DE183653C - - Google Patents
Info
- Publication number
- DE183653C DE183653C DENDAT183653D DE183653DA DE183653C DE 183653 C DE183653 C DE 183653C DE NDAT183653 D DENDAT183653 D DE NDAT183653D DE 183653D A DE183653D A DE 183653DA DE 183653 C DE183653 C DE 183653C
- Authority
- DE
- Germany
- Prior art keywords
- objects
- different
- liquid
- question
- heated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000007788 liquid Substances 0.000 claims description 7
- RYGMFSIKBFXOCR-UHFFFAOYSA-N copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 5
- 229910052802 copper Inorganic materials 0.000 claims description 5
- 239000010949 copper Substances 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 4
- 238000000137 annealing Methods 0.000 claims 1
- 238000010791 quenching Methods 0.000 claims 1
- 230000000171 quenching Effects 0.000 claims 1
- 239000003086 colorant Substances 0.000 description 5
- 238000001816 cooling Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 3
- 240000002799 Prunus avium Species 0.000 description 2
- 235000019693 cherries Nutrition 0.000 description 2
- 238000005530 etching Methods 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 210000004369 Blood Anatomy 0.000 description 1
- 244000132059 Carica parviflora Species 0.000 description 1
- 235000014653 Carica parviflora Nutrition 0.000 description 1
- 241000189705 Dunedin group Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 239000000110 cooling liquid Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000004579 marble Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000005494 tarnishing Methods 0.000 description 1
- 238000005496 tempering Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C8/00—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C8/80—After-treatment
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C8/00—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C8/06—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases
- C23C8/08—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases only one element being applied
- C23C8/10—Oxidising
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Crystals, And After-Treatments Of Crystals (AREA)
Description
U
J' "'U
J '"'
i ii i
KAISERLICHESIMPERIAL
PATENTAMT.PATENT OFFICE.
PATENTSCHRIFTPATENT LETTERING
- Λ£ 183653 -KLASSE 48 d. GRUPPE - Λ £ 183653 - CLASS 48 d. GROUP
J.WINHART & CIE in MÜNCHEN.J.WINHART & CIE in MUNICH.
Um Kupferflächen durch bunte Muster mittels Anlauffarben zu dekorieren, werden nach bekannten Verfahren die gleichartig oder unter Zuhilfenahme einer Stichflamme verschiedenfarbig angelaufenen Kupferflächen mittels Ätzgrundes mit dem gewollten Muster versehen, worauf die übrige Oxydschicht durch verdünnte Säure entfernt und dann der Ätzgrund weggewaschen wird, so daß das nurIn order to decorate copper surfaces with colorful patterns using tempering colors, according to known methods the same or different colors with the aid of a jet flame Tarnished copper surfaces are provided with the desired pattern by means of an etching base, whereupon the remaining oxide layer shows through diluted acid is removed and then the etch base is washed away, so that's just
ίο durch die Anlauffarben gebildete Muster vorliegt. ίο there is a pattern formed by the temper colors.
Diese Verfahren ergeben aber keine für die Praxis brauchbaren Resultate, denn abgesehen davon, daß die Formen des Musters und der Verlauf der Farben nur sehr selten einigermaßen in Übereinstimmung gebracht werden können, fehlt der Färbung des. Musters künstlerische Tönung, Tiefe und Kraft und diese Muster sind nicht licht- bezw. luftbeständig, indem sie schon nach kurzer Zeit durch Nachoxydieren ihr Aussehen verändern und allmählich ganz verschwinden. Auch ist die fabrikmäßige Ausnutzung jener Verfahren in der Hauptsache an ebene Flächen gebunden.However, these methods do not produce any useful results in practice, because apart from that from the fact that the shapes of the pattern and the course of the colors are only very rarely brought into line with one another the color of the pattern lacks artistic tint, depth and strength and these patterns are not light or air-resistant by becoming after a short time change their appearance through post-oxidation and gradually disappear completely. Also is the factory use of those processes is mainly tied to flat surfaces.
Im Gegensatze hierzu betrifft vorliegende Erfindung ein Verfahren, um auf getriebenen, kunstgewerblichen Kupfergegenständen unter Benutzung der Anlauftechnik (ohne Ätzung) malerische Farbeneffekte und Töne, z. B. matt oder schillernd in Perlmutter-, Korallen- und Marmorimitatipn, zu erzeugen, welche zur wirksamen Unterstützung des Effektes der Treibarbeiten den plastischen Formen dieser letzteren Wärme und Leben geben.In contrast to this, the present invention relates to a method in order to Crafted copper objects using the tarnishing technique (without etching) picturesque color effects and tones, e.g. B. matt or shimmering in mother-of-pearl, coral and Marble imitatipn, which effectively support the effect of the Drifting work gives the plastic forms of these latter warmth and life.
Dieses Verfahren besteht darin, daß die betreffenden Kupfergegenstände nach einem vorhergehenden Blankscheuern in bekannter Weise wiederholt ganz oder stellenweise mehr oder weniger am Feuer erhitzt und ' nach jeder solchen Erwärmung ganz oder teilweise in einer Flüssigkeit abgekühlt werden. Diese Prozedur wird nach jedesmaligem Trocknen der Gegenstände so lange wiederholt, bis durch die dabei stattfindende Oxydation die gewünschten Muster- und Farbeneffekte an der Oberfläche der betreffenden Gegenstände erzielt sind. Dabei findet ein förmliches Einbrennen der betreffenden Farben in das Metall statt, so daß willkürliche Veränderungen derselben im Laufe der Zeit durch Nachoxydieren nicht stattfinden können. Durch nachträgliches Scheuern der Oberfläche wird dem betreffenden Farbenmuster Glanz und Frische sowie Transparenz gegeben.This method consists in that the copper objects in question after a previous bare chafing repeated in a known manner in whole or in places more or less heated by the fire and 'after each such heating in whole or in part be cooled in a liquid. This procedure is repeated after each drying the objects are repeated until the desired pattern and color effects on the surface of the objects in question are achieved. The colors in question are literally burned into the metal instead, so that arbitrary changes in the same in the course of time due to post-oxidation cannot take place. Subsequent rubbing of the surface gives the relevant color sample shine and freshness and given transparency.
Die Flüssigkeit, mit welcher das erwähnte Abkühlen der Gegenstände nach dem Erwärmen stattfindet, kann eine verschiedene sein, z. B. Wasser, öle oder bestimmte Lösungen allein oder gemischt, mit verschiedenen Zusätzen in verschiedenen Temperaturen.The liquid with which the mentioned cooling of the objects after heating takes place can be different, e.g. B. water, oils or certain solutions alone or mixed, with different additives at different temperatures.
Um beim Abkühlen die Flüssigkeit gleichzeitig mit verschiedenen Temperaturen auf die heißen Gegenstände wirken zu lassen, kann z. B. auf Wasser eine Schicht Eis oder öl gegeben werden, welche auf den betreffenden Gegenständen anders wirkt und dadurch andere Farbeneffekte herbeiführt, wie die darunter befindliche Flüssigkeitsschicht,In order to cool down the liquid at the same time with different temperatures to let the hot objects act, z. B. a layer of ice or water oil are given, which has a different effect on the objects in question and thereby creates other color effects, such as the layer of liquid underneath,
Zweckmäßig- wird die betreffende Kühlflüssigkeit je nach der g-ewünschten Wirkung entsprechend mehr oder weniger warm zur Anwendung gebracht. Ebenso wird die Erzeugung der betreffenden Farbeneffekte beim Abkühlen in jenen Flüssigkeiten eine verschiedene sein, je nachdem der betreffende Gegenstand kirschrot, heiß, schwachrot, gut erhitzt oder schwach erhitzt wurde.The relevant cooling liquid is expedient depending on the desired effect applied accordingly more or less warm. Likewise is the generation the color effects involved when cooling in those liquids are different be cherry red, hot, pale red, well heated or weakly heated, depending on the object in question.
ίο Ein sehr schönes Hochrot und sattes Schwarz kann z.. B. bei Kirschrothitze der Gegenstände und Abkühlung in heißem Wasser erzielt werden, Gelb, Grün, Braun beispielsweise durch schwaches Erhitzen und Abkühlen in kaltem Wasser usw.ίο A very nice crimson and deep black can be achieved, for example, when the objects are heated to cherry red and cooling in hot water become, yellow, green, brown for example by weak heating and cooling in cold water etc.
Die Wirkung der kühlen Flüssigkeit auf den erwärmten Gegenstand kann des weiteren auch in bekannter Weise durch Beimischung bestimmter Chemikalien, wie z. B. einer Blutlaugensalzlösung u. dgl. geregelt werden.The effect of the cool liquid on the heated object can furthermore also in a known manner by adding certain chemicals, such as. B. a blood liquor salt solution and the like.
Claims (1)
Publications (1)
Publication Number | Publication Date |
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DE183653C true DE183653C (en) |
Family
ID=447648
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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DENDAT183653D Active DE183653C (en) |
Country Status (1)
Country | Link |
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DE (1) | DE183653C (en) |
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- DE DENDAT183653D patent/DE183653C/de active Active
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