethylethe-r oder [(Phenyl)-3-(3-phenoxyhenyl)-propyl](dimethyl)-silane wie z. B. (4-Ethoxyphenyl)-[3-(4-fluoro-3-phenoxy phenylpropyl]dimethyl-silan, Silafluofin;
Pyrethroide wie Methrin, Alphamethrin, Bioresmethrin, Byfenthrin, Cycloprothrin, Cyfluthrin, Decamethrin, Cyhalothrin, Cypermethrin, Deltamethrin, Alpha-cyano-3-phenyl-2-methylbenzyl-2,2-dimethyl-3-(2-chlor-2- trifluor-methylvinyl)cydopropancarboxylat, Fenpropathrin, Fenfluthrin, Fenvalerate, Flucythrinate, Flu methrin, Fluvalinate, Permethrin, Resmethrin und Tralomethrin, Naturpyrethrumextrakt;
Nitroimine und Nitromethylene wie 1-[(6-Chlor-3-pyridinyl)-methyl]-4,5-dihydro-N-nitro-1H-imidazol-2- amin (Imidacloprid), N-[(6-Chlor-3-pyridyl)methyl-]N²-cyano-N¹-methylacetamide (NI-25), Abamectin, AC 303,630, Acephate, Acrinathrin, Alanycarb, Aldoxycarb, Aldrin, Ammoniumbifluoride, Amitraz, Azamethi phos, Bacillus thuringiensis, Phosmet, Phosphamidon, Phosphine, Prallethrin, Propaphos, Propetamphos, Prothoate, Pyraclophos, Pyrethrins, Pyridaben, Pyridafenthion, Pyriproxyfen, Quinalphos, RH7988, Rote none, Sodium fluonde, Sodium hexafluorosilicate, Sulfotep, Sulfurylfluoride, Tar Oils, Teflubenzuron, Te fluthrin, Temephos, Terbuphos, Tetrachlorvinphos, Tetramethrin, O-2-tert.-Butyl-pyflinidrin-5-yl-o-isopro pylphosphorothiate, Thiocyclam, Thiofanox, Thiometon, Tralomethrin, Triflumuron, Trimethacarb, Vami dothion, Verticillium Lacanii, XMC, Xylylcarb, Benfuracarb, Bensultap, Bifenthrin, Bioallethrin, MERbioal lethrin (S)-cyclopentenyl isomer, Bromophos, Bromophosethyl, Buprofezin, Cadusaphos, Calcium Polysul fide, Carbophenothion, Cartap, Chinomethionat, Chlordane, Chlorfenvinphos, Chlorfluazuron, Chlormephos, Chloropicrin, Chlorpyriphos, Cyanophos, Beta-Cyfluthrin, Alphacypermethrin, Cyophenothrin, Cyromazine, Dazomet, DDT, Demeton-S-methylsulphon, Diafenthiuron, Dialiphos, Dicrotophos, Diflubenzuron, Dino seb, Dioxabenzophos, Diaxacarb, Disulfoton, DNOC, Empenthrin, Endosulfan, EPN, Esfenvalerate, Ethiofencarb, Ethion, Etofenprox, Fenobucarb, Fenoxycarb, Fensulfothion, Fipronil, Flucycloxuron, Flu fenprox, Flufenoxuron, Fonophos, Formetanate, Formothion, Phosmethilan, Furathiocarb, Heptachlor, Hexaflumuron, Hydramethylnon, Hydrogen Cyanide, Hydroprene, IPSP, Isazophos, Isofenphos, Isoprothio lane, Isoxathion, Iodfenphos, Kadethrin, Lindane, Malathion, Mecarbam, Mephosfolan, Mercurouschloride, Metam, Metarthizium anisophae, Methacriphos, Methamidophos, Methidathion, Methiocarb, Methoprene, Methoxychlor, Methyl isothiocyanate, Metholcarb, Mevinphos, Monocrotophos, Naled, Neodipnon sertifer NPV, Nicotme, Omethoate, Oxydemetonmethyl, Pentachlorophenol, Petroleum oils, Phenothrin, Phenthoate, Phorate;
Benzoylharnstoffe wie Chlorfluazuron, Diflubenzuron, Flufenoxuron, Flucycloxuron, Hexaflumuron, Penflu ron, Teflubenzuron, andere Entwicklungsinhibitoren wie beispielsweise Benzoesäure-[2-benzoyl-1-(1,1-di methylethyl)]-hydrazid, 2,6-Dimethoxy-N-[5-]4-(pentafluorethoxy)-phenyl-[2,3,4-thiadiazol-2--yl]-benzamid, N-Cyclo-propyl-1,3,5-triazin-2,4-triamin, 2-(4-Phenoxyphenyl)-ethyl-ethylcarbamat, 1-(Decydoxy)-4-[(6- methoxy-4-hexinyl)-oxy]benzene, (2-Propinyl)-4-methoxy-benzoat, Fenoxycarb, Pyriproxyfen, Triarathene, Thiapronil, Hexythiazox, Clofentezine, 4-Chloro-5-(6-chloro-3-pyridylmethoxy)-2-(3,4-dichlorophenyl)-pyrida-zin3(2H)-one, Buprofezin, Hydroprene, Kinoprene, Methoprene, Cycloprate, Gusathin, Padan, Para xon, Tribunil, Isomere und Triprene sowie Sulfamid und Propuxur
sind, wobei diese insbesondere zusätzlich mikroverkapselt sein können. 4. Insecticidal paint or paint according to claim 3 or one of the preceding claims, characterized in that the insecticide or phosphoric acid esters such as azinphos-ethyl, aznphos-methyl a-1 (4-chlorophenyl) 4- (O-ethyl, S-propyl) ) phos phoryloxy-pyrazole, Chlorpyriphos, Coumaphos, Demeton, Demeton-S-methyl, Diazinon, Dichlorvos, Dime thoate, Ethoate. Bthoprophos, Etrimphos, Fenitrothion, Fenthion, Heptenophos, Parathion, Parathionmethyl, Phosalone, Phoxim, Pirimiphos-ethyl, Pirimiphos-methyl, Profenophos Prothiophos, Sullprophos, Triazo phos and Trichlorphon;
Carbamates such as aldicarb, bendiocarb, a-2- (1-methylpropyl) phenylmethyl carbamate, butocarboxime, butoxy carboxim, carbaryl, carbofuran, carbosulfan, cloethocarb, isoprocarb, methomyl, oxamyl, pirimicarb, promecarb, propoxur, difenacoum;
Organosilicon compounds, preferably dimethyl (phenyl) silylmethyl-3-phenoybenzyl ether such as dimethyl (4-ethoxyphenyl) silylmethyl-3-phenoxybenzyl ether or (dimethylphenyl) silylmethyl-2-phenoxy-6-pyridylmethyl ether such as e.g. B. Dimethyl- (9-ethoxy-phenyl) -silylmethyl-2-phenoxy-6-pyridylmethylethe-r or [(phenyl) -3- (3-phenoxyhenyl) propyl] (dimethyl) -silanes such as, for. B. (4-Ethoxyphenyl) - [3- (4-fluoro-3-phenoxyphenylpropyl] dimethyl silane, silafluofin;
Pyrethroids such as methrin, alphamethrin, bioresmethrin, byfenthrin, cycloprothrin, cyfluthrin, decamethrin, cyhalothrin, cypermethrin, deltamethrin, alpha-cyano-3-phenyl-2-methylbenzyl-2,2-dimethyl-3- (2-chloro-2-trif -methylvinyl) cydopropane carboxylate, fenpropathrin, fenfluthrin, fenvalerate, flucythrinate, flu methrin, fluvalinate, permethrin, resmethrin and tralomethrin, natural pyrethrum extract;
Nitroimines and nitromethylenes such as 1 - [(6-chloro-3-pyridinyl) methyl] -4,5-dihydro-N-nitro-1H-imidazol-2-amine (imidacloprid), N - [(6-chloro-3 -pyridyl) methyl-] N²-cyano-N¹-methylacetamide (NI-25), Abamectin, AC 303,630, Acephate, Acrinathrin, Alanycarb, Aldoxycarb, Aldrin, Ammoniumbifluoride, Amitraz, Azamethi phos, Bacillus thuringiensis, Phosmetine, Phosphamidon Prallethrin, Propaphos, Propetamphos, Prothoate, Pyraclophos, Pyrethrins, Pyridaben, Pyridafenthion, Pyriproxyfen, Quinalphos, RH7988, Rote none, Sodium fluonde, Sodium hexafluorosilicate, Sulfotep, Sulfurylfluoride, Tar Oils, Teflubhrinetron, Teflubhrinuron, Teflubenzuron , O-2-tert-butyl-pyflinidrin-5-yl-o-isopropylphosphorothiate, Thiocyclam, Thiofanox, Thiometon, Tralomethrin, Triflumuron, Trimethacarb, Vami dothion, Verticillium Lacanii, XMC, Xylylifhrinin, Benfuracin , MERbioal lethrin (S) -cyclopentenyl isomer, bromophos, bromophosethyl, buprofezin, Cadusaphos, Calcium Polysul fide, Carbophenothion, Cartap, Chinomethionate, Chlordane, Chlorfenvinphos, Chlorfluazuron, Chlormephos, Chloropicrin, Chlorpyriphos, Cyanophos, Beta-Cyfluthrin, Alphacypermethrin, Cyophenothrin, Cyromazine, Methylphosphonium, Dafomethonon, Dafomethonon Dicrotophos, Diflubenzuron, Dino seb, Dioxabenzophos, Diaxacarb, Disulfoton, DNOC, Empenthrin, Endosulfan, EPN, Esfenvalerate, Ethiofencarb, Ethion, Etofenprox, Fenobucarb, Fenoxycarb, Fensulfothion, Fipronil, Fencyclofonate, Flucyclproxonon, Flucyclproxonon, Flucyclproxonon, Flucyclproxetonon Phosmethilan, Furathiocarb, Heptachlor, Hexaflumuron, Hydramethylnon, Hydrogen Cyanide, Hydroprene, IPSP, Isazophos, Isofenphos, Isoprothio lane, Isoxathion, Iodfenphos, Kadethrin, Lindane, Malathion, Mecarbam, Mephosfolide, Methamhaethidos, Methamhaosidos, Methamhaosidos, Methamhahaidos, Methurha Chloros, Methamoshaidos, Methamoshaidos, Methurha Chloride, Methamha, Methosha , Methiocarb, Methoprene, Methoxychlor, Methyl isothiocyanate, Metholcarb, Mevinphos, Monocrotoph os, Naled, Neodipnon sertifer NPV, Nicotme, Omethoate, Oxydemetonmethyl, Pentachlorophenol, Petroleum oils, Phenothrin, Phenthoate, Phorate;
Benzoylureas such as chlorfluazuron, diflubenzuron, flufenoxuron, flucycloxuron, hexaflumuron, penfluoron, teflubenzuron, other development inhibitors such as benzoic acid [2-benzoyl-1- (1,1-di methylethyl)] hydrazide, 2,6-dimethoxy-N- [5-] 4- (pentafluoroethoxy) phenyl- [2,3,4-thiadiazol-2-yl] benzamide, N-cyclopropyl-1,3,5-triazine-2,4-triamine, 2 - (4-phenoxyphenyl) ethyl ethyl carbamate, 1- (decydoxy) -4 - [(6-methoxy-4-hexynyl) -oxy] benzene, (2-propynyl) -4-methoxy benzoate, fenoxycarb, pyriproxyfen, Triarathenes, thiapronil, hexythiazox, clofentezine, 4-chloro-5- (6-chloro-3-pyridylmethoxy) -2- (3,4-dichlorophenyl) -pyrida-zin3 (2H) -one, buprofezin, hydroprene, kinoprene, methoprene , Cycloprate, Gusathin, Padan, Para xon, Tribunil, Isomers and Triprene as well as Sulfamide and Propuxur
are, which in particular can additionally be microencapsulated.
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DE1995148586 DE19548586A1 (en) | 1995-12-23 | 1995-12-23 | Insecticidal coating for controlling creeping insects |
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DE1995148586 DE19548586A1 (en) | 1995-12-23 | 1995-12-23 | Insecticidal coating for controlling creeping insects |
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CN114342959A (en) * | 2022-01-18 | 2022-04-15 | 山东省农业科学院 | Composition for simultaneously preventing and treating cucumber aphid and cucumber bacterial angular leaf spot |
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DE102004022528A1 (en) * | 2004-05-05 | 2005-12-01 | Ecs Environment Care Systems Gmbh | Film that releases an active substance, e.g. insecticide or herbicide, in a controlled manner under the action of water comprises a water-soluble matrix material and the active substance |
CN114342959A (en) * | 2022-01-18 | 2022-04-15 | 山东省农业科学院 | Composition for simultaneously preventing and treating cucumber aphid and cucumber bacterial angular leaf spot |
CN114342959B (en) * | 2022-01-18 | 2023-06-09 | 山东省农业科学院 | Composition for simultaneously preventing and controlling cucumber aphids and cucumber bacterial angular leaf spot |
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